| Preface |
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xv | |
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1 Rate-Base Simulations of Absorption Processes; Fata Morgana or Panacea? |
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1 | (16) |
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1 | (1) |
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1.2 Procede Process Simulator (PPS) |
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2 | (1) |
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1.3 Mass Transfer Fundamentals |
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3 | (5) |
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8 | (7) |
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1.5 Conclusions and Recommendations |
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15 | (2) |
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16 | (1) |
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2 Modelling in Acid Gas Removal Processes |
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17 | (12) |
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17 | (1) |
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2.2 Vapour-Liquid Equilibria |
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18 | (3) |
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21 | (4) |
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22 | (1) |
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2.3.2 Activity Coefficient Models |
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22 | (1) |
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2.3.3 Two (and more) Solvent Models |
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23 | (1) |
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2.3.4 Single Solvent Models |
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24 | (1) |
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2.3.5 Equation of State Models |
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24 | (1) |
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25 | (4) |
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26 | (3) |
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3 Thermodynamic Approach of CO2 Capture, Combination of Experimental Study and Modeling |
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29 | (10) |
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Karine Ballerat-Busserolles |
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30 | (1) |
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31 | (1) |
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3.3 Carbon Dioxide Absorption in Aqueous Solutions of Alkanolamines |
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32 | (3) |
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35 | (4) |
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36 | (3) |
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4 Employing Simulation Software for Optimized Carbon Capture Process |
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39 | (8) |
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40 | (1) |
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4.2 Acid Gas Cleaning - Process and Business Goals |
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40 | (2) |
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4.3 Modeling Gas Treating in Aspen HYSYS® |
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42 | (3) |
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4.3.1 Inbuilt Thermodynamics |
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43 | (1) |
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4.3.2 Rate-Based Distillation in Aspen HYSYS |
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44 | (1) |
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45 | (2) |
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46 | (1) |
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5 Expectations from Simulation |
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47 | (22) |
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48 | (1) |
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48 | (4) |
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49 | (1) |
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50 | (1) |
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50 | (1) |
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51 | (1) |
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5.3 Reliability of Simulation Data: What's Data and What's Not |
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52 | (4) |
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54 | (1) |
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54 | (1) |
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55 | (1) |
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55 | (1) |
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56 | (11) |
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5.4.1 Hellenic Petroleum Refinery Revamp |
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56 | (2) |
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5.4.2 Treating a Refinery Fuel Gas |
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58 | (2) |
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5.4.3 Carbon Dioxide Removal in an LNG Unit |
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60 | (5) |
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65 | (2) |
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67 | (2) |
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67 | (2) |
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6 Calorimetry in Aqueous Solutions of Demixing Amines for Processes in CO2 Capture |
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69 | (12) |
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Karine Ballerat-Busserolles |
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70 | (2) |
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72 | (1) |
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6.3 Liquid-Liquid Phase Equilibrium |
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73 | (2) |
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6.4 Mixing Enthalpies of {Water-Amine} and {Water-Amine-CO2} |
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75 | (4) |
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77 | (1) |
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6.4.2 Enthalpies of Solution |
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78 | (1) |
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79 | (2) |
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79 | (2) |
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7 Speciation in Liquid-Liquid Phase-Separating Solutions of Aqueous Amines for Carbon Capture Applications by Raman Spectroscopy |
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81 | (14) |
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81 | (3) |
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84 | (3) |
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84 | (1) |
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84 | (1) |
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7.2.3 Raman Spectroscopic Measurements |
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85 | (1) |
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7.2.4 Methodology Validation |
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86 | (1) |
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7.2.5 Laser Selection Optimization |
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86 | (1) |
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7.3 Results and Discussion |
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87 | (4) |
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7.3.1 Ammonium Carbamate System |
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87 | (1) |
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7.3.2 Methylpiperidine Band Identification |
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88 | (1) |
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7.3.3 (N-methylpiperidine + Water + CO2) System |
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89 | (1) |
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7.3.4 (2-methylpiperidine + Water + CO2) System |
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90 | (1) |
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7.3.5 (4-methylpiperidine + Water + CO2) System |
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91 | (1) |
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91 | (1) |
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92 | (3) |
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93 | (2) |
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8 A Simple Model for the Calculation of Electrolyte Mixture Viscosities |
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95 | (12) |
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95 | (3) |
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8.2 The Expanded Fluid Viscosity Model |
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98 | (1) |
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8.3 Results and Discussion |
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99 | (5) |
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8.3.1 EF Model for Salts Neglecting Dissociation |
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100 | (2) |
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8.3.2 EF Model for Ionic Species |
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102 | (2) |
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104 | (3) |
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104 | (3) |
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9 Phase Equilibria Investigations of Acid Gas Hydrates: Experiments and Modelling |
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107 | (8) |
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107 | (1) |
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108 | (2) |
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9.3 Results and Discussion |
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110 | (2) |
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112 | (1) |
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112 | (3) |
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112 | (3) |
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10 Thermophysical Properties, Hydrate and Phase Behaviour Modelling in Acid Gas-Rich Systems |
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115 | (26) |
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116 | (1) |
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10.2 Experimental Setups and Procedures |
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117 | (5) |
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10.2.1 Saturation and Dew Pressure Measurements and Procedures |
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117 | (2) |
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10.2.2 Hydrate Dissociation Measurements and Procedures |
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119 | (1) |
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10.2.3 Water Content Measurements and Procedures |
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120 | (1) |
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10.2.4 Viscosity and Density Measurements and Procedures |
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120 | (1) |
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10.2.5 Frost Point Measurements and Procedures |
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120 | (1) |
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121 | (1) |
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10.3 Thermodynamic and Viscosity Modelling |
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122 | (6) |
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10.3.1 Fluid and Hydrate Phase Equilibria Model |
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122 | (6) |
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10.4 Results and Discussions |
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128 | (8) |
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136 | (1) |
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136 | (5) |
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136 | (5) |
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11 "Self-Preservation" of Methane Hydrate in Pure Water and (Water + Diesel Oil + Surfactant) Dispersed Systems |
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141 | (12) |
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142 | (1) |
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142 | (4) |
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142 | (1) |
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143 | (3) |
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11.2.3 Experimental Procedure |
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146 | (1) |
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11.3 Results and Discussion |
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146 | (5) |
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11.3.1 Self-Preservation Effect without Surfactant in Low Water Cut Oil-Water Systems |
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146 | (2) |
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11.3.2 Self-Preservation Effect without Surfactant in High Water Cut Oil-Water Systems |
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148 | (1) |
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11.3.3 The Effect of Different Surfactants on Self-Preservation Effect in Different Water Cut Oil-Water Systems |
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149 | (2) |
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151 | (1) |
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151 | (2) |
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151 | (2) |
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12 The Development of Integrated Multiphase Flash Systems |
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153 | (16) |
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154 | (1) |
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12.2 Algorithmic Challenges |
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155 | (1) |
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12.3 Physical-Chemical Challenges |
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156 | (1) |
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156 | (1) |
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12.5 Equation of State Modifications |
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157 | (3) |
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12.6 Complex Liquid-Liquid Phase Behaviour |
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160 | (2) |
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12.7 Hydrate Calculations |
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162 | (3) |
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12.7 Conclusions and Future Work |
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165 | (4) |
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167 | (2) |
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13 Reliable PVT Calculations --- Can Cubics Do It? |
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169 | (14) |
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169 | (2) |
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13.2 Two Parameter Equations of State |
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171 | (1) |
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13.3 Two Parameter Cubic Equations of State Using Volume Translation |
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172 | (3) |
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13.4 Three Parameter Cubic Equations of State |
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175 | (2) |
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13.5 Four Parameter Cubic Equations of State |
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177 | (1) |
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13.6 Conclusions and Recommendations |
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177 | (6) |
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180 | (3) |
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14 Vapor-Liquid Equilibria Predictions of Carbon Dioxide + Hydrogen Sulfide Mixtures using the CPA, SRK, PR, SAFT, and PC-SAFT Equations of State |
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183 | (8) |
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184 | (1) |
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14.2 Results and Discussion |
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185 | (3) |
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188 | (1) |
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188 | (3) |
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188 | (3) |
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15 Capacity Control Considerations for Acid Gas Injection Systems |
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191 | (30) |
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191 | (1) |
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15.2 Requirement for Capacity Control |
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192 | (4) |
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15.3 Acid Gas Injection Systems |
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196 | (1) |
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15.4 Compressor Design Considerations |
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197 | (2) |
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15.5 Capacity Control in Reciprocating AGI Compressors |
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199 | (14) |
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15.6 Capacity Control in Reciprocating Compressor/PD Pump Combinations |
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213 | (2) |
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15.7 Capacity Control in Reciprocating Compressor/Centrifugal Pump Combinations |
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215 | (1) |
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15.8 Capacity Control When Using Screw Compressors |
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215 | (3) |
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15.9 Capacity Control When Using Centrifugal Compression |
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218 | (1) |
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219 | (1) |
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220 | (1) |
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220 | (1) |
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16 Review and Testing of Radial Simulations of Plume Expansion and Confirmation of Acid Gas Containment Associated with Acid Gas Injection in an Underpressured Clastic Carbonate Reservoir |
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221 | (22) |
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222 | (1) |
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16.2 Site Subsurface Geology |
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223 | (4) |
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16.2.1 General Stratigraphy and Structure |
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224 | (3) |
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16.2.2 Geology Observed in AGI #1 and AGI #2 |
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227 | (1) |
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16.3 Well Designs, Drilling and Completions |
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227 | (5) |
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228 | (3) |
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231 | (1) |
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16.4 Reservoir Testing and Modeling |
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232 | (4) |
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233 | (1) |
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233 | (1) |
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16.4.3 Comparison of Reservoir between Wells |
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234 | (1) |
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16.4.4 Initial Radial Model and Plume Prediction |
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234 | (2) |
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16.4.5 Confirmation of Plume Migration Model and Integrity of Caprock |
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236 | (1) |
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16.5 Injection History and AGI #1 Responses |
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236 | (2) |
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16.6 Discussion and Conclusions |
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238 | (5) |
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241 | (2) |
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17 Three-Dimensional Reservoir Simulation of Acid Gas Injection in Complex Geology - Process and Practice |
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243 | (16) |
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244 | (1) |
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17.2 Step by Step Approach to a Reservoir Simulation Study for Acid Gas Injection |
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245 | (1) |
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17.3 Seismic Data and Interpretation |
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245 | (1) |
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246 | (1) |
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17.5 Petrophysical Studies |
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246 | (1) |
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17.6 Reservoir Engineering Analysis |
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247 | (1) |
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247 | (1) |
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17.8 Reservoir Simulation |
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248 | (1) |
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249 | (1) |
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17.10 Injection Interval Structure and Modeling |
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249 | (1) |
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17.11 Petrophysical Modeling and Development of Static Model |
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250 | (1) |
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17.12 Injection Zone Characterization |
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251 | (2) |
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17.13 Reservoir Simulation |
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253 | (3) |
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17.14 Summary and Conclusions |
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256 | (3) |
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257 | (2) |
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18 Production Forecasting of Fractured Wells in Shale Gas Reservoirs with Discontinuous Micro-Fractures |
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259 | (22) |
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260 | (1) |
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18.2 Multi-Scale Flow in Shale Gas Reservoir |
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261 | (3) |
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18.2.1 Multi-scale Nonlinear Seepage Flow Model of Shale Gas Reservoir |
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261 | (2) |
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18.2.2 Adsorption -- Desorption Model of Shale Gas Reservoir |
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263 | (1) |
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18.3 Physical Model and Solution of Fractured Well of Shale Gas Reservoir |
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264 | (9) |
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18.3.1 The Dual Porosity Spherical Model with Micro-Fractures Surface Layer |
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264 | (2) |
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18.3.2 The Establishment and Solvement of Seepage Mathematical Model |
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266 | (7) |
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18.4 Analysis of Influencing Factors of Sensitive Parameters |
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273 | (4) |
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277 | (1) |
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278 | (3) |
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278 | (3) |
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19 Study on the Multi-Scale Nonlinear Seepage Flow Theory of Shale Gas Reservoir |
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281 | (20) |
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282 | (1) |
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19.2 Multi-Scale Flowstate Analyses of the Shale Gas Reservoirs |
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283 | (2) |
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19.3 Multi-Scale Nonlinear Seepage Flow Model in Shale Gas Reservoir |
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285 | (6) |
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19.3.1 Nonlinear Seepage Flow Model in Nano-Micro Pores |
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285 | (3) |
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19.3.2 Multi-Scale Seepage Model Considering of Diffusion, Slippage |
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288 | (1) |
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19.3.3 Darcy Flow in Micro Fractures and Fractured Fractures |
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289 | (2) |
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19.4 Transient Flow Model of Composite Fracture Network System |
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291 | (3) |
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19.5 Production Forecasting |
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294 | (4) |
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298 | (1) |
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299 | (2) |
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299 | (2) |
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20 CO2 EOR and Sequestration Technologies in PetroChina |
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301 | (18) |
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302 | (1) |
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20.2 Important Progress in Theory and Technology |
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302 | (9) |
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20.2.1 The Miscible Phase Behaviour of Oil-CO2 System |
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302 | (2) |
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20.2.2 CO2 Flooding Reservoir Engineering Technology |
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304 | (2) |
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20.2.3 Separated Layer CO2 Flooding, Wellbore Anti-Corrosion and High Efficiency Lift Technology |
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306 | (1) |
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20.2.4 Long Distance Pipeline Transportation and Injection Technology |
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306 | (1) |
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20.2.5 Produced Fluid Treatment for CO2 Flooding and Cycling Gas Injection Technology |
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306 | (1) |
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20.2.6 CO2 Flooding Reservoir Monitoring, Performance Analysis Technology |
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307 | (1) |
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20.2.7 Potential Evaluation for CO2 Flooding and Storage |
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308 | (3) |
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20.3 Progress of Pilot Area |
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311 | (4) |
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312 | (1) |
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313 | (2) |
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315 | (1) |
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316 | (3) |
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317 | (2) |
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21 Study on the Microscopic Residual Oil of CO2 Flooding for Extra-High Water-Cut Reservois |
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319 | (12) |
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319 | (1) |
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21.2 Overview of CO2 EOR Mechanisms for Extra High Water Cut Reservoirs |
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320 | (1) |
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21.3 Experimental Microscopic Residual Oil Distribution of CO2 Flooding for Extra High Water Cut Reservoirs |
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321 | (4) |
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321 | (1) |
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21.3.2 In situ NMR Test for Water Flooding and CO2 Flooding |
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322 | (3) |
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21.4 Displacement Characteristics of CO2 Flooding and Improve Oil Recovery Method for Post CO2 Flooding |
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325 | (2) |
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21.4.1 CO2 Displacement Characteristics for Extra High Water Cut Reservoirs |
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325 | (1) |
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21.4.2 Improved Oil Recovery for Post CO2 Flooding |
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326 | (1) |
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327 | (4) |
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328 | (3) |
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22 Monitoring of Carbon Dioxide Geological Utilization and Storage in China: A Review |
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331 | (28) |
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332 | (1) |
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22.2 Status of CCUS in China |
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332 | (4) |
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336 | (7) |
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22.3.1 Monitoring Technology at Home and Abroad |
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336 | (5) |
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22.3.2 U-tube Sampling System |
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341 | (1) |
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22.3.3 Monitoring Technologies in China's CCUS Projects |
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341 | (2) |
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22.4 Monitoring Technology of China's Typical CCUS Projects |
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343 | (2) |
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22.4.1 Shenhua CCS Demonstration Project |
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343 | (2) |
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22.4.2 Shengli CO2 -EOR Project |
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345 | (1) |
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22.5 Environmental Governance and Monitoring Trends in China |
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345 | (6) |
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351 | (1) |
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22.7 Acknowledgements 352 References |
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352 | (7) |
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23 Separation of Methane from Biogas by Absorption-Adsorption Hybrid Method |
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359 | (18) |
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359 | (2) |
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361 | (6) |
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23.2.1 Experimental Apparatus |
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361 | (1) |
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362 | (1) |
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23.2.3 Synthesis and Activation of ZIF-67 |
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363 | (1) |
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23.2.4 Gas-Slurry Equilibrium Experiments |
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363 | (1) |
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364 | (2) |
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23.2.6 Breakthrough Experiment |
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366 | (1) |
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23.3 Results and Discussions |
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367 | (7) |
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23.3.1 Adsorbent Characterization |
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367 | (1) |
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23.3.2 Ab-Adsorption Isothermal |
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368 | (2) |
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23.3.3 Breakthrough Experiment |
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370 | (4) |
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374 | (1) |
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374 | (3) |
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374 | (3) |
| Index |
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377 | |