Preface |
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xi | |
About the Author |
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xiii | |
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Chapter 1 Brief Review of the Structure and Electronic Bands in Skutterudites |
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1 | (12) |
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1 | (1) |
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2 | (2) |
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1.3 Ternary Skutterudites |
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4 | (1) |
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5 | (4) |
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1.4.1 Filled Skutterudites with the [ M4X12] Framework |
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6 | (1) |
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1.4.2 Filled Skutterudites with the [ T4XI2]4 - Framework |
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6 | (1) |
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1.4.3 Filled Skutterudites with the [ Pt4Ge12] Framework |
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7 | (1) |
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1.4.4 Filled Skutterudites with Electronegative Fillers |
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8 | (1) |
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9 | (4) |
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Chapter 2 Superconducting Skutterudites |
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13 | (100) |
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13 | (2) |
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2.2 Useful Relations for Superconducting Parameters |
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15 | (4) |
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2.3 La-Filled Superconducting Skutterudites |
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19 | (9) |
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2.4 Superconductivity of PrOs4Sb12 |
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28 | (32) |
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2.4.1 Crystalline Electric Field in PrOs4Sb12 |
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28 | (1) |
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2.4.2 Specific Heat of PrOs4Sb12 |
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29 | (4) |
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2.4.3 Nuclear Quadrupole Resonance in PrOs4Sb12 |
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33 | (2) |
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2.4.4 High Field-Ordered Phase (HFOP) in PrOs4Sb12 |
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35 | (3) |
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2.4.5 Magneto-Thermal Conductivity of PrOs4Sb12 |
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38 | (6) |
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2.4.6 Breakdown of TRS in PrOs4Sb12 |
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44 | (3) |
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2.4.7 Fermi Surface of PrOs4Sb12 |
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47 | (2) |
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2.4.8 Point-Contact Spectroscopy |
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49 | (1) |
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2.4.9 Superconducting Solid Solutions of Pr(Os1-xRux)Sb12 |
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50 | (3) |
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2.4.10 Superconducting Solid Solutions of (Pr1-xLax)Os4Sb12 |
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53 | (2) |
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2.4.11 Superconducting Solid Solutions of (Pr1-xNdx)Os4Sb12 |
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55 | (2) |
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2.4.12 Other Pr-Filled Skutterudite Superconductors |
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57 | (1) |
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57 | (2) |
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59 | (1) |
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2.5 YT4P12, (T = Fe, Ru, and Os) Superconductors |
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60 | (3) |
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60 | (1) |
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2.5.2 YOs4P12 and YRu4P12 |
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61 | (2) |
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2.6 Superconductors with the [ Pt4Ge12] Framework |
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63 | (30) |
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2.6.1 Alkaline-Earth-Filled BaPt4Ge12 and SrPt4Ge12 Superconductors |
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63 | (4) |
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2.6.2 Actinide-Filled ThPt4Ge12 Superconductor |
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67 | (1) |
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2.6.3 Rare-Earth-Filled [ Pt4Ge12]-Based Superconductors |
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67 | (24) |
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2.6.4 Effect of Pressure on Platinum Germanide Superconductors |
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91 | (2) |
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2.7 Critical Current Density of Superconductors |
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93 | (8) |
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2.7.1 Fields and Currents Inside Type-I Superconductors |
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93 | (1) |
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2.7.2 Critical State Model of Bean |
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94 | (7) |
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101 | (5) |
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106 | (7) |
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Chapter 3 Magnetic Properties of Skutterudites |
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113 | (182) |
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113 | (24) |
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115 | (1) |
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3.1.2 Paramagnetism of Localized Magnetic Moments and Curie Law |
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116 | (5) |
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3.1.3 Paramagnetism in Metals and Pauli Susceptibility |
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121 | (2) |
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3.1.4 Magnetically Ordered Structures |
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123 | (2) |
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3.1.4.1 Weiss Molecular Field Model and Mean Field Theory |
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125 | (1) |
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3.1.4.1.1 The Case of a Ferromagnet |
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126 | (4) |
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3.1.4.1.2 The Case of an Antiferromagnet |
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130 | (2) |
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3.1.4.1.3 The Case of a Ferrimagnet |
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132 | (1) |
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3.1.4.2 Magnetic Excitations and Spin Waves |
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133 | (1) |
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3.1.4.3 Magnetic Anisotropy |
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134 | (1) |
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3.1.4.4 Effect of Crystalline Electric Field (CEF) |
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135 | (2) |
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3.2 Techniques of Measuring Magnetic Properties |
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137 | (5) |
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3.2.1 Measurements of Magnetic Moments and Magnetic Susceptibility |
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137 | (2) |
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3.2.2 Mossbauer Spectroscopy |
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139 | (1) |
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3.2.3 Neutron Spectroscopy |
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140 | (2) |
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3.3 Magnetic Properties of Skutterudites |
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142 | (138) |
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3.3.1 Mossbauer Studies of Skutterudites |
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142 | (11) |
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3.3.2 Magnetic Susceptibility of Binary Skutterudites |
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153 | (4) |
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3.3.3 Magnetic Properties of Partially Filled CoSb3 |
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157 | (1) |
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3.3.4 Magnetic Properties of Filled Skutterudites with the [ T4X12] Framework |
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158 | (5) |
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3.3.4.1 Lanthanum-Filled Skutterudites |
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163 | (2) |
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3.3.4.2 Ce-Filled Skutterudites |
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165 | (14) |
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3.3.4.3 Pr-Filled Skutterudites |
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179 | (1) |
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3.3.4.3.1 Pr-Filled Phosphides |
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179 | (8) |
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3.3.4.3.2 Pr-Filled Arsenides |
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187 | (4) |
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3.3.4.3.3 Pr-Filled Antimonides |
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191 | (3) |
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3.3.4.4 Nd-Filled Skutterudites |
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194 | (1) |
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3.3.4.4.1 Nd-Filled Phosphides |
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194 | (3) |
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3.3.4.4.2 Nd-Filled Arsenides |
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197 | (3) |
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3.3.4.4.3 Nd-Filled Antimonides |
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200 | (7) |
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3.3.4.5 Sm-Filled Skutterudites |
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207 | (1) |
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3.3.4.5.1 Sm-Filled Phosphides |
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207 | (11) |
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3.3.4.5.2 Sm-Filled Arsenides |
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218 | (1) |
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3.3.4.5.3 Sm-Filled Antimonides |
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219 | (9) |
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3.3.4.6 Eu-Filled Skutterudites |
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228 | (1) |
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3.3.4.6.1 Eu-Filled Phosphides |
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228 | (1) |
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3.3.4.6.2 Eu-Filled Arsenides |
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229 | (3) |
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3.3.4.6.3 Eu-Filled Antimonides |
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232 | (4) |
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3.3.4.7 Yb-Filled Skutterudites |
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236 | (1) |
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3.3.4.7.1 Yb-Filled Phosphides |
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236 | (1) |
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3.3.4.7.2 Yb-Filled Arsenides |
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237 | (1) |
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3.3.4.7.3 Yb-Filled Antimonides |
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237 | (6) |
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3.3.4.8 Gd-Filled Skutterudites |
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243 | (3) |
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3.3.4.9 Heavy Lanthanide-Filled Skutterudites |
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246 | (4) |
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3.3.4.10 Yttrium-Filled Skutterudites |
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250 | (1) |
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3.3.4.11 Alkali Metal-Filled Skutterudites and T1-Filled Skutterudites |
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250 | (4) |
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3.3.4.12 Skutterudites Filled with Alkaline-Earth Metals |
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254 | (7) |
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3.3.4.13 Skutterudites Filled with Actinide Elements |
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261 | (1) |
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3.3.4.13.1 Th-Filled Skutterudites |
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261 | (2) |
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3.3.4.13.2 U-Filled Skutterudites |
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263 | (4) |
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3.3.4.13.3 Np-Filled Skutterudites |
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267 | (2) |
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3.3.5 Magnetic Properties of Skutterudites with the [ Pt4Ge12] Framework |
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269 | (1) |
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3.3.5.1 Ce-Filled [ Pt4Ge12] Framework |
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269 | (4) |
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3.3.5.2 Nd-Filled [ Pt4Ge12] Framework |
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273 | (2) |
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3.3.5.3 Sm-Filled [ Pt4Ge12] Framework |
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275 | (1) |
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3.3.5.4 Eu-Filled [ Pt4Ge12] Framework |
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276 | (2) |
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3.3.5.5 Actinide-Filled [ Pt4Ge12] Framework |
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278 | (2) |
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280 | (1) |
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281 | (1) |
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281 | (14) |
Index |
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295 | |