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E-raamat: Superconductivity and Magnetism in Skutterudites [Taylor & Francis e-raamat]

(University of Michigan, Ann Arbor, USA)
  • Formaat: 298 pages, 20 Tables, black and white; 123 Line drawings, color; 82 Line drawings, black and white; 1 Halftones, color; 124 Illustrations, color; 82 Illustrations, black and white
  • Ilmumisaeg: 14-Jan-2022
  • Kirjastus: CRC Press
  • ISBN-13: 9781003225898
  • Taylor & Francis e-raamat
  • Hind: 267,74 €*
  • * hind, mis tagab piiramatu üheaegsete kasutajate arvuga ligipääsu piiramatuks ajaks
  • Tavahind: 382,48 €
  • Säästad 30%
  • Formaat: 298 pages, 20 Tables, black and white; 123 Line drawings, color; 82 Line drawings, black and white; 1 Halftones, color; 124 Illustrations, color; 82 Illustrations, black and white
  • Ilmumisaeg: 14-Jan-2022
  • Kirjastus: CRC Press
  • ISBN-13: 9781003225898
"Superconductivity and Magnetism in Skutterudites discusses superconducting and magnetic properties of a class of materials called skutterudites. With a brief introduction of the fundamental structural features of skutterudites, the book then provides a detailed assessment of the superconducting and magnetic properties, focusing particularly on the rare earth-filled skutterudites where a plethora of fascinating properties and ground states is realized due to interactions of the filler species with the framework ions. Such interactions underpin the exciting forms of superconductivity and magnetism, most notably realized in the exotic heavy fermion superconductor of composition PrOs4Sb12. The two main topics of superconductivity and magnetism are provided with a concise introduction of superconducting and magnetic properties so that a reader can appreciate and understand the main arguments in the text. This book would appeal to graduate students, postdoctoral students, and anyone interested in superconducting and magnetic properties of a large family of minerals called skutterudites. Key Features: Gives a thorough account of the superconducting and magnetic properties of skutterudites. Each topic is accompanied by introductory sections to assist in the understanding of the text. Supported by numerous figures and all key references"--

Superconductivity and Magnetism in Skutterudites discusses superconducting and magnetic properties of a class of materials called skutterudites.

Preface xi
About the Author xiii
Chapter 1 Brief Review of the Structure and Electronic Bands in Skutterudites
1(12)
1.1 Introduction
1(1)
1.2 Binary Skutterudites
2(2)
1.3 Ternary Skutterudites
4(1)
1.4 Filled Skutterudites
5(4)
1.4.1 Filled Skutterudites with the [ M4X12] Framework
6(1)
1.4.2 Filled Skutterudites with the [ T4XI2]4 - Framework
6(1)
1.4.3 Filled Skutterudites with the [ Pt4Ge12] Framework
7(1)
1.4.4 Filled Skutterudites with Electronegative Fillers
8(1)
References
9(4)
Chapter 2 Superconducting Skutterudites
13(100)
2.1 Introduction
13(2)
2.2 Useful Relations for Superconducting Parameters
15(4)
2.3 La-Filled Superconducting Skutterudites
19(9)
2.4 Superconductivity of PrOs4Sb12
28(32)
2.4.1 Crystalline Electric Field in PrOs4Sb12
28(1)
2.4.2 Specific Heat of PrOs4Sb12
29(4)
2.4.3 Nuclear Quadrupole Resonance in PrOs4Sb12
33(2)
2.4.4 High Field-Ordered Phase (HFOP) in PrOs4Sb12
35(3)
2.4.5 Magneto-Thermal Conductivity of PrOs4Sb12
38(6)
2.4.6 Breakdown of TRS in PrOs4Sb12
44(3)
2.4.7 Fermi Surface of PrOs4Sb12
47(2)
2.4.8 Point-Contact Spectroscopy
49(1)
2.4.9 Superconducting Solid Solutions of Pr(Os1-xRux)Sb12
50(3)
2.4.10 Superconducting Solid Solutions of (Pr1-xLax)Os4Sb12
53(2)
2.4.11 Superconducting Solid Solutions of (Pr1-xNdx)Os4Sb12
55(2)
2.4.12 Other Pr-Filled Skutterudite Superconductors
57(1)
2.4.12.1 PrRu4Sb12
57(2)
2.4.12.2 PrRu4As12
59(1)
2.5 YT4P12, (T = Fe, Ru, and Os) Superconductors
60(3)
2.5.1 YFe4P12
60(1)
2.5.2 YOs4P12 and YRu4P12
61(2)
2.6 Superconductors with the [ Pt4Ge12] Framework
63(30)
2.6.1 Alkaline-Earth-Filled BaPt4Ge12 and SrPt4Ge12 Superconductors
63(4)
2.6.2 Actinide-Filled ThPt4Ge12 Superconductor
67(1)
2.6.3 Rare-Earth-Filled [ Pt4Ge12]-Based Superconductors
67(24)
2.6.4 Effect of Pressure on Platinum Germanide Superconductors
91(2)
2.7 Critical Current Density of Superconductors
93(8)
2.7.1 Fields and Currents Inside Type-I Superconductors
93(1)
2.7.2 Critical State Model of Bean
94(7)
2.8 Concluding Remarks
101(5)
References
106(7)
Chapter 3 Magnetic Properties of Skutterudites
113(182)
3.1 Introduction
113(24)
3.1.1 Diamagnetism
115(1)
3.1.2 Paramagnetism of Localized Magnetic Moments and Curie Law
116(5)
3.1.3 Paramagnetism in Metals and Pauli Susceptibility
121(2)
3.1.4 Magnetically Ordered Structures
123(2)
3.1.4.1 Weiss Molecular Field Model and Mean Field Theory
125(1)
3.1.4.1.1 The Case of a Ferromagnet
126(4)
3.1.4.1.2 The Case of an Antiferromagnet
130(2)
3.1.4.1.3 The Case of a Ferrimagnet
132(1)
3.1.4.2 Magnetic Excitations and Spin Waves
133(1)
3.1.4.3 Magnetic Anisotropy
134(1)
3.1.4.4 Effect of Crystalline Electric Field (CEF)
135(2)
3.2 Techniques of Measuring Magnetic Properties
137(5)
3.2.1 Measurements of Magnetic Moments and Magnetic Susceptibility
137(2)
3.2.2 Mossbauer Spectroscopy
139(1)
3.2.3 Neutron Spectroscopy
140(2)
3.3 Magnetic Properties of Skutterudites
142(138)
3.3.1 Mossbauer Studies of Skutterudites
142(11)
3.3.2 Magnetic Susceptibility of Binary Skutterudites
153(4)
3.3.3 Magnetic Properties of Partially Filled CoSb3
157(1)
3.3.4 Magnetic Properties of Filled Skutterudites with the [ T4X12] Framework
158(5)
3.3.4.1 Lanthanum-Filled Skutterudites
163(2)
3.3.4.2 Ce-Filled Skutterudites
165(14)
3.3.4.3 Pr-Filled Skutterudites
179(1)
3.3.4.3.1 Pr-Filled Phosphides
179(8)
3.3.4.3.2 Pr-Filled Arsenides
187(4)
3.3.4.3.3 Pr-Filled Antimonides
191(3)
3.3.4.4 Nd-Filled Skutterudites
194(1)
3.3.4.4.1 Nd-Filled Phosphides
194(3)
3.3.4.4.2 Nd-Filled Arsenides
197(3)
3.3.4.4.3 Nd-Filled Antimonides
200(7)
3.3.4.5 Sm-Filled Skutterudites
207(1)
3.3.4.5.1 Sm-Filled Phosphides
207(11)
3.3.4.5.2 Sm-Filled Arsenides
218(1)
3.3.4.5.3 Sm-Filled Antimonides
219(9)
3.3.4.6 Eu-Filled Skutterudites
228(1)
3.3.4.6.1 Eu-Filled Phosphides
228(1)
3.3.4.6.2 Eu-Filled Arsenides
229(3)
3.3.4.6.3 Eu-Filled Antimonides
232(4)
3.3.4.7 Yb-Filled Skutterudites
236(1)
3.3.4.7.1 Yb-Filled Phosphides
236(1)
3.3.4.7.2 Yb-Filled Arsenides
237(1)
3.3.4.7.3 Yb-Filled Antimonides
237(6)
3.3.4.8 Gd-Filled Skutterudites
243(3)
3.3.4.9 Heavy Lanthanide-Filled Skutterudites
246(4)
3.3.4.10 Yttrium-Filled Skutterudites
250(1)
3.3.4.11 Alkali Metal-Filled Skutterudites and T1-Filled Skutterudites
250(4)
3.3.4.12 Skutterudites Filled with Alkaline-Earth Metals
254(7)
3.3.4.13 Skutterudites Filled with Actinide Elements
261(1)
3.3.4.13.1 Th-Filled Skutterudites
261(2)
3.3.4.13.2 U-Filled Skutterudites
263(4)
3.3.4.13.3 Np-Filled Skutterudites
267(2)
3.3.5 Magnetic Properties of Skutterudites with the [ Pt4Ge12] Framework
269(1)
3.3.5.1 Ce-Filled [ Pt4Ge12] Framework
269(4)
3.3.5.2 Nd-Filled [ Pt4Ge12] Framework
273(2)
3.3.5.3 Sm-Filled [ Pt4Ge12] Framework
275(1)
3.3.5.4 Eu-Filled [ Pt4Ge12] Framework
276(2)
3.3.5.5 Actinide-Filled [ Pt4Ge12] Framework
278(2)
3.4 Concluding Remarks
280(1)
Note
281(1)
References
281(14)
Index 295
Ctirad Uher is a C. Wilbur Peters Professor of Physics at the University of Michigan in Ann Arbor. He earned his BSc in physics with the University Medal from the University of New South Wales in Sydney, Australia. He carried out his graduate studies at the same institution under Professor H. J. Goldsmid on the topic of Thermomagnetic effects in bismuth and its dilute alloys, and received his PhD in 1975. He then accepted a postdoctoral position at Michigan State University, where he worked with Profs. W. P. Pratt, P. A. Schroeder, and J. Bass on transport properties at ultra-low temperatures. In 1978, Professor Uher was awarded the prestigious Queen Elizabeth II Research Fellowship, which he spent at the Commonwealth Scientific and Industrial Research Organization (CSIRO), National Measurement Laboratory (NML), in Sydney. Professor Uher started his academic career in 1980 as an assistant professor of physics at the University of Michigan. He progressed through the ranks and became full professor in 1989. That same year the University of New South Wales awarded him the title of DSc for his work on transport properties of semimetals. At the University of Michigan, he served as an associate chair of the Department of Physics and subsequently as an associate dean for research at the College of Literature, Sciences and Arts. In 1994, he was appointed as chair of physics, the post he held for the next 10 years. Professor Uher has had over 45 years of research, described in more than 530 refereed publications in the areas of transport properties of solids, superconductivity, diluted magnetic semiconductors, and thermoelectricity. In the field of thermoelectricity, to which he returned during the past 25 years, he worked on the development of skutterudites, half-Heusler alloys, modified lead telluride materials, magnesium silicide solid solutions, tetrahedrites, and Molecular Beam Epitaxy (MBE)grown thin films forms of Bi2Te3-based materials. He has written a number of authoritative review articles and has presented his research at numerous national and international conferences as invited and plenary talks. Professor Uhers research work has generated more than 34 000 citations and his h-index stands at 86. In 1996, he was elected fellow of the American Physical Society. Professor Uher was honored with the title of Doctor Honoris Causa from the University of Pardubice in the Czech Republic in 2002, and in 2010 was awarded a named professorship at the University of Michigan. He received the prestigious China Friendship Award in 2011. Professor Uher supervised 17 PhD thesis projects and mentored numerous postdoctoral researchers, many of whom are leading scientists in academia and research institutions all over the world. Professor Uher served on the Board of Directors of the International Thermoelectric Society. In 20042005, he was elected vice president of the International Thermoelectric Society and during 20062008 served as its president.