| Preface |
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xi | |
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1 | (42) |
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1.1 Irreversibility: The Arrow of Time |
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2 | (17) |
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3 | (4) |
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7 | (2) |
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1.1.3 Ensembles and Probability Distribution |
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9 | (2) |
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1.1.4 Entropy in Equilibrium Systems |
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11 | (3) |
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1.1.5 Fundamental Time Arrows, Units |
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14 | (3) |
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1.1.6 Example: Ideal Quantum Gases |
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17 | (2) |
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1.2 Thermodynamics of Irreversible Processes |
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19 | (24) |
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39 | |
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1.2.2 Statistical Thermodynamics with Relevant Observables |
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22 | (3) |
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1.2.3 Phenomenological Description of Irreversible Processes |
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25 | (4) |
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1.2.4 Example: Reaction Rates |
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29 | (2) |
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1.2.5 Principle of Weakening of Initial Correlations and the Method of Nonequilibrium Statistical Operator |
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31 | (7) |
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38 | (5) |
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43 | (74) |
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2.1 Stochastic Processes with Discrete Event Times |
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42 | (19) |
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2.1.1 Potentiality and Options, Chance and Probabilities |
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43 | (3) |
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2.1.2 Stochastic Processes |
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46 | (4) |
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2.1.3 Reduced Probabilities |
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50 | (4) |
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2.1.4 Properties of Probability Distributions: Examples |
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54 | (4) |
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2.1.5 Example: One-Step Process on a Discrete Space-Time Lattice and Random Walk |
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58 | (3) |
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2.2 Birth-and-Death Processes and Master Equation |
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61 | (28) |
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2.2.1 Continuous Time Limit and Master Equation |
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63 | (4) |
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2.2.2 Example: Radioactive Decay |
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67 | (2) |
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2.2.3 Spectral Density and Autocorrelation Functions |
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69 | (7) |
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2.2.4 Example: Continuum Limit of Random Walk and Wiener Process |
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76 | (2) |
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2.2.5 Further Examples for Stochastic One-Step Processes |
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78 | (6) |
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2.2.6 Advanced Example: Telegraph Equation and Poisson Process |
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84 | (5) |
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2.3 Brownian Motion and Langevin Equation |
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89 | (28) |
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89 | (5) |
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2.3.2 Solution of the Langevin Equation by Fourier Transformation |
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94 | (1) |
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2.3.3 Example Calculations for a Langevin Process on Discrete Time |
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95 | (1) |
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2.3.4 Fokker-Planck Equation |
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96 | (9) |
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2.3.5 Application to Brownian Motion |
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105 | (2) |
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2.3.6 Important Continuous Markov Processes |
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107 | (2) |
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2.3.7 Stochastic Differential Equations and White Noise |
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109 | (1) |
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2.3.8 Applications of Continuous Stochastic Processes |
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110 | (3) |
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113 | (4) |
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3 Quantum Master Equation |
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117 | (40) |
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3.1 Derivation of the Quantum Master Equation |
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119 | (19) |
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3.1.1 Open Systems Interacting with a Bath |
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119 | (5) |
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3.1.2 Derivation of the Quantum Master Equation |
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124 | (3) |
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3.1.3 Born-Markov and Rotating Wave Approximations |
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127 | (5) |
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3.1.4 Example: Harmonic Oscillator in a Bath |
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132 | (3) |
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3.1.5 Example: Atom Coupled to the Electromagnetic Field |
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135 | (3) |
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3.2 Properties of the Quantum Master Equation and Examples |
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138 | (19) |
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138 | (5) |
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3.2.2 Properties of the Pauli Equation, Examples |
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143 | (3) |
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3.2.3 Discussion of the Pauli Equation |
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146 | (2) |
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3.2.4 Example: Linear Coupling to the Bath |
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148 | (3) |
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3.2.5 Quantum Fokker-Planck Equation |
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151 | (3) |
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3.2.6 Quantum Brownian Motion and the Classical Limit |
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154 | (2) |
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156 | (1) |
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157 | (60) |
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4.1 The Boltzmann Equation |
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158 | (28) |
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4.1.1 Distribution Function |
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159 | (4) |
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4.1.2 Classical Reduced Distribution Functions |
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163 | (3) |
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4.1.3 Quantum Statistical Reduced Distribution Functions |
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166 | (3) |
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169 | (4) |
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4.1.5 Derivation of the Boltzmann Equation from the Nonequilibrium Statistical Operator |
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173 | (7) |
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4.1.6 Properties of the Boltzmann Equation |
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180 | (1) |
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4.1.7 Example: Hard Spheres |
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181 | (2) |
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4.1.8 Beyond the Boltzmann Kinetic Equation |
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183 | (3) |
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4.2 Solutions of the Boltzmann Equation |
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186 | (13) |
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4.2.1 The Linearized Boltzmann Equation |
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187 | (2) |
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4.2.2 Relaxation Time Method |
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189 | (5) |
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4.2.3 The Kohler Variational Principle |
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194 | (2) |
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4.2.4 Example: Thermal Conductivity in Gases |
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196 | (3) |
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4.3 The Vlasov-Landau Equation and Hydrodynamic Equations |
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199 | (18) |
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4.3.1 Derivation of the Vlasov Equation |
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199 | (2) |
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4.3.2 The Landau Collision Term |
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201 | (2) |
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4.3.3 Example for the Vlasov Equation: The RPA Dielectric Function |
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203 | (3) |
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4.3.4 Equations of Hydrodynamics |
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206 | (7) |
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4.3.5 General Remarks to Kinetic Equations |
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213 | (1) |
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214 | (3) |
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217 | (44) |
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5.1 Linear Response Theory and Generalized Fluctuation-Dissipation Theorem (FDT) |
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218 | (17) |
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5.1.1 External Fields and Relevant Statistical Operator |
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219 | (3) |
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5.1.2 Nonequilibrium Statistical Operator for Linear Response Theory |
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222 | (3) |
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5.1.3 Response Equations and Elimination of Lagrange Multipliers |
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225 | (1) |
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5.1.4 Example: Ziman Formula for the Conductivity and Force-Force Correlation Function |
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226 | (4) |
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5.1.5 The Choice of Relevant Observables and the Kubo Formula |
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230 | (5) |
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5.2 Generalized Linear Response Approaches |
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235 | (26) |
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5.2.1 Thermal Perturbations |
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236 | (3) |
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5.2.2 Example: Thermoelectric Effects in Plasmas |
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239 | (4) |
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5.2.3 Example: Hopping Conductivity of Localized Electrons |
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243 | (3) |
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5.2.4 Time-Dependent Perturbations |
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246 | (3) |
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5.2.5 Generalized Linear Boltzmann Equation |
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249 | (2) |
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5.2.6 Variational Approach to Transport Coefficients |
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251 | (3) |
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5.2.7 Further Results of Linear Response Theory |
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254 | (5) |
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259 | (2) |
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6 Quantum Statistical Methods |
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261 | (76) |
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6.1 Perturbation Theory for Many-Particle Systems |
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262 | (17) |
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6.1.1 Equilibrium Statistics of Quantum Gases |
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262 | (5) |
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6.1.2 Three Relations for Elementary Perturbation Expansions |
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267 | (7) |
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6.1.3 Example: Equilibrium Correlation Functions in Hartree-Fock Approximation |
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274 | (5) |
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6.2 Thermodynamic Green's Functions |
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279 | (21) |
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6.2.1 Thermodynamic Green's Functions: Definitions and Properties |
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280 | (5) |
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6.2.2 Green's Function and Spectral Function |
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285 | (4) |
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6.2.3 Example: Thermodynamic Green's Function for the Ideal Fermi Gas |
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289 | (2) |
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6.2.4 Perturbation Theory for Thermodynamic Green's Functions |
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291 | (6) |
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6.2.5 Application of the Diagram Rules: Hartree-Fock Approximation |
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297 | (3) |
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6.3 Partial Summation and Many-Particle Phenomena |
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300 | (29) |
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6.3.1 Mean-Field Approximation and Quasiparticle Concept |
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301 | (3) |
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6.3.2 Dyson Equation and Self-Energy |
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304 | (3) |
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6.3.3 Screening Equation and Polarization Function |
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307 | (5) |
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6.3.4 Lowest Order Approximation for the Polarization Function: RPA |
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312 | (2) |
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314 | (4) |
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6.3.6 Excursus: Solution to the Two-Particle Schrodinger Equation with a Separable Potential |
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318 | (6) |
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6.3.7 Cluster Decomposition and the Chemical Picture |
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324 | (5) |
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329 | (8) |
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6.4.1 The Onsager-Machlup Function |
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329 | (3) |
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6.4.2 Dirac Equation in 1 + 1 Dimensions |
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332 | (3) |
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335 | (2) |
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7 Outlook: Nonequilibrium Evolution and Stochastic Processes |
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337 | (34) |
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7.1 Stochastic Models for Quantum Evolution |
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338 | (15) |
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7.1.1 Measuring Process and Localization |
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339 | (3) |
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7.1.2 The Caldeira-Leggett Model and Quantum Brownian Motion |
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342 | (3) |
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7.1.3 Dynamical Reduction Models |
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345 | (2) |
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7.1.4 Stochastic Quantum Electrodynamics |
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347 | (2) |
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7.1.5 Quantum Dynamics and Quantum Evolution |
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349 | (4) |
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353 | (18) |
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353 | (2) |
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7.2.2 Bremsstrahlung Emission |
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355 | (4) |
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359 | (1) |
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7.2.4 The 1/f (Flicker) Noise |
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360 | (2) |
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7.2.5 The Hydrogen Atom in the Radiation Field |
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362 | (3) |
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7.2.6 Comments on Nonequilibrium Statistical Physics |
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365 | (6) |
| References |
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371 | (4) |
| Index |
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375 | |