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E-raamat: Liquid Electrolyte Chemistry for Lithium Metal Batteries: Design, Mechanisms, Strategies

  • Formaat: PDF+DRM
  • Ilmumisaeg: 09-Feb-2022
  • Kirjastus: Blackwell Verlag GmbH
  • Keel: eng
  • ISBN-13: 9783527836376
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  • Formaat: PDF+DRM
  • Ilmumisaeg: 09-Feb-2022
  • Kirjastus: Blackwell Verlag GmbH
  • Keel: eng
  • ISBN-13: 9783527836376

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Liquid Electrolyte Chemistry for Lithium Metal Batteries

An of-the-moment treatment of liquid electrolytes used in lithium metal batteries

Considered by many as the most-promising next-generation batteries, lithium metal batteries have grown in popularity due to their low potential and high capacity. Crucial to the development of this technology, electrolytes can provide efficient electrode electrolyte interfaces, assuring the interconversion of chemical and electrical energy. The quality of electrode electrolyte interphase, in turn, directly governs the performance of batteries.

In Liquid Electrolyte Chemistry, provides a comprehensive look at the current understanding and status of research regarding liquid electrolytes for lithium metal batteries. Offering an introduction to lithium-based batteries from development history to their working mechanisms, the book further offers a glimpse at modification strategies of anode electrolyte interphases and cathode electrolytic interphases. More, by discussing the high-voltage electrolytes from their solvents—organic solvents and ionic liquids—to electrolyte additives, the text provides a thorough understanding on liquid electrolyte chemistry in the remit of lithium metal batteries.

Liquid Electrolyte Chemistry for Lithium Metal Batteries readers will also find:

  • A unique focus that reviews the development of liquid electrolytes for lithium metal batteries
  • State-of-the-art progress and development of electrolytes for lithium metal batteries
  • Consideration of safety, focusing the design principles of flame retardant and non-flammable electrolytes
  • Principles and progress on low temperature and high temperature electrolytes

Liquid Electrolyte Chemistry for Lithium Metal Batteries is a useful reference for electrochemists, solid state chemists, inorganic chemists, physical chemists, surface chemists, materials scientists, and the libraries that supply them.

Preface ix
1 Lithium Metal Batteries
1(54)
1.1 History
1(1)
1.2 Types
2(39)
1.2.1 Lithium-Oxygen Batteries
2(1)
1.2.1.1 Working Mechanism of Li-O2 Batteries
2(2)
1.2.1.2 Cathode Design of Li-O2 Batteries
4(4)
1.2.1.3 Anode Protection of Li-O2 Batteries
8(3)
1.2.2 Lithium-Sulfur Batteries
11(1)
1.2.2.1 Conductive Matrixes for S Cathode
12(3)
1.2.2.2 Modifying Separators of Li-S Batteries
15(2)
1.2.2.3 Electrolyte Design for Li-S Batteries
17(1)
1.2.2.4 Anode Protection for Li-S Batteries
18(4)
1.2.3 Lithium-Selenium or -Tellurium Batteries
22(1)
1.2.3.1 Lithium-Selenium Batteries
22(7)
1.2.3.2 Lithium-Tellurium Batteries
29(2)
1.2.4 Lithium-Iodine/Bromine Batteries
31(1)
1.2.4.1 Lithium-Iodine Batteries
31(5)
1.2.4.2 Lithium-Bromine Battery
36(1)
1.2.5 TMO Batteries
37(4)
1.3 Introductive Electrolytes
41(3)
1.4 Prospects
44(11)
References
45(10)
2 Electrode-Electrolyte Interphase
55(24)
2.1 Introduction
55(1)
2.2 Solid Electrolyte Interphase
55(11)
2.2.1 Concept and Roles
55(1)
2.2.2 Types and Modification Strategies
56(10)
2.3 Cathode Electrolyte Interphase
66(13)
2.3.1 Concept and Roles
66(1)
2.3.2 Types and Modification Strategies
66(9)
References
75(4)
3 Safe Electrolytes
79(20)
3.1 Introduction
79(1)
3.2 Flame-Retardant Mechanism
80(1)
3.3 Flame-Retardant Electrolytes
80(5)
3.4 Nonflammable Electrolytes
85(8)
3.5 Prospects
93(6)
References
95(4)
4 High-Voltage Electrolytes
99(34)
4.1 Introduction
99(2)
4.2 The General Implications of High-Voltage Electrochemical Operation
101(10)
4.2.1 Electrochemical Stability and Voltage Window for Electrolytes
101(1)
4.2.2 Parasitic Electrolyte Oxidation and Formation of CEI
102(4)
4.2.3 Metal Ion Diffusion, Surface Structural Reconstruction, and Mechanical Fracture of Cathode Materials
106(3)
4.2.4 Instability of Other Cell Components at High Voltage
109(2)
4.3 The Electrolyte Engineering for Various High-Voltage Cathodes
111(16)
4.3.1 Nickel-Containing Layered Oxides
111(5)
4.3.2 LiCoO2
116(4)
4.3.3 Layered Li-Rich Cathodes
120(1)
4.3.4 Other Cathode Materials
121(6)
4.4 Conclusions
127(6)
References
127(6)
5 Extreme Temperature Electrolytes
133(24)
5.1 Low-Temperature Electrolytes
133(10)
5.1.1 The Limitations of Battery Performance at Low Temperature
133(4)
5.1.2 The Improvement of Electrolytes
137(6)
5.2 High-Temperature Electrolytes
143(8)
5.2.1 The Limitations of Battery Performance at High Temperature
144(4)
5.2.2 The Improvement of Electrolytes
148(3)
5.3 Prospective
151(6)
References
152(5)
6 High-Concentration Electrolytes
157(26)
6.1 High-Concentration Electrolytes
157(11)
6.1.1 Concept, Design Strategies
157(1)
6.1.2 Developments
158(10)
6.2 Local High-concentration Electrolytes
168(10)
6.2.1 Concept, Design Strategies
169(1)
6.2.2 Developments
169(9)
6.3 Prospects
178(5)
References
178(5)
7 Theoretical Basis for Electrolyte and Electrode Study
183(16)
7.1 Redox Potential
183(4)
7.1.1 Theoretical Basis
183(2)
7.1.2 Solvents and Salts
185(1)
7.1.3 Redox Potential of the Complex
186(1)
7.2 Solvation Structure
187(5)
7.2.1 Basic Theory
187(1)
7.2.2 Influencing Factors and Implicit Solvent Model
188(1)
7.2.3 Solvation Analysis
189(1)
7.2.4 De-Solvation
190(2)
7.3 Lithium Diffusion
192(3)
7.3.1 Lithium Diffusion in SEI
192(2)
7.3.2 Lithium Diffusion in Electrode Material
194(1)
7.3.2.1 Calculation of Electrode Materials
194(1)
7.3.2.2 Equilibrium Voltage
194(1)
7.3.2.3 Ionic Mobility
195(1)
7.4 Conclusion
195(4)
References
196(3)
8 Outlook
199(4)
Index 203
Jianmin Ma is Professor at the University of Electronic Science and Technology of China. He received his B.S. degree in Chemistry from the Shanxi Normal University in 2003 and Ph.D. degree in Materials Physics and Chemistry from Nankai University in 2011. During 20112015, he also conducted the research in several overseas universities as a postdoctoral research associate. He serves as the Academic Editor for Rare Metals, the Associate Editor for Chinese Chemical Letters, and editorial board member for Journal of Energy Chemistry, Nano-Micro Letters, Journal of Physics: Condensed Matter, JPhys Energy, and others. His research interest focuses on the energy storage devices and components including metal anodes and electrolytes, and theoretical calculations from Density Functional Theory and Molecular Dynamics to Finite Element Analysis.