An introduction to organosilicon chemistry, focusing on applications in materials and polymer science, written by experts from industry and academia. Owing to its interdisciplinary approach this work should be of interest to industrial, organometallic, inorganic, materials and polymer chemists.
Part 1 Tetravalent Organosilicon Compounds: Chemistry and Structure:
Introduction, N. Auner, J. Weis; structures of small silicon containing
compounds - why and how?, D.W.H. Rankin; sterically overcrowded organosilicon
compounds and their properties, H. Bock, J. Meuret, et al; synthesis of
functionally substituted oligosilanes based on silyltriflate derivatives, W.
Uhlig; electroreductive formation of Di- and polysilanes, E. Hengge, Ch.
Jammegg; linear tetrasilanes with internal substituents: oligosilanes with
optical activity, H. Stuger; a new way to Si-Ge and Si-Sn bonds -
hexachlorodisilane cleavage of organometal phosphanes, R. Martens, W.W. du
Mont; 29Si29Si coupling constants of bromo-and iododisilanes and -trisilanes
- XnSi2H6n and XnSi3H8n (X = Br,1), U. Katzenbeisser, K. Hassler; calculation
of the 29Si NMR chemical shifts in molecules with SiN, SiCl, and SiSi Bonds,
R. Wolff, R. Radeglia; reactivity of very electron-rich organosilyl amines,
W. Kaim, A. Lichtblau, et al; lithiated aminofluorosilanes as precursors for
monometic and dimeric iminosilanes, K. Dippel, U. Klingebiel, et al;
fluorofunctional silylamines and -hydrazines - precursors for (Si-N) ring
systems, C. Drost, I. Hemme, et al; new approaches to (fluoromethyl) silanes,
H. Burger, P. Moritz; homo- and heterocyclic Si-O systems - rings and cages,
U. Klingebiel; silaheterocycles from intramolecular reactions of
silicon-functionalized diazoacetic esters, F. Krebs, S. Bender, et al;
synthesis and reaction behaviour of organoalkoxysilylphenols, E.
Nietzschmann, O. Boge, et al; n-silylation: new possibilities for long-known
amines, K. Paulini, H. -U Reibig; on the acid-catalyzed reaction of siloxanes
with alcohols, H. Kelling, D. Lange, et al; on the reactivity of
chlorosiloxanes, K. Kappler, U. Scheim, et al; chlorosilanols - more stable
than you think - shown with 29Si NMR, R. Lehnert; diorganosilyl-bis
(o-alkylphosphonates), K. Kellner, L. Rodewald. Part 2 Subvalent and
unsaturated organosilicon compounds - formation and reactivity: introduction,
N. Auner, J. Weis; basic principles of the theory of bonding in silicon
compounds, R. Janoschek; expectations from an unusual compound - the
chemistry of decamethylsilicocene, P. Jutzi; Cp2Si (CO) and Cp2Si(N2):
complexes of decamethylsilicocene, M. Tacke, Ch. Klein, et al; silicon and
phosphinomethanides - a novel entry to hypervalent and low valent
organosilicon chemistry, H.H. Karsch. Part contents.
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