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E-raamat: Analytical and Physical Electrochemistry [Taylor & Francis e-raamat]

(Lab of Electrochemistry, Lausanne, Switzerland)
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  • Taylor & Francis e-raamat
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Teised raamatud teemal:
The study of electrochemistry is pertinent to a wide variety of fields, including bioenergetics, environmental sciences, and engineering sciences. In addition, electrochemistry plays a fundamental role in specific applications as diverse as the conversion and storage of energy and the sequencing of DNA.

Intended both as a basic course for undergraduate students and as a reference work for graduates and researchers, Analytical and Physical Electrochemistry covers two fundamental aspects of electrochemistry: electrochemistry in solution and interfacial electrochemistry. By bringing these two subjects together into a single volume, the author clearly establishes the links between the physical foundation and the analytical applications of electrochemistry.

The philosophy of Analytical and Physical Electrochemistry has been to publish all the mathematical derivations in detail, allowing you, if you so desire, to follow the calculations that lead to the main results. With this rigorous approach, the author has provided a book of reference constructed from first principles. In this respect, the nomenclature and standards of the IUPAC (International Union of Pure and Applied Chemistry) are observed.
Preface vii
Preface to the Original French Version viii
Electrochemical Potential
1(32)
Electrochemical potential of ions
1(22)
Electrochemical potential of electrons
23(10)
Electrochemical Equilibria
33(50)
Redox reactions at metallic electrodes
33(17)
Cells and accumulators
50(4)
Pourbaix diagrams
54(3)
Electrochemical equilibria at the interface between two electrolytes
57(6)
Analytical applications of potentiometry
63(15)
Ion exchange membranes
78(5)
Appendix: The respiratory chain
82(1)
Electrolyte Solutions
83(50)
Liquids
83(2)
Thermodynamic aspects of solvation
85(15)
Structural aspects of ionic solvation
100(5)
Ion-ion interactions
105(18)
Ion pairs
123(6)
Computational methods
129(4)
Appendix
131(2)
Transport in Solution
133(44)
Transport in electrolyte solutions
133(5)
Conductivity of electrolyte solutions
138(7)
Influence of concentration on conductivity
145(7)
Dielectric friction
152(8)
Thermodynamics of irreversible systems
160(3)
Statistical aspects of diffusion
163(14)
Appendix: Elements of fluid mechanics
171(6)
Electrified Interfaces
177(44)
Interfacial tension
177(3)
Interfacial thermodynamics
180(4)
Thermodynamics of electrified interfaces
184(10)
Spatial distribution of polarisation charges
194(21)
Structure of electrochemical interfaces
215(6)
Electrokinetic Phenomena and Electrochemical Separation Methods
221(44)
Electrokinetic phenomena
221(8)
Capillary electrophoresis
229(10)
Electrophoretic methods of analytical separation
239(5)
Electrophoretic separation of biopolymers
244(12)
Ion chromatography
256(5)
Industrial methods of electrochemical separation
261(4)
Steady State Amperometry
265(36)
Electrochemical kinetics
265(3)
Current controlled by the kinetics of the redox reactions
268(7)
Reversible systems: Current limited by diffusion
275(5)
Electrodes with a diffusion layer of controlled thickness
280(8)
Quasi-reversible systems: Current limited by kinetics and diffusion
288(6)
Irreversible systems: Current limited by kinetics and diffusion
294(1)
Quasi-reversible systems: Current limited by diffusion, migration and kinetics
295(1)
Experimental aspects of amperometry
296(5)
Pulse Voltammetry
301(38)
Chronoamperometry following a potential step
301(10)
Polarography
311(8)
Square wave voltammetry
319(14)
Stripping voltammetry
Thin layer voltammetry
333(4)
Amperometric detectors for chromatograpy
337(2)
Electrochemical Impedance
339(36)
Transfer function
339(4)
Elementary circuits
343(8)
Impedance of an electrochemical system
351(17)
AC voltammetry
368(7)
Cyclic Voltammetry
375(36)
Electrochemically reversible reactions with semi-infinite linear diffusion
375(7)
Influence of the kinetics
382(3)
EC reactions
385(11)
Electron transfer at liquid | liquid interfaces
396(3)
Assisted ion transfer at liquid | liquid interfaces
399(3)
Surface reactions
402(2)
Hemi-spherical diffusion
404(3)
Voltabsorptometry
407(1)
Semi-integration
408(3)
ANNEX A VECTOR ANALYSIS
411(6)
Coordinate systems
411(1)
Circulation of the field vector
412(1)
The vector gradient
413(1)
Flux of the field vector
414(1)
The Green-Ostrogradski theorem
414(3)
ANNEX B Work functions and standard redox potentials
417(8)
Symbols 425(4)
Index 429