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E-raamat: Nanocarbons for Electroanalysis [Wiley Online]

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Nanocarbons for ElectroanalysisSuurem pilt
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Raamatu kodulehekülg: https://onlinelibrary.wiley.com/doi/book/10.1002/9781119243915

A comprehensive look at the most widely employed carbon-based electrode materials and the numerous electroanalytical applications associated with them.

A valuable reference for the emerging age of carbon-based electronics and electrochemistry, this book discusses diverse applications for nanocarbon materials in electrochemical sensing. It highlights the advantages and disadvantages of the different nanocarbon materials currently used for electroanalysis, covering the electrochemical sensing of small-sized molecules, such as metal ions and endocrine disrupting chemicals (EDCs), as well as large biomolecules such as DNA, RNA, enzymes and proteins.

  • A comprehensive look at state-of-the-art applications for nanocarbon materials in electrochemical sensors
  • Emphasizes the relationship between the carbon structures and surface chemistry, and electrochemical performance
  • Covers a wide array of carbon nanomaterials, including nanocarbon films, carbon nanofibers, graphene, diamond nanostructures, and carbon-dots
  • Edited by internationally renowned experts in the field with contributions from researchers at the cutting edge of nanocarbon electroanalysis

Nanocarbons for Electroanalysis is a valuable working resource for all chemists and materials scientists working on carbon based-nanomaterials and electrochemical sensors. It also belongs on the reference shelves of academic researchers and industrial scientists in the fields of nanochemistry and nanomaterials, materials chemistry, material science, electrochemistry, analytical chemistry, physical chemistry, and biochemistry.

List of Contributors
ix
Series Preface xiii
Preface xv
1 Electroanalysis with Carbon Film-based Electrodes
1(26)
Shunsuke Shiba
Tomoyuki Kamata
Dai Kato
Osamu Niwa
1.1 Introduction
1(1)
1.2 Fabrication of Carbon Film Electrodes
2(2)
1.3 Electrochemical Performance and Application of Carbon Film Electrodes
4(23)
1.3.1 Pure and Oxygen Containing Groups Terminated Carbon Film Electrodes
5(3)
1.3.2 Nitrogen Containing or Nitrogen Terminated Carbon Film Electrodes
8(3)
1.3.3 Fluorine Terminated Carbon Film Electrode
11(2)
1.3.4 Metal Nanoparticles Containing Carbon Film Electrode
13(6)
References
19(8)
2 Carbon Nanofibers for Electroanalysis
27(28)
Tianyan You
Dong Liu
Libo Li
2.1 Introduction
27(1)
2.2 Techniques for the Preparation of CNFs
28(2)
2.3 CNFs Composites
30(2)
2.3.1 NCNFs
30(2)
2.3.2 Metal nanoparticles-loaded CNFs
32(1)
2.4 Applications of CNFs for electroanalysis
32(15)
2.4.1 Technologies for electroanalysis
32(1)
2.4.2 Non-enzymatic biosensors
33(7)
2.4.3 Enzyme-based biosensors
40(4)
2.4.4 CNFs-based immunosensors
44(3)
2.5 Conclusions
47(8)
References
47(8)
3 Carbon Nanomaterials for Neuroanalytical Chemistry
55(30)
Cheng Yang
B. Jill Venton
3.1 Introduction
55(2)
3.2 Carbon Nanomaterial-based Microelectrodes and Nanoelectrodes for Neurotransmitter Detection
57(8)
3.2.1 Carbon Nanomaterial-based Electrodes Using Dip Coating/Drop Casting Methods
57(2)
3.2.2 Direct Growth of Carbon Nanomaterials on Electrode Substrates
59(2)
3.2.3 Carbon Nanotube Fiber Microelectrodes
61(1)
3.2.4 Carbon Nanoelectrodes and Carbon Nanomaterial-based Electrode Array
62(2)
3.2.5 Conclusions
64(1)
3.3 Challenges and Future Directions
65(8)
3.3.1 Correlation Between Electrochemical Performance and Carbon Nanomaterial Surface Properties
65(2)
3.3.2 Carbon Nanomaterial-based Anti-fouling Strategies for in vivo Measurements of Neurotransmitters
67(3)
3.3.3 Reusable Carbon Nanomaterial-based Electrodes
70(3)
3.4 Conclusions
73(12)
References
74(11)
4 Carbon and Graphene Dots for Electrochemical Sensing
85(34)
Ying Chen
Lingling Li
Jun-Jie Zhu
4.1 Introduction
85(1)
4.2 CDs and GDs for Electrochemical Sensors
86(15)
4.2.1 Substrate Materials in Electrochemical Sensing
86(1)
4.2.1.1 Immobilization and Modification Function
86(1)
4.2.1.2 Electrocatalysis Function
87(6)
4.2.2 Carriers for Probe Fabrication
93(2)
4.2.3 Signal Probes for Electrochemical Performance
95(1)
4.2.4 Metal Ions Sensing
96(1)
4.2.5 Small Molecule Sensing
97(3)
4.2.6 Protein Sensing
100(1)
4.2.7 DNA/RNA Sensing
101(1)
4.3 Electrochemiluminescence Sensors
101(6)
4.4 Photoelectrochemical Sensing
107(3)
4.5 Conclusions
110(9)
References
110(9)
5 Electroanalytical Applications of Graphene
119(20)
Edward P. Randviir
Craig E. Banks
5.1 Introduction
119(1)
5.2 The Birth of Graphene
120(2)
5.3 Types of Graphene
122(2)
5.4 Electroanalytical Properties of Graphene
124(8)
5.4.1 Free-standing 3D Graphene Foam
124(1)
5.4.2 Chemical Vapour Deposition and Pristine Graphene
125(2)
5.4.3 Graphene Screen-printed Electrodes
127(2)
5.4.4 Solution-based Graphene
129(3)
5.5 Future Outlook for Graphene Electroanalysis
132(7)
References
133(6)
6 Graphene/gold Nanoparticles for Electrochemical Sensing
139(34)
Sabine Szunerits
Qian Wang
Alina Vasilescu
Musen Li
Rabah Boukherroub
6.1 Introduction
139(2)
6.2 Interfacing Gold Nanoparticles with Graphene
141(5)
6.2.1 Ex-situ Au NPs Decoration of Graphene
142(1)
6.2.2 In-situ Au NPs Decoration of Graphene
143(2)
6.2.3 Electrochemical Reduction
145(1)
6.3 Electrochemical Sensors Based on Graphene/Au NPs Hybrids
146(15)
6.3.1 Detection of Neurotransmitters: Dopamine, Serotonin
146(5)
6.3.2 Ractopamine
151(1)
6.3.3 Glucose
152(1)
6.3.4 Detection of Steroids: Cholesterol, Estradiol
153(1)
6.3.5 Detection of Antibacterial Agents
154(1)
6.3.6 Detection of Explosives Such as 2, 4, 6-trinitrotoluene (TNT)
154(1)
6.3.7 Detection of NADH
154(1)
6.3.8 Detection of Hydrogen Peroxide
155(1)
6.3.9 Heavy Metal Ions
156(1)
6.3.10 Amino Acid and DNA Sensing
156(1)
6.3.11 Detection of Model Protein Biomarkers
157(4)
6.4 Conclusion
161(12)
Acknowledgement
162(1)
References
162(11)
7 Recent Advances in Electrochemical Biosensors Based on Fullerene-C60 Nano-structured Platforms
173(24)
Sanaz Pilehvar
Karolien De Wael
7.1 Introduction
173(3)
7.1.1 Basics and History of Fullerene (C60)
174(1)
7.1.2 Synthesis of Fullerene
175(1)
7.1.3 Functionalization of Fullerene
175(1)
7.2 Modification of Electrodes with Fullerenes
176(14)
7.2.1 Fullerene (C60)-DNA Hybrid
177(1)
7.2.1.1 Interaction of DNA with Fullerene
178(1)
7.2.1.2 Fullerene for DNA Biosensing
179(1)
7.2.1.3 Fullerene as an Immobilization Platform
179(4)
7.2.2 Fullerene(C60)-Antibody Hybrid
183(2)
7.2.3 Fullerene(C60)-Protein Hybrid
185(1)
7.2.3.1 Enzymes
185(3)
7.2.3.2 Redox Active Proteins
188(2)
7.3 Conclusions and Future Prospects
190(7)
References
191(6)
8 Micro- and Nano-structured Diamond in Electrochemistry: Fabrication and Application
197(30)
Fang Gao
Christoph E. Nebel
8.1 Introduction
197(1)
8.2 Fabrication Method of Diamond Nanostructures
198(11)
8.2.1 Reactive Ion Etching
198(2)
8.2.2 Templated Growth
200(4)
8.2.3 Surface Anisotropic Etching by Metal Catalyst
204(1)
8.2.4 High Temperature Surface Etching
204(2)
8.2.5 Selective Material Removal
206(1)
8.2.6 sp2-Carbon Assisted Growth of Diamond Nanostructures
207(2)
8.2.7 High Pressure High Temperature (HPHT) Methods
209(1)
8.3 Application of Diamond Nanostructures in Electrochemistry
209(9)
8.3.1 Biosensors Based on Nanostructured Diamond
209(2)
8.3.2 Energy Storage Based on Nanostructured Diamond
211(3)
8.3.3 Catalyst Based on Nanostructured Diamond
214(2)
8.3.4 Diamond Porous Membranes for Chemical/Electrochemical Separation Processes
216(2)
8.4 Summary and Outlook
218(9)
Acronyms
219(1)
References
219(8)
9 Electroanalysis with C3N4 and SiC Nanostructures
227(32)
Mandana Amiri
9.1 Introduction to g-C3N4
227(2)
9.2 Synthesis of g-C3N4
229(2)
9.3 Electrocatalytic Behavior of g-C3N4
231(2)
9.4 Electroanalysis with g-CsN4 Nanostructures
233(8)
9.4.1 Electrochemiluminescent Sensors
233(3)
9.4.2 Photo-electrochemical Detection Schemes
236(3)
9.4.3 Voltammetric Determinations
239(2)
9.5 Introduction to SiC
241(2)
9.6 Synthesis of SiC Nanostructures
243(1)
9.7 Electrochemical Behavior of SiC
244(2)
9.8 SiC Nanostructures in Electroanalysis
246(4)
9.9 Conclusion
250(9)
Acknowledgements
250(1)
References
250(9)
Index 259
Editors

Sabine Szunerits is Professor in Chemistry at the University Lille 1, France.



Rabah Boukherroub is Director of research at the CNRS, Institute of Electronics, Microelectronics and Nanotechnology, France.

Alison Downard is Professor of Chemistry at the University of Canterbury, Christchurch, New Zealand.

Jun-Jie Zhu is Professor in the School of Chemistry and Chemical Engineering at Nanjing University, Nanjing, China.
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