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E-raamat: Handbook of Nanomaterials for Hydrogen Storage [Taylor & Francis e-raamat]

Edited by (Poznan University of Technology, Poland)
  • Formaat: 322 pages, 39 Tables, black and white; 10 Line drawings, color; 59 Line drawings, black and white; 81 Halftones, black and white; 10 Illustrations, color; 140 Illustrations, black and white
  • Ilmumisaeg: 06-Nov-2017
  • Kirjastus: Pan Stanford Publishing Pte Ltd
  • ISBN-13: 9781315364445
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Handbook of Nanomaterials for Hydrogen StorageSuurem pilt
  • Formaat: 322 pages, 39 Tables, black and white; 10 Line drawings, color; 59 Line drawings, black and white; 81 Halftones, black and white; 10 Illustrations, color; 140 Illustrations, black and white
  • Ilmumisaeg: 06-Nov-2017
  • Kirjastus: Pan Stanford Publishing Pte Ltd
  • ISBN-13: 9781315364445
Teised raamatud teemal:
Taylor & Francis e-raamatudRohkem infot Taylor & Francis e-raamatute kohta
Raamatu kodulehekülg: https://www.taylorfrancis.com/books/9781315364445

Over the past years, nanoscale metallic and ceramic materials, also called nanomaterials, have attracted enormous interest from researchers. Nanomaterials demonstrate novel properties compared with conventional (microcrystalline) materials owing to their nanoscale features. Recently, the mechanical alloying method and the powder metallurgy process for the fabrication of metal/alloy-ceramic nanocomposites with a unique microstructure have been developed.

This book focuses on the fabrication of nanostructured materials and nanocomposites for hydrogen storage applications. The potential application of this research fits well to the EU Framework Programme for Research and Innovation Horizon 2020, where one of the societal challenges is secure, clean, and efficient energy. Replacement of conventional technologies by hydride technologies may also contribute to the reduction of greenhouse gas emissions. The goal of this book is to provide comprehensive and complete knowledge about materials for energy applications to graduate students and researchers in chemistry, chemical engineering, and materials science.

Preface xi
1 Introduction 1(14)
Mieczyslaw Jurczyk
1.1 Motivation
1(2)
1.2 Hydrogen
3(1)
1.3 Hydrogen Storage
4(2)
1.4 Materials Demands
6(1)
1.5 Prospects for Nanostructured Metal Hydrides
6(9)
2 Nanomaterials 15(24)
Madej Tulinski
Mieczyslaw Jurczyk
2.1 Introduction
15(1)
2.2 Different Approaches to Produce Nanomaterials
16(2)
2.3 The Structure of Nanomaterials
18(3)
2.4 Methods of Synthesizing Nanomaterials
21(13)
2.4.1 Biological Synthesis
21(1)
2.4.2 Chemical Vapor Deposition
22(1)
2.4.3 Colloidal Dispersion
23(1)
2.4.4 Epitaxial Growth
23(1)
2.4.5 Hydrothermal Synthesis
24(1)
2.4.6 Ion Beam Techniques
25(1)
2.4.7 Lithography
26(1)
2.4.8 Microemulsions
27(1)
2.4.9 Micromachining
27(1)
2.4.10 Physical Vapor Deposition
28(2)
2.4.11 Plasma Synthesis
30(1)
2.4.12 Polymer Route
31(1)
2.4.13 Pulsed Laser Deposition
31(1)
2.4.14 Severe Plastic Deformation
32(1)
2.4.15 Sol-Gel
33(1)
2.5 Summary
34(5)
3 Solid-State Hydrides 39(22)
Marek Nowak
Mieczyslaw Jurczyk
3.1 Metal Hydrides
39(1)
3.2 Intermetallic Hydrides
40(7)
3.3 Advanced Carbon Hydrides
47(1)
3.3.1 Fullerenes
47(1)
3.3.2 Carbon Nanotubes
47(1)
3.3.3 Graphene
48(1)
3.4 Complex Hydrides
48(13)
3.4.1 Alanates
49(1)
3.4.2 Nitrides and Other Systems
50(11)
4 Preparation Methods of Hydrogen Storage Materials and Nanomaterials 61(18)
Marek Nowak
Mieczyslaw Jurczyk
4.1 Introduction
61(3)
4.2 Microcrystalline Hydride Materials
64(1)
4.3 Nanotechnology for the Storage of Hydrogen
65(8)
4.3.1 Mechanical Methods
65(8)
4.4 XPS and EAS Studies
73(6)
5 X-Ray Diffraction 79(24)
Maciej Tulinski
5.1 Introduction
79(1)
5.2 Geometry of Crystals
80(5)
5.2.1 Lattices and Crystal Systems
80(2)
5.2.2 Designation of Planes
82(1)
5.2.3 Defects in Crystals
83(2)
5.3 Properties of X-Rays
85(7)
5.3.1 Electromagnetic Radiation
85(1)
5.3.2 The Continuous Spectrum
86(1)
5.3.3 The Characteristic Spectrum
87(1)
5.3.4 Production of X-Rays
88(1)
5.3.5 Detection of X-Rays
89(3)
5.4 Diffraction
92(11)
5.4.1 Bragg's Law
92(1)
5.4.2 Laue's Equations
93(2)
5.4.3 Crystallite Size
95(3)
5.4.4 X-Ray Diffraction Methods
98(5)
6 Atomic Force Microscopy in Hydrogen Storage Materials Research 103(16)
Jaroslaw Jakubowicz
6.1 Principles of the AFM Technique
103(4)
6.2 Measurement Procedure
107(2)
6.3 Hydrogen Storage Nanomaterial Imaging
109(5)
6.4 Typical Problems Observed during Nanomaterial Imaging
114(2)
6.5 Conclusion and Future Perspectives
116(3)
7 Characterization of Hydrogen Absorption/Desorption in Metal Hydrides 119(6)
Mateusz Balcerzak
7.1 What Is a Sievert-Type Apparatus
119(2)
7.2 Preparation of Material to PCT Tests
121(2)
7.3 Types of Tests That Can Be Performed Using Sievert-Type Apparatus
123(2)
8 Electrochemical Characterization of Metal Hydride Electrode Materials 125(6)
Mateusz Balcerzak
Marek Nowak
8.1 Fundamentals of Electrochemical Research
125(2)
8.2 Preparation of Materials for Electrochemical Measurements
127(1)
8.3 The Results of Electrochemical Measurements
127(4)
9 TiFe-Based Hydrogen Storage Alloys 131(18)
Marek Nowak
Mieczyslaw Jurczyk
9.1 Phase Diagram and Structure
131(2)
9.2 Ti-Fe Alloy Synthesized by Mechanical Alloying
133(5)
9.3 Electronic Structure
138(11)
10 TiNi-Based Hydrogen Storage Alloys and Compounds 149(30)
Mateusz Balcerzak
10.1 Phase Diagram and Structure
149(3)
10.2 Electrochemical and Gaseous Hydrogen Sorption Measurements
152(7)
10.2.1 Cycle-Life Curves
153(4)
10.2.2 Electrodes and Electrochemical Measurement Conditions
157(1)
10.2.3 The Influence of Temperature on Hydrogen Sorption/Desorption Properties
158(1)
10.3 Arc Melted Alloys
159(2)
10.3.1 Chemical Modification of Arc Melted Alloys
159(2)
10.3.2 Composites Containing Arc Melted Alloys
161(1)
10.4 Mechanically Alloyed Alloys
161(7)
10.5 Other Methods of Alloy Production
168(1)
10.6 Gaseous Hydrogen Sorption and Desorption of Ti-Ni Alloys
169(1)
10.7 Electrochemical and Gaseous Hydrogen Sorption and Desorption of Ti2Ni Chemically Modified by Pd and Multi-Walled Carbon Nanotubes
170(9)
11 ZrV2-Based Hydrogen Storage Alloys 179(20)
Marek Nowak
Mieczyslaw Jurczyk
11.1 Zr-V Phase Diagram and Structure
179(2)
11.2 ZrV2 Type Alloys Synthesized by Mechanical Alloying
181(3)
11.3 Electrochemical and Thermodynamic Properties
184(6)
11.4 Electronic Structure
190(2)
11.5 Zr-Based Alloys with MWCNT Addition
192(7)
12 LaNi5-Based Hydrogen Storage Alloys 199(28)
Marek Nowak
Mieczyslaw Jurczyk
12.1 Phase Diagram and Structure
199(2)
12.2 LaNis-Type Compounds
201(2)
12.3 LaNis Phase Synthesized by Mechanical Alloying
203(3)
12.4 XPS and AES Studies
206(5)
12.5 Thermodynamical Properties
211(1)
12.6 Electrochemical Properties
212(2)
12.7 Electronic Structure
214(4)
12.8 Composite LaNis-Type Materials
218(9)
13 Mg-3d-Based Hydrogen Storage Alloys 227(34)
Marek Nowak
Mieczyslaw Jurczyk
13.1 Introduction
227(1)
13.2 Mg-Ni and Mg-Cu Phase Diagrams
228(1)
13.3 Mg2Ni-Type Alloys
229(5)
13.4 Mg2Cu-Type Alloys
234(4)
13.5 Effect of Ball-Milling with Graphite and Palladium
238(2)
13.6 Amorphous 2Mg + 3d Alloys Doped by Nickel Atoms (3d = Fe, Co, Ni, Cu)
240(6)
13.7 XPS Valence Band and Segregation Effect in Nanocrystalline Mg2Ni Materials
246(6)
13.8 Mg-Based Nanocomposite Hydrides for Room Temperature Storage
252(9)
14 (La, Mg)2Ni7-Based Hydrogen Storage Alloys 261(18)
Marek Nowak
Mieczyslaw Jurczyk
14.1 Phase Diagram and Structure
261(2)
14.2 Electrochemical Properties
263(4)
14.3 (La,Mg)2Ni7-Type Alloys Synthesized by Mechanical Alloying
267(5)
14.4 RE-Mg-Ni-Based Alloy Electrodes
272(7)
15 Ni-MHx Batteries 279(24)
Mieczyslaw Jurczyk
Marek Nowak
15.1 Introduction
279(1)
15.2 The Fundamental Concept of Hydride Electrode and Ni-MHz Battery
280(2)
15.3 Electrode Materials for Ni-MHz Batteries
282(7)
15.4 Sealed Ni-MHz Batteries
289(5)
15.5 A Composite Hydrogen Storage Alloy in Application in Sealed Ni-MHz Batteries
294(1)
15.6 Major Markets for Ni-MHx Batteries
295(8)
Index 303
Mieczyslaw Jurczyk is full professor at Poznan University of Technology, Poland, since 2002 and director of the Institute of Materials Science and Engineering, Poland, since 1999. In recent years, his research activity has focused on advanced nanomaterials for hydrogen storage and advanced bionanomaterials for medical applications. Prof. Jurczyk has 7 books, 10 book chapters, 40 invited presentations, more than 350 literature articles, and more than 80 conference presentations to his credit.
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