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E-raamat: Fundamentals of Perovskite Oxides: Synthesis, Structure, Properties and Applications [Taylor & Francis e-raamat]

(Fayetteville State University, Fayetteville, NC), (Fayetteville State University, Fayetteville, NC), (Fayetteville State University, Fayetteville, NC)
  • Formaat: 384 pages, 80 Tables, black and white; 112 Illustrations, black and white
  • Ilmumisaeg: 07-Oct-2020
  • Kirjastus: CRC Press
  • ISBN-13: 9780429351419
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  • Taylor & Francis e-raamat
  • Hind: 230,81 €*
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Fundamentals of Perovskite Oxides: Synthesis, Structure, Properties and ApplicationsSuurem pilt
  • Formaat: 384 pages, 80 Tables, black and white; 112 Illustrations, black and white
  • Ilmumisaeg: 07-Oct-2020
  • Kirjastus: CRC Press
  • ISBN-13: 9780429351419
Teised raamatud teemal:
Taylor & Francis e-raamatudRohkem infot Taylor & Francis e-raamatute kohta
Raamatu kodulehekülg: https://www.taylorfrancis.com/books/9780429351419
"This book summaries the structure, synthesis route, and potential applications of perovskite oxide materials and is suitable for engineers and researchers working with advanced ceramic materials. It begins with fundamentals of the structure of the materials. A brief overview of techniques available for the synthesis of perovskite oxide materials and for size control is provided. It demonstrates characteristics unique to perovskite-type compounds, such as chemical, dielectric, magnetic, electronic, thermal and optical properties, and the contributing factors and approaches to enhance those properties. It also covers potential applications of perovskite-type materials in device fabrication"--

This textbook entitled Fundamentals of Perovskite Oxides: Synthesis, Structure, Properties and Applications summarizes the structure, synthesis routes, and potential applications of perovskite oxide materials. Since these perovskite-type ceramic materials offer opportunities in a wide range of fields of science and engineering, the chapters are broadly organized into four sections of perovskite-type oxide materials and technology.

  • Covers recent developments in perovskite oxides

  • Serves as a quick reference of perovskite oxides information

  • Describes novel synthesis routes for nanostructured perovskites

  • Discusses comprehensive details for various crystal structures, synthesis methods, properties, and applications

  • Applies to academic education, scientific research, and industrial R&D for materials research in real-world applications like bioengineering, catalysis, energy conversion, energy storage, environmental engineering, and data storage and sensing

This book serves as a handy and practical guideline suitable for students, engineers, and researchers working with advanced ceramic materials.

List of Figures
xi
List of Tables
xxiii
List of Symbols
xxv
Preface xxxi
Authors xxxiii
Chapter 1 Introduction to Perovskites
1(16)
1.1 History of Perovskites
1(1)
1.2 Formation of Perovskites
2(2)
1.3 Classification of Perovskites
4(7)
References
11(6)
Chapter 2 Synthesis of Perovskite Oxides
17(70)
2.1 Solid-State Reactions
17(5)
2.1.1 High-Temperature Synthesis
17(2)
2.1.2 Solution-Assisted Synthesis
19(1)
2.1.3 Combustion Synthesis
19(3)
2.2 Liquid-Phase Reactions
22(19)
2.2.1 Coprecipitation
22(3)
2.2.2 Hydrothermal/Solvothermal Synthesis
25(1)
2.2.3 Sol-Gel Processing
26(7)
2.2.4 Microemulsion
33(2)
2.2.5 Template-Assisted Synthesis
35(3)
2.2.6 Microwave Synthesis
38(2)
2.2.7 Freeze Drying
40(1)
2.3 Gas-Phase Reactions
41(11)
2.3.1 Physical Vapor Deposition
41(1)
2.3.1.1 Pulsed Laser Deposition
41(3)
2.3.1.2 Reactive Sputtering
44(1)
2.3.1.3 Reactive Molecular Beam Epitaxy
44(4)
2.3.1.4 Reactive Thermal Evaporation
48(1)
2.3.2 Chemical Vapor Deposition
49(3)
2.4 Miscellaneous Techniques
52(18)
2.4.1 Molten-Salt Synthesis
52(2)
2.4.2 Electrochemical Synthesis
54(4)
2.4.2.1 Anodic Oxidation
58(1)
2.4.2.2 Electrogeneration of the Base by Cathodic Reduction
59(1)
2.4.3 Electrospinning
60(4)
2.4.4 Spin Coating
64(3)
2.4.5 Langmuir-Blodgett Technique
67(1)
2.4.6 Spray Pyrolysis
68(2)
References
70(17)
Chapter 3 Crystal Structure of Simple Perovskites
87(16)
3.1 Description of Perovskite Structures
87(3)
3.2 Distortions in Perovskite Oxides
90(10)
3.2.1 Octahedral Tilting
90(4)
3.2.2 B-cation Displacement
94(5)
3.2.3 Jahn-Teller (JT) Distortion
99(1)
References
100(3)
Chapter 4 Structural Variants of Perovskite Oxides
103(52)
4.1 Double Perovskites
103(7)
4.2 Layered Perovskites
110(15)
4.2.1 Ruddlesden-Popper Phase
111(3)
4.2.2 Dion-Jacobson Phases
114(1)
4.2.3 Aurivillius Phases
114(4)
4.2.4 AnBnO3n+2-Layered Structures
118(6)
4.2.5 Superconducting Cuprates
124(1)
4.3 Anion-Deficient Perovskites
125(4)
4.4 Cation-Deficient Perovskites
129(3)
4.5 Hexagonal Perovskites
132(9)
References
141(14)
Chapter 5 Magnetic Properties of Perovskite Oxides
155(30)
5.1 Paramagnetic Perovskites
158(4)
5.2 Antiferromagnetic Perovskites
162(7)
5.3 Ferrimagnetic Perovskites
169(2)
5.4 Ferromagnetic Perovskites
171(2)
5.5 Spin-Glass Behavior
173(2)
5.6 Spin Canting
175(1)
5.7 Multiferroic Perovskites
176(3)
5.8 Nanomaterials and Thin Films
179(4)
References
183(2)
Chapter 6 Electronic Properties of Perovskite Oxides
185(50)
6.1 Band Structure in Perovskite Oxides
185(3)
6.2 Perovskite Insulators
188(2)
6.3 Metal-Insulator Transition in Perovskites
190(15)
6.3.1 Metal Insulator Transition by Doping and Temperature
191(7)
6.3.2 Metal-Insulator Transition under Pressure and Temperature
198(1)
6.3.3 Metal-Insulator Transition under Magnetic Field
199(1)
6.3.3.1 Colossal Magnetoresistance
199(6)
6.4 Half Metals
205(1)
6.5 Superconductivity
206(4)
6.6 Dielectric Properties
210(11)
6.6.1 Linear Dielectrics
212(1)
6.6.2 Non-linear Dielectrics
212(1)
6.6.2.1 Paraelectrics
213(1)
6.6.2.2 Ferroelectrics
214(4)
6.6.2.3 Relaxor Ferroelectrics
218(1)
6.6.2.4 Piezoelectric Properties
218(2)
6.6.2.5 Antiferroelectrics
220(1)
6.7 Thermoelectric Properties
221(3)
6.8 Magnetocaloric, Pyroelectric, and Electrocaloric Effects
224(2)
References
226(9)
Chapter 7 Diffusion, Thermal, and Optical Properties of Perovskites
235(38)
7.1 Diffusion
235(13)
7.1.1 Laws of Diffusion
235(2)
7.1.2 Ionic Conductivity
237(2)
7.1.2.1 Oxygen Conductivity
239(3)
7.1.2.2 Proton Conductivity
242(3)
7.1.2.3 Li-ion Conductivity
245(1)
7.1.2.4 Mixed Conductors
245(3)
7.2 Thermal Properties
248(8)
7.2.1 Thermal Conductivity
249(2)
7.2.2 Thermal Expansion
251(5)
7.3 Optical Properties
256(8)
7.3.1 Refraction
256(2)
7.3.2 Reflectance
258(1)
7.3.3 Absorption
258(2)
7.3.4 Luminescence
260(1)
7.3.4.1 Thermoluminescence
260(1)
7.3.4.2 Mechano and Electroluminescence (ML & EL)
260(1)
7.3.4.3 Photoluminescence
261(1)
7.3.4.4 Scintillation
262(1)
7.3.5 Transmittance
262(2)
7.4 Electro-Optical Properties
264(3)
7.4.1 Electrochromic Films
265(2)
References
267(6)
Chapter 8 Applications of Perovskite Oxides
273(64)
8.1 Biomedical Applications
274(4)
8.1.1 Biocatalysts or Enzyme Carriers
274(1)
8.1.2 Cancer Treatment
274(1)
8.1.2.1 Imaging
274(1)
8.1.2.2 Hyperthermia Therapy
274(1)
8.1.3 Orthopedic Implants
275(1)
8.1.4 Biosensors
276(1)
8.1.4.1 Hydrogen Peroxide and Glucose Sensing
276(1)
8.1.4.2 Sensing of Neurotransmitters
277(1)
8.2 Catalysis
278(17)
8.2.1 Electrocatalysis
278(1)
8.2.1.1 Hydrogen Evolution Reaction
279(2)
8.2.1.2 Oxygen Evolution Reaction (OER) and Oxygen Reduction Reaction (ORR)
281(3)
8.2.2 Photocatalysis
284(1)
8.2.2.1 Photoelectrochemical Catalysis
284(3)
8.2.2.2 Photocatalytic Dye Degradation
287(2)
8.2.3 Chemical Catalysis
289(6)
8.2.3.1 Reforming of Hydrocarbons
295(1)
8.2.3.2 Catalyst Supports
295(1)
8.3 Energy Storage and Conversion
295(21)
8.3.1 Batteries
295(1)
8.3.1.1 Lithium-Ion Batteries
295(2)
8.3.1.2 Metal-Air Batteries
297(3)
8.3.2 Supercapacitors
300(10)
8.3.3 Fuel Cells
310(1)
8.3.3.1 Perovskites Used in Proton Exchange Membrane Fuel Cell
310(1)
8.3.3.2 Perovskites Used in Solid Oxide Fuel Cells
310(4)
8.3.3.3 Perovskite-Based Catalysts for Direct Methanol Fuel Cells
314(1)
8.3.4 Photovoltaics
315(1)
8.3.5 Hydrogen Storage
316(1)
8.4 Other Applications
316(4)
8.4.1 Sensors
316(1)
8.4.1.1 Gas Sensing
317(1)
8.4.1.2 Optical Sensors
317(1)
8.4.2 Resistive Random-Access Memory (RRAM)
318(2)
References
320(17)
Appendix A1 Examples of Single Perovskites with the Structural Lattice Parameters 337(10)
Index 347
Dr. Gibin George is a Postdoctoral Fellow in the Department of Chemistry and Physics at Fayetteville State University, North Carolina. He was as an Assistant Professor in the Department of Mechanical Engineering at Jyothi Engineering College, Thrissur, India, before joining Fayetteville State University. Gibin completed his Ph.D. in 2015 from National Institute of Technology Karnataka, India. His research interest is in electrospinning, oxide nanomaterials for energy storage and production, and photoluminescence.



Dr. Sivasankara Rao Ede is a Postdoctoral Fellow in the Department of Chemistry and Physics at Fayetteville State University, North Carolina. S. R. Ede received his Ph.D. in 2018 from Central Electrohemial Research Intitute, Karaikudi, India. His research mainly focused on synthesis of perovskite oxide nanomaterials for energy conversion and energy storage.

Dr. Zhiping Luo is a Professor in Material Science in the Department of Chemistry and Physics at Fayetteville State University, North Carolina. He received a Ph.D. from Chinese Aeronautical Establishment in 1994, followed with postdoc research at Okayama University of Science, Japan. From 1998-2001, he worked at Argonne National Laboratory as a Visiting Scholar, with a promotion to Assistant Scientist; and from 2001-2012, he worked at Texas A&M University as a Research Scientist. Dr. Luo joined the current position in 2012 and established his research on the nanomaterials for energy-related applications. Dr. Luo has coauthored over 250 articles in peer-reviewed journals, and two books as a single author.
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