Muutke küpsiste eelistusi

E-raamat: Principles and Advances in Supramolecular Catalysis [Taylor & Francis e-raamat]

  • Formaat: 226 pages, 6 Tables, black and white; 20 Illustrations, color; 219 Illustrations, black and white
  • Ilmumisaeg: 03-Apr-2019
  • Kirjastus: CRC Press
  • ISBN-13: 9780429059063
Teised raamatud teemal:
  • Taylor & Francis e-raamat
  • Hind: 230,81 €*
  • * hind, mis tagab piiramatu üheaegsete kasutajate arvuga ligipääsu piiramatuks ajaks
  • Tavahind: 329,73 €
  • Säästad 30%
Principles and Advances in Supramolecular CatalysisSuurem pilt
  • Formaat: 226 pages, 6 Tables, black and white; 20 Illustrations, color; 219 Illustrations, black and white
  • Ilmumisaeg: 03-Apr-2019
  • Kirjastus: CRC Press
  • ISBN-13: 9780429059063
Teised raamatud teemal:
Taylor & Francis e-raamatudRohkem infot Taylor & Francis e-raamatute kohta
Raamatu kodulehekülg: https://www.taylorfrancis.com/books/9780429059063
Supramolecular catalysis is involved in assimilation or growth of biological products and it has advantages over conventional catalysis in dealing with systems beyond molecules to mimic the biological catalytic processes. Principles and Advances in Supramolecular Catalysis shows how a supramolecular catalytic reaction proceeds and how interactions among molecules provide vessels or specific binding sites to carry out chemical reactions. The utilities of such catalytic reactions in waste, hazard management, medicine, food, etc. are explained in this book. The book focuses on examples to provide a fundamental basis so that, in the future, supramolecular catalytic reactions are utilised in the field of chemical, biological, biophysical sciences and technologies.

Features:











Discusses fundamental and interdisciplinary aspects of supramolecular catalysis





Narrates mechano-chemical and stimuli-guided supramolecular catalytic reactions





Divulges the intriguing aspects of self-replications and self-assembling performed through supramolecular catalysis





Incorporates supramolecular catalytic reactions of metal-organic frameworks as artificial metalloenzymes
Preface vii
Acknowledgments ix
Author xi
Chapter 1 Introduction
1(40)
1.1 Definition and Approaches
1(1)
1.2 What Biology Tells Us about Catalysis: Specific Cases
2(10)
1.3 Complementary Weak Interactions and Molecular Recognition
12(7)
1.4 Self-Assembly of Multicomponents Suitable for Catalytic Reactions
19(6)
1.5 Energetic Aspects of Supramolecular Catalysis
25(9)
1.6 Advantages of Supramolecular Catalysis
34(4)
References
38(3)
Chapter 2 Organic and Inorganic Supramolecular Catalysts: Design and Function
41(80)
2.1 Salient Features of Supramolecular Catalysis
41(28)
2.1.1 Fundamental Basis
42(12)
2.1.2 Intermediate Characterization
54(8)
2.1.3 Product Selectivity Including Stereo Specificity
62(7)
2.2 Inorganic Supramolecular Catalysis
69(29)
2.2.1 Design of Mononuclear Inorganic Complexes for Supramolecular Catalysis
74(8)
2.2.2 Polynuclear Inorganic Complexes as Supramolecular Catalyst
82(8)
2.2.3 Metal Organic Frameworks and Coordination Polymers
90(8)
2.3 Artificial Enzymes
98(13)
2.3.1 Biomimetic Metal Organic Frameworks
106(5)
2.4 Applied Organocatalytic Reactions Taking Advantage of Supramolecular Features
111(4)
References
115(6)
Chapter 3 Containers and Vessels for Supramolecular Catalysis
121(38)
3.1 Container Molecules
121(15)
3.1.1 Cages and Containers for Supramolecular Catalysis
127(2)
3.1.2 Noncovalently Linked Cages for Supramolecular Catalysis
129(1)
3.1.3 Cavitands for Supramolecular Catalysis
130(3)
3.1.4 Foldamers for Supramolecular Catalysis
133(3)
3.2 Inorganic Container Molecules
136(20)
3.2.1 Polydentate Ligands and Metal Coordination
138(3)
3.2.2 Inorganic Container Molecules from Mono- and Dinuclear Complexes
141(3)
3.2.3 Molecular Flasks
144(2)
3.2.4 Inorganic Cages for Supramolecular Catalysis
146(7)
3.2.5 Confining Inorganic Active Sites
153(3)
References
156(3)
Chapter 4 Interlocked Systems in Catalysis and Switching
159(24)
4.1 Principles of Dynamic Interlocked Systems in Catalysis
159(12)
4.1.1 Dynamic Aspects of Concealing and Revealing Catalytic Sites
165(3)
4.1.2 Utility of Interlocked Systems in Supramolecular Catalysis
168(1)
4.1.3 Metallacycles in Catalysis
168(3)
4.2 Control of Catalytic Activity by Switching
171(9)
4.2.1 Chemical Switching
175(1)
4.2.2 Electrochemical and Photochemical Switching
176(1)
4.2.3 Stimulus-Guided Switching
177(3)
References
180(3)
Chapter 5 Dendrimers in Supramolecular Catalysis
183(24)
5.1 Principles and Definitions
183(1)
5.2 Convergent and Divergent Approaches for Dendrimers
183(1)
5.3 Modification of Interior and Exterior of Dendrimers
184(11)
5.4 Micelles in Supramolecular Catalysis
195(3)
5.5 Gels and Ionic Liquids as Catalysts
198(5)
References
203(4)
Chapter 6 Versatility in Supramolecular Catalysis
207(16)
6.1 Material Design and Processes
207(1)
6.1.1 Biomaterials
207(1)
6.2 Confinement of Nanoparticles as Catalysts
207(2)
6.3 Supramolecular Catalyst Immobilisation
209(2)
6.4 Supramolecular Autocatalysis
211(5)
6.5 Sensing through Supramolecular Catalysis
216(2)
6.6 Modified Biomolecules as Catalysts
218(1)
6.7 Conclusion and Outlook
219(1)
References
220(3)
Index 223
Jubaraj Bikash Baruah hails from Assam, India obtained Ph. D. degree from Indian Institute of Science, Bangalore from research under the supervision of Prof. A. G. Samuelson. After Ph.D. he did a postdoctoral study under Prof. Kohtaro Osakada and Prof. Takakazu Yamamoto of Tokyo Institute of Technology, Japan. He served Gauhati University as a lecturer before moving to Indian Institute of Technology, Guwahati. He was the founder member of Department of Chemistry of Indian Institute of Technology Guwahati where he is serving as a senior professor. He served as founder Head in-charge of Chemistry, Head of Chemistry Department and Dean, Research and Development of Indian Institute of Technology, Guwahati. His major research interest is on novel properties associated with supramolecular systems. He has published over 250 research articles in reputed journals and written two books.
Püsilink: https://www.kriso.ee/db/9780429059063_pe.html
Märksõnad: