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E-raamat: Structure And Properties Of Oxide Melts, The: Application Of Basic Science To Metallurgical Processing

(Univ Of Toronto, Canada), (Tohoku Univ, Japan)
  • Formaat: 248 pages
  • Ilmumisaeg: 22-Aug-1998
  • Kirjastus: World Scientific Publishing Co Pte Ltd
  • Keel: eng
  • ISBN-13: 9789814496704
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Structure And Properties Of Oxide Melts, The: Application Of Basic Science To Metallurgical ProcessingSuurem pilt
  • Formaat: 248 pages
  • Ilmumisaeg: 22-Aug-1998
  • Kirjastus: World Scientific Publishing Co Pte Ltd
  • Keel: eng
  • ISBN-13: 9789814496704
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This book is an extended introductory treatise on the atomic scale structure and physicochemical properties of oxide melts (mainly silicates), from both the basic science and applied engineering points of view. It provides current experimental information on the structure of oxide melts and glasses as well as a convenient outline of their various physicochemical properties, including the subject of how structural data can be correlated with their macroscopic properties.The book also includes a fundamental introduction to the beneficial utilization of waste oxides largely arising from metal production around the world. This will be very useful for people working in the fields of metallurgy and environmental science. With more than 300 references, and numerous illustrations and tables, this book is a unique and valuable source of information and guidance for specialists and nonspecialists alike.
Preface ix(3)
Acknowledgements xii
Chapter 1 Fundamentals of Oxide Melts
1(14)
1.1 Introduction
1(1)
1.2 Network Formers and Network Modifiers
1(4)
1.3 Silicates (Polymerized Oxides)
5(2)
1.4 Phase Diagrams of Binary and Ternary Silicate Systems
7(7)
1.5 Summary
14(1)
Chapter 2 Direct Determination of the Local Structure in Oxide Melts
15(30)
2.1 Introduction
15(1)
2.2 Structure of Molten Silicates by X-ray Diffraction
15(13)
2.3 Structural Information of Non-silicate Melts
28(5)
2.4 EXAFS and AXS Analysis
33(10)
2.5 Summary
43(2)
Chapter 3 Structural Characterization of Oxide Melts by Several Methods
45(22)
3.1 Introduction
45(1)
3.2 Infrared and Raman Spectroscopy
45(5)
3.3 Mossbauer Spectroscopy and NMR
50(4)
3.4 X-ray Induced Photo-electron Spectroscopy (ESCA)
54(2)
3.5 Lentz-Chromatography
56(2)
3.6 Computer Simulation
58(8)
3.7 Summary
66(1)
Chapter 4 Structure and Thermodynamic Properties of Oxide Melts
67(40)
4.1 Introduction
67(1)
4.2 Basicity of Oxide Melts
67(10)
4.3 The Equilibrium Between the Three Forms of Oxygen in Silicate Melts
77(16)
4.4 The Relationship Between Silicate Anion Distribution and Activity
93(10)
4.5 Comments on the Equilibrium Constant K(TS) and K(M)
103(2)
4.6 Summary
105(2)
Chapter 5 General Survey of Physical Properties of Molten Oxides
107(52)
5.1 Introduction
107(1)
5.2 Density
107(6)
5.3 Viscosity
113(15)
5.4 Electrical Conductivity
128(5)
5.5 Surface Tension
133(5)
5.6 Diffusion
138(4)
5.7 Mutual Relationships between Viscosity, Electrical Conductivity and Diffusion Coefficient
142(4)
5.7.1 Walden's Rule
142(2)
5.7.2 Nernst-Einstein Relation
144(2)
5.7.3 Stokes-Einstein Relation
146(1)
5.8 Thermal Conductivity and Thermal Diffusivity
146(11)
5.9 Summary
157(2)
Chapter 6 Process Implications of Metallurgical Slags
159(58)
6.1 Introduction
159(1)
6.2 General Compositions of Metallurgical Slags
160(6)
6.2.1 Ferrous Slags
160(3)
6.2.2 Non-ferrous Slags
163(3)
6.3 Capacity of a Specific Element in Slag
166(8)
6.4 Metal Loss to the Slag Phase in Non-ferrous Metallurgy
174(7)
6.5 Magnetite in Non-ferrous Metallurgical Slags
181(1)
6.6 Relatively New Type of Slags
182(13)
6.6.1 Fundamentals of Ferrite Slags for Copper Smelting
182(11)
6.6.2 New Lead Smelting Process by Use of Ferrite-based Slag
193(1)
6.6.3 Arsenic and Antimony Removal in Copper Refining by Use of Soda-based Slag
194(1)
6.7 Fundamentals for Beneficial Utilization of Metallurgical Slags
195(18)
6.7.1 Grinding and Mechanochemical Effect
195(12)
6.7.2 Work Index
207(6)
6.8 Summary
213(4)
References 217(12)
Subject Index 229
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