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E-raamat: High Performance Pigments 2nd Edition [Wiley Online]

Edited by (SunChemical Corp., Cincinnati, Ohio, USA), Edited by (SunChemical Corp., Cincinnati, Ohio, USA)
  • Formaat: 538 pages
  • Ilmumisaeg: 14-Jan-2009
  • Kirjastus: Blackwell Verlag GmbH
  • ISBN-10: 3527626913
  • ISBN-13: 9783527626915
  • Wiley Online
  • Hind: 290,76 €*
  • * hind, mis tagab piiramatu üheaegsete kasutajate arvuga ligipääsu piiramatuks ajaks
  • Formaat: 538 pages
  • Ilmumisaeg: 14-Jan-2009
  • Kirjastus: Blackwell Verlag GmbH
  • ISBN-10: 3527626913
  • ISBN-13: 9783527626915
"High performance" pigments are organic and inorganic pigments that exhibit enhanced durability, most importantly in terms of resistance to visible and ultraviolet radiation, but also in terms of heat stability and chemical resistance. The editors (both of Sun Chemical Corporation) present 25 papers that provide an overview of the field. Chapters discuss bismuth vanadates, cadmium pigments, cerium pigments, complex inorganic color pigments, titanate pigments, special effect pigments, crystal design of high performance pigments, the global market for organic high performance pigments, benzimidazolone pigments and related structures, diketopyrrolopyrrole pigments, dioxazine violet pigments, disazocondensation pigments, isoindoline pigments, isoindolinone pigments, perylene pigments, phthalocyanine pigments, quinacridone pigments, quinophthalone pigments, imidazolone-anellated tryphenedioxazine pigments, chemical and physical characterization of high performance organic pigments, regulatory and legislative aspects of high performance pigments in North America and Europe, infrared reflecting complex inorganic colored pigments, and toxicology and ecotoxicology issues with high performance pigments. Annotation ©2010 Book News, Inc., Portland, OR (booknews.com)

High Performance Pigments have become increasingly important in recent years, with a growth rate well in advance of the more classical types of pigments.
This book provides up-to-date information on the market for high performance pigments, synthesis, reaction mechanisms, physical and chemical properties, applications, regulatory affairs, toxicology and ecotoxicology. It is the only one on the market covering all high performance pigments in a single volume, offering both producers and users of High Performance Pigments the opportunity to review and update their understanding of latest technologies and market issues, together with assessing key regulatory affairs, in this specialty niche of the chemical industry.
The new edition has been revised and provides an up-to-date overview of scientific and technological aspects on high performance pigments. It addresses current issues such as environmental and health aspects, and regulatory affairs.

"Anyone seeking up-to-date information about the physical-chemical principles of high performance pigments and their special technical properties will find that this book gives an excellent survey of relevant aspects." Angewandte Chemie International Edition.
"This book will effectively help chemists, physicists, engineers and material scientists to stay ahead in this fast-changing field." Osterreichische Chemie
"... Wiley-VCH has assembled an international team of high performance experts... This is an enjoyable and stimulating read and beautifully produced. You will find it fascinating - don't miss it." Colour Chemistry
Preface xix
List of Contributors
xxi
Part I
Introduction to Inorganic High Performance Pigments
3(4)
Gunter Buxbaum
Introduction
3(1)
Survey of Inorganic Pigments
4(1)
New Candidates on the Catwalk of Color
5(1)
Challenges for the Future
6(1)
Bismuth Vanadates
7(6)
Hartmut Endriss
Introduction
7(1)
Historical Background
7(1)
Manufacture
8(1)
Properties and Applications
8(2)
Chemical Properties
8(1)
Physical Properties
9(1)
Coloristic Properties
9(1)
Dispersibility
10(1)
Light Fastness and Weather Resistance
10(1)
Chemical and Solvent Resistance
10(1)
Applications
10(2)
Coatings
10(1)
Plastics
11(1)
Properties
11(1)
Applications
11(1)
Conformity of Pigments for Plastics Coloration to Food and Drug Regulations
11(1)
Toxicology
12(1)
Acute Toxicity
12(1)
Chronic Toxicity
12(1)
Ecology
12(1)
Cadmium Pigments
13(14)
Paul Dunning
Introduction
13(1)
Pigment History
13(2)
Raw Materials
15(1)
Cadmium
15(1)
Selenium
15(1)
Chemistry of Cadmium, Selenium and Cadmium Sulfide
16(1)
Cadmium
16(1)
Selenium
16(1)
Substitution in the CdS Lattice
17(1)
Method of Pigment Manufacture
17(5)
General Points
17(2)
Cadmium Oxide Formation
19(1)
Cadmium Metal Dissolution
19(1)
Other Solution Making
20(1)
Precipitation
20(1)
Filtration and Washing
21(1)
Drying
21(1)
Calcination
21(1)
Wet Milling
22(1)
Removal of Soluble Cadmium
22(1)
Final Drying and Milling
22(1)
Physical Properties
22(2)
Regulatory Issues
24(1)
Uses
25(2)
Cerium Pigments
27(14)
Jean-Noel Berte
Introduction
27(1)
Rare Earth Sulfides and the Origins of their Color
28(3)
Cerium Sulfide Pigment: Manufacture
31(3)
Properties and Applications
34(5)
Coloration of Plastics
34(4)
Paint and Coatings Application
38(1)
Miscellaneous Applications
39(1)
Toxicology and Environmental Aspects
39(1)
Toxicological and Environmental Concerns during the Manufacturing Process
40(1)
Complex Inorganic Color Pigments: An Overview
41(12)
James White
Introduction
41(1)
Structures of CICPs
42(2)
Production of CICPs
44(1)
Titanate Pigments
44(3)
Rutile Titanates
45(1)
Spinel Titanates
46(1)
Other Titanates
47(1)
Aluminate Pigments
47(1)
Cobalt Aluminates
47(1)
Cobalt Chromium Aluminates
48(1)
Chromites and Ferrites
49(1)
Black CICPs
49(1)
Brown Pigments
50(1)
Green Chromites
51(2)
Titanate Pigments: Colored Rutile, Priderite, and Pseudobrookite Structured Pigments
53(24)
John Maloney
Introduction
53(2)
History
55(3)
Doped-Rutile (DR) Pigments
57(1)
Priderite Pigments
58(1)
Pseudobrookite Pigments
58(1)
Synthesis
58(4)
DR Pigments
59(2)
Priderite Pigments
61(1)
Pseudobrookite Pigments
62(1)
Applications
62(1)
Properties
63(14)
Spectral Properties
63(1)
Visible Spectral Characterization
63(3)
UV and NIR Spectral Characterization
66(1)
Physical Properties
66(1)
Particle Size Distribution
66(1)
X-ray Diffraction Characterization
67(1)
Specific Gravity
68(1)
Oil Absorption and Specific Surface Area
69(1)
Powder Flow and Dusting
70(1)
Chemical Properties
70(1)
pH Measurement
70(1)
Weathering
71(1)
Particle Chemistry
72(5)
Part II
Special Effect Pigments
77(28)
Gerhard Pfaff
Introduction
77(1)
Pearlescent and Interference Pigments
78(18)
Optical Principles of Pearlescent and Interference Pigments
79(3)
Substrate-Free Pearlescent Pigments
82(1)
Natural Pearl Essence
82(1)
Basic Lead Carbonate
82(1)
Bismuth Oxychloride
82(1)
Micaceous Iron Oxide
83(1)
Titanium Dioxide Flakes
83(1)
Pigments Formed by Coating of Substrates
84(1)
Metal Oxide-Mica Pigments
84(6)
Silica Flake Pigments
90(4)
Alumina Flake Pigments
94(2)
Borosilicate-based Pigments
96(1)
Effect Pigments Formed by Coating of Metal Flakes
96(1)
Pigments Formed by Grinding a Film
97(1)
Pigments Based on Liquid Crystal Polymers
98(7)
Diffractive Pigments
101(1)
Pigments Based on Holography and Gratings
102(1)
Acknowledgments
103(2)
Crystal Design of High Performance Pigments
105(24)
Martin Schmidt
Introduction
105(1)
Crystal Engineering of Organic Pigments
106(7)
Close Packing
106(2)
Crystal Energy
108(1)
Specific Interactions
109(4)
Crystal Structure Determination
113(2)
Crystal Structure Calculation
115(7)
General Methods
115(1)
Crystal Structure Calculations of Pigments
116(2)
Crystallochromy
118(1)
Morphology Calculation
119(2)
Pigment Morphologies
121(1)
Control of Interfacial Properties Through Tailor-Made Additives
122(7)
Part III
129(226)
The Global Market for Organic High Performance Pigments
131(8)
Fritz Brenzikofer
Introduction
131(1)
The 1999 Market for Organic High Performance Pigments
132(1)
The Producers of High Performance Pigments
133(1)
The Demand for HPP by Consumer Market Segments
133(4)
The Demand by Regions
134(1)
The Trade Balance of HPP among these Regions
134(3)
Demand Factors for HPPs
137(1)
Market Requirements and Trends
138(1)
Industrial/Decorative Paints
138(1)
Plastics
138(1)
New Markets
138(1)
Marketing Strategies of Main HPP Producers
138(1)
Globalization Prozess
138(1)
Conclusions/Outlook
138(1)
Benzimidazolone Pigments and Related Structures
139(26)
Hans-Joachim Metz
Frank Morgenroth
Introduction
139(4)
Historical Background
143(2)
Method of Manufacture
145(1)
Typical Properties and Major Reasons for Use
146(8)
Pigment Grades, Discussion of Individual Pigments
154(4)
Pigment Manufacturers, Economics
158(6)
Safety, Health and Environmental Aspects
164(1)
Diketopyrrolopyrrole (DPP) Pigments
165(30)
Olof Wallquist
Roman Lenz
Introduction
165(1)
History
165(1)
Syntheses
166(4)
Reformatsky Route
166(2)
Succinic Ester Route
168(1)
Succinic Amide Route
169(1)
Miscellaneous Routes
169(1)
Molecular Structure and Properties
170(6)
Spectral Properties
170(2)
Spectral Properties - Fluorescence
172(2)
Single X-ray Structure Analysis
174(2)
Chemical Properties
176(4)
Electrophilic Aromatic Substitution
177(1)
Nucleophilic Aromatic Substitution
177(1)
N-Alkylation
178(1)
Transformations on the Carbonyl Group
179(1)
Solid-State Properties
180(5)
General Properties
180(1)
Particle Size Control
180(1)
Polymorphism
181(1)
Solid Solutions
182(2)
Surface Modifications
184(1)
Conventional Applications
185(5)
Nonconventional Applications
190(5)
Dioxazine Violet Pigments
195(10)
Terence Chamberlain
Introduction
195(1)
The Chemistry of Dioxazine Pigments
195(1)
Synthesis
196(6)
Dianil Formation
197(1)
Cyclization of the Dianil
197(5)
Pigmentation and Properties
202(1)
Pigment Violet 23
202(1)
Pigment Violet 37
203(1)
Recent Developments
203(2)
Preparation/Production Methods
203(1)
New Products
204(1)
Disazocondensation Pigments
205(16)
Fritz Herren
Introduction
205(1)
Historical Background
205(1)
Chemistry
206(8)
Commercialized Pigments (Past and Present [ 4])
207(5)
Recent Developments
212(2)
Synthesis and Manufacture
214(2)
Characterization, Properties, Application
216(5)
Physical Characterization
216(1)
Available Grades
216(1)
Properties and Applications
217(4)
Isoindoline Pigments
221(22)
Volker Radtke
Peter Erk
Benno Sens
Introduction
221(3)
Historical Background
224(2)
Methods of Manufacture
226(3)
Typical Properties and Major Reasons for Use
229(1)
Crystal Structures of Isoindoline Pigments
229(7)
Structure Determination
229(3)
Discussion
232(1)
ESA Data
233(3)
Pigment Grades; Discussion of Individual Pigments
236(3)
Pigment Manufacturers; Economics
239(1)
Toxicology and Ecology
240(3)
Isoindolinone Pigments
243(18)
Abul Iqbal
Fritz Herren
Olof Wallquist
Introduction
243(1)
Chemistry
244(10)
Azomethine-Type Isoindolinones
244(8)
Methine-Type Isoindolinones
252(1)
Metal Complexes Based on Isoindolinones
253(1)
Physicochemical Properties
254(3)
Commercial Products and Applications
257(4)
Perylene Pigments
261(14)
Brian Thompson
Definition of Perylene Pigments
261(2)
History
261(1)
Color Index and Identity
261(2)
Synthesis of Perylenes
263(4)
Conversion of Perylenes: Acenaphthene to Perylene Tetracarboxylic Acid Diimide (PTCI, Pigment Violet 29)
263(2)
Synthesis of Perylene Tetracarboxylic Acid Dianhydride (PTCA) by Hydrolysis of PTCI to PTCA, and PTCA as a Pigment (Pigment Red 224)
265(1)
Alkylation of PTCI to Pigment Red 179 and other Perylene Pigments
265(1)
Synthesis of Perylene Pigments and Mixed Crystals by Condensation of PTCA with Amines
266(1)
Half Imide, Half Anhydrides of PTCA (10)
266(1)
Derivatives of Perylene as Performance Enhancers
267(1)
The Conditioning of Perylene Diimide Pigments
267(1)
Mixed Crystals and Solid Solutions of Perylene Diimide Pigments
268(1)
Drying of Perylene Pigments
268(1)
Physical Chemistry and Color Physics of Perylene Pigments
269(1)
Perylene Pigments and their Applications
270(1)
Perylenes as Functional Colorants
271(1)
Current Producers
271(1)
Pricing Trends and Economics of Use
272(1)
Health, Safety, and Environmental Considerations
272(3)
Phthalocyanines - High Performance Pigments and Their Applications
275(18)
Masao Tanaka
Introduction
275(1)
Application of Optical Properties
276(6)
Color Filters for Liquid Crystal Display Devices
276(1)
Ink Jet Inks
277(2)
Infrared Ray Absorbents
279(2)
CD-R
281(1)
Application of Optoelectronic Properties
282(5)
Electrophotographic Photoreceptor
282(4)
Nonlinear Optical Devices
286(1)
Application of Catalysis
287(2)
Deodorizers
287(1)
Photodynamic Therapy
288(1)
Conclusion
289(4)
Quinacridone Pigments
293(38)
Terence R. Chamberlain
Edward E. Jaffe
Introduction
293(1)
Historical Background
293(2)
Quinacridone Syntheses
295(9)
The Synthesis of DMSS from Dimethyl Succinate
295(1)
By-Products Produced During the Synthesis and Isolation of DMSS
295(2)
Synthesis of DMSS from Diketene (Methyl 4-Chloroacetoacetate)
297(1)
Synthesis of Quinacridones by the Thermal Process
298(2)
Synthesis of Quinacridones by the PPA Process
300(3)
Synthesis of Quinacridones by Application of the Ullmann Reaction
303(1)
Recently Introduced Quinacridone Products
304(1)
Structural Data and Spectra
305(3)
Polymorphism
308(3)
Substituted Quinacridones
311(2)
Photostability and a Suggested Mechanism
313(2)
Quinacridonequinone
315(2)
Other 6,13-Disubstituted Quinacridones
317(1)
Solid Solutions
318(5)
Conditioning and Surface Treatment of Quinacridones
323(2)
Applications
325(1)
Health and Safety Factors
326(1)
Business Aspects
326(5)
Quinophthalone Pigments
331(10)
Volker Radtke
Introduction
331(2)
Historical Background
333(1)
Methods of Manufacture
334(1)
Typical Properties and Major Reasons for Use
335(1)
Pigment Grades and Discussion of Individual Pigments
336(3)
Discussion of Individual Pigments
338(1)
Pigment Manufacturers: Economics
339(1)
Toxicology and Ecology
340(1)
Imidazolone-Annellated Triphenedioxazine Pigments
341(14)
Martin U. Schmidt
Introduction
341(1)
On the Structure of Pigment Violet 23
342(2)
Imidazolone-Annellated Triphenedioxazine Pigments
344(11)
Syntheses
345(1)
Properties
346(1)
Pigment Blue 80
346(1)
Other Imidazolone-Annellated Triphenedioxazine Pigments
347(1)
Crystal Engineering on Imidazolone-Annellated Triphenedioxazine Pigments
347(1)
Structure Determination from X-Ray Powder Data
348(1)
Crystal Structures of Pigment Blue 80 and the Dimethyl Derivative (4b)
349(2)
Crystal Engineering: Pigment Violet 57
351(4)
Part IV
355(142)
Chemical and Physical Characterization of High Performance Organic Pigments
357(52)
Constantinos Nicolaou
Introduction
357(2)
Visible Spectrophotometry
359(9)
Introduction
359(3)
Applications of Visible Spectroscopy
362(1)
Copper Phthalocyanines
362(2)
Visible Spectra of Quinacridone Pigments
364(2)
Visible Spectra of Other Pigments
366(2)
Applications of FT-IR Spectroscopy
368(5)
Introduction
368(2)
Applications of Infrared Spectroscopy
370(3)
Mass Spectrometry Techniques
373(5)
Introduction
373(5)
High-Performance Liquid Chromatography
378(2)
Introduction
378(1)
HPLC Applications
378(2)
Powder X-ray Diffraction
380(10)
Introduction
380(2)
XRD Sample Preparation
382(1)
Applications of XRD
382(8)
Particle Sizing Techniques
390(14)
Introduction
390(3)
Transmission Electron Microscopy
393(1)
Sample Preparation for TEM Analysis
393(1)
Applications of TEM
394(2)
Optical Microscopy
396(1)
Introduction
396(1)
Applications of Optical Microscopy
397(1)
Particle Size by Ultracentrifugal Sedimentation and Comparison to TEM
398(1)
Introduction
398(1)
Applications of Particle Sizing by Ultracentrifugation
399(5)
Thermal Analysis and Decomposition Temperatures of HPOPs
404(3)
Product Safety and Environmental Testing of HPOPs
407(2)
Regulatory Affairs for High Performance Pigments: North America
409(22)
Harold F. Fitzpatrick
Glenn C. Merritt
Introduction
409(1)
Toxic Substances Control Act
409(2)
Canada
411(2)
Assessment of the Canadian DSL
412(1)
Mexico
413(1)
Toxic Release Inventory Reporting
414(1)
Regulation of de minimis Levels
414(1)
Food and Drug Administration
415(1)
Color Pigments in General
415(3)
PBT-TRI Rules
418(2)
Nanotechnology and Regulation
420(3)
High Production Volume (HPV) Substances
423(1)
Phthalocyanine Pigments
424(1)
Quinacridone Pigments
424(1)
Carbazole Violet Pigments
425(1)
Perylene Pigments
426(1)
Inorganic Pigments
426(2)
Complex Inorganic Color Pigments
426(1)
Cadmium Pigments
427(1)
Conclusion
428(3)
Regulatory and Legislative Aspects of Relevance to High Performance Pigments: Europe
431(36)
Eric Clarke
Herbert Motschi
Introduction
431(1)
The European Union and its Institutions
431(4)
European Commission
432(1)
European Parliament (E.P.)
433(1)
The Council of the European Union and other Institutions
434(1)
Legal Instruments
434(1)
The Major EU Directives Governing Chemical Control
435(17)
Dangerous Substances (Commission Directive 67/548/EEC)
436(1)
Some Differences between EU and US Requirements
437(1)
Notification
438(2)
Classification and Labeling
440(4)
Dangerous Preparations (E.P. and Council Directive 1999/45/EEC)
444(1)
Safety Data Sheets (Commission Directive 2001/58/EC)
444(1)
Existing Substances, Priority Lists, Risk Assessment (Council Regulation EEC 793/93)
444(1)
Restrictions of Marketing and Use
445(2)
Reach
447(1)
Pollution Control
448(1)
Packaging and Packaging Waste (E.P. and Council Directive 94/62/EC)
448(1)
Eco-Labels
448(1)
Food Packaging Legislation
449(3)
Technical Barriers to Trade
452(1)
National Regulations
452(6)
Germany
453(1)
Wassergefahrdungsklassen (Water-Hazard Classes)
453(1)
Dioxin Limits
454(1)
France
455(2)
Switzerland
457(1)
Future Enlargement of the EU (PHARE and similar programs)
458(2)
Nonregulatory Initiatives
460(2)
High Production Volume (HPV) Chemicals Testing Initiative
460(1)
Precautionary Principle
460(1)
Black-listing
461(1)
Confidentiality
462(1)
Availability of Information on Current Regulations
462(1)
Future Outlook
463(4)
Infrared Reflecting Complex Inorganic Colored Pigments
467(22)
Terry Detrie
Dan Swiler
Introduction
467(1)
Background/Physics
468(3)
Source of Infrared Light
468(1)
Heating Mechanisms
469(1)
Cooling Mechanisms
470(1)
Measurement
471(2)
ASTM E903: Integrating Sphere Spectrophotometer [ 3]
471(1)
ASTM C1549: Portable Solar Reflectometer [ 4]
471(1)
ASTM E1918: Pyranometer [ 5]
472(1)
ASTM D4803: Heat Buildup [ 6]
472(1)
Pigments
473(9)
Introduction
473(1)
Doped Rutile Titanate Yellows and Tans
473(2)
CICP Tans and Browns
475(1)
CrFe and Other CICP IR Blacks
476(3)
New Inorganic IR Black Pigments
479(1)
Blue Pigments
480(1)
Green CICP Pigments
481(1)
Formulation with IR Pigments
482(3)
Opacity
483(1)
Absorptions
484(1)
Market Driving Forces
485(2)
Studies
485(1)
Specifications on ``Cool Roof''
486(1)
Rebate Programs
486(1)
Conclusions
487(2)
Toxicology and Ecotoxicology Issues with High Performance Pigments
489(8)
Robert Mott
Hugh M. Smith
Introduction
489(1)
Recent Toxicological Testing of High Performance Pigments
489(1)
Past Confusion in Assessment of HPPs
490(3)
Confusion between Water Soluble Salts of Inorganic Metals and Related but Insoluble Pigments
490(1)
Confusion bBetween Pigments and their Associated Impurities
491(1)
False Positives in Genotoxicity Testing of Organic HPPs
491(1)
Over-Reliance on Structure Activity Relationship (SAR) Assessment of HPPs
491(1)
Confusion over Inaccurate ``PBT'' Classifications of HPPs
492(1)
Inadequacy of Recent Computer-Driven Models for Substance Profiling
492(1)
Inadequacy of Partition Coefficient Calculations in Evaluating Bioaccumulation
492(1)
Continued Polarization Between Environmental NGOs and Industry Groups
493(1)
Current Programs for Toxicological and Ecotoxicological Assessment of HPPs
493(1)
The Way Ahead
494(3)
Future Protocols for HPPs
494(1)
Implementation of the Prior Informed Consent (PIC) Treaty
494(3)
Appendix 497(6)
Index 503
Ed Faulkner has been with the Sun Chemical Corporation since 1973 and is currently Director of Product Management & Communications. He holds a degree in chemistry from Widener University and has over 30 years of experience in the color industry. Ed is an adjunct professor at the University of Cincinnati and as such teaches in the Masters Program in Cosmetic Science. In addition, he is an instructor for both the Center for Professional Advancement in New Brunswick, New Jersey, and the Society of Cosmetic Chemists: He is currently also active in the Colored Pigments Manufacturers Association (CPMA), including serving as Chairman of the Annual Conference. Ed has had numerous articles published on organic pigments.

Russell J. Schwartz is Vice President, Colors Technology, at Sun Chemical Corporation. Russell earned both his B.S. and M.S. degrees in Chemistry from the State University of New York. He started with Sun Chemical in 1981 as a Research Chemist and served as Senior Scientist, Technical Manager, Group Leader, Research Manager and Director of Research before being named Vice President, Colors Technology. Russell also directs research activities at Sun Chemical's manufacturing facilities at K?ge, Denmark, and Bushy Park, South Carolina. He has coauthored a number of technical publications and has also been issued 15 U.S. patents for his work in pigments over his career with Sun Chemical.