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E-raamat: Structured Glass-Fiber Catalysts [Taylor & Francis e-raamat]

, (Boreskov Institute of Catalysis)
  • Formaat: 142 pages, 16 Tables, black and white; 104 Illustrations, black and white
  • Ilmumisaeg: 02-Dec-2019
  • Kirjastus: CRC Press
  • ISBN-13: 9780429317569
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  • Taylor & Francis e-raamat
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Structured Glass-Fiber CatalystsSuurem pilt
  • Formaat: 142 pages, 16 Tables, black and white; 104 Illustrations, black and white
  • Ilmumisaeg: 02-Dec-2019
  • Kirjastus: CRC Press
  • ISBN-13: 9780429317569
Teised raamatud teemal:
Taylor & Francis e-raamatudRohkem infot Taylor & Francis e-raamatute kohta
Raamatu kodulehekülg: https://www.taylorfrancis.com/books/9780429317569

Structured Glass-Fiber Catalysts discusses the synthesis of advanced glass-fiber catalysts for various emerging applications, investigation of their properties, and development of the engineering basis required for their wide practical application.

This book describes how to create and use such catalysts for different chemical reactions. It discusses how to efficiently arrange them into structured catalytic cartridges and gives examples of their successful application for purification of waste gases from different hazardous contaminants and environmentally safe combustion of fuels. It covers nanosize surface science fundamentals through large-scale commercial catalytic reactors.

This book is aimed at researchers and engineers in the fields of chemical engineering, industrial engineering, and materials engineering.

Preface xi
Acknowledgments xiii
About the Authors xv
Chapter 1 Current State of Research and Development in the Field of Catalysts With Various Shapes and Their Practical Application
1(10)
1.1 Introduction
1(1)
1.1 Traditional Catalyst Shapes
2(1)
1.2 Fixed Beds of Granular Catalysts
2(2)
1.3 Monolith Catalysts
4(1)
1.4 Catalysts With Foam Supports
5(1)
1.5 Catalysts With Flexible Metal Supports
6(5)
References
8(3)
Chapter 2 Glass-Fiber Catalysts
11(36)
2.1 General Description
11(1)
2.2 Synthesis of Glass-Fiber Catalysts
12(2)
2.3 Platinum Catalyst IC-12-S111
14(6)
2.4 Copper-Chromite GFC for the Deep Oxidation of Organic Compounds
20(8)
2.5 Vanadia and Iron Oxide Catalysts for the Oxidation of Hydrogen Sulfide
28(6)
2.6 Multilayer Composite Material With the Ternary Layer of Nanofibrous Carbon
34(4)
2.7 Conclusion
38(9)
References
39(8)
Chapter 3 Arrangement of the Beds of the Glass-Fiber Catalysts
47(16)
3.1 Structuring of the Microfibrous Catalysts
47(2)
3.2 GFC Packing With the Propagative Flow of Reaction Fluid
49(2)
3.3 GFC Packing With the Gliding Flow or Reaction Media
51(6)
3.3.1 Cylindrical Cartridges
51(2)
3.3.2 Prismatic Cartridges
53(3)
3.3.3 Reinforced Cartridges
56(1)
3.4 Lemniscate GFCs
57(6)
References
59(4)
Chapter 4 Experimental Investigation of Pressure Drop and Mass Transfer in GFC Packing
63(42)
4.1 The Scope and Properties of the Research Objects
63(11)
4.4.1 Experimental GFC Cartridges With the Corrugated Metal Mesh Structuring Elements
64(4)
4.1.2 GFC Beds With the Lemniscate Structures
68(1)
4.1.3 GFC Cartridges With the Flat Mesh Structuring Elements
68(3)
4.1.4 Reference Catalysts
71(3)
4.2 Pressure Drop in GFC Cartridges
74(6)
4.2.1 Experimental Technique
74(1)
4.2.2 Experimental Results
75(3)
4.2.3 Partial Anisotropy of GFC Cartridges
78(2)
4.3 Investigation of Mass Transfer in GFC-Based Cartridges
80(22)
4.3.1 Experimental Technique
80(2)
4.3.2 Experimental Results
82(7)
4.3.3 Intrinsic Kinetics of the Toluene Oxidation Pt/GFCs
89(2)
4.3.4 Intra-Thread Diffusion Limitations
91(1)
4.3.5 On the Intra-Fiber Mass Transfer
92(3)
4.3.6 External Diffusion Limitations in the GFC Cartridges
95(5)
4.3.7 Verification of the Mass Transfer Limitation Model
100(2)
4.4 Conclusion
102(3)
References
103(2)
Chapter 5 Development and Application of Commercial and Pilot-Scale GFC-Based Processes
105(34)
5.1 GFC-Based Processes for the Abatement of Toxic Organic Compounds in Waste Gases
105(12)
5.1.1 Process for VOC Deep Oxidation in the Waste Gases of a Synthetic Rubber Plant
105(4)
5.1.2 Process for the Purification and Cooling of the Exhausts From a Stationary Diesel Power Plant
109(8)
5.2 GFC-Based Processes of Environmentally Safe Combustion of Fuels
117(4)
5.2.1 Combustion of Solid Fuels in the Fluidized Beds of the Dispersed Heat Carrier Using Reinforced GFC Cartridges
117(2)
5.2.2 Catalytic Air Heaters on the Base of GFCs
119(2)
5.3 Sulfur Dioxide Oxidation Processes at Pt-Containing GFCs
121(18)
5.3.1 Processes of SO2 Oxidation in Sulfuric Acid Production
122(2)
5.3.2 Reverse-Flow Process With the Additional GFC Beds for Smelter Gas Processing, Which Contains CO and SO2
124(6)
5.3.3 Conditioning of Flue Gases from Coal-Fired Power Plants
130(5)
References
135(4)
Conclusions 139(2)
Index 141
Professor Andrey Zagoruiko, Doctor of Technical Sciences (rehab.), Leading Researcher of Boreskov Institute of Catalysis, Novosibirsk, Russia, graduated in 1985 from Moscow Institute of Fine Chemical Technology. He has over 30 years of experience in research, development, engineering and simulation of catalytic reactors and catalytic processes. His area of scientific and practical interests include unsteady-state catalytic processes, reverse-flow reactors, sulfur production from H2S, oxidation of SO2, deep oxidation of volatile organic compounds, micro-fibrous catalysts, and naphtha reforming. He is author of more than 300 scientific publications, including over 70 patents. He is permanent member of scientific and program committees of international conferences ChemReactor and HydroCat, guest editor in Chemical Engineering Journal and Catalysis Today, member of editorial boards in the journals Reviews in Chemical Engineering and Catalysis in Industry. He was awarded the Russian Academy Award in the name of Professor Koptyug, golden medals of Russian Exhibition Center and Siberian Fair for developments on the area of environmental protection technologies.

Sergey Lopatin, Group Leader at the Boreskov Institute of Catalysis, Novosibirsk, Russia, graduated from Kuzbass Polytechnic University. He is expert in the area of mass transfer studies in the catalytic structures, engineering of catalytic processes, development and modelling of catalytic reactors design, creation of new shapes of catalysts and novel technologies for their manufacturing. He has over 13 years of experience in scientific work and his scientific and practical interests include catalytic processes on the base of micro-fibrous catalysts for purification of waste gases from hazardous organic contaminants and for environmentally safe combustion of fuels and organic wastes. He is author of more than 80 scientific publications, including over 30 patents.
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