Since its inception 50 years ago, electron paramagnetic resonance (EPR, also called ESR or EMR) has become a major tool in diverse fields ranging from biology and chemistry to solid state physics and materials science. This important book includes personal descriptions of early experiments by pioneers who laid the foundations for the field, perspectives on the state of the art, and glimpses of future opportunities. It presents a broad view of the foundations of EPR and its applications, and will therefore appeal to scientists in many fields. Even the expert will find here history not previously recorded and provocative views of future directions.
Preface v(6) Contributors xi Part A. Historical Introduction 1(149) A.1. The Discovery of the Electron Spin 1(12) S.A. Goudsmit J.H. van der Waals A.2. Preparing the Way for Paramagnetic Resonance 13(12) C.P. Poole, Jr. H.A. Farach A.3. Paramagnetism, Before Magnetic Resonance 25(12) B. Bleaney A.4. Cryomagnetism and Magnetic Resonance in Oxford Physics 37(8) B. Bleaney A.5. The Scientific Work of E.K. Zavoisky 45(6) K.M. Salikhov A.6. Spin-Lattice Relaxation Studies in Kazan University 51(6) L.K. Aminov A.7. Paramagnetic Resonance in the Early Years of the Zavoisky Institute 57(6) Yu.V. Yablokov A.8. The First Sesquidecade of Paramagnetic Resonance 63(21) C.P. Poole, Jr. H.A. Farach A.9. EPR in The Netherlands 84(21) E.de Boer A.10. EPR at Berkeley 1951-55: An Annotated Bibliography 105(6) A.M. Portis A.11. EPR at Harvard 111(21) A.H. Maki A.12. EPR: The Indian Scene 132(18) B. Venkataraman Part B. Transition Metals 150(46) B.1. Hyperfine Structure 150(11) B.R. McGarvey B.2. A Remembrance of ESRs Past 161(4) D. Kivelson B.3. Lanthanides 165(20) J.M. Baker B.4. High-spin Systems 185(11) J.R. Pilbrow Part C. Organic Radicals 196(69) C.1. Early Studies of Exchange Between Paramagnetic and Diamagnetic Molecules 196(6) S.I. Weissman C.2. EPR and the History of the Thianthrene Cation Radical 202(11) H.J. Shine C.3. Organic Radical Ions as Studied by EPR Spectroscopy 213(23) F. Gerson C.4. Theories of Molecular Electronic Structure 236(5) H.M. McConnell C.5. Spin Trapping 241(24) E.G. Janzen Part D. Gas Phase EPR 265(13) D.1. Electron Paramagnetic Resonance in Gases 265(6) B. Bleaney D.2. Early EPR in Some Gases 271(7) J.G. Castle Part E. Electrochemically Generated Radicals 278(17) E.1 EPR And Electrochemistry 278(17) A.J. Bard T.M. McKinney I.B. Goldberg Part F. Radicals Formed by Radiation 295(36) F.1. Radicals I Have Loved: I -- Organic Free Radicals 295(15) M.C.R. Symons F.2. Radical Formation in Irradiated Biological Systems 310(7) H.C. Box F.3. EPR of Short-lived Radicals 317(14) R.W. Fessenden Part G. Applications to Biological Systems 331(129) G.1. Early Applications to Biological Systems 331(15) D.J.E. Ingram G.2. EPR of Metalloproteins: Truth Tables Revisited 346(15) J. Peisach G.3. In Vivo EPR 361(18) H.M. Swartz L.J. Berliner G.4. Biological Applications of EPR Involving Iron 379(31) H. Beinert R.H. Sands G.5. Spin Labels 410(13) H.M. McConnell G.6. Site-Directed Spin Labeling: A Strategy for Determination of Structure and Dynamics of Proteins 423(13) C. Altenbach W. Hubbell G.7. EPR in Biochemistry 436(15) I. Yamazaki G.8. EPR Studies of Cells and Tissues 451(9) H.M. Swartz Part H. Spin-Spin Interactions 460(147) H.1. Inhomogeneous Broadening, Spectral Diffusion, and All That 460(9) A.M. Portis H.2. The Effect of Concentration and Oxygen in EPR 469(13) K.H. Hausser H. Brunner H.3. Electron Paramagnetic Resonance and the Phosphorescent State of Aromatic Organic Molecules 482(14) C.A. Hutchison Jr. H.4. The Path that led to the Study of Luminescent Triplet States by EPR with Optical Detection in Zero Field 496(16) J.H. van der Waals H.5. Triplet Exciton Spin Exchange Effects in the Ion Radical Salts of Tetracyanoquinodimethane 512(10) D.B. Chesnut H.6. Electron-Electron Spin-Spin Splitting 522(8) S.S. Eaton G.R. Eaton H.7. EPR of Non-Kramers Systems in Biology 530(18) M.P. Hendrich P.G. Debrunner H.8. The Development of ENDOR and other Reminiscences of the 1950s 548(9) G. Feher H.9. ENDOR in Liquids 557(20) K. Mobius H.10. ELDOR Spectroscopy 577(10) J.S. Hyde H.11. Chemically Induced Dynamic Electron Polarization (CIDEP) 587(15) K.A. McLauchlan H.12. RYDMR of Short-Lived Spin-Correlated Pairs 602(5) Yu.N. Molin Part I. Time-Domain EPR 607(77) I.1. Saturation Recovery 607(12) J.S. Hyde I.2. Electron Spin-Lattice Relaxation by Pulsed Field Sweep 619(10) J.G. Castle D.W. Feldman I.3. Electron Spin Echo Experiments Then and Now 629(6) W.B. Mims I.4. Electron Spin Echo in Siberia 635(6) Yu. D. Tsvetkov I.5. Applications of Electron Spin Echo Modulation 641(11) L. Kevan I.6. Fourier Transform EPR 652(6) M.K. Bowman I.7. Linewidths, Lineshapes, and Spin-Relaxation in the One and Two-Dimensional ESR of Organic Radicals and Spin Labels 658(26) J.H. Freed Part J. Imaging 684(11) J.1 EPR Imaging 684(11) S.S. Eaton G.R. Eaton Part K. Development of EPR Instrumentation 695(46) K.1. EPR at Varian: 1954-1974 695(22) J.S. Hyde K.2. A Bruker EPR History 717(14) D. Schmalbein K.3. Very-High-Field EPR 731(10) Ya.S. Lebedev Part L. Other EPR Detection Methods 741(51) L.1. Multiquantum EPR 741(17) James S. Hyde L.2. Longitudinal Techniques in ESR and ENDOR Spectroscopy 758(10) C. Pinzino L.3. Microwave Amplitude Modulation and Short T(1) Measurement 768(13) J. Pescia L.4. From 10(10) Spins to a Single Spin 781(11) Y. Manassen E. Ter-Ovanesyan D. Shachal Part M. The Next 50 Years 792(2) G.R. Eaton S.S. Eaton K.M. Salikhov Index 794
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