| Preface |
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ix | |
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1 Lithium Metal Batteries |
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1 | (54) |
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1 | (1) |
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2 | (39) |
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1.2.1 Lithium-Oxygen Batteries |
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2 | (1) |
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1.2.1.1 Working Mechanism of Li-O2 Batteries |
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2 | (2) |
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1.2.1.2 Cathode Design of Li-O2 Batteries |
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4 | (4) |
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1.2.1.3 Anode Protection of Li-O2 Batteries |
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8 | (3) |
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1.2.2 Lithium-Sulfur Batteries |
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11 | (1) |
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1.2.2.1 Conductive Matrixes for S Cathode |
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12 | (3) |
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1.2.2.2 Modifying Separators of Li-S Batteries |
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15 | (2) |
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1.2.2.3 Electrolyte Design for Li-S Batteries |
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17 | (1) |
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1.2.2.4 Anode Protection for Li-S Batteries |
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18 | (4) |
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1.2.3 Lithium-Selenium or -Tellurium Batteries |
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22 | (1) |
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1.2.3.1 Lithium-Selenium Batteries |
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22 | (7) |
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1.2.3.2 Lithium-Tellurium Batteries |
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29 | (2) |
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1.2.4 Lithium-Iodine/Bromine Batteries |
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31 | (1) |
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1.2.4.1 Lithium-Iodine Batteries |
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31 | (5) |
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1.2.4.2 Lithium-Bromine Battery |
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36 | (1) |
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37 | (4) |
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1.3 Introductive Electrolytes |
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41 | (3) |
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44 | (11) |
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45 | (10) |
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2 Electrode-Electrolyte Interphase |
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55 | (24) |
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55 | (1) |
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2.2 Solid Electrolyte Interphase |
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55 | (11) |
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55 | (1) |
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2.2.2 Types and Modification Strategies |
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56 | (10) |
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2.3 Cathode Electrolyte Interphase |
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66 | (13) |
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66 | (1) |
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2.3.2 Types and Modification Strategies |
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66 | (9) |
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75 | (4) |
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79 | (20) |
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79 | (1) |
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3.2 Flame-Retardant Mechanism |
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80 | (1) |
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3.3 Flame-Retardant Electrolytes |
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80 | (5) |
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3.4 Nonflammable Electrolytes |
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85 | (8) |
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93 | (6) |
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95 | (4) |
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4 High-Voltage Electrolytes |
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99 | (34) |
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99 | (2) |
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4.2 The General Implications of High-Voltage Electrochemical Operation |
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101 | (10) |
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4.2.1 Electrochemical Stability and Voltage Window for Electrolytes |
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101 | (1) |
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4.2.2 Parasitic Electrolyte Oxidation and Formation of CEI |
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102 | (4) |
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4.2.3 Metal Ion Diffusion, Surface Structural Reconstruction, and Mechanical Fracture of Cathode Materials |
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106 | (3) |
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4.2.4 Instability of Other Cell Components at High Voltage |
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109 | (2) |
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4.3 The Electrolyte Engineering for Various High-Voltage Cathodes |
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111 | (16) |
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4.3.1 Nickel-Containing Layered Oxides |
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111 | (5) |
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116 | (4) |
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4.3.3 Layered Li-Rich Cathodes |
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120 | (1) |
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4.3.4 Other Cathode Materials |
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121 | (6) |
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127 | (6) |
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127 | (6) |
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5 Extreme Temperature Electrolytes |
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133 | (24) |
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5.1 Low-Temperature Electrolytes |
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133 | (10) |
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5.1.1 The Limitations of Battery Performance at Low Temperature |
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133 | (4) |
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5.1.2 The Improvement of Electrolytes |
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137 | (6) |
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5.2 High-Temperature Electrolytes |
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143 | (8) |
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5.2.1 The Limitations of Battery Performance at High Temperature |
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144 | (4) |
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5.2.2 The Improvement of Electrolytes |
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148 | (3) |
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151 | (6) |
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152 | (5) |
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6 High-Concentration Electrolytes |
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157 | (26) |
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6.1 High-Concentration Electrolytes |
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157 | (11) |
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6.1.1 Concept, Design Strategies |
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157 | (1) |
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158 | (10) |
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6.2 Local High-concentration Electrolytes |
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168 | (10) |
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6.2.1 Concept, Design Strategies |
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169 | (1) |
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169 | (9) |
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178 | (5) |
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178 | (5) |
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7 Theoretical Basis for Electrolyte and Electrode Study |
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183 | (16) |
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183 | (4) |
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183 | (2) |
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185 | (1) |
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7.1.3 Redox Potential of the Complex |
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186 | (1) |
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187 | (5) |
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187 | (1) |
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7.2.2 Influencing Factors and Implicit Solvent Model |
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188 | (1) |
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189 | (1) |
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190 | (2) |
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192 | (3) |
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7.3.1 Lithium Diffusion in SEI |
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192 | (2) |
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7.3.2 Lithium Diffusion in Electrode Material |
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194 | (1) |
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7.3.2.1 Calculation of Electrode Materials |
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194 | (1) |
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7.3.2.2 Equilibrium Voltage |
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194 | (1) |
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195 | (1) |
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195 | (4) |
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196 | (3) |
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199 | (4) |
| Index |
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203 | |