Preface |
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ix | |
Introduction |
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1 | (4) |
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1 Fundamentals of Magnetochemistry |
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5 | (38) |
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1.1 Method of Static Magnetic Susceptibility in Coordination Chemistry |
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5 | (13) |
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1.2 Exchange Effect and Spin-Spin Interactions |
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18 | (8) |
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1.3 Magnetic Phenomena in Solids |
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26 | (4) |
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1.4 Magnetic Dilution Method |
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30 | (13) |
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2 Phase Composition and Magnetic Characteristics of Solid Solutions and Complex Oxides Based on Scandium Molybdate Sc2-2xGd2xMo3O12 (0 ≤ × ≤ 1) |
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43 | (16) |
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43 | (2) |
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2.2 Synthesis, Structural and X-Ray Data |
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45 | (6) |
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51 | (4) |
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2.4 Magnetic Susceptibility Measurements and Their Analysis |
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55 | (4) |
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3 Problems of Electron Structure of Colossal Magnetoresistors |
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59 | (38) |
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59 | (5) |
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3.2 State of Manganese Atoms and Exchange Interactions in the Solid Solutions Based on Lanthanum Aluminate |
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64 | (33) |
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3.2.1 The xLa0.33A0.67MnO3-(1-x)LaAlO3 (A = Ca, Sr, Ba) Solid Solutions |
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64 | (3) |
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3.2.2 The xLa0.67(CaySr1-y)0.33MnO3-(1-x) LaAlO3 (y = 0.3; 0.5; 0.7) Solid Solutions |
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67 | (4) |
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3.2.3 The x(La1.zY2)0.67Ca0.33MnO3-(1-x)La1-z YzAlO3 (z = 0.1; 0.2) Solid Solutions |
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71 | (9) |
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3.2.4 The x(La1-zY2)0.67Sr0.33MnO3-(1-x)La1-z YzAlO3 (z = 0.1; 0.2) Solid Solutions |
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80 | (17) |
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4 Influence of the Nature and Concentration of Dia-and Paramagnetic Elements on Electron Structure and Electrophysical Properties of Doped Lanthanum Gallate |
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97 | (70) |
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97 | (5) |
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4.2 Synthesis and Material Characterization |
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102 | (2) |
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102 | (1) |
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4.2.2 Methods of Material Characterization |
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103 | (1) |
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4.3 Lanthanum Gallate Doped with Transition Element and Strontium |
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104 | (10) |
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4.3.1 Lanthanum Gallate Doped with Transition Element and Strontium in Ratio M:Sr = 5:1 |
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104 | (1) |
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4.3.1.1 Chromium-containing systems |
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104 | (5) |
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4.3.1.2 Manganese-containing systems |
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109 | (2) |
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4.3.1.3 Cobalt-containing systems |
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111 | (1) |
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4.3.1.4 Nickel-containing systems |
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112 | (2) |
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4.4 Conductivity of Lanthanum Gallate Doped with Transition Element and Strontium in Ratio M:Sr = 5:1 |
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114 | (4) |
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4.5 The Impact of the Increased Fraction of Strontium and Introduction of Magnesium on Electron Structure and Electrophysical Properties of Doped Lanthanum Gallate |
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118 | (31) |
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4.5.1 Chromium-Containing Systems |
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118 | (13) |
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4.5.2 Nickel-Containing Systems |
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131 | (1) |
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4.5.2.1 La1.0.5xSro.5xNixGa1.x03-δ, LaNixGa1-1.2xMg0.2xO3-δ and LaNixGa1-1.5xMg0.5xO3-δ systems |
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131 | (6) |
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4.5.2.2 La1-0.2xSr0.2xNixMg0.2XGa1-1.2xO3-δ system |
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137 | (1) |
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4.5.3 LaCOxMg0.2xGa1-1.2xO3-δ and LaCOxMg0.5x Ga1-1.5x3-δ Systems |
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138 | (1) |
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4.5.3.1 X-ray diffraction and phase composition |
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138 | (5) |
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4.5.3.2 Magnetic features |
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143 | (6) |
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4.6 Conductivity in the Systems with Magnesium and an Increased Content of Strontium |
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149 | (3) |
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4.6.1 Chromium-Containing Systems |
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149 | (1) |
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4.6.2 Nickel-Containing Systems |
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149 | (3) |
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4.7 Lanthanum Gallate Doped with Chromium and Calcium or Barium |
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152 | (5) |
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157 | (10) |
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5 Magnetic Behavior of Multicomponent Bismuth Niobates and Bismuth Titanates, with Pyrochlore and Layered Perovskite-Type Structures |
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167 | (64) |
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167 | (2) |
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5.2 Magnetic Behavior of the Doped Titanates and Substituted Niobates of Bismuth with Layered Perovskite Structure |
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169 | (19) |
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5.2.1 Structure of Layered Doped Bismuth Titanates and Bismuth Niobates |
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169 | (3) |
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5.2.2 Magnetic Properties of Doped Bismuth Niobates and Titanates |
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172 | (2) |
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5.2.3 Magnetic Behavior of Chromium Containing Bismuth Titanates |
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174 | (5) |
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5.2.4 Magnetic Properties of Iron-Containing Bismuth Titanates and Niobates |
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179 | (4) |
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5.2.5 Magnetic Properties of Manganese Containing Bismuth Titanates and Niobates |
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183 | (5) |
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5.3 Magnetic Behavior of Doped Bismuth Titanates and Niobates with Pyrochlore-Type Structure |
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188 | (31) |
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5.3.1 Pyrochlore Structure Type and Special Features of Bismuth-Containing Pyrochlores |
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188 | (7) |
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5.3.2 Magnetic Properties of Chromium, Iron, Manganese Containing Bismuth Niobates and Titanates with Pyrochlore-Type Structure |
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195 | (1) |
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5.3.2.1 Magnetic properties of Bi16 CrxTi2O7-δ and Bi1.6Mg0.8-xCrx Nb1.6O7-δ |
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196 | (6) |
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5.3.2.2 Magnetic properties of iron-containing bismuth titanates and niobates |
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202 | (6) |
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5.3.2.3 Magnetic properties of manganese-containing bismuth titanates and niobates |
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208 | (8) |
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5.3.2.4 Magnetic properties of diluted manganese-containing bismuth niobates |
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216 | (3) |
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219 | (12) |
Index |
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231 | |