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E-raamat: Designing Electrolytes for Lithium-Ion and Post-Lithium Batteries [Taylor & Francis e-raamat]

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  • Formaat: 344 pages, 8 Tables, black and white; 8 Illustrations, color; 58 Illustrations, black and white
  • Ilmumisaeg: 24-Jun-2021
  • Kirjastus: Jenny Stanford Publishing
  • ISBN-13: 9781003050933
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  • Taylor & Francis e-raamat
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Designing Electrolytes for Lithium-Ion and Post-Lithium BatteriesSuurem pilt
  • Formaat: 344 pages, 8 Tables, black and white; 8 Illustrations, color; 58 Illustrations, black and white
  • Ilmumisaeg: 24-Jun-2021
  • Kirjastus: Jenny Stanford Publishing
  • ISBN-13: 9781003050933
Teised raamatud teemal:
Taylor & Francis e-raamatudRohkem infot Taylor & Francis e-raamatute kohta
Raamatu kodulehekülg: https://www.taylorfrancis.com/books/9781003050933
Every electrochemical source of electric current is composed of two electrodes with an electrolyte in between. Since storage capacity depends predominantly on the composition and design of the electrodes, most research and development efforts have been focused on them. Considerably less attention has been paid to the electrolyte, a battery’s basic component. This book fills this gap and shines more light on the role of electrolytes in modern batteries. Today, limitations in lithium-ion batteries result from non-optimal properties of commercial electrolytes as well as scientific and engineering challenges related to novel electrolytes for improved lithium-ion as well as future post-lithium batteries.
Introduction: Challenges toward Designing Novel Electrolytes for Modern Lithium-Ion and Post-Lithium Batteries xi
Janusz Ptocharski
Wfadysiaw Wieczorek
PART I Novel Electrolytes for Lithium Batteries
1 New Strategies In Designing Salts And Solutions For The New Generation Of Electrolytes
3(40)
Leszek Niedzicki
Marta Kasprzyk
1.1 Introduction
3(1)
1.2 Anion Structure Impact
4(4)
1.3 Requirements toward Electrolyte
8(1)
1.4 Classes of Anions Investigated So Far
9(2)
1.5 Properties of Anion Classes Investigated So Far
11(2)
1.6 Properties of Commonly Used Salts
13(3)
1.7 Strategy for New Anion Design
16(3)
1.8 Anions Designed with the New Described Strategy
19(3)
1.9 Other Concepts
22(2)
1.10 Electrolyte Design: Solvent Effect
24(3)
1.11 Electrolyte Design: Maximizing Parameters
27(3)
1.12 Other Electrolytes for Li-Ion Cells
30(3)
1.13 Anions for Post-Li-Ion Cells
33(1)
1.14 Examples of Electrolytes for Li-Ion Cells
34(9)
2 X-Ray Crystallography In Developing New Electrolyte Systems Based On Heterocyclic Anions
43(28)
Maciej Dranka
Janusz Zachara
2.1 Introduction
43(2)
2.2 Aggregation Phenomena: Solid-State and Concentrated Liquid Electrolytes
45(1)
2.3 Crystal Structure Analysis: Hints about the Properties of Heterocyclic Anions
46(5)
2.4 Structural Studies of LiTDI Solvates with Glymes: Disproportionation Mechanism
51(6)
2.5 Structural Studies of Sodium Salts with Heterocyclic Anions
57(4)
2.6 Structural Studies of Lithium Salt Hydrates with Dicyanoimidazole Anions
61(3)
2.7 Conclusions
64(7)
3 Overview Of Polymer And Solid Electrolytes: Towards All Solid-State Batteries
71(70)
Michaf Marzantowicz
Michat Struzik
3.1 Introduction
71(1)
3.2 Classification of Polymer Electrolytes
72(2)
3.3 Dissociation and Transport of Ions: Microscopic View
74(5)
3.3.1 Dissociation
74(2)
3.3.2 Ion Transport
76(3)
3.4 Quantitative Models for Describing Ion Transport
79(6)
3.4.1 Arrhenius Model
79(2)
3.4.2 Vogel-Tammann-Fulcher Model
81(2)
3.4.3 Conductivity of an Inhomogeneous Medium: Percolation Models
83(2)
3.5 Lithium Transference Numbers
85(3)
3.6 Polymer Electrolyte as an Element of the Cell: Electrolyte/Electrode Interface
88(3)
3.7 Examples of Solid Polymer Electrolytes
91(19)
3.7.1 Polymer with a Salt
91(1)
3.7.1.1 Electrolytes based on PEO
91(3)
3.7.1.2 Electrolytes based on other polymers
94(2)
3.7.2 Organic/Inorganic Composite Systems
96(5)
3.7.3 Polymer in a Salt and Systems with Ionic Liquids
101(6)
3.7.4 Polyelectrolytes and Oligomeric Salts
107(3)
3.8 Ceramic Electrolytes
110(31)
3.8.1 NASICON-Type Conductors
112(2)
3.8.2 Electrolytes with Perovskite Structure
114(2)
3.8.3 Lithium Sulfides
116(2)
3.8.4 Electrolytes with a Garnet Structure
118(23)
PART II Electrolytes for Post-Lithium-Ion Systems
4 Electrolytes For Sodium And Sodium-Ion Batteries
141(24)
Marek Marcinek
Anna Bitner-Michalska
Anna Szczesna-Chrzan
Tomasz Trzeciak
4.1 Introduction
141(5)
4.2 Electrolyte
146(10)
4.2.1 Solvents and Systematics
147(1)
4.2.1.1 Liquid electrolytes
147(3)
4.2.1.2 Ionic liquid-based electrolytes
150(2)
4.2.1.3 Gel systems
152(1)
4.2.1.4 Polymer electrolytes
153(1)
4.2.2 Salts
154(2)
4.3 Summary
156(9)
5 Multivalent Cation Systems: Electrolytes For Magnesium Batteries
165(26)
Janusz Piocharski
5.1 Electrolytes Evolved from Grignard Compounds
167(1)
5.2 Electrolytes with Boron Compounds
168(5)
5.3 Electrolytes with Hexamethyldisilazide Ions
173(1)
5.4 Simple Inorganic Electrolyte
174(2)
5.5 Electrolytes with TFSI Anion
176(6)
5.6 Miscellaneous Electrolytes
182(1)
5.7 Comparison of Various Electrolyte Systems
183(1)
5.8 Problem of Dendrites
184(1)
5.9 Summary
185(6)
6 Multivalent Cation Systems: Toward Aluminum, Zinc, And Calcium Batteries
191(24)
Michat Piszcz
Maciej Siekierski
6.1 Introduction
191(4)
6.2 Aluminum
195(8)
6.2.1 Water-Based Electrolytes
196(3)
6.2.2 Nonaqueous Systems
199(4)
6.3 Calcium
203(3)
6.4 Zinc
206(1)
6.5 Conclusions
207(8)
7 Electrolytes For Metal-Air Batteries
215(78)
Maciej Siekierski
Michat Piszcz
Grazyna Zukowska
7.1 Introduction
215(2)
7.2 Lithium-Air Systems
217(25)
7.2.1 Organic and Polymeric Electrolytes
217(5)
7.2.2 Aqueous
222(5)
7.2.3 Ceramic and Glassy
227(9)
7.2.4 Hybrid Systems
236(6)
7.3 Sodium
242(4)
7.4 Potassium
246(2)
7.5 Magnesium
248(3)
7.6 Calcium
251(1)
7.7 Aluminum
251(3)
7.8 Zinc
254(7)
7.9 Miscellaneous
261(3)
7.10 Conclusions
264(29)
8 Electrolytes For Lithium-Sulfur Batteries
293(26)
Maciej Marczewski
8.1 Introduction
293(3)
8.2 Electrolyte Requirements
296(1)
8.3 Liquid Electrolytes
296(10)
8.3.1 Carbonates
301(1)
8.3.2 Ethers
302(1)
8.3.3 Sulfones
303(1)
8.3.4 Ionic Liquids
304(1)
8.3.5 Concentrated Electrolytes
305(1)
8.3.6 Novel Approach
305(1)
8.4 Solid Electrolytes
306(4)
8.4.1 Polymer Electrolytes
309(1)
8.4.2 Ceramic Electrolytes
310(1)
8.5 Additives
310(2)
8.6 Summary
312(7)
Index 319
Wadysaw Wieczorek is professor of chemistry (chemical technology) at the Warsaw University of Technology.

Janusz Pocharski graduated from the Faculty of Chemistry, Warsaw University of Technology, in 1974 and then became a member of the research and teaching staff of the faculty.
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