Preface |
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xi | |
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Basics of Pulse and Fourier Transform NMR |
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1 | (13) |
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14 | (6) |
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20 | (15) |
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Introduction to pulse NMR |
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21 | (4) |
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25 | (10) |
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Introduction to Fourier transform NMR |
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35 | (12) |
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The driven vs. the pulsed simple harmonic oscillator: An introduction to Fourier transform pairs |
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36 | (2) |
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The nature of Fourier transform NMR |
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38 | (6) |
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Comparison of FT and cw NMR |
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44 | (3) |
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Details of Pulse and Fourier Transform NMR |
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47 | (30) |
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Some useful Fourier transform theorems |
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47 | (3) |
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Pulse length, tip angle, and all that (or just what is the rf pulse doing to the magnetization?) |
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50 | (10) |
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60 | (17) |
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77 | (21) |
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Digitizing rate and the size of the transform |
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77 | (2) |
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Dynamic range and digitizer resolution |
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79 | (2) |
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81 | (3) |
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84 | (4) |
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Digitally massaging the FID |
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88 | (4) |
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FT spectroscopy of wide lines |
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92 | (6) |
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Decoupling in Solution NMR |
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98 | (8) |
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selective and off resonance decoupling |
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106 | (19) |
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Pulse response in the presence of quadrupole splitting |
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106 | (6) |
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112 | (5) |
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117 | (4) |
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121 | (2) |
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123 | (2) |
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125 | (11) |
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What is spin-lattice relaxation? |
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How does spin-lattice relaxation take place? |
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Other kinds of nuclear relaxation |
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136 | (3) |
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139 | (25) |
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Spin-lattice relaxation mechanisms |
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139 | (12) |
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How to differentiate between mechanisms |
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151 | (5) |
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Relaxation of quadrupolar nuclei |
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156 | (5) |
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Oxygen removal from samples |
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161 | (3) |
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Measurement of spin-lattice relaxation |
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164 | (33) |
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165 | (3) |
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Some typical pulse sequences for T1 measurements |
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168 | (8) |
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progressive saturation with inversion recovery |
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T1 measurements in high resolution NMR |
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176 | (6) |
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182 | (3) |
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Analysis of exponential time constants |
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185 | (12) |
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Molecular diffusion in a field gradient |
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197 | (13) |
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Diffusion in a steady field gradient |
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198 | (4) |
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Pulse field gradient method |
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202 | (8) |
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Stejskal and Tanner sequence |
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potential problems with pulsed gradient method |
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210 | (7) |
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217 | (24) |
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Homogeneous and inhomogeneous lines |
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218 | (9) |
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Moments of absorption lines |
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227 | (14) |
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241 | (20) |
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The meaning of dipolar and Zeeman order |
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241 | (5) |
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Rotating frame adiabatic demagnetization |
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246 | (5) |
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The solid echo and other two pulse echoes |
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251 | (5) |
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256 | (5) |
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Rotating frame relaxation |
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261 | (9) |
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Rotating frame spin-lattice relaxation measurements |
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262 | (4) |
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The strong and weak collision regimes |
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266 | (4) |
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270 | (5) |
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High resolution NMR of solids |
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275 | (22) |
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Magic angle spinning (MAS) |
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279 | (4) |
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283 | (1) |
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Cross polarization (CP) experiments |
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284 | (8) |
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how to make thermal contact: the Hartmann-Hahn condition |
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CP experiment: implementation |
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Multiple pulse line-narrowing in solids |
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292 | (5) |
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Basic spectrometer considerations |
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297 | (38) |
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297 | (15) |
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312 | (6) |
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Transient data acquisition system |
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318 | (7) |
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Recovery times in pulse NMR |
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325 | (6) |
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331 | (4) |
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Purchasing a spectrometer |
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335 | (23) |
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335 | (15) |
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pulse sequence and phase capabilities |
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Desirable features in high resolution spectrometers |
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350 | (2) |
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352 | (2) |
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Dealing with instrument companies |
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354 | (4) |
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Spectrometers and components |
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358 | (67) |
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An example of a simple liquids machine |
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358 | (3) |
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An example of a high power machine for solids |
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361 | (6) |
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Use of CAMAC for computer interface |
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367 | (6) |
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373 | (13) |
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Probes for superconducting solenoids |
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386 | (2) |
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Crossed diodes and other non-linear elements |
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388 | (4) |
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392 | (8) |
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Quarterwave lines and network |
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400 | (7) |
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Tank circuits, impedance matching, and all that |
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407 | (9) |
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Useful packaged components |
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416 | (5) |
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How to tune a passive circuit and measure its impedance |
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421 | (1) |
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422 | (3) |
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Turning it on and tuning it |
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425 | (27) |
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A procedure for tuning up a pulse NMR apparatus |
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425 | (7) |
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RF signal source: pulse source |
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fine tuning with an NMR signal |
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How to set the phase of an FID |
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432 | (2) |
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434 | (3) |
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437 | (3) |
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Searching for resonance in high resolution NMR |
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440 | (2) |
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Searching for a resonance: general considerations |
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442 | (4) |
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Choice of tip angle for optimum S/N |
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446 | (3) |
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When you cannot use lock solvents |
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449 | (1) |
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450 | (2) |
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452 | (16) |
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Troubleshooting suggestions |
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452 | (2) |
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Maintenance equipment suggestions |
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454 | (4) |
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458 | (2) |
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460 | (3) |
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463 | (5) |
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468 | (15) |
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Removal of coherent noise |
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468 | (6) |
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The analog filter and the FID |
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474 | (5) |
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479 | (4) |
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483 | (14) |
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483 | (4) |
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High speed spinning of samples |
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487 | (4) |
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Chemical shift concertina |
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491 | (2) |
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Zero time resolution of the FID |
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493 | (4) |
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497 | (12) |
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Calculational aides in NMR |
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498 | (8) |
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506 | (1) |
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507 | (2) |
POSTSCRIPT |
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509 | (20) |
APPENDICES |
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A. References, general and review |
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513 | (2) |
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B. Review journals in magnetic resonance |
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515 | (2) |
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C. Conferences in magnetic resonance |
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517 | (4) |
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521 | (6) |
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527 | (2) |
Author Index |
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529 | (6) |
Subject Index |
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535 | |