| Preface |
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ix | (3) |
| Acknowledgements |
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xii | |
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Chapter 1 Fundamentals of Oxide Melts |
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1 | (14) |
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1 | (1) |
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1.2 Network Formers and Network Modifiers |
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1 | (4) |
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1.3 Silicates (Polymerized Oxides) |
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5 | (2) |
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1.4 Phase Diagrams of Binary and Ternary Silicate Systems |
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7 | (7) |
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14 | (1) |
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Chapter 2 Direct Determination of the Local Structure in Oxide Melts |
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15 | (30) |
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15 | (1) |
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2.2 Structure of Molten Silicates by X-ray Diffraction |
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15 | (13) |
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2.3 Structural Information of Non-silicate Melts |
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28 | (5) |
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2.4 EXAFS and AXS Analysis |
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33 | (10) |
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43 | (2) |
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Chapter 3 Structural Characterization of Oxide Melts by Several Methods |
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45 | (22) |
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45 | (1) |
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3.2 Infrared and Raman Spectroscopy |
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45 | (5) |
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3.3 Mossbauer Spectroscopy and NMR |
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50 | (4) |
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3.4 X-ray Induced Photo-electron Spectroscopy (ESCA) |
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54 | (2) |
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56 | (2) |
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58 | (8) |
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66 | (1) |
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Chapter 4 Structure and Thermodynamic Properties of Oxide Melts |
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67 | (40) |
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67 | (1) |
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4.2 Basicity of Oxide Melts |
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67 | (10) |
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4.3 The Equilibrium Between the Three Forms of Oxygen in Silicate Melts |
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77 | (16) |
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4.4 The Relationship Between Silicate Anion Distribution and Activity |
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93 | (10) |
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4.5 Comments on the Equilibrium Constant K(TS) and K(M) |
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103 | (2) |
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105 | (2) |
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Chapter 5 General Survey of Physical Properties of Molten Oxides |
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107 | (52) |
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107 | (1) |
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107 | (6) |
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113 | (15) |
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5.4 Electrical Conductivity |
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128 | (5) |
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133 | (5) |
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138 | (4) |
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5.7 Mutual Relationships between Viscosity, Electrical Conductivity and Diffusion Coefficient |
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142 | (4) |
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142 | (2) |
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5.7.2 Nernst-Einstein Relation |
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144 | (2) |
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5.7.3 Stokes-Einstein Relation |
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146 | (1) |
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5.8 Thermal Conductivity and Thermal Diffusivity |
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146 | (11) |
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157 | (2) |
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Chapter 6 Process Implications of Metallurgical Slags |
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159 | (58) |
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159 | (1) |
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6.2 General Compositions of Metallurgical Slags |
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160 | (6) |
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160 | (3) |
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163 | (3) |
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6.3 Capacity of a Specific Element in Slag |
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166 | (8) |
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6.4 Metal Loss to the Slag Phase in Non-ferrous Metallurgy |
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174 | (7) |
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6.5 Magnetite in Non-ferrous Metallurgical Slags |
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181 | (1) |
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6.6 Relatively New Type of Slags |
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182 | (13) |
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6.6.1 Fundamentals of Ferrite Slags for Copper Smelting |
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182 | (11) |
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6.6.2 New Lead Smelting Process by Use of Ferrite-based Slag |
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193 | (1) |
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6.6.3 Arsenic and Antimony Removal in Copper Refining by Use of Soda-based Slag |
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194 | (1) |
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6.7 Fundamentals for Beneficial Utilization of Metallurgical Slags |
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195 | (18) |
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6.7.1 Grinding and Mechanochemical Effect |
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195 | (12) |
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207 | (6) |
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213 | (4) |
| References |
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217 | (12) |
| Subject Index |
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229 | |