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E-raamat: Nuclear Magnetic Resonance Studies of Interfacial Phenomena [Taylor & Francis e-raamat]

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  • Formaat: 1040 pages, 131 Tables, black and white; 784 Illustrations, black and white
  • Sari: Surfactant Science
  • Ilmumisaeg: 08-Apr-2013
  • Kirjastus: CRC Press Inc
  • ISBN-13: 9780429088292
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  • Taylor & Francis e-raamat
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  • Tavahind: 402,26 €
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Nuclear Magnetic Resonance Studies of Interfacial PhenomenaSuurem pilt
  • Formaat: 1040 pages, 131 Tables, black and white; 784 Illustrations, black and white
  • Sari: Surfactant Science
  • Ilmumisaeg: 08-Apr-2013
  • Kirjastus: CRC Press Inc
  • ISBN-13: 9780429088292
Teised raamatud teemal:
Taylor & Francis e-raamatudRohkem infot Taylor & Francis e-raamatute kohta
Raamatu kodulehekülg: https://www.taylorfrancis.com/books/9780429088292
Properties and applications of high surface area materials depend on interfacial phenomena, including diffusion, sorption, dissolution, solvation, surface reactions, catalysis, and phase transitions. Among the physicochemical methods that give useful information regarding these complex phenomena, nuclear magnetic resonance (NMR) spectroscopy is the most universal, yielding detailed structural data regarding molecules, solids, and interfaces. Nuclear Magnetic Resonance Studies of Interfacial Phenomena summarizes NMR research results collected over the past three decades for a wide range of materialsfrom nanomaterials and nanocomposites to biomaterials, cells, tissues, and seeds.

This book describes the applications of important new NMR spectroscopic methods to a variety of useful materials and compares them with results from other techniques such as adsorption, differential scanning calorimetry, thermally stimulated depolarization current, dielectric relaxation spectroscopy, infrared spectroscopy, optical microscopy, and small-angle and wide-angle x-ray scattering. The text explores the application of NMR spectroscopy to examine interfacial phenomena in objects of increasing complexity, beginning with unmodified and modified silica materials. It then describes properties of various mixed oxides with comparisons to individual oxides and also describes carbon materials such as graphite and carbon nanotubes.

Chapters deal with carbonmineral hybrids and their mosaic surface structures, and interfacial phenomena at the surface of natural and synthetics polymers. They also explore a variety of biosystems, which are much more complex, including biomacromolecules (proteins, DNA, and lipids), cells and tissues, and seeds and herbs. The authors cover trends in interfacial phenomena investigations, and the final chapter describes NMR and other methods used in the book. This text presents a comprehensive description of a large array of hard and soft materials, allowing the analysis of the structureproperty relationships and generalities on the interfacial behavior of materials and adsorbates.
Glossary of Abbreviations xiii
Preface xxiii
Authors xxv
Introduction xxvii
Chapter 1 Unmodified and Modified Silicas
1(338)
1.1 Interfacial Phenomena at a Surface of Nanosilica
1(251)
1.1.1 Structural and Adsorptive Characteristics of Nanosilicas
1(14)
1.1.2 Adsorption of Water onto Nanosilica Dispersed in Gases and Organic Liquids
15(32)
1.1.3 Adsorption of CH4 in the Presence of Preadsorbed Water
47(15)
1.1.4 Competitive Adsorption of Water and Low-Molecular-Weight Organics
62(13)
1.1.5 Adsorption of Ice Nucleators
75(31)
1.1.6 Aqueous Suspensions
106(20)
1.1.7 Adsorption of Dissolved Compounds
126(21)
1.1.8 Effects of Surface Modification on Adsorption Phenomena
147(23)
1.1.9 Mixtures of Hydrophilic and Hydrophobic Silicas
170(8)
1.1.10 Adsorption of Low- and High-Molecular Organic Compounds
178(22)
1.1.11 Influences of Thermal, Hydrothermal, and Mechanical Treatments
200(27)
1.1.12 Cryoporometry and Relaxometry
227(8)
1.1.13 Comparison of NMR, DSC, TSDC, Adsorption Data, and Quantum Chemical Models
235(17)
1.2 Silica Gels, Aerogels, Silochrome, and Poly(methylsiloxane): Structural, Interfacial and Adsorption Characteristics, and Structure-Property Relationships
252(44)
1.3 Interfacial Phenomena at Surfaces of Structurally Ordered Silicas
296(33)
1.4 Thin Films and Other Moieties on Silica Supports
329(10)
Chapter 2 Interfacial Phenomena at Surfaces of Mixed Oxides
339(116)
2.1 Mixed Nanooxides
339(79)
2.1.1 Surface Structure of Nanoparticles
342(10)
2.1.2 Morphology, Structural Hierarchy, and Textural Characteristics of Powders
352(17)
2.1.3 Effects of Dispersion Media: Gaseous Phase and Aqueous Suspensions
369(7)
2.1.4 Adsorption Phenomena
376(42)
2.2 Porous Oxides as a Function of Morphology
418(11)
2.3 Structurally Ordered Oxides
429(3)
2.4 Nanocrystalline and Microcrystalline Materials
432(4)
2.5 Clays, Zeolites, and Other Natural Minerals
436(19)
2.5.1 Silicalite
436(6)
2.5.2 Influence of Al Content on Hydration of Zeolites of a ZSM-5 Type in Aqueous Suspension
442(3)
2.5.3 Zeolites and Other Aluminosilicates
445(10)
Chapter 3 Interfacial Phenomena at Surfaces of Carbon Materials
455(68)
3.1 Texture of Carbonaceous Materials and Chemical Shift of Adsorbed Molecules
457(6)
3.1.1 Graphitized Materials
458(1)
3.1.2 Nongraphitized Carbonaceous Materials
459(1)
3.1.3 Polar Sites on a Carbon Surface
460(2)
3.1.4 Peculiarities of NMR Spectroscopy for Molecules Adsorbed on Carbon Surface
462(1)
3.2 Activated Carbons
463(43)
3.2.1 ACs Obtained from Natural Precursors
464(13)
3.2.2 ACs Obtained from Synthetic Precursors
477(1)
3.2.2.1 Location of Adsorbates in Porous Media
477(12)
3.2.2.2 Effect of Weakly Polar Organics on Adsorbate Localization in Pores of ACs
489(17)
3.3 Graphitized Carbons and Graphite
506(13)
3.3.1 Exfoliated Graphite
506(3)
3.3.2 Oxidized Graphite and Graphene
509(4)
3.3.3 Intercalated Graphite
513(2)
3.3.4 Partly Graphitized AC
515(4)
3.4 Carbon Nanotubes
519(4)
Chapter 4 Interfacial Phenomena at Carbon-Mineral Composites
523(56)
4.1 Carbon Blacks
524(2)
4.2 Carbonized Silicas and Mixed Oxides
526(53)
4.2.1 Structure of Adsorption Sites on CS Composed of Nonporous Nanoparticles
543(3)
4.2.2 Ordered Layers of Water at a Surface of CS Composed of Nonporous Nanoparticles
546(3)
4.2.3 Influence of the Degree of Carbonization on Hydration Parameters of Modified Porous Silica
549(9)
4.2.4 CS Modified with Zinc, Titanium, and Zirconium Oxides
558(21)
Chapter 5 Interfacial Phenomena at Polymer Surfaces
579(80)
5.1 Natural Polymers: Cellulose, Starch, Chitosan, Hyaluronic Acid, and Others
579(21)
5.2 Synthetic Polymers
600(19)
5.2.1 Structural Features of Polymer Adsorbent LiChrolut EN and Interfacial Behavior of Water and Water-Organic Mixtures
607(12)
5.3 Hydrogels and Cryogels
619(21)
5.4 Polymer-Nanooxide Systems
640(8)
5.5 Polymers in Confined Space of Pores
648(11)
Chapter 6 Interactions of Biomacromolecules with Water, Organic Compounds, and Oxides, Polymers, and Carbon Adsorbents
659(118)
6.1 Proteins
659(21)
6.2 Proteins in Adsorbed State
680(70)
6.2.1 Interactions of Proteins with Oxides
680(53)
6.2.2 Interactions of Proteins with Carbon Materials
733(7)
6.2.3 Interactions of Proteins with Polymers
740(10)
6.3 DNA
750(22)
6.4 Lipids
772(5)
Chapter 7 Water Associated with Bio-Objects: Cells and Tissues
777(100)
7.1 Yeast Saccharomyces cerevisiae Cells
777(34)
7.1.1 Water Bound in Weakly and Strongly Hydrated Yeast S. cerevisiae Cells
780(10)
7.1.2 Structural and Energetic Differentiation of Water in Partially Dried Yeast Cells Affected by Organic Solvents
790(9)
7.1.3 Effect of Disperse Silica on Bound Water in Frozen Cellular Suspensions
799(6)
7.1.4 Effects of Nanosilica on Phase Equilibrium in Aqueous Suspensions of Yeast Cells and Gelatin
805(2)
7.1.5 Influence of Highly Disperse Materials on Physiological Activity of Yeast Cells
807(4)
7.2 Intracellular Water in Partially Dehydrated Bone Marrow Cells
811(9)
7.3 Freeze-Dried Bovine Gametes with Organic Additives
820(4)
7.4 Red Blood Cells
824(12)
7.5 Bone Tissue
836(24)
7.5.1 WAW and SAW Bound in Bone Tissue
836(5)
7.5.2 Characteristics of Water Bound in Human Bone Tissues Healthy and Affected by Osteoporosis
841(6)
7.5.3 Self-Organization of Water-Organic Systems in Bone Tissue and Products of Its Chemical Degradation
847(8)
7.5.4 Bone Tissue Models
855(5)
7.6 Muscular Tissues
860(9)
7.6.1 Chicken Muscular Tissue
860(5)
7.6.2 Effect of Dispersed Silica on Hydration of Forcemeat
865(2)
7.6.3 Pork Meat and Fat
867(2)
7.7 Intracellular Water and Cryopreservation
869(8)
7.7.1 Water-DMSO Mixtures
869(3)
7.7.2 Clusterization of Water in Ternary Systems with DMSO or Acetonitrile and Chloroform
872(5)
Chapter 8 Interaction of Seeds, Herbs, and Related Materials with Water and Nanooxides
877(32)
Chapter 9 Recurring Trends in Adsorption, Spectroscopy, and Other Interfacial Experiments
909(6)
Chapter 10 Methods
915(35)
10.1 Low-Temperature 1H NMR Spectroscopy
915(12)
10.2 Low-Temperature Nitrogen Adsorption
927(5)
10.3 Adsorption of Water and Organics
932(2)
10.4 Polymer and Protein Adsorption
934(1)
10.5 Infrared Spectroscopy
934(1)
10.6 Thermogravimetry
935(1)
10.7 Differential Scanning Calorimetry
935(1)
10.8 Auger Electron Spectroscopy
935(1)
10.9 Temperature-Programmed Desorption with Mass-Spectrometry Control
936(1)
10.10 Thermally Stimulated Depolarization Current
937(2)
10.11 Dielectric Relaxation Spectroscopy
939(1)
10.12 Ultraviolet-Visible Spectroscopy
940(1)
10.13 Rheometry
941(1)
10.14 Potentiometric Titration
942(1)
10.15 Photon Correlation Spectroscopy
942(2)
10.16 Adsorption of Metal Ions
944(1)
10.17 X-Ray Diffraction
944(1)
10.18 Raman Spectroscopy
945(1)
10.19 AFM, SEM, and TEM
945(1)
10.20 Quantum Chemistry
946(2)
10.21 Conclusions
948(2)
Acknowledgments 950(1)
References 951(54)
Index 1005
Vladimir M. Gunko, DSc, is a professor and head of the Department of Amorphous and Structurally Ordered Oxides, Chuiko Institute of Surface Chemistry of the National Academy of Sciences of Ukraine. He has coauthored 3 books, edited 1 book, published about 400 papers, and made about 200 presentations at conferences. He also serves on the editorial board of four journals and Surface, a periodic book published one to two times per year. He is a member of the American Nano Society (USA) and an electronic member of The Royal Society of Chemistry (UK). Gunkos research interests include quantum and molecular mechanics and dynamics, development of computational algorithms in molecular physics and surface chemistry, modeling of interfacial phenomena, and synthesis and characterization of nanomaterials.

Vladimir V. Turov, DSc, is a professor and head of the Department of Biomedical Problems of Surface, Chuiko Institute of Surface Chemistry of the National Academy of Sciences of Ukraine. He has coauthored 3 books, edited 1 book, published about 250 papers, and has presented at about 100 conferences. He serves on the editorial board of the journal Chemistry, Physics & Technology of Surface and the periodic book Surface, published one to two times per year. He has been a member of the Society of Chemistry of Ukraine since 1986. Turovs research interests include molecular interactions in confined space, low-temperature NMR spectroscopy of porous nanomaterials and bio-objects, and water structure in complex mixtures.
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