| Preface |
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vii | |
| Author |
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ix | |
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PART 1 Gases and Gas Laws |
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3 | (8) |
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3 | (1) |
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Law of Corresponding States |
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4 | (1) |
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4 | (3) |
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Key Points -- Mixtures of Gases |
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7 | (1) |
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7 | (4) |
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PART 2 The First Law of Thermodynamics: Work (PV) and Heat, as ΔU and ΔH |
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11 | (14) |
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Key Points -- The First Law |
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11 | (1) |
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12 | (2) |
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14 | (1) |
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14 | (1) |
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Key Points -- Calorimetry |
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15 | (1) |
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16 | (1) |
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Key Points -- Hess's Law Calculation for ΔH |
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17 | (1) |
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17 | (1) |
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Key Points -- Indirect Methods for ΔH Determination |
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17 | (1) |
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18 | (1) |
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Key Points -- Using Cyclic Diagrams for ΔH |
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19 | (1) |
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19 | (1) |
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Key Points -- Temperature Dependence of ΔH |
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20 | (1) |
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21 | (4) |
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PART 3 Second and Third Law of Thermodynamics, ΔS |
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25 | (10) |
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Key Points -- The Second Law |
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25 | (2) |
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27 | (6) |
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Key Points -- Real Gases and Entropy |
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33 | (2) |
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PART 4 Free Energy (ΔG), Helmholtz Energy (ΔA), and Phase Equilibrium |
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35 | (14) |
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Key Points -- Gibbs and Helmholtz Free Energy |
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35 | (2) |
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37 | (6) |
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Key Points -- The Chemical Potential and Phase Diagrams |
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43 | (1) |
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43 | (3) |
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Key Points -- The Chemical Potential of Real Gases and Fugacity |
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46 | (1) |
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47 | (2) |
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PART 5 Free Energy (ΔG) of Mixing, Binary Liquid Mixtures, Colligative Properties, and Activity |
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49 | (28) |
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Key Points -- Free Energy of Mixing |
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49 | (1) |
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49 | (1) |
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Key Points -- ΔG and Two-Component Liquid Mixtures |
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50 | (1) |
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Key Points -- Real Solutions and Excess Thermodynamic Functions for Mixtures |
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51 | (1) |
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52 | (5) |
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Key Points -- Vapor Pressure, Raoult's Law, and Henry's Law for Mixtures |
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57 | (1) |
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Key Points -- Henry's Law for Binary Mixtures |
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58 | (1) |
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Key Points -- Liquid --Vapor Phase Diagrams |
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59 | (1) |
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Lever Rule Liquid Vapor Diagrams |
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60 | (1) |
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Key Points -- Non-Ideal or Regular Solutions: Azeotropes |
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60 | (1) |
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Key Points -- Activity and Activity Coefficients for Mixtures |
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61 | (1) |
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61 | (6) |
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Key Points -- Colligative Properties |
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67 | (1) |
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68 | (3) |
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Key Points -- Activity Coefficients in Colligative Properties for Real Solutions |
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71 | (1) |
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72 | (1) |
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Key Points -- Henry's Law and Saturated Solutions of Solute B in A |
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73 | (1) |
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74 | (3) |
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PART 6 Free Energy, Equilibrium Constants, and Electromotive Force |
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77 | (18) |
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Key Points -- Free Energy and Chemical Reactions |
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77 | (1) |
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78 | (4) |
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Key Points -- Ionic Strength, Activity Coefficients, and Effect on Equilibria |
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82 | (1) |
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83 | (1) |
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Key Points -- Electrochemistry, Equilibrium, and Activities |
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84 | (2) |
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86 | (1) |
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Electrochemistry and Equilibrium in Biochemical Redox Reactions |
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87 | (1) |
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88 | (2) |
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Key Points -- Thermodynamics of Redox Reactions: ΔS° and ΔH° |
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90 | (1) |
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90 | (1) |
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Mean Ionic Activity and Redox Reactions |
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91 | (1) |
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92 | (3) |
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Answers to Example Problems |
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95 | (32) |
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95 | (1) |
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Part 1 Gases and Gas Laws |
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95 | (1) |
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Part 2 First Law of Thermodynamics -- Work (PV), Heat, ΔU and ΔH |
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96 | (4) |
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Part 3 Second and Third Laws -- Entropy |
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100 | (3) |
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Part 4 Free Energy (ΔG), Helmholtz Energy (ΔA), and Phase Equilibrium |
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103 | (6) |
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Part 5 Free Energy (ΔG) of Mixing, Binary Liquid Mixtures, Colligative Properties, and Activity |
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109 | (10) |
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Part 6 Free Energy (ΔG), Equilibrium, and Electrochemistry |
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119 | (8) |
| Index |
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127 | |