Preface |
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xi | |
1 Introduction and Overview |
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1 | (12) |
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1 | (1) |
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2 | (2) |
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4 | (1) |
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1.4 New Ingredients and Compositions |
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5 | (1) |
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6 | (1) |
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7 | (1) |
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1.7 Managing Contamination and Clean-Up |
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7 | (1) |
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1.8 Disposal Now and in the Future |
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8 | (1) |
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8 | (1) |
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9 | (1) |
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9 | (4) |
2 General Introduction to Ammunition Demilitarization |
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13 | (34) |
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2.1 Part One - Logistics, Costs, and Management |
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13 | (14) |
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13 | (1) |
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2.1.2 Context of Demilitarization |
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14 | (3) |
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2.1.2.1 The Scale of the Issue |
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14 | (1) |
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2.1.2.2 Factors Influencing Demilitarization |
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15 | (2) |
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2.1.3 Demilitarization Process |
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17 | (3) |
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2.1.3.1 Basic Stages of Demilitarization |
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17 | (3) |
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2.1.3.2 Demilitarization Facilities |
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20 | (1) |
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2.1.4 Demilitarization Techniques |
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20 | (6) |
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2.1.4.1 Demilitarization Techniques and Processes |
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20 | (1) |
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2.1.4.2 Maturity and Use of Demilitarization Techniques |
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21 | (5) |
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26 | (1) |
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2.2 Part Two - Environmental Issues and Demilitarization |
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27 | (19) |
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27 | (1) |
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2.2.2 Demilitarization Process |
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27 | (13) |
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2.2.2.1 Technical and Environmental Issues |
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27 | (2) |
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2.2.2.2 Open Burning (OB) and Open Detonation (OD) |
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29 | (3) |
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32 | (1) |
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33 | (3) |
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2.2.2.5 Examples of Cost and CO2 in Demilitarization Options |
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36 | (4) |
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2.2.3 Design for Demilitarization (DFD) |
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40 | (12) |
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2.2.3.1 NATO AOP 4518 (Revised 2018) |
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40 | (4) |
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2.2.3.2 A Munition Manager's Perspective of Disposal Plans |
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44 | (1) |
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45 | (1) |
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46 | (1) |
3 Assessment and Sustainment of the Environmental Health of Military Live-fire Training Ranges |
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47 | (28) |
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47 | (1) |
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3.2 Background and Context |
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48 | (3) |
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3.3 Munition-Related Contaminants |
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51 | (1) |
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3.4 Surface Soil Characterization in Live-fire Training Ranges |
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52 | (9) |
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53 | (1) |
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3.4.2 Data Quality and Sampling Objectives |
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53 | (3) |
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3.4.3 Importance of Soil Sample Processing to Ensure Representativeness |
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56 | (1) |
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3.4.4 How Clean is Clean? |
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57 | (1) |
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3.4.5 Risk to the Receptors Through the Transport of Munitions Constituents |
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58 | (3) |
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3.5 Methodology for the Precise Measurements of MC Sources |
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61 | (6) |
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3.5.1 Explosive Footprints in Impact Areas |
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61 | (3) |
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64 | (3) |
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3.6 Tailored Management Practices: Mitigation and Remediation |
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67 | (2) |
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3.6.1 Mitigation Measures |
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67 | (15) |
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3.6.1.1 Analytical Tool and Adsorption Method for MCs in Aqueous Samples |
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67 | (1) |
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3.6.1.2 Thermal Treatment of Shoulder Rocket Propellant-Contaminated Surface and Subsurface Soils |
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68 | (1) |
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3.7 Emerging Constituents |
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69 | (1) |
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70 | (1) |
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71 | (4) |
4 Greener Munitions |
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75 | (28) |
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4.1 Background and Context |
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75 | (2) |
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4.2 Munitions Constituents of Concern |
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77 | (1) |
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4.3 Source of Munitions Constituents |
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78 | (1) |
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4.4 Greener Munitions Development Approach |
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79 | (3) |
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82 | (10) |
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4.5.1 Energetic Formulation Selection |
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83 | (3) |
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4.5.1.1 Main Explosive Charge |
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83 | (1) |
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83 | (1) |
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83 | (1) |
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4.5.1.4 Fate, Transport, and Toxicity |
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84 | (2) |
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4.5.2 Main Propellant Charge |
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86 | (3) |
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86 | (1) |
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87 | (1) |
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87 | (1) |
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4.5.2.4 Fate, Transport, and Toxicity |
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88 | (1) |
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4.5.3 Field Demonstration |
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89 | (2) |
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89 | (1) |
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89 | (1) |
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4.5.3.3 Detonation Residues |
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90 | (1) |
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4.5.4 Life-Cycle Analysis |
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91 | (1) |
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92 | (1) |
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4.6 New Enhanced and Green Plastic Explosive for Demolition and Ordnance Disposal |
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92 | (4) |
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93 | (2) |
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93 | (1) |
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94 | (1) |
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4.6.1.3 Fate, Transport, and Toxicity |
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94 | (1) |
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95 | (1) |
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96 | (1) |
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96 | (2) |
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98 | (5) |
5 Pyrotechnics and The Environment |
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103 | (36) |
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103 | (2) |
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5.2 Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) |
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105 | (2) |
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107 | (1) |
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107 | (2) |
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109 | (1) |
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110 | (2) |
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112 | (1) |
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5.8 Raw Materials Acquisition and Quality Control |
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112 | (2) |
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5.9 Specific Materials Production |
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114 | (1) |
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115 | (1) |
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5.11 Perchlorates and Chlorates |
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116 | (1) |
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116 | (1) |
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5.13 Volatilization Smokes |
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116 | (1) |
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5.14 Magnesium Teflon Viton (MTV) Countermeasures |
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116 | (1) |
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5.15 Resins, Binders, and Solvents |
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117 | (1) |
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117 | (1) |
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118 | (1) |
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118 | (1) |
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118 | (4) |
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5.20 Perchlorates and Chlorates |
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122 | (2) |
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124 | (2) |
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124 | (1) |
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5.21.2 Volatilization Smokes |
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124 | (1) |
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125 | (1) |
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5.22 Disposal and Waste Burning |
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126 | (1) |
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127 | (1) |
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5.24 Suitably Qualified and Experienced Person (SQEP) Issues |
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128 | (1) |
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129 | (4) |
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133 | (1) |
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133 | (6) |
6 Munitions in the Sea |
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139 | (30) |
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139 | (2) |
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6.2 The Controlling Factors |
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141 | (4) |
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6.2.1 Environmental Aspects |
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141 | (1) |
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142 | (2) |
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6.2.3 Fate and Transport of Constituents |
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144 | (1) |
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6.2.4 Sea-Disposal Process |
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145 | (1) |
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6.3 Tools for Assessment and Remediation |
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145 | (5) |
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145 | (1) |
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146 | (1) |
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146 | (1) |
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146 | (1) |
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6.3.5 Navigation and Positioning |
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147 | (2) |
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149 | (1) |
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6.4 The Outstanding Problems |
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150 | (9) |
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150 | (2) |
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150 | (1) |
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150 | (1) |
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151 | (1) |
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151 | (1) |
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6.4.2 Environmental Aspects |
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152 | (4) |
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6.4.2.1 Chemical Degradation of MEC |
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152 | (1) |
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6.4.2.2 Long- Term and Long-Distance Transport |
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153 | (1) |
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6.4.2.3 Ecotoxicological Aspects |
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154 | (2) |
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6.4.3 Geopolitical Aspects |
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156 | (3) |
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159 | (3) |
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6.5.1 Global Collaboration |
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159 | (1) |
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6.5.2 Recent Global EU and NATO Efforts |
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160 | (1) |
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6.5.3 Advantages of Joint Efforts |
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161 | (1) |
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162 | (1) |
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163 | (1) |
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163 | (6) |
7 Environmental Assessment of Military Systems with the Life-Cycle Assessment Methodology |
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169 | (30) |
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7.1 Overview of the Life-Cycle Assessment Methodology |
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170 | (4) |
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7.1.1 Life-Cycle Thinking |
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170 | (1) |
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7.1.2 Life-Cycle Assessment |
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171 | (2) |
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7.1.3 Purpose of Life-Cycle Assessment Studies |
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173 | (1) |
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7.2 The Four Phases of the LCA Methodology Applied to a Case Study |
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174 | (20) |
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174 | (4) |
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175 | (1) |
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7.2.1.2 System Boundaries |
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176 | (2) |
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7.2.2 Life-Cycle Inventory |
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178 | (4) |
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7.2.3 Life-Cycle Impact Assessment |
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182 | (18) |
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7.2.3.1 Life-Cycle Impact Assessment Methods |
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185 | (2) |
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7.2.3.2 Life-Cycle Impact Assessment Software |
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187 | (1) |
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7.2.3.3 Life-Cycle Impact Assessment of the Case Study |
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188 | (6) |
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7.3 Limitations of Life-Cycle Assessment |
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194 | (1) |
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194 | (1) |
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195 | (4) |
8 Integrating the 'One Health' Approach in the Design of Sustainable Munition Systems |
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199 | (14) |
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199 | (1) |
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8.2 Munition Compounds and Aetiology of Environmental, Safety, and Occupational Health Issues: Lessons Learnt |
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199 | (1) |
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8.3 Core Operational ESOH Data: Needs and Requirements |
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200 | (7) |
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8.3.1 Life Cycle Environmental Assessment |
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200 | (1) |
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8.3.2 Bridging Communication Between Research and Acquisition |
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200 | (1) |
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8.3.3 ESOH Data Requirements |
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201 | (6) |
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201 | (6) |
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8.4 Current and Evolving Regulatory Interests |
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207 | (1) |
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8.5 Case Studies and Cost Analysis |
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207 | (3) |
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8.5.1 M116, 117, 118 Simulators |
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207 | (1) |
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208 | (1) |
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8.5.3 Cost and Time Considerations |
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208 | (2) |
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210 | (1) |
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210 | (1) |
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210 | (3) |
9 Overview of REACH Regulation and Its Implications for the Military Sector |
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213 | (14) |
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213 | (1) |
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9.2 Regulation for Hazard Substances |
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214 | (11) |
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9.2.1 Overview of Previous Legislation Concerning Hazard Substances in the European Union |
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214 | (1) |
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9.2.2 Overview of REACH Regulation |
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215 | (2) |
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9.2.3 Discussion of REACH Regulation |
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217 | (8) |
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225 | (1) |
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225 | (2) |
10 Development and Integration of Environmental, Safety, and Occupational Health Information |
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227 | (14) |
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227 | (1) |
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10.2 Phased Approach to a Toxicology Data Requirement |
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228 | (1) |
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10.3 Research, Development, Testing, and Evaluation |
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228 | (7) |
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228 | (3) |
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231 | (1) |
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10.3.3 Testing/Demonstration |
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232 | (1) |
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233 | (1) |
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10.3.5 Engineering and Manufacturing |
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234 | (1) |
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235 | (1) |
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10.4 Other Data Requirements |
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235 | (3) |
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235 | (3) |
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10.4.1.1 Fate and Transport |
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235 | (2) |
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237 | (1) |
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10.4.1.3 Field Monitoring |
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237 | (1) |
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237 | (1) |
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10.4.1.5 Occupational - Industrial Hygiene |
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237 | (1) |
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238 | (1) |
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10.4.2.1 Toxic Substance Control Act |
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238 | (1) |
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238 | (1) |
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10.4.3 Integrating Weight-of-Evidence into Decision-Making |
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238 | (1) |
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238 | (1) |
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239 | (1) |
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239 | (2) |
11 Research Priorities and the Future |
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241 | (12) |
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241 | (1) |
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242 | (1) |
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11.3 Studies and Their Effect |
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243 | (2) |
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11.4 The Problems and the Changing Requirements |
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245 | (2) |
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11.4.1 Land Management and History |
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246 | (1) |
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11.5 Security Issues and Their Impact on Requirement |
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247 | (1) |
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11.6 Future Options and Needs in a Changing Political Landscape |
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247 | (3) |
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250 | (1) |
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251 | (2) |
Index |
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253 | |