| Foreword |
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xi | |
| Preface |
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xiii | |
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Chapter 1 Schrodinger's Equation and its Applications |
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1 | (126) |
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1.1 Physical state and physical quantity |
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2 | (1) |
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1.1.1 Dynamic state of a particle |
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2 | (1) |
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1.1.2 Physical quantities associated with a particle |
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3 | (1) |
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1.2 Square-summable wave function |
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3 | (2) |
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1.2.1 Definition, superposition principle |
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3 | (1) |
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4 | (1) |
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5 | (6) |
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1.3.1 Definition of an operator, examples |
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5 | (1) |
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5 | (2) |
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1.3.3 Linear observable operator |
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7 | (1) |
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1.3.4 Correspondence principle, Hamiltonian |
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8 | (3) |
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1.4 Evolution of physical systems |
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11 | (4) |
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1.4.1 Time-dependent Schrodinger equation |
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11 | (1) |
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1.4.2 Stationary Schrodinger equation |
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12 | (2) |
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14 | (1) |
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1.5 Properties of Schrodinger's equation |
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15 | (4) |
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1.5.1 Determinism in the evolution of physical systems |
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15 | (1) |
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1.5.2 Superposition principle |
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15 | (1) |
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1.5.3 Probability current density |
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16 | (3) |
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1.6 Applications of Schrodinger's equation |
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19 | (26) |
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1.6.1 Infinitely deep potential well |
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19 | (5) |
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24 | (8) |
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1.6.3 Potential barrier, tunnel effect |
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32 | (7) |
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39 | (3) |
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1.6.5 Ground state energy of hydrogen-like systems |
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42 | (3) |
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45 | (20) |
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1.7.1 Exercise 1 - Probability current density |
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45 | (1) |
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1.7.2 Exercise 2 - Heisenberg's spatial uncertainty relations |
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46 | (1) |
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1.7.3 Exercise 3 - Finite-depth potential step |
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47 | (1) |
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1.7.4 Exercise 4 - Multistep potential |
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48 | (2) |
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1.7.5 Exercise 5 - Particle confined in a rectangular potential |
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50 | (1) |
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1.7.6 Exercise 6 - Square potential well: unbound states |
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51 | (1) |
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1.7.7 Exercise 7 - Square potential well: bound states |
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52 | (1) |
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1.7.8 Exercise 8 - Infinitely deep rectangular potential well |
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53 | (1) |
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1.7.9 Exercise 9 - Metal assimilated to a potential well, cold emission |
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54 | (2) |
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1.7.10 Exercise 10 - Ground state energy of the harmonic oscillator |
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56 | (1) |
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1.7.11 Exercise 11 - Quantized energy of the harmonic oscillator |
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57 | (1) |
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1.7.12 Exercise 12 - HC1 molecule assimilated to a linear oscillator |
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58 | (1) |
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1.7.13 Exercise 13 - Quantized energy of hydrogen-like systems |
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59 | (1) |
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1.7.14 Exercise 14 - Line integral of the probability current density vector, Bohr's magneton |
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60 | (2) |
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1.7.15 Exercise 15 - The Schrodinger equation in the presence of a magnetic field, Zeeman-Lorentz triplet |
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62 | (1) |
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1.7.16 Exercise 16 - Deduction of the stationary Schrodinger equation from De Broglie relation |
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63 | (2) |
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65 | (62) |
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1.8.1 Solution 1 - Probability current density |
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65 | (2) |
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1.8.2 Solution 2 - Heisenberg's spatial uncertainty relations |
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67 | (3) |
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1.8.3 Solution 3 - Finite-depth potential step |
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70 | (4) |
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1.8.4 Solution 4 - Multistep potential |
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74 | (3) |
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1.8.5 Solution 5 - Particle confined in a rectangular potential |
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77 | (4) |
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1.8.6 Solution 6 - Square potential well: unbound states |
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81 | (5) |
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1.8.7 Solution 7 - Square potential well: bound states |
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86 | (8) |
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1.8.8 Solution 8 - Infinitely deep rectangular potential well |
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94 | (5) |
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1.8.9 Solution 9 - Metal assimilated to a potential well, cold emission |
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99 | (2) |
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1.8.10 Solution 10 - Ground state energy of the harmonic oscillator |
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101 | (3) |
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1.8.11 Solution 11 - Quantized energy of the harmonic oscillator |
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104 | (4) |
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1.8.12 Solution 12 - HC1 molecule assimilated to a linear oscillator |
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108 | (4) |
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1.8.13 Solution 13 - Quantized energy of hydrogen-like systems |
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112 | (4) |
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1.8.14 Solution 14 - Line integral of the probability current density vector, Bohr's magneton |
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116 | (3) |
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1.8.15 Solution 15 - The Schrodinger equation in the presence of a magnetic field, Zeeman-Lorentz triplet |
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119 | (3) |
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1.8.16 Solution 16 - Deduction of the Schrodinger equation from De Broglie relation |
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122 | (5) |
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Chapter 2 Hermitian Operator, Dirac's Notations |
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127 | (48) |
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2.1 Orthonormal bases in the space of square-summable wave functions |
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129 | (3) |
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2.1.1 Subspace of square-summable wave functions |
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129 | (1) |
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2.1.2 Definition of discrete orthonormal bases |
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129 | (1) |
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2.1.3 Component and norm of a wave function |
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130 | (1) |
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131 | (1) |
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2.2 Space of states, Dirac's notations |
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132 | (3) |
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132 | (1) |
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2.2.2 Ket vector, bra vector |
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133 | (1) |
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2.2.3 Properties of the scalar product |
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134 | (1) |
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2.2.4 Discrete orthonormal bases, ket component |
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134 | (1) |
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135 | (6) |
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2.3.1 Linear operator, matrix element |
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135 | (1) |
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2.3.2 Projection operator on a ket and projection operator on a sub-space |
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136 | (3) |
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2.3.3 Self-adjoint operator, Hermitian conjugation |
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139 | (1) |
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140 | (1) |
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141 | (8) |
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141 | (3) |
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2.4.2 Commutation of operator functions |
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144 | (4) |
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2.4.3 Trace of an operator |
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148 | (1) |
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149 | (4) |
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2.5.1 Exercise 1 - Properties of commutators |
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149 | (1) |
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2.5.2 Exercise 2 - Trace of an operator |
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150 | (1) |
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2.5.3 Exercise 3 - Function of operators |
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150 | (1) |
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2.5.4 Exercise 4 - Infinitesimal unitary operator |
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151 | (1) |
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2.5.5 Exercise 5 - Properties of Pauli matrices |
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151 | (1) |
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2.5.6 Exercise 6 - Density operator |
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152 | (1) |
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2.5.7 Exercise 7 - Evolution operator |
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152 | (1) |
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2.5.8 Exercise 8 - Orbital angular momentum operator |
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153 | (1) |
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153 | (22) |
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2.6.1 Solution 1 - Properties of commutators |
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153 | (4) |
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2.6.2 Solution 2 - Trace of an operator |
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157 | (2) |
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2.6.3 Solution 3 - Function of operators |
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159 | (2) |
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2.6.4 Solution 4 - Infinitesimal unitary operator |
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161 | (2) |
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2.6.5 Solution 5 - Properties of Pauli matrices |
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163 | (4) |
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2.6.6 Solution 6 - Density operator |
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167 | (1) |
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2.6.7 Solution 7 - Evolution operator |
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168 | (4) |
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2.6.8 Solution 8 - Orbital angular momentum operator |
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172 | (3) |
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Chapter 3 Eigenvalues and Eigenvectors of an Observable |
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175 | (82) |
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176 | (4) |
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176 | (1) |
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3.1.2 Representation of kets and bras |
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177 | (1) |
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3.1.3 Representation of operators |
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177 | (2) |
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179 | (1) |
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3.2 Eigenvalues equation, mean value |
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180 | (9) |
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3.2.1 Definitions, degeneracy |
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180 | (3) |
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3.2.2 Characteristic equation |
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183 | (3) |
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3.2.3 Properties of eigenvectors and eigenvalues of a Hermitian operator |
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186 | (1) |
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3.2.4 Evolution of the mean value of an observable |
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187 | (2) |
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3.2.5 Complete set of commuting observables |
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189 | (1) |
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189 | (5) |
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189 | (1) |
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3.3.2 Integration of the Schrodinger equation |
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190 | (2) |
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3.3.3 Ehrenfest's theorem |
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192 | (2) |
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194 | (11) |
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3.4.1 Exercise 1 - Pauli matrices, eigenvalues and eigenvectors |
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194 | (1) |
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3.4.2 Exercise 2 - Observables associated with the spin |
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194 | (2) |
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3.4.3 Exercise 3 - Evolution of a 1/2 spin in a magnetic field: CSCO, Larmor precession |
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196 | (1) |
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3.4.4 Exercise 4 - Eigenvalue of the squared angular momentum operator |
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197 | (1) |
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3.4.5 Exercise 5 - Constant of motion, good quantum numbers |
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198 | (1) |
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3.4.6 Exercise 6 - Evolution of the mean values of the operators associated with position and linear momentum |
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198 | (1) |
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3.4.7 Exercise 7-Particle subjected to various potentials |
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199 | (1) |
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3.4.8 Exercise 8 - Oscillating molecular dipole, root mean square deviation |
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199 | (1) |
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3.4.9 Exercise 9 - Infinite potential well, time-energy uncertainty relation |
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200 | (2) |
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3.4.10 Exercise 10 - Study of a conservative system |
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202 | (1) |
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3.4.11 Exercise 11 - Evolution of the density operator |
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203 | (1) |
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3.4.12 Exercise 12 - Evolution of a 1/2 spin in a magnetic field |
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203 | (2) |
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205 | (52) |
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3.5.1 Solution 1 - Pauli matrices, eigenvalues and eigenvectors |
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205 | (3) |
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3.5.2 Solution 2 - Observables associated with the spin |
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208 | (4) |
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3.5.3 Solution 3 - Evolution of a 1/2 spin in a magnetic field: CSCO, Larmor precession |
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212 | (2) |
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3.5.4 Solution 4 - Eigenvalue of the square angular momentum operator |
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214 | (6) |
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3.5.5 Solution 5 - Constant of motion, good quantum numbers |
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220 | (1) |
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3.5.6 Solution 6 - Evolution of the mean values of the operators associated with position and linear momentum |
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221 | (5) |
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3.5.7 Solution 7 - Particle subjected to various potentials |
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226 | (2) |
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3.5.8 Solution 8 - Oscillating molecular dipole, root mean square deviation |
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228 | (5) |
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3.5.9 Solution 9 - Infinite potential well, time-energy uncertainty relation |
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233 | (9) |
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3.5.10 Solution 10 - Study of a conservative system |
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242 | (7) |
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3.5.11 Solution 11 - Evolution of the density operator |
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249 | (3) |
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3.5.12 Solution 12 - Evolution of a 1/2 spin in a magnetic field |
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252 | (5) |
| Appendix 1 |
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257 | (8) |
| Appendix 2 |
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265 | (4) |
| Appendix 3 |
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269 | (6) |
| References |
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275 | (2) |
| Index |
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277 | |