| Contributors |
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xix | |
| Preface |
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xxiii | |
| Licensing Contacts |
|
xxv | |
| Part 1: Intermediates |
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Chapter 1.1 Badger Cumene Technology |
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1.3 | (1) |
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1.3 | (1) |
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1.3 | (1) |
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1.5 | (1) |
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1.5 | (1) |
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Catalyst Performance and Contaminants |
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1.8 | (1) |
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1.8 | (1) |
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1.9 | (1) |
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1.9 | (1) |
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Chapter 1.2 Badger Ethylbenzene Technology |
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1.11 | (1) |
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1.11 | (1) |
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Feedstocks for Ethylbenzene Production |
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1.12 | (1) |
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ExxonMobil EBMax Catalysts |
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1.14 | (1) |
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Process Chemistry and EBMax Catalyst Performance |
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1.14 | (1) |
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1.16 | (1) |
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Process Design Optimization |
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1.18 | (1) |
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EBMax Designs Using Chemical-Grade Ethylene Feedstocks |
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1.18 | (1) |
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Ethylbenzene Product Quality |
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1.19 | (1) |
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Raw Materials, Utilities, and Catalyst Requirements |
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1.20 | (1) |
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1.21 | (1) |
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1.21 | (1) |
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Chapter 1.3 BP Para-Xylene Process |
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1.23 | (1) |
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1.23 | (1) |
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Para-Xylene Recovery in an Aromatics Complex |
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1.24 | (1) |
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Development of Crystallization Process |
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1.25 | (1) |
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Comparison of Crystallization to Selective Adsorption |
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1.27 | (1) |
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1.29 | (1) |
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1.30 | (1) |
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1.33 | (1) |
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1.33 | (1) |
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1.34 | (1) |
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Chapter 1.4 Isomalk-3 (n-Butane Isomerization) |
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1.35 | (1) |
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1.35 | (1) |
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1.36 | (1) |
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1.36 | (1) |
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1.38 | (1) |
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1.38 | (1) |
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1.38 | (1) |
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Isomalk-3 Catalyst Contaminants |
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1.39 | (1) |
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1.39 | (1) |
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1.40 | (1) |
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Advantages of SI-3 Catalyst |
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1.40 | (1) |
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1.40 | (1) |
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Hydrocarbon Feed and Makeup Gas Dryers |
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1.41 | (1) |
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1.41 | (1) |
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1.42 | (1) |
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1.42 | (1) |
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1.42 | (1) |
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Chapter 1.5 CrystPX(Service Mark): Modern Crystallization Technology for Para-Xylene Production |
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1.43 | (1) |
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1.43 | (1) |
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CrystPX for High-Purity Para-Xylene Production |
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1.43 | (1) |
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Process Chemistry and Thermodynamics |
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1.44 | (1) |
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Detailed Process Description |
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1.45 | (1) |
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Product and By-Product Specifications |
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1.47 | (1) |
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1.48 | (1) |
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1.48 | (1) |
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1.48 | (1) |
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Chapter 1.6 EB-X: A Process for Ethylbenzene Separation and Xylenes Upgrade |
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1.51 | (1) |
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1.51 | (1) |
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Process Chemistry (Separation Enhancing of Ethylbenzene from Para-Xylene by the Solvent Function) |
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1.51 | (1) |
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1.52 | (1) |
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1.53 | (1) |
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1.54 | (1) |
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1.54 | (1) |
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Chapter 1.7 GT-BTX Plus®: Aromatics and Sulfur Extraction from FCC Gasoline |
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1.55 | (1) |
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1.55 | (1) |
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General Process Description |
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1.55 | (1) |
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1.61 | (1) |
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1.64 | (1) |
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Chapter 1.8 GT-BTX® Aromatics Extraction Process |
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1.65 | (1) |
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1.65 | (1) |
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General Process Description |
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1.65 | (1) |
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1.68 | (1) |
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1.70 | (1) |
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Key/Proprietary Equipment |
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1.72 | (1) |
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1.72 | (1) |
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1.74 | (1) |
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1.74 | (1) |
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Chapter 1.9 GT-DWC® Applications |
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1.75 | (1) |
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1.75 | (1) |
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General Information for GT-DWC |
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1.75 | (1) |
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GT-DWC for Naphtha Splitter Revamp |
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1.85 | (1) |
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1.87 | (1) |
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1.89 | (1) |
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Feed and Product Specifications |
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1.91 | (1) |
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1.92 | (1) |
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1.92 | (1) |
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Chapter 1.10 GT-HDS(Service Mark) Process for CB/C9 Pygas Components |
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1.93 | (1) |
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General Process Description |
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1.93 | (1) |
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Process Chemistry and Thermodynamics |
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1.93 | (1) |
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1.94 | (1) |
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1.95 | (1) |
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1.95 | (1) |
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Detailed Process Description |
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1.95 | (1) |
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1.98 | (1) |
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1.98 | (1) |
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Chapter 1.11 GT-TolAlk(Service Mark): Toluene Methylation to Xylenes |
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1.99 | (1) |
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1.99 | (1) |
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1.99 | (1) |
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Description of the Process Flow |
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1.100 | (1) |
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1.101 | (1) |
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1.102 | (1) |
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1.102 | (1) |
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1.103 | (1) |
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1.104 | (1) |
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1.104 | (1) |
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Chapter 1.12 Lummus/UOP Liquid-Phase EBone Process and Mixed-Phase CDTECH EB® Process |
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1.105 | (1) |
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1.105 | (1) |
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1.106 | (1) |
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1.106 | (1) |
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1.106 | (1) |
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1.111 | (1) |
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Summary of Process Features |
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1.113 | (1) |
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Chapter 1.13 Lurgi Distapex Extractive Distillation Process |
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1.115 | (1) |
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1.115 | (1) |
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1.115 | (1) |
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1.115 | (1) |
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1.116 | (1) |
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Highlights and Benefits of the Technology |
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1.117 | (1) |
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Economics of the Technology |
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1.118 | (1) |
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1.118 | (1) |
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Chapter 1.14 MaxEne™ Process |
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1.121 | (1) |
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1.121 | (1) |
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Description of the Honeywell UOP MaxEne Process |
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1.121 | (1) |
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MaxEne Process Configurations |
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1.123 | (1) |
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1.124 | (1) |
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MaxEne Process Specifications |
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1.126 | (1) |
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1.127 | (1) |
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1.127 | (1) |
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Chapter 1.15 UOP Parex™ Process |
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1.129 | (1) |
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1.129 | (1) |
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Parex Versus Crystallization |
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1.129 | (1) |
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1.131 | (1) |
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1.132 | (1) |
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Description of the Process Flow |
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1.133 | (1) |
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1.134 | (1) |
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1.135 | (1) |
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1.135 | (1) |
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1.135 | (1) |
| Part 2: Olefins |
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Chapter 2.1 Lurgi Megamethanol™ Technology |
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2.3 | (1) |
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2.3 | (1) |
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Lurgi Megamethanol Technology |
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2.4 | (1) |
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2.5 | (1) |
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Chapter 2.2 Axens On-Purpose 1-Butene and 1-Hexene Production Technologies |
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2.15 | (1) |
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2.15 | (1) |
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On-Purpose Dimerization and Trimerization Chemistry |
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2.16 | (1) |
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2.18 | (1) |
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2.19 | (1) |
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Chapter 2.3 BASF Selective and Full Hydrogenation Technology SELOP® |
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2.21 | (1) |
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2.21 | (1) |
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2.21 | (1) |
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Process Description and Reactor Designs |
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2.22 | (1) |
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Process Safety and Hot Spot Prevention |
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2.23 | (1) |
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Characteristics of SELOP Hydrogenation Performance |
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2.23 | (1) |
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Catalysts for Hydrogenation Technologies |
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2.28 | (1) |
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Chapter 2.4 Lummus Ethylene Process |
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2.29 | (1) |
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2.29 | (1) |
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Development and Commercial History |
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2.29 | (1) |
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2.31 | (1) |
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2.33 | (1) |
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2.35 | (1) |
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Ethylene Process Flow Schematic |
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2.37 | (1) |
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Refinery and Ethylene Plant Integration |
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2.47 | (1) |
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Recent Technology Advances |
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2.47 | (1) |
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2.51 | (1) |
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Chapter 2.5 Olefins Conversion Technology |
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2.53 | (1) |
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2.53 | (1) |
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2.55 | (1) |
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2.56 | (1) |
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2.57 | (1) |
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OCT Commercial Applications |
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2.58 | (1) |
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2.64 | (1) |
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2.65 | (1) |
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2.66 | (1) |
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Chapter 2.6 Lummus Methanol to Olefins Recovery and Olefin Interconversion |
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2.67 | (1) |
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2.67 | (1) |
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Development and Commercial History |
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2.67 | (1) |
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2.68 | (1) |
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2.70 | (1) |
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2.73 | (1) |
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Summary of Process Features |
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2.74 | (1) |
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2.75 | (1) |
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Chapter 2.7 INDMAX FCC: Advanced Fluid Catalytic Cracking Technology for Producing Petrochemicals |
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2.77 | (1) |
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2.77 | (1) |
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INDMAX FCC Process Description |
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2.78 | (1) |
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2.88 | (1) |
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Chapter 2.8 UOP Oleflex Process for Light Olefin Production |
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2.89 | (1) |
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2.89 | (1) |
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2.90 | (1) |
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Process Chemistry and Contaminants |
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2.92 | (1) |
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Oleflex Process Configurations and Conditions |
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2.93 | (1) |
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2.95 | (1) |
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Chapter 2.9 UOP Paco!™ Dehydrogenation Process |
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2.97 | (1) |
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2.97 | (1) |
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2.98 | (1) |
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Pacol Process Improvements |
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2.100 | (1) |
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2.102 | (1) |
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2.102 | (1) |
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2.103 | (1) |
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2.103 | (1) |
| Part 3: Diolefins |
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Chapter 3.1 BASF Butadlene Extraction Technology |
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3.3 | (1) |
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3.3 | (1) |
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3.3 | (1) |
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3.5 | (1) |
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Environment and Safety Aspects |
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3.6 | (1) |
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Chapter 3.2 C5 Separation with GT-C5(Service Mark) and GT-Isoprene(Service Mark) |
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3.9 | (1) |
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Part 1: GT-05-Process for Production of Piperylene Concentrates and Dicyclopentadiene |
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3.9 | (1) |
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3.13 | (1) |
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Overall Product Yields and Recovery |
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3.15 | (1) |
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3.16 | (1) |
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3.16 | (1) |
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3.16 | (1) |
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Chapter 3.3 Light Olefins/Diolefins Production via Lummus's CATOFIN®/CATADIENE® Processes |
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3.17 | (1) |
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3.17 | (1) |
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3.18 | (1) |
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3.19 | (1) |
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3.23 | (1) |
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3.23 | (1) |
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3.24 | (1) |
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Product Quality and By-Products |
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3.25 | (1) |
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3.26 | (1) |
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3.26 | (1) |
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Summary of Technology Features |
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3.27 | (1) |
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3.27 | (1) |
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Chapter 3.4 BASF Butadiene Extraction Technology (Licensed by Lummus Technology) |
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3.29 | (1) |
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3.29 | (1) |
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3.29 | (1) |
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3.30 | (1) |
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3.32 | (1) |
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3.33 | (1) |
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Environmental Considerations |
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3.34 | (1) |
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Summary of Process Features |
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3.35 | (1) |
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Chapter 3.5 TPC/UOP OXO-DT™ Process |
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3.37 | (1) |
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3.37 | (1) |
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Process Chemistry/Catalysts |
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3.38 | (1) |
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3.39 | (1) |
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3.39 | (1) |
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3.40 | (1) |
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3.40 | (1) |
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Chapter 3.6 BASF Butadiene Extraction Process Licensed by Air Liquide |
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3.41 | (1) |
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3.41 | (1) |
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3.41 | (1) |
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3.43 | (1) |
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Economics of the Technology |
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3.44 | (1) |
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3.45 | (1) |
| Part 4: Alcohols and Monomers |
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Chapter 4.1 Badger Bisphenol A Technology |
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4.3 | (1) |
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4.3 | (1) |
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4.3 | (1) |
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4.4 | (1) |
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4.5 | (1) |
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Bisphenol A Manufacturing |
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4.6 | (1) |
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4.8 | (1) |
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Process Description of Badger BPA Process |
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4.11 | (1) |
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Product Specification and Commercial Acceptance |
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4.12 | (1) |
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Chapter 4.2 The DAVY Butanediol (BDO) Process from Johnson Matthey |
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4.15 | (1) |
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4.15 | (1) |
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4.16 | (1) |
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General Process Description |
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4.16 | (1) |
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Detailed Process Description |
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4.17 | (1) |
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4.20 | (1) |
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4.21 | (1) |
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4.21 | (1) |
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Chapter 4.3 The DAVY Methanol Process from Johnson Matthey |
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4.23 | (1) |
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4.23 | (1) |
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4.24 | (1) |
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General Process Description |
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4.24 | (1) |
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Detailed Process Description |
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4.25 | (1) |
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Combined Reforming (SMR + ATR) |
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4.27 | (1) |
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4.28 | (1) |
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4.30 | (1) |
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Product and By-Product Specifications |
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4.31 | (1) |
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4.31 | (1) |
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4.35 | (1) |
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Chapter 4.4 G2PG: Glycerin to Propylene Glycol (1,2-Propanediol)-Extending Oleochemistry into Petrochemistry |
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4.37 | (1) |
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4.37 | (1) |
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Chemistry, Reaction Conditions, Catalyst |
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4.37 | (1) |
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4.38 | (1) |
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Hydrogenation Steps/Reactor Designs |
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4.38 | (1) |
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4.39 | (1) |
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Specific Consumption Figures |
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4.39 | (1) |
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Chapter 4.5 GT-ProG(Service Mark): Glycerin to Propylene Glycol Process |
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4.41 | (1) |
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4.41 | (1) |
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4.41 | (1) |
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4.43 | (1) |
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4.44 | (1) |
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4.45 | (1) |
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4.45 | (1) |
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4.46 | (1) |
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Chapter 4.6 Propylene from any Carbon-Based Feedstock-The Lurgi MTPTI, Technology from Air Liquid. |
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4.47 | (1) |
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4.47 | (1) |
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4.47 | (1) |
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Detailed Process Description |
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4.49 | (1) |
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4.53 | (1) |
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Process Economics of an Integrated MTP Plant |
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4.54 | (1) |
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4.55 | (1) |
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Chapter 4.7 UOP Phenol 3G Process |
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4.57 | (1) |
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4.57 | (1) |
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4.57 | (1) |
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4.58 | (1) |
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Phenol 3G Cumene Peroxidation Route to Phenol Production |
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4.59 | (1) |
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Overall Process Description/Chemistry |
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4.59 | (1) |
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Process Flow and Recent Technology Advances |
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4.60 | (1) |
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4.70 | (1) |
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4.71 | (1) |
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4.71 | (1) |
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Chapter 4.8 Versalis/Lummus Cumene and Phenol Technology |
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4.73 | (1) |
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4.73 | (1) |
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4.73 | (1) |
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4.74 | (1) |
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4.74 | (1) |
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Raw Material and Energy Consumption |
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4.76 | (1) |
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4.76 | (1) |
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4.77 | (1) |
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4.77 | (1) |
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4.78 | (1) |
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Raw Material and Energy Consumption |
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4.81 | (1) |
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4.81 | (1) |
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4.82 | (1) |
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4.83 | (1) |
| Part 5: Acid, Ester, and Aromatic Monomers |
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|
Chapter 5.1 Badger Styrene Technology |
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5.3 | (1) |
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5.3 | (1) |
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5.3 | (1) |
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5.4 | (1) |
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5.4 | (1) |
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5.5 | (1) |
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5.6 | (1) |
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5.8 | (1) |
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5.11 | (1) |
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5.12 | (1) |
|
Direct Heating Technology |
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5.12 | (1) |
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Chapter 5.2 GT-Styrene®: Recovering Styrene by Extractive Distillation |
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5.15 | (1) |
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General Process Description |
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5.15 | (1) |
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Process Chemistry and Thermodynamics |
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5.16 | (1) |
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5.17 | (1) |
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5.17 | (1) |
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5.17 | (1) |
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5.17 | (1) |
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Detailed Process Description |
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5.18 | (1) |
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Product and By-Product Specifications |
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5.22 | (1) |
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5.23 | (1) |
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5.23 | (1) |
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Chapter 5.3 Lummus/UOP "Classic" Styrene Technology and Lummus/UOP SMART(Service Mark) Styrene Technology |
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5.25 | (1) |
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5.25 | (1) |
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5.25 | (1) |
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5.27 | (1) |
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5.28 | (1) |
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5.31 | (1) |
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Summary of Process Features |
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5.32 | (1) |
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Chapter 5.4 Lurgi/Nlppon Kayaku Acrylic Acid Process |
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5.33 | (1) |
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5.33 | (1) |
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Chemistry Overview and Product Specification |
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5.33 | (1) |
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5.34 | (1) |
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Highlights and Benefits of the Technology |
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5.37 | (1) |
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Economics of the Technology |
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5.37 | (1) |
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5.38 | (1) |
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Chapter 5.5 SYNTHOMER/Lurgi Acrylate Processes |
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5.39 | (1) |
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5.39 | (1) |
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Chemistry Overview and Product Specification |
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5.39 | (1) |
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5.41 | (1) |
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Highlights and Benefits of the Technology |
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5.45 | (1) |
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Economics of the Technology |
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5.45 | (1) |
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5.46 | (1) |
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Chapter 5.6 Versalis Dimethyl Carbonate and Diphenyl Carbonate Production Technologies Licensed by Lummus Technology |
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5.47 | (1) |
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5.47 | (1) |
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5.48 | (1) |
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5.48 | (1) |
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Feedstock Specifications and Consumption |
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5.50 | (1) |
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5.52 | (1) |
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5.53 | (1) |
|
Summary of Technology Features |
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5.53 | (1) |
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5.54 | (1) |
| Part 6: Vinyl Chloride Monomers |
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|
Chapter 6.1 The DAVY Vinyl Chloride Monomer (VCM) Process from Johnson Matthey |
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6.3 | (1) |
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6.3 | (1) |
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6.4 | (1) |
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General Process Description |
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6.4 | (1) |
|
Process Chemistry and Thermodynamics |
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6.4 | (1) |
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6.4 | (1) |
|
Detailed Process Description |
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6.5 | (1) |
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6.5 | (1) |
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6.5 | (1) |
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6.6 | (1) |
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6.6 | (1) |
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6.6 | (1) |
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Product and By-Product Specifications |
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6.6 | (1) |
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6.7 | (1) |
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6.7 | (1) |
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6.7 | (1) |
| Part 7: Polymers |
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|
Chapter 7.1 Borstar LLDPE, MDPE, and HDPE Technology |
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7.3 | (1) |
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7.3 | (1) |
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Features of Borstar PE Process Technology |
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7.3 | (1) |
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7.5 | (1) |
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7.9 | (1) |
|
Capacities and Locations of Borstar PE Plants |
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|
7.11 | (1) |
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7.12 | (1) |
|
High Alpha Olefin Terpolymer Film |
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7.14 | (1) |
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7.15 | (1) |
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7.17 | (1) |
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7.18 | (1) |
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|
7.18 | (1) |
|
Chapter 7.2 Borstar Polypropylene Technology |
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|
7.21 | (1) |
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7.21 | (1) |
|
Features of Borstar PP Process Technology |
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|
7.23 | (1) |
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7.24 | (1) |
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|
7.28 | (1) |
|
Capacities and Locations of Borstar PP Plants |
|
|
7.30 | (1) |
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|
7.30 | (1) |
|
Heterophasic Copolymers and rTPOs |
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|
7.33 | (1) |
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7.34 | (1) |
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7.36 | (1) |
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7.37 | (1) |
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7.37 | (1) |
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|
7.37 | (1) |
|
Chapter 7.3 McDermott's Lummus Novolen® Technology Gas-Phase Polypropylene Process |
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|
7.39 | (1) |
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7.39 | (1) |
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7.40 | (1) |
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7.40 | (1) |
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|
7.40 | (1) |
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|
7.46 | (1) |
|
Products and Applications |
|
|
7.46 | (1) |
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|
7.51 | (1) |
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|
7.51 | (1) |
|
Chapter 7.4 NOVA Chemicals SCLAIRTECH™ LLDPE/HDPE Swing Technology |
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7.53 | (1) |
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7.53 | (1) |
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7.54 | (1) |
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|
7.56 | (1) |
|
Advantages of the SCLAIRTECH Technology Platform |
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|
7.58 | (1) |
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7.61 | (1) |
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7.61 | (1) |
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7.64 | (1) |
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7.64 | (1) |
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|
7.65 | (1) |
|
Chapter 7.5 TechnipFMC/Total Polystyrene Technology |
|
|
7.67 | (1) |
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7.67 | (1) |
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7,68 | (1) |
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7.69 | (1) |
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7.71 | (1) |
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7.72 | (1) |
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7.72 | (1) |
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7.72 | (1) |
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|
7.74 | (1) |
|
Chapter 7.6 TechnipFMC/SABIC Mass and Emulsion ABS Technology |
|
|
7.75 | (1) |
|
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|
7.75 | (1) |
|
|
|
7.77 | (1) |
|
Emulsion Process Description |
|
|
7.78 | (1) |
|
Typical Emissions Summary |
|
|
7.80 | (1) |
|
|
|
7.80 | (1) |
|
|
|
7.82 | (1) |
|
Products and Applications |
|
|
7.83 | (1) |
|
|
|
7.86 | (1) |
|
|
|
7.86 | (1) |
|
Chapter 7.7 UNIPOL® Polypropylene Process Technology |
|
|
7.87 | (1) |
|
|
|
General UNIPOL PP Process Description |
|
|
7.87 | (1) |
|
|
|
7.90 | (1) |
|
|
|
7.91 | (1) |
|
|
|
7.94 | (1) |
|
UNIPOL PP Product Attributes Summary |
|
|
7.95 | (1) |
|
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|
7.97 | (1) |
|
|
|
7.97 | (1) |
|
Chapter 7.8 UOP Sinco Solid-State Polymerization Process |
|
|
7.99 | (1) |
|
|
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|
|
|
7.99 | (1) |
|
Melt-Phase Polymerization |
|
|
7.101 | (1) |
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|
|
7.102 | (1) |
|
|
|
7.104 | (1) |
|
|
|
7.106 | (1) |
|
Detailed Process Description |
|
|
7.106 | (1) |
|
Reactions of the Catalytic Nitrogen Purification System |
|
|
7.109 | (1) |
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|
|
7.110 | (1) |
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|
|
7.110 | (1) |
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7.111 | (1) |
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7.112 | (1) |
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7.112 | (1) |
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7.112 | (1) |
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7.112 | (1) |
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7.112 | (1) |
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7.114 | (1) |
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|
7.114 | (1) |
|
Chapter 7.9 Sabic High-Pressure Process for LOPE-CTR™ Technology |
|
|
7.115 | (1) |
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|
|
7.115 | (1) |
|
|
|
7.115 | (1) |
|
Detailed Process Description and Thermodynamics |
|
|
7.120 | (1) |
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|
|
7.122 | (1) |
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|
7.123 | (1) |
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|
7.124 | (1) |
|
|
|
7.124 | (1) |
| Part 8: Methylamines, Formaldehyde, and Dimethyl Ether |
|
|
Chapter 8.1 The DAVY Dimethyl Ether (DME) Process from Johnson Matthey |
|
|
8.3 | (1) |
|
|
|
|
|
8.3 | (1) |
|
General Process Description |
|
|
8.3 | (1) |
|
Product and By-Product Specifications |
|
|
8.4 | (1) |
|
|
|
8.5 | (1) |
|
|
|
8.5 | (1) |
|
Chapter 8.2 The DAVY Methylamines Process from Johnson Matthey |
|
|
8.7 | (1) |
|
|
|
|
|
8.7 | (1) |
|
|
|
8.8 | (1) |
|
General Process Description |
|
|
8.8 | (1) |
|
Process Chemistry and Thermodynamics |
|
|
8.9 | (1) |
|
|
|
8.10 | (1) |
|
Detailed Process Description |
|
|
8.10 | (1) |
|
Product and By-Product Specifications |
|
|
8.12 | (1) |
|
|
|
8.12 | (1) |
|
|
|
8.13 | (1) |
|
|
|
8.13 | (1) |
|
Chapter 8.3 The FORMOX Formaldehyde Process from Johnson Matthey |
|
|
8.15 | |
|
|
|
|
|
8.15 | (1) |
|
General Process Description |
|
|
8.15 | (1) |
|
|
|
8.17 | (1) |
|
Performance, Product, and By-Product Specification for the FORMOX Process |
|
|
8.17 | (1) |
|
|
|
8.18 | (1) |
|
|
|
8.18 | (1) |
|
|
|
8.18 | (1) |
|
|
|
8.18 | (1) |
|
|
|
8.18 | (1) |
|
|
|
8.19 | (1) |
|
An Integrated UFC Process |
|
|
8.19 | (1) |
|
Operation Criteria and Plant Capacities |
|
|
8.19 | (1) |
|
|
|
8.19 | |
| Glossary and Abbreviations |
|
G.1 | |
| Index |
|
I.1 | |