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E-raamat: Potassium-ion Batteries - Materials and Applications: Materials and Applications [Wiley Online]

Edited by (National Center for Nanoscience and Technology (NCNST, Beijing)), Edited by , Edited by (King Abdulaziz University, Jeddah, Saudi Arabia)
  • Formaat: 432 pages
  • Ilmumisaeg: 05-Jun-2020
  • Kirjastus: Wiley-Scrivener
  • ISBN-10: 1119663288
  • ISBN-13: 9781119663287
Teised raamatud teemal:
  • Wiley Online
  • Hind: 245,24 €*
  • * hind, mis tagab piiramatu üheaegsete kasutajate arvuga ligipääsu piiramatuks ajaks
Potassium-ion Batteries - Materials and Applications: Materials and ApplicationsSuurem pilt
  • Formaat: 432 pages
  • Ilmumisaeg: 05-Jun-2020
  • Kirjastus: Wiley-Scrivener
  • ISBN-10: 1119663288
  • ISBN-13: 9781119663287
Teised raamatud teemal:
Wiley Online e-raamatudRohkem infot Wiley Online kohta
Raamatu kodulehekülg: https://onlinelibrary.wiley.com/doi/book/10.1002/9781119663287
"Potassium-ion batteries have gained the most attention in emerging electrochemical energy storage technology of the future. Potassium-ion batteries have abundant resources and similar electrochemical behavior to lithium-ion batteries and thus can meet the needs of electrochemical energy storage applications. These batteries possess low cost, long cycle life, high energy density, safety, and reliability. The invention of potassiumion batteries came to the surface of energy storage research in 2004, over two decades after the revolutionary invention of lithium-ion batteries. Potassium-ion batteries are the potential alternative to lithium-ion batteries, fueling a new direction of energy storage research for many universities"--

Battery technology is constantly changing, and the concepts and applications of these changes are rapidly becoming increasingly more important as more and more industries and individuals continue to make “greener” choices in their energy sources.  As global dependence on fossil fuels slowly wanes, there is a heavier and heavier importance placed on cleaner power sources and methods for storing and transporting that power.  Battery technology is a huge part of this global energy revolution.

Potassium-ion batteries were first introduced to the world for energy storage in 2004, over two decades after the invention of lithium-ion batteries.  Potassium-ion (or “K-ion”) batteries have many advantages, including low cost, long cycle life, high energy density, safety, and reliability. Potassium-ion batteries are the potential alternative to lithium-ion batteries, fueling a new direction of energy storage research in many applications and across industries.

Potassium-ion Batteries: Materials and Applications explores the concepts, mechanisms, and applications of the next-generation energy technology of potassium-ion batteries. Also included is an in-depth overview of energy storage materials and electrolytes. This is the first book on this technology and serves as a reference guide for electrochemists, chemical engineers, students, research scholars, faculty, and R&D professionals who are working in electrochemistry, solid-state science, material science, ionics, power sources, and renewable energy storage fields.
Preface xiii
1 Phosphorous-Based Materials for K-Ion Batteries
1(18)
Maryatn Meshksar
Fatemeh Afshariani
Mohammad Reza Rahimpour
1.1 Introduction
1(4)
1.2 Principles of Potassium-Ion Batteries
5(8)
1.2.1 Cathode Materials
6(1)
1.2.2 Anode Materials
6(2)
1.2.2.1 Carbon-Based Materials
8(1)
1.2.2.2 Alloy-Based Anode Materials
9(4)
1.3 Conclusions
13(6)
List of Abbreviations
14(1)
References
14(5)
2 Antimony-Based Electrodes for Potassium Ion Batteries
19(24)
S. Bharadwaj
M. Chaitanya Varma
Ramesh Singampalli
2.1 Introduction
19(2)
2.2 Insight of Experimental Method
21(2)
2.2.1 Synthesis Methods
21(1)
2.2.2 Characterization Tools
22(1)
2.2.3 Measurement Techniques
22(1)
2.3 KIB as Batteries
23(1)
2.3.1 Progress in KIB
23(1)
2.4 Use of Antimony (Sb) Based K-Ion Batteries (KIB)
24(8)
2.4.1 What Is Antimony?
24(1)
2.4.2 Structure of Antimony Based KIB
25(1)
2.4.3 Antimony Used in KIBs
25(2)
2.4.4 Research Based on K-Sb Ion Batteries in the Last 5 Years
27(5)
2.5 DFT Studies
32(2)
2.6 Future Perceptive and Challenges
34(9)
References
36(7)
3 K-Ion Battery Practical Application Toward Grid-Energy Storage
43(56)
Seyyed Mojtaba Mousavi
Maryam Zarei
Seyyed Alireza Hashemi
Chin Wei Lai
Sonia Bahrani
3.1 Introduction
44(6)
3.2 Intercalation Reaction
50(10)
3.3 Cathode Materials
60(10)
3.3.1 Layered Metal Oxides
60(2)
3.3.2 Prussian Blue Analogs
62(3)
3.3.3 Polyanionic-Based Compounds
65(3)
3.3.4 Organic Materials
68(2)
3.4 Anode Materials
70(11)
3.4.1 Carbon-Based Materials
70(3)
3.4.2 Non-Carbonaceous Materials
73(3)
3.4.3 Alloy-Based Materials
76(2)
3.4.4 Organic Anodes
78(3)
3.5 Electrolyte and Binder
81(2)
3.6 Conclusions
83(16)
References
83(16)
4 Mn-Based Materials for K-Ion Batteries
99(24)
Pallavi Jain
Palak Pant
Sapna Raghav
Dinesh Kumar
4.1 Introduction
100(4)
4.2 Anode Material
104(1)
4.3 Cathode Materials
105(7)
4.3.1 Manganese Layered Compounds
106(2)
4.3.2 Manganese Based Multi-Layered Compounds
108(2)
4.3.3 Prussian Blue Analogs
110(2)
4.4 Electrolyte
112(1)
4.5 Perspectives
112(2)
4.6 Conclusion
114(9)
Acknowledgment
115(1)
References
115(8)
5 Electrode Materials for K-Ion Batteries and Applications
123(14)
M. Prakash
N. Suresh Kumar
K. Chandra Babu Naidu
M.S.S.R.K.N. Sarma
Prasun Banerjee
R. Jeevan Kumar
Ramyakrishna Pothu
Rajender Boddula
5.1 Introduction
124(9)
5.1.1 Why Batteries?
124(1)
5.1.2 Background of Rechargeable Batteries
125(1)
5.1.3 Classification of Batteries
125(2)
5.1.4 Potassium Ion Battery
127(6)
5.2 Conclusions
133(4)
References
134(3)
6 Active Materials for Flexible K-Ion Batteries
137(10)
Prasun Banerjee
Adolfo Franco Jr
K. Chandra Babu Naidu
D. Baba Basha
Ramyakrishna Pothu
Rajender Boddula
6.1 Introduction
138(1)
6.2 Flexible Prussian Blue
138(1)
6.3 Flexible Carbon Nanotube/Prussian Blue
139(1)
6.4 Flexible Film From the Trace of Pencil
140(1)
6.5 Flexible Carbon Nanofiber Mat
141(1)
6.6 Flexible SeS2-Porous Carbon
141(1)
6.7 Flexible ReS2-Nanofiber Carbon
142(1)
6.8 Conclusions
143(4)
Acknowledgments
144(1)
References
144(3)
7 Hollow Nanostructures for K-Ion Batteries
147(20)
Peetam Mandal
Mitali Saha
7.1 Introduction
147(1)
7.2 Current Scenario of Nanostructured Materials for K-Ion Batteries
148(2)
7.3 Hollow Nanostructure Based K-Ion Batteries
150(10)
7.3.1 Metallic Hollow Nanostructured Anodes for K-Ion Batteries
151(2)
7.3.2 Carbonaceous Hollow Nanostructured Anodes for K-Ion Batteries
153(7)
7.4 Conclusion
160(7)
References
161(6)
8 Polyanion Materials for K-Ion Batteries
167(24)
Shankara S. Kalanur
Hyungtak Seo
Basanth S. Kalanoor
8.1 Introduction
168(1)
8.2 Potassium-Ion Batteries
169(1)
8.3 Cathode Materials for Potassium-Ion Batteries
170(1)
8.4 Polyanionic Materials
171(5)
8.4.1 The NASICON and Anti-NASICON Structured Polyanions
172(2)
8.4.2 Olivine Structured Polyanion Materials
174(1)
8.4.3 Tavorite Structured Polyanion Materials
175(1)
8.5 Polyanions as Cathode Material for Potassium-Ion Batteries
176(8)
8.5.1 Potassium-Based Fluorosulfates
176(1)
8.5.2 Amorphous Potassium-Based Iron Phosphates
177(1)
8.5.3 Potassium-Based Double Phosphates of Titanium
178(1)
8.5.4 Potassium-Based Vanadyl Phosphates
179(2)
8.5.5 Potassium-Based Vanadyl Flourophosphates
181(3)
8.6 Summary and Outlook
184(7)
References
185(6)
9 Fundamental Mechanism and Key Performance Factor in K-Ion Batteries
191(22)
Sapna Raghav
Pallavi Jain
Praveen Kumar Yadav
Dinesh Kumar
9.1 Introduction
192(3)
9.1.1 Primary vs. Secondary Batteries
194(1)
9.1.2 Classification of Secondary Potassium Batteries
195(1)
9.2 Recognizing Potential Materials for Their Usage as a Cathode and Observing Their Storage Functionalities
195(2)
9.3 Aqueous Potassium-Ion Batteries
197(5)
9.3.1 KIB Electrolytes
198(1)
9.3.2 Potassium Metal Batteries
199(2)
9.3.3 K-S Battery
201(1)
9.4 Non-Aqueous Potassium-Ion Batteries
202(3)
9.4.1 Cathode
202(1)
9.4.1.1 Hexacyanometalates (HCM)
202(1)
9.4.1.2 Layered Oxides
202(1)
9.4.1.3 Polyanionic Frameworks
203(1)
9.4.1.4 Organic Crystals
203(1)
9.4.2 Anodes
203(1)
9.4.2.1 Graphite
204(1)
9.4.2.2 Other Carbonaceous Materials
204(1)
9.5 Opportunities and Challenges
205(8)
Acknowledgments
206(1)
References
207(6)
10 Fabrication of the Components of K-Ion Batteries: Material Selection and the Cell Assembly Techniques Toward the Higher Battery Performance
213(80)
Iqra Reyaz Hamdani
Ashok N. Bhaskarwar
10.1 Introduction
214(3)
10.2 Recent Materials Studied for Cathodes
217(30)
10.2.1 Cathodes Based on Transition-Metal Oxides
217(13)
10.2.2 Cathodes Based on Transition-Metal Polyanions
230(17)
10.2.3 Cathodes Based on Organic Compounds
247(1)
10.3 Anodes
247(33)
10.3.1 Intercalation Anodes
250(15)
10.3.2 Conversion Anodes
265(7)
10.3.3 Alloying Anodes
272(7)
10.3.4 Organic Compounds
279(1)
10.4 Electrolytes and Binders
280(2)
10.5 Conclusion and Future Perspective
282(11)
Acknowledgment
282(1)
References
283(10)
11 MXenes for K-Ion Batteries
293(20)
Jingya Feng
Oi Lun Li
Qixun Xia
Aiguo Zhou
11.1 Introduction
293(2)
11.2 Synthesis Method of MXene
295(5)
11.2.1 Synthesis of Ti3C2Tx MXene
297(1)
11.2.2 Synthesis of K2Ti4O9(M-KTO)
298(1)
11.2.3 Synthesis of Alkalized Ti3C2 MXene Nanosheets
299(1)
11.3 Structure and Electrochemical Properties of MXenes
300(7)
11.3.1 TLC2 MXene
300(1)
11.3.2 K2Ti409 (M-KTO)
300(5)
11.3.3 Alkalized Ti3C2 MXene Nanosheetsis as Electrode Materials
305(2)
11.4 Summary and Outlook
307(6)
Acknowledgments
308(1)
References
308(5)
12 Metal Sulfides for K-Ion Batteries
313(24)
Xinxin Hu
Ningyuan Zhang
Nanasaheb M. Shinde
Rajaram S. Mane
Qixun Xia
Kwang Ho Kim
12.1 Introduction
314(1)
12.2 SynthesisApproach.es
315(9)
12.2.1 SnS2-Based Composites
315(2)
12.2.2 MoS2-Based Composites
317(2)
12.2.3 CoS-Based Composites
319(1)
12.2.4 Sb2S3-Based Composites
320(1)
12.2.5 FeS2-Based Composites
321(1)
12.2.6 Ni3S2-Based Composites
322(1)
12.2.7 ReS2/N-CNFs
322(2)
12.3 Structures, Properties, and K-Ion Battery Applications
324(7)
12.3.1 SnS2-Based Composites
324(1)
12.3.2 MoS2-Based Composites
325(1)
12.3.3 CoS-Based Composites
326(2)
12.3.4 Sb2S3-Based Composites
328(1)
12.3.5 FeS2-Based Composites
329(1)
12.3.6 Ni3S2-Based Composites
329(2)
12.4 Summary and Outlook
331(6)
Acknowledgments
331(1)
References
331(6)
13 Electrodes for Potassium Oxygen Batteries
337(20)
Kritika S. Sharma
Rekha Sharma
Dinesh Kumar
13.1 Introduction
337(3)
13.2 Categorization of Potassium Secondary Batteries
340(1)
13.3 Potassium-Oxygen Battery
341(1)
13.4 State-of-the-Art or Current Status
341(2)
13.4.1 High Capacity Sb-Based Anode
341(1)
13.4.2 Enhanced Cycle Life by Functionally Graded Cathode (FGC)
342(1)
13.5 Advancement in Rechargeable Alkali Metal-O2 Cells
343(6)
13.5.1 Metal Anodes
343(3)
13.5.2 02-Cathodes
346(1)
13.5.2.1 C-Cathodes
346(2)
13.5.2.2 Non-C-Cathodes
348(1)
13.6 Conclusion
349(8)
Acknowledgment
351(1)
References
352(5)
14 Ti-Based Materials for K-Ion Batteries
357(16)
Rekha Sharma
Sapna Nehra
Dinesh Kumar
14.1 Introduction
357(2)
14.2 Titanium-Based Compounds
359(3)
14.3 Some Other Materials for KIBs Such as K2Ti8O7 and K Ti O
362(1)
14.4 Promises and Challenges of KIBs
362(2)
14.5 Summary and Future Scenario
364(8)
Acknowledgments
366(1)
References
366(6)
14.6 Summary
372(1)
Abbreviations
372(1)
15 Newborn Electrodes for K-Ion Batteries
373(38)
Fatemeh Rezaei
Zeynab Rezaeian
Mohammad Reza Rahimpour
15.1 Introduction
373(2)
15.2 Negative Electrode Materials
375(14)
15.2.1 Carbon Based Materials
381(1)
15.2.4.1 Graphite
381(2)
15.2.1.2 Other Carbonaceous Materials
383(3)
15.2.2 Alloying and Conversion Electrodes
386(2)
15.2.3 Organic Anodes
388(1)
15.3 Positive Electrode Materials
389(9)
15.3.1 Layered Oxide Compounds
389(5)
15.3.2 Hexacyanometallate Groups
394(1)
15.3.3 Polyanionic Compounds
395(1)
15.3.4 Organic Cathode
396(2)
15.4 Conclusions
398(13)
List of Abbreviations
399(1)
References
399(12)
Index 411
Inamuddin, PhD, is an assistant professor at King Abdulaziz University, Jeddah, Saudi Arabia and is also an assistant professor in the Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India. He has published about 150 research articles in various international scientific journals, 18 book chapters, and 60 edited books with multiple well-known publishers.

Rajender Boddula, PhD, is currently working for the Chinese Academy of Sciences President's International Fellowship Initiative (CAS-PIFI) at the National Center for Nanoscience and Technology (NCNST, Beijing). He has numerous honors, book chapters, and academic papers to his credit and is an editorial board member and a referee for several reputed international peer-reviewed journals.

Abdullah M. Asiri is the Head of the Chemistry Department at King Abdulaziz University and the founder and Director of the Center of Excellence for Advanced Materials Research (CEAMR). He holds multiple patents, has authored ten books, more than one thousand publications in international journals, and multiple book chapters.
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