| Preface |
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ix | |
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xi | |
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Nanostructured Electrodes with Unique Properties for Biological and Other Applications |
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1 | (56) |
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1 | (1) |
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High Surface Area Electrodes |
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2 | (21) |
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Attachment of Nanoparticles onto Electrodes |
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3 | (9) |
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Templating using Membranes |
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12 | (7) |
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Templating using Lyotropic Liquid Crystals |
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19 | (3) |
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22 | (1) |
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23 | (4) |
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Exploiting Nanoscale Control to Interface Electrodes with Biomolecules |
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27 | (12) |
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Plugging Nanomaterials into Proteins - Nanoparticles |
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27 | (2) |
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Plugging Nanomaterials into Proteins - Carbon Nanotubes |
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29 | (2) |
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Plugging Nanomaterials into Proteins - Molecular Wires |
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31 | (1) |
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Nanostructuring Electrodes to Achieve Intimate Connectivity with Biomolecules |
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32 | (1) |
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Nanostructuring Electrodes using Rigid Molecules |
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32 | (3) |
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The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications |
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35 | (4) |
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39 | (11) |
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Switching Properties of Monolayer Systems |
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39 | (4) |
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Control and Enhancement of Electrochemical Reactions using Magnetic Nanostructures on Electrodes |
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43 | (7) |
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50 | (7) |
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50 | (7) |
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Electrochemically Active Polyelectrolyte-Modified Electrodes |
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57 | (60) |
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57 | (7) |
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Chemically Modified Electrodes |
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58 | (1) |
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59 | (1) |
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Redox Polyelectrolyte Monolayers |
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60 | (1) |
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Redox Polymer Brushes and Grafted DNA |
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61 | (1) |
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Layer-by-Layer Polyelectrolyte Multilayers |
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62 | (2) |
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64 | (8) |
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Polyelectrolye Interpenetration |
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66 | (1) |
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Compensation of Polyelectrolyte Charges |
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66 | (1) |
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66 | (1) |
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Effect of the Assembly pH |
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67 | (1) |
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68 | (4) |
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72 | (12) |
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72 | (1) |
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Peak Position and Donnan Potential |
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73 | (5) |
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Coupling Between the Acid-Base and Redox Equilibria |
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78 | (1) |
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79 | (2) |
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Nonreversible Electrochemistry: Charge Transport |
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81 | (3) |
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Dynamics of Solvent and Ion Exchange |
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84 | (5) |
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84 | (2) |
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86 | (1) |
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86 | (2) |
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88 | (1) |
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Molecular Description of Redox Polyelectrolyte-Modified Electrodes |
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89 | (8) |
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Formulation of the Molecular Theory |
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89 | (7) |
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Comparison with Phenomenological Models, Advantages and Limitations |
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96 | (1) |
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97 | (9) |
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Amperometric Enzymatic Electrodes |
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97 | (8) |
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105 | (1) |
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106 | (11) |
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109 | (8) |
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Electrochemistry on Carbon-Nanotube-Modified Surfaces |
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117 | (52) |
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117 | (1) |
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Structure and Properties of Carbon Nanotubes |
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118 | (10) |
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Structure and Electronic Properties |
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118 | (3) |
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121 | (2) |
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Electrochemical Properties |
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123 | (5) |
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Towards the Design of CNT-Modified Electrodes |
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128 | (19) |
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128 | (1) |
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129 | (1) |
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Chemical and Biochemical Functionalization |
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130 | (1) |
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131 | (2) |
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133 | (1) |
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Chemical Modification for CNT Sorting |
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133 | (2) |
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Chemical Doping, Intercalation and Artificial Defects |
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135 | (1) |
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CNT Deposition on Electrode Surfaces |
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135 | (1) |
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135 | (6) |
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141 | (3) |
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Individual CNT Electrodes |
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144 | (2) |
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CNT-Modified Electrode Pretreatments |
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146 | (1) |
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Electrochemical Applications of CNT Electrodes |
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147 | (13) |
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147 | (1) |
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Enzymatic and Redox Protein Biosensors |
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148 | (3) |
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151 | (5) |
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156 | (1) |
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Electrochemical Actuators |
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157 | (1) |
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Electrochemical Energy-Harvesting Devices |
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157 | (3) |
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Conclusions and Future Prospects |
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160 | (9) |
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162 | (7) |
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Electrochemistry of Electroactive Surface-Immobilized Nanoparticles |
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169 | (28) |
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169 | (2) |
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Synthetic Approaches and Characterization |
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171 | (3) |
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174 | (4) |
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178 | (8) |
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178 | (2) |
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180 | (4) |
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184 | (1) |
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185 | (1) |
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Other Metal Oxides and Metal Sulfides |
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186 | (1) |
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Prussian Blue and Its Derivatives |
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187 | (5) |
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192 | (5) |
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193 | (4) |
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Structure, Electrochemistry and Applications of Self-Assembled Monolayers of Thiols |
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197 | (60) |
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197 | (3) |
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Structural Aspects of Thiol-Like SAMs |
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200 | (9) |
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Reductive Desorption of SAMs |
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209 | (9) |
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Metal Deposition on SAM-Modified Electrodes |
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218 | (27) |
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218 | (2) |
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220 | (8) |
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Underpotential Deposition |
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228 | (11) |
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239 | (6) |
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245 | (12) |
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247 | (10) |
| Index |
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257 | |