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E-raamat: Crystallography and Surface Structure - An Introduction for Surface Scientists and Nanoscientists: An Introduction for Surface Scientists and Nanoscientists 2nd Edition [Wiley Online]

(FHI, Berlin, Germany)
  • Formaat: 448 pages
  • Ilmumisaeg: 23-Nov-2016
  • Kirjastus: Blackwell Verlag GmbH
  • ISBN-10: 3527697136
  • ISBN-13: 9783527697137
  • Wiley Online
  • Hind: 153,31 €*
  • * hind, mis tagab piiramatu üheaegsete kasutajate arvuga ligipääsu piiramatuks ajaks
  • Formaat: 448 pages
  • Ilmumisaeg: 23-Nov-2016
  • Kirjastus: Blackwell Verlag GmbH
  • ISBN-10: 3527697136
  • ISBN-13: 9783527697137
A valuable learning tool as well as a reference, this book provides students and researchers in surface science and nanoscience with the theoretical crystallographic foundations, which are necessary to understand local structure and symmetry of bulk crystals, including ideal and real single crystal surfaces. The author deals with the subject at an introductory level, providing numerous graphic examples to illustrate the mathematical formalism. The book brings together and logically connects many seemingly disparate structural issues and notations used frequently by surface scientists and nanoscientists. Numerous exercises of varying difficulty, ranging from simple questions to small research projects, are included to stimulate discussions about the different subjects.
From the content:
Bulk Crystals, Three-Dimensional Lattices
- Nanoparticles and Crystallites, Quasicrystals
- Crystal Layers, Two-Dimensional Lattices
- Ideal Single Crystal Surfaces
- Real Crystal Surfaces
- Adsorbate layers
- Interference Lattices, Chirality
- Experimental Analysis of Real Crystal Surfaces
- Nanotubes
Preface to the Second Edition ix
Preface to the First Edition xi
1 Introduction
1(6)
2 Bulk Crystals: Three-Dimensional Lattices
7(84)
2.1 Basic Definition
7(4)
2.2 Representation of Bulk Crystals
11(24)
2.2.1 Alternative Descriptions Conserving the Lattice Representation
12(2)
2.2.2 Alternative Descriptions Affecting the Lattice Representation
14(2)
2.2.2.1 Cubic, Hexagonal, and Trigonal Lattices
16(9)
2.2.2.2 Superlattices and Repeated Slabs
25(4)
2.2.2.3 Linear Transformations of Lattice Vectors
29(2)
2.2.3 Centered Lattices
31(4)
2.3 Periodicity Cells of Lattices
35(3)
2.4 Lattice Symmetry
38(11)
2.5 Reciprocal Lattice
49(3)
2.6 Neighbor Shells
52(11)
2.7 Nanoparticles and Crystallites
63(8)
2.8 Incommensurate Crystals and Quasicrystals
71(11)
2.8.1 Modulated Structures
71(2)
2.8.2 Incommensurate Composite Crystals
73(3)
2.8.3 Quasicrystals
76(6)
2.9 Exercises
82(9)
3 Crystal Layers: Two-Dimensional Lattices
91(78)
3.1 Basic Definition, Miller Indices
91(5)
3.2 Netplane-Adapted Lattice Vectors
96(2)
3.3 Symmetrically Appropriate Lattice Vectors: Minkowski Reduction
98(2)
3.4 Miller Indices for Cubic and Trigonal Lattices
100(6)
3.5 Alternative Definition of Miller Indices and Miller--Bravais Indices
106(3)
3.6 Symmetry Properties of Netplanes
109(35)
3.6.1 Centered Netplanes
110(1)
3.6.2 Inversion
111(3)
3.6.3 Rotation
114(5)
3.6.4 Mirror Operation
119(12)
3.6.5 Glide Reflection
131(8)
3.6.6 Symmetry Groups
139(5)
3.7 Crystal Systems and Bravais Lattices in Two Dimensions
144(5)
3.8 Crystallographic Classification of Netplanes and Monolayers
149(15)
3.8.1 Oblique Netplanes
151(1)
3.8.2 Primitive Rectangular Netplanes
151(4)
3.8.3 Centered Rectangular Netplanes
155(2)
3.8.4 Square Netplanes
157(1)
3.8.5 Hexagonal Netplanes
158(5)
3.8.6 Classification Overview
163(1)
3.9 Exercises
164(5)
4 Ideal Single Crystal Surfaces
169(40)
4.1 Basic Definition, Termination
169(6)
4.2 Morphology of Surfaces, Stepped and Kinked Surfaces
175(3)
4.3 Miller Index Decomposition
178(14)
4.4 Chiral and Achiral Surfaces
192(12)
4.5 Exercises
204(5)
5 Real Crystal Surfaces
209(26)
5.1 Surface Relaxation
209(1)
5.2 Surface Reconstruction
210(12)
5.3 Growth Processes
222(4)
5.4 Faceting
226(5)
5.5 Exercises
231(4)
6 Adsorbate Layers
235(70)
6.1 Definition and Classification
235(6)
6.2 Adsorbate Sites
241(10)
6.3 Wood Notation of Surface Structure
251(7)
6.4 High-Order Commensurate (HOC) Overlayers
258(5)
6.5 Interference Lattices
263(20)
6.5.1 Basic Formalism
264(8)
6.5.2 Interference and Wood Notation
272(7)
6.5.3 Anisotropic Scaling, Stretching, and Shifting
279(4)
6.6 Symmetry and Domain Formation
283(10)
6.7 Adsorption at Surfaces and Chirality
293(6)
6.8 Exercises
299(6)
7 Experimental Analysis of Real Crystal Surfaces
305(10)
7.1 Experimental Methods
305(1)
7.2 Surface Structure Compilations
306(5)
7.3 Database Formats for Surface and Nanostructures
311(2)
7.4 Exercises
313(2)
8 Nanotubes
315(14)
8.1 Basic Definition
315(4)
8.2 Nanotubes and Symmetry
319(4)
8.3 Complex Nanotubes
323(3)
8.4 Exercises
326(3)
Appendix A Sketches of High-Symmetry Adsorbate Sites
329(22)
A.1 Face-Centered Cubic (fcc) Surface Sites
330(8)
A.2 Body-Centered Cubic (bcc) Surface Sites
338(4)
A.3 Hexagonal Close-Packed (hcp) Surface Sites
342(4)
A.4 Diamond Surface Sites
346(3)
A.5 Zincblende Surface Sites
349(2)
Appendix B Parameter Tables of Crystals
351(4)
Appendix C Mathematics of the Wood Notation
355(12)
C.1 Basic Formalism and Examples
355(6)
C.2 Wood-Representability
361(6)
Appendix D Mathematics of the Minkowski Reduction
367(4)
Appendix E Details of Number Theory
371(20)
E.1 Basic Definitions and Functions
371(5)
E.2 Euclid's Algorithm
376(1)
E.3 Linear Diophantine Equations
377(3)
E.4 Quadratic Diophantine Equations
380(6)
E.5 Number Theory and 2 × 2 Matrices
386(5)
Appendix F Details of Vector Calculus and Linear Algebra
391(4)
Appendix G Details of Fourier Theory
395(4)
Appendix H List of Surface Web Sites
399(2)
Appendix I List of Surface Structures
401(2)
Glossary and Abbreviations 403(14)
References 417(8)
Index 425
Klaus Hermann is a senior scientist at the Fritz-Haber Institute and staff member of the Physics department of the Free University Berlin (Germany). He obtained a PhD in Physics from the Technical University Clausthal (Germany), worked as postdoc in Mexico and the USA before being appointed Professor at the Technical University Clausthal. He was visiting professor in the USA, Austria, Poland, Spain and in Hong Kong. Klaus Hermann has (co-)authored 175 scientific publications, three books, two scientific movies, and different software projects on various subjects of surface science, catalysis, quantum chemistry, and computer science. He is co-author of the open Surface Structure Database, formerly NIST Surface Structure Database.