| Preface |
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vii | |
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1 | (47) |
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1 | (1) |
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1 | (1) |
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2 | (4) |
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6 | (2) |
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Distribution of the Molecules on the Available Energy States |
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8 | (2) |
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The Internal Energy of Polyatomic Molecules |
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10 | (2) |
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The Specific Heats and their Ratio |
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12 | (3) |
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The Molecular Velocity Distribution. Averaged Values |
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15 | (1) |
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The Mean Free Path and the Transport Coefficients |
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16 | (6) |
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Classical Dynamics of Binary Collisions |
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22 | (10) |
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32 | (4) |
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36 | (3) |
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Different Regimes of a Gas in Thermal Equilibrium |
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39 | (1) |
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On the Possibility of a Macroscopic Description of the Gas Behaviour |
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40 | (8) |
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40 | (3) |
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43 | (3) |
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46 | (2) |
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The Non-Equilibrium Equations and the Relaxation of the Internal Degrees of Freedom |
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48 | (22) |
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48 | (1) |
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The Boltzmann Transport Equation |
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48 | (2) |
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The Wang Chang-Uhlembeck and the Master Equations |
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50 | (3) |
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Energy Transfer During Collisions |
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53 | (4) |
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The Vibrational Energy Relaxation |
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57 | (7) |
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The Rotational Energy Relaxation |
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64 | (6) |
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68 | (2) |
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The Fundamental Equations of Gas Dynamics |
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70 | (40) |
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70 | (1) |
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Notes on the Fluid Motion |
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71 | (3) |
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Kinematics of a Fluid Element |
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74 | (3) |
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The Forces Acting on Fluids |
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77 | (3) |
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More on the Forces on a Fluid Element |
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80 | (3) |
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The Stress--Strain Relationship for a Viscous Fluid |
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83 | (4) |
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The Navier--Stokes Equations |
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87 | (2) |
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89 | (1) |
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The Fundamental Equations of Fluid Dynamics |
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90 | (5) |
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The Bernoulli Theorem for Compressible Fluids |
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95 | (2) |
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The Propagation of Small Disturbances through a Compressible Fluid |
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97 | (3) |
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100 | (3) |
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103 | (3) |
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106 | (4) |
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109 | (1) |
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Isoentropic Flow. Characteristic Lines |
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110 | (28) |
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110 | (1) |
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Isoentropic and Stationary Flow of a Perfect Gas |
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110 | (6) |
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Temperature and Stagnation Pressure |
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116 | (2) |
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118 | (2) |
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Propagation of Small Disturbances in a Gas in Equilibrium. Characteristic Lines |
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120 | (2) |
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The Propagation of Finite Amplitude Disturbances. Characteristic Lines |
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122 | (3) |
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Compression and Rarefaction Waves |
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125 | (4) |
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Generation of Compression and Rarefaction Waves in a Gas Inside a Tube |
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129 | (4) |
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Evolution of the Distribution of the Finite Disturbances |
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133 | (5) |
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133 | (2) |
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135 | (2) |
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137 | (1) |
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The Method of Characteristics |
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138 | (48) |
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138 | (1) |
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The Differential Equations of the Characteristics |
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139 | (4) |
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143 | (9) |
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Alternative Form of the Compatibility Equations |
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152 | (3) |
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Properties of the Characteristic Lines. Weak Discontinuities |
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155 | (1) |
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The Equations of the Planar Isoentropic Flow in the Hodograph Plane |
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156 | (6) |
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Weakly Perturbed Two-Dimensional Flow. Mach Lines |
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162 | (5) |
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The Flow Near a Curved Wall |
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167 | (9) |
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168 | (3) |
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171 | (5) |
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Reflection of Rarefaction and Compression Waves |
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176 | (6) |
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Reflection from a frictionless rigid wall |
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176 | (3) |
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Reflection from a constant pressure free boundary |
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179 | (3) |
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Intersection of Rarefaction and Compression Waves |
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182 | (4) |
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185 | (1) |
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186 | (38) |
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186 | (1) |
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Discontinuities in the Flow Fields |
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187 | (2) |
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Normal Shock. Shock Adiabatic |
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189 | (2) |
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Application to a Perfect Gas |
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191 | (2) |
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The Flow Variables Downstream of the Shock as Functions of the Upstream Mach Number |
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193 | (5) |
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198 | (4) |
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The Relationship Between the Deflection and Shock Angles |
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202 | (4) |
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206 | (3) |
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209 | (5) |
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209 | (3) |
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Pressure-deflection shock polar |
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212 | (2) |
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214 | (6) |
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Regular shock reflection from a planar rigid wall |
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214 | (2) |
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Mach reflection (M.R.) of an oblique shock |
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216 | (3) |
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Reflection of the shock from the free boundary between a moving and stagnating gas |
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219 | (1) |
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220 | (4) |
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222 | (2) |
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The Flow in Nozzles and Jets |
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224 | (27) |
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224 | (1) |
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Stationary and Isoentropic Flow in Variable Section Ducts |
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224 | (5) |
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Expressions of the Nozzle Flow Rate |
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229 | (4) |
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Effects of the Discharge Pressure Reduction |
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233 | (4) |
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Flow Regimes of a de Laval Nozzle. The Emitted Jet |
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237 | (9) |
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Flow Regimes of a Converging Nozzle. The Emitted Jet |
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246 | (5) |
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250 | (1) |
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251 | (28) |
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251 | (1) |
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The Axisymmetric Under-expanded Jet Emitted from Converging Nozzle |
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251 | (4) |
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255 | (3) |
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Variations of the Variables in the Continuous Regime |
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258 | (3) |
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Non-Equilibrium Cooling of a Monatomic Gas |
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261 | (4) |
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Non-Equilibrium Cooling of a Polyatomic Gas |
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265 | (4) |
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The Sudden Freeze Approximation |
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269 | (4) |
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Influence of the Relaxation of an Internal Degree of Freedom on the Flow Variables |
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273 | (6) |
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278 | (1) |
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Application of the Boltzmann Equation to a Jet of Monatomic Gas |
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279 | (20) |
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279 | (1) |
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Fundamental Hypotheses and the Method of Moments |
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279 | (4) |
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Calculation of the Collisional Term |
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283 | (4) |
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The Moment Equations in Reduced Forms |
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287 | (3) |
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Some Considerations about the Obtained Equations |
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290 | (2) |
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Calculation of the Parallel Speed Ratio |
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292 | (3) |
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Comparison with the Experimental Data |
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295 | (4) |
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298 | (1) |
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Characterisation of a Particle Source and Extraction of the Molecular Beam |
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299 | (19) |
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299 | (1) |
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Characterisation of a Particle Source |
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299 | (4) |
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The Virtual Source and the Non-Maxwellian Distribution of v |
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303 | (5) |
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Extraction of a Molecular Beam by a Skimmer |
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308 | (10) |
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317 | (1) |
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The Condensation in a Supersonic Free Jet |
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318 | (10) |
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318 | (1) |
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The Gas Expansion in the p-T Phase Diagram |
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319 | (1) |
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The Dimers Formation Mechanism |
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320 | (2) |
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The Dimers Formation Rate |
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322 | (6) |
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327 | (1) |
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328 | (15) |
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328 | (1) |
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The Energetic Balance in a Free Supersonic Jet |
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328 | (3) |
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328 | (1) |
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329 | (1) |
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330 | (1) |
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Mixture of two monatomic gases |
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330 | (1) |
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Mixture of a monatomic gas (carrier) with a biatomic gas (sample) |
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330 | (1) |
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331 | (6) |
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331 | (1) |
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Free jet of a binary mixture |
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332 | (5) |
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Expressions of the Molecular Beam Intensity |
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337 | (6) |
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342 | (1) |
| Appendix A.1 Different Forms of Eq. (1.2.2) |
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343 | (1) |
| Appendix A.2 Intermolecular Potential Energy |
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344 | (1) |
| Appendix A.3 Molecular Energy Levels |
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345 | (3) |
| Appendix B.1 Deduction of Eqs. (2.5.8;9;10) |
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348 | (1) |
| Appendix C.1 Deduction of Eqs. (3.9.10;13) |
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349 | (3) |
| Appendix C.2 Alternative Deduction of the Bernoulli Equation |
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352 | (1) |
| Appendix D.1 Use of the Prandtl--Meyer Function in the Method of Characteristics |
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353 | (1) |
| Appendix D.2 Planar Flow Classification |
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354 | (2) |
| Appendix D.3 Characteristic Lines and Weak Discontinuities |
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356 | (4) |
| Appendix E.1 Spherical Symmetry Source |
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360 | (2) |
| Appendix E.2 A New Determination of the Flow Field |
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362 | (4) |
| Appendix E.3 Deduction of Eqs. (8.5.1;2) |
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366 | (2) |
| Appendix F.1 Deduction of Eqs. (9.2.9;10;11;12) |
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368 | (3) |
| Appendix F.2 Deduction of Eqs. (9.3.5;6) |
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371 | (3) |
| Appendix F.3 Deduction of Eq. (9.3.14) |
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374 | (1) |
| Appendix G.1 Calculation of the Integral /1 and /2 in Eqs. (12.4.7;14) |
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375 | (4) |
| Index |
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379 | |