| Preface |
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vii | |
| Preface to the Original French Version |
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viii | |
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Electrochemical Potential |
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1 | (32) |
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Electrochemical potential of ions |
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1 | (22) |
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Electrochemical potential of electrons |
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23 | (10) |
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Electrochemical Equilibria |
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33 | (50) |
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Redox reactions at metallic electrodes |
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33 | (17) |
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50 | (4) |
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54 | (3) |
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Electrochemical equilibria at the interface between two electrolytes |
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57 | (6) |
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Analytical applications of potentiometry |
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63 | (15) |
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78 | (5) |
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Appendix: The respiratory chain |
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82 | (1) |
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83 | (50) |
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83 | (2) |
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Thermodynamic aspects of solvation |
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85 | (15) |
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Structural aspects of ionic solvation |
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100 | (5) |
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105 | (18) |
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123 | (6) |
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129 | (4) |
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131 | (2) |
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133 | (44) |
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Transport in electrolyte solutions |
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133 | (5) |
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Conductivity of electrolyte solutions |
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138 | (7) |
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Influence of concentration on conductivity |
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145 | (7) |
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152 | (8) |
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Thermodynamics of irreversible systems |
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160 | (3) |
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Statistical aspects of diffusion |
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163 | (14) |
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Appendix: Elements of fluid mechanics |
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171 | (6) |
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177 | (44) |
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177 | (3) |
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Interfacial thermodynamics |
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180 | (4) |
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Thermodynamics of electrified interfaces |
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184 | (10) |
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Spatial distribution of polarisation charges |
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194 | (21) |
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Structure of electrochemical interfaces |
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215 | (6) |
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Electrokinetic Phenomena and Electrochemical Separation Methods |
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221 | (44) |
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221 | (8) |
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Capillary electrophoresis |
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229 | (10) |
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Electrophoretic methods of analytical separation |
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239 | (5) |
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Electrophoretic separation of biopolymers |
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244 | (12) |
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256 | (5) |
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Industrial methods of electrochemical separation |
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261 | (4) |
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265 | (36) |
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265 | (3) |
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Current controlled by the kinetics of the redox reactions |
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268 | (7) |
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Reversible systems: Current limited by diffusion |
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275 | (5) |
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Electrodes with a diffusion layer of controlled thickness |
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280 | (8) |
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Quasi-reversible systems: Current limited by kinetics and diffusion |
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288 | (6) |
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Irreversible systems: Current limited by kinetics and diffusion |
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294 | (1) |
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Quasi-reversible systems: Current limited by diffusion, migration and kinetics |
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295 | (1) |
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Experimental aspects of amperometry |
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296 | (5) |
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301 | (38) |
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Chronoamperometry following a potential step |
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301 | (10) |
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311 | (8) |
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319 | (14) |
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333 | (4) |
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Amperometric detectors for chromatograpy |
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337 | (2) |
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Electrochemical Impedance |
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339 | (36) |
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339 | (4) |
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343 | (8) |
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Impedance of an electrochemical system |
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351 | (17) |
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368 | (7) |
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375 | (36) |
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Electrochemically reversible reactions with semi-infinite linear diffusion |
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375 | (7) |
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Influence of the kinetics |
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382 | (3) |
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385 | (11) |
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Electron transfer at liquid | liquid interfaces |
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396 | (3) |
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Assisted ion transfer at liquid | liquid interfaces |
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399 | (3) |
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402 | (2) |
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404 | (3) |
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407 | (1) |
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408 | (3) |
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411 | (6) |
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411 | (1) |
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Circulation of the field vector |
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412 | (1) |
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413 | (1) |
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414 | (1) |
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The Green-Ostrogradski theorem |
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414 | (3) |
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ANNEX B Work functions and standard redox potentials |
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417 | (8) |
| Symbols |
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425 | (4) |
| Index |
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429 | |