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E-raamat: Thermodynamics Problem Solving in Physical Chemistry: Study Guide and Map [Taylor & Francis e-raamat]

(Daemen College, Amherst, NY, USA)
  • Formaat: 128 pages, 226 Illustrations, black and white
  • Ilmumisaeg: 25-Mar-2020
  • Kirjastus: CRC Press
  • ISBN-13: 9780429278402
  • Taylor & Francis e-raamat
  • Hind: 152,33 €*
  • * hind, mis tagab piiramatu üheaegsete kasutajate arvuga ligipääsu piiramatuks ajaks
  • Tavahind: 217,62 €
  • Säästad 30%
  • Formaat: 128 pages, 226 Illustrations, black and white
  • Ilmumisaeg: 25-Mar-2020
  • Kirjastus: CRC Press
  • ISBN-13: 9780429278402

Thermodynamics Problem Solving in Physical Chemistry: Study Guide and Map is an innovative and unique workbook that guides physical chemistry students through the decision-making process to assess a problem situation, create appropriate solutions, and gain confidence through practice solving physical chemistry problems.

The workbook includes six major sections with 20 - 30 solved problems in each section that span from easy, single objective questions to difficult, multistep analysis problems. Each section of the workbook contains key points that highlight major features of the topic to remind students of what they need to apply to solve problems in the topic area. 

Key Features: 

  • Includes a visual map that shows how all the “equations” used in thermodynamics are connected and how they are derived from the three major energy laws. 
  • Acts as a guide in deriving the correct solution to a problem. 
  • Illustrates the questions students should ask themselves about the critical features of the concepts to solve problems in physical chemistry 
  • Can be used as a stand-alone product for review of Thermodynamics questions for major tests.
Preface vii
Author ix
WORKBOOK
PART 1 Gases and Gas Laws
3(8)
Key Points -- Gas Laws
3(1)
Law of Corresponding States
4(1)
Example Problems
4(3)
Key Points -- Mixtures of Gases
7(1)
Example Problems
7(4)
PART 2 The First Law of Thermodynamics: Work (PV) and Heat, as ΔU and ΔH
11(14)
Key Points -- The First Law
11(1)
Example Problems
12(2)
Adiabatic Processes
14(1)
Example Problems
14(1)
Key Points -- Calorimetry
15(1)
Example Problems
16(1)
Key Points -- Hess's Law Calculation for ΔH
17(1)
Example Problems
17(1)
Key Points -- Indirect Methods for ΔH Determination
17(1)
Example Problems
18(1)
Key Points -- Using Cyclic Diagrams for ΔH
19(1)
Example Problems
19(1)
Key Points -- Temperature Dependence of ΔH
20(1)
Example Problems
21(4)
PART 3 Second and Third Law of Thermodynamics, ΔS
25(10)
Key Points -- The Second Law
25(2)
Example Problems
27(6)
Key Points -- Real Gases and Entropy
33(2)
PART 4 Free Energy (ΔG), Helmholtz Energy (ΔA), and Phase Equilibrium
35(14)
Key Points -- Gibbs and Helmholtz Free Energy
35(2)
Example Problems
37(6)
Key Points -- The Chemical Potential and Phase Diagrams
43(1)
Example Problems
43(3)
Key Points -- The Chemical Potential of Real Gases and Fugacity
46(1)
Example Problems
47(2)
PART 5 Free Energy (ΔG) of Mixing, Binary Liquid Mixtures, Colligative Properties, and Activity
49(28)
Key Points -- Free Energy of Mixing
49(1)
Example Problems
49(1)
Key Points -- ΔG and Two-Component Liquid Mixtures
50(1)
Key Points -- Real Solutions and Excess Thermodynamic Functions for Mixtures
51(1)
Example Problems
52(5)
Key Points -- Vapor Pressure, Raoult's Law, and Henry's Law for Mixtures
57(1)
Key Points -- Henry's Law for Binary Mixtures
58(1)
Key Points -- Liquid --Vapor Phase Diagrams
59(1)
Lever Rule Liquid Vapor Diagrams
60(1)
Key Points -- Non-Ideal or Regular Solutions: Azeotropes
60(1)
Key Points -- Activity and Activity Coefficients for Mixtures
61(1)
Example Problems
61(6)
Key Points -- Colligative Properties
67(1)
Example Problems
68(3)
Key Points -- Activity Coefficients in Colligative Properties for Real Solutions
71(1)
Example Problems
72(1)
Key Points -- Henry's Law and Saturated Solutions of Solute B in A
73(1)
Example Problems
74(3)
PART 6 Free Energy, Equilibrium Constants, and Electromotive Force
77(18)
Key Points -- Free Energy and Chemical Reactions
77(1)
Example Problems
78(4)
Key Points -- Ionic Strength, Activity Coefficients, and Effect on Equilibria
82(1)
Example Problems
83(1)
Key Points -- Electrochemistry, Equilibrium, and Activities
84(2)
Example Problems
86(1)
Electrochemistry and Equilibrium in Biochemical Redox Reactions
87(1)
Example Problems
88(2)
Key Points -- Thermodynamics of Redox Reactions: ΔS° and ΔH°
90(1)
Example Problems
90(1)
Mean Ionic Activity and Redox Reactions
91(1)
Example Problems
92(3)
FINAL ANSWERS
Answers to Example Problems
95(32)
Final Answers and Hints
95(1)
Part 1 Gases and Gas Laws
95(1)
Part 2 First Law of Thermodynamics -- Work (PV), Heat, ΔU and ΔH
96(4)
Part 3 Second and Third Laws -- Entropy
100(3)
Part 4 Free Energy (ΔG), Helmholtz Energy (ΔA), and Phase Equilibrium
103(6)
Part 5 Free Energy (ΔG) of Mixing, Binary Liquid Mixtures, Colligative Properties, and Activity
109(10)
Part 6 Free Energy (ΔG), Equilibrium, and Electrochemistry
119(8)
Index 127
Kathleen Murphy grew up near Saginaw Michigan and obtained a B.S. degree in Chemistry from Central Michigan University (Mount Pleasant, MI). She then went on to receive a PhD in Physical Chemistry from the University of Vermont (Burlington, VT) and did postdoctoral work at Rensselaer Polytechnic Institute (Troy, NY). Dr. Murphy is currently a Professor of Chemistry, in the Natural Science Department at Daemen College (Amherst, NY) and has been teaching general, analytical and physical chemistry for over 40 years. Eighteen of those years were spent being in an administrative role within the department and the College and oversaw the transition of the College into health-related areas and major expansion of the department. Dr. Murphy never left the classroom though and looks forward to devoting much more of her time using her experience to develop new strategies for students to address their weaknesses in problem-solving and surmounting them. Her research interests have been the role of oxygen in wound healing and various environmental topics, such as bioremediation or detection of metals in the soil or water.