| Preface |
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xix | |
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xxiii | |
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On the Origins and Development of ``Surface Organometallic Chemistry'' |
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1 | (22) |
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1 | (3) |
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Use of Probe Molecules on Metallic Surfaces as Evidence of Coordination and Organometallic Chemistry at Metal Surfaces |
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4 | (1) |
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Chemical and Strutural Analogy between Molecular Clusters and Small Metallic Particles |
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5 | (1) |
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Analogy between Supported Molecular Clusters and Small Supported Catalytic Particles |
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6 | (3) |
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Foundation of Surface Organometallic Chemistry |
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9 | (4) |
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From Organometallic Surface Chemistry to the Elementary Steps Occurring on Surfaces and Stabilization by the Surface of Rather Unstable Molecular Species |
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13 | (2) |
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From Surface Organometallic Chemistry on Oxides to Surface Organometallic Chemistry on Metals |
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15 | (1) |
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From Surface Organometallic Chemistry to Surface-Mediated Organometallic Synthesis |
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16 | (1) |
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Single Metal Site Heterogeneous Catalysts and the Design of New Catalysts |
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17 | (6) |
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18 | (5) |
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Preparation of Single Site Catalysts on Oxides and Metals Prepared via Surface Organometallic Chemistry |
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23 | (52) |
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23 | (3) |
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Surface Organometallic Chemistry on Oxides |
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26 | (30) |
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Boron. (Case of Weakly Coordinating Lewis Acids, Such as (C6F5)3B, in the Presence of a Brønsted Base) |
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26 | (1) |
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27 | (1) |
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27 | (1) |
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28 | (1) |
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29 | (1) |
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30 | (1) |
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Synthesis and Characterization of Aerosil Silica and MCM-41 Supported Complexes (≡SiO)nTi(CH2CMe3)4-n (n = 1 and 2) |
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30 | (1) |
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Synthesis and Characterization of Titanium Hydride [ (≡SiO)pTiH4-p] Supported on MCM-41 |
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31 | (2) |
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Various Syntheses of (≡SiO)nTi(OX)4-n (n = 1, 2 or 3) Complexes Supported on Silica |
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33 | (2) |
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35 | (1) |
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Cp*ZrMe3 Chemistry on Silica SiO2(800) |
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35 | (1) |
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36 | (2) |
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38 | (1) |
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Synthesis and Characterization of (≡SiO)Ta(CH2CMe3)2(=CHCMe3) Supported on MCM-41 |
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39 | (1) |
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Synthesis, Characterization and Properties of the Tantalum Hydride [ (≡SiO)2TaHx] Supported on MCM-41 |
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40 | (2) |
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Synthesis and Characterization of Silica Supported Ta Imido Comlplexes |
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42 | (6) |
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48 | (1) |
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49 | (1) |
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Grafting of W(CH2CMe3)3(≡CCMe3) Complex on Silica(200) and Silica(700) |
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50 | (1) |
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Grafting of the Complex W(CH2CMe3)3(≡CCMe3) on Silica-Alumina and Alumina |
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51 | (1) |
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Preparation of Tungsten Hydrides on Silica, Silica-Alumina and Alumina |
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51 | (1) |
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52 | (1) |
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Surface Cationic Derivatives |
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53 | (3) |
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Reaction of Organometallic Compounds with Supported or Unsupported Group VIII Metals Particles |
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56 | (11) |
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Definitions Regarding Metallic Nanoparticles |
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56 | (3) |
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Characterization of Metallic Surfaces and Metal Particles |
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59 | (1) |
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Reactivity of Organometallic Compounds with Metallic Surfaces |
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60 | (4) |
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Mercury: Reaction of Mercuric Compounds with Ni |
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64 | (1) |
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Silicon; Reaction of Silanes with Ni, Rh, Pd, Pt |
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65 | (1) |
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Germanium: Reaction of Germanes with Ni, Rh, Pd, Pt |
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66 | (1) |
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Arsenic: Reaction of AsPh3 with Ni |
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66 | (1) |
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67 | (8) |
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68 | (7) |
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Catalytic Properties of Single Site Catalysts Prepared via Surface Organometallic Chemistry on Oxides and on Metals |
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75 | (62) |
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75 | (1) |
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Stoichiometric Activation of Alkane C-H Bonds |
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76 | (6) |
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Activation of CH4 with [ Zr]-H/silica: a Tool to Demonstrate ``Surface Heterogeneity'' and to Identify Difficulties in Achieving Single Sites on Classical Supports |
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76 | (5) |
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Stoichiometric Activation of Cyclic Alkanes by Tantalum Complexes |
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81 | (1) |
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Alkane C-C Bond Activation by Tantalum Hydrides. Low Temperature Catalytic Hydrogenolysis of Alkanes |
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82 | (5) |
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Hydrogenolysis of Acyclic Alkanes |
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82 | (4) |
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Study of the Hydrogenolysis of Cyclic Alkanes |
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86 | (1) |
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Metathesis of Acyclic Alkanes |
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87 | (5) |
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Generalities about Alkane Metathesis Reaction |
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87 | (1) |
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Alkane Metathesis in a Continuous Flow Reactor (Mechanistic Assertion) |
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88 | (3) |
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Propane Metathesis: Comparison between Supported Tantalum and Tungsten Hydrides |
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91 | (1) |
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Cross-Metathesis Reactions of Alkanes |
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92 | (3) |
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Cross-Metathesis between Toluene and Ethane |
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92 | (1) |
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Methane-Propane Cross-Metathesis (``Alkane Methane-Olysis'') |
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93 | (2) |
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95 | (4) |
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Polystyrene Modification and Hydrogenolysis of Linear Alkanes and Polyethylene by a Supported Zirconium Hydride |
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99 | (9) |
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101 | (2) |
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Some Aspects of Linear Alkanes and Polyethylene Hydrogenolysis |
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103 | (5) |
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108 | (5) |
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113 | (3) |
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Influence of the Number of Bonds (n) with the Surface on Catalytic Activity of (≡SiO)nTi(OCap)4-n |
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113 | (1) |
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Influence of -OCap Ligands of Tripodal (≡SiO)3TiOCap Complexes on the Initial Catalytic Activity |
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113 | (1) |
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OCap Ligand Lability of (≡SiO)3TiOCap During the Reaction |
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114 | (1) |
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Influence of the -OCap Ligand on Titanium Lixiviation with (≡SiO)3TiOCap |
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115 | (1) |
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115 | (1) |
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Deperoxidation of Cyclohexyl Hydroperoxide |
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116 | (1) |
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Some Applications of Supported Nanoparticles Modified by Organometallics |
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117 | (14) |
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117 | (2) |
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Group a: Evidence for a Selective Effect in Catalysis of the Grafted ``Organometallic Ligand'' |
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119 | (1) |
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Competitive Hydrogenation of Hex-2-en-1-ol and Hex-5-en-1-ol Unsaturated Alcohols |
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119 | (2) |
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Hydrogenation of α,β-Unsaturated Aldehydes |
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121 | (2) |
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Group b: Role of ``Adatoms'' on Selectivity |
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123 | (1) |
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Isomerization of 3-Carene into 2-Carene |
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124 | (1) |
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Dehydrogenation of Butan-2-ol into Methyl Ethyl Ketone |
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124 | (1) |
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Selective Hydrogenation of Acetophenone into Phenylethanol |
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124 | (1) |
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Group c: Phenomenon of ``Site Isolation'' |
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125 | (1) |
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Decane Dehydrogenation into Decene |
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126 | (2) |
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Dehydrogenation of Isobutane into Isobutene |
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128 | (1) |
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Selective Hydrogenolysis of Esters and Acids to Aldehydes and Alcohols |
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129 | (2) |
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131 | (6) |
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132 | (5) |
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Building Block Approaches to Nanostructured, Single Site, Heterogeneous Catalysts |
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137 | (30) |
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137 | (1) |
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Current Challenges in Catalysis |
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138 | (1) |
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What is a Nanostructured Catalyst? |
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139 | (2) |
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Benefits of Nanostructuring Catalysts |
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141 | (1) |
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Current Approaches to Nanostructured Catalysts |
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141 | (5) |
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Building Block Approaches to Nanostructured Materials and Catalysis |
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146 | (2) |
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Nanostructured Catalysts via a Non-Aqueous Building Block Methodology |
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148 | (3) |
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A Model for the Growth of Building Block Matrices and a Nanostructuring Strategy |
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151 | (2) |
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A General Procedure for Preparing Nanostructured Catalysts in Silicate Matrices |
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153 | (3) |
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Atomically Dispersed Titanium and Vanadium, Single Site Catalysts |
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156 | (3) |
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Bridge between Nanostructuring and Catalysis |
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159 | (3) |
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162 | (5) |
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162 | (1) |
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163 | (4) |
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Transition Metal Single Site Catalysts---From Homogeneous to Immobilized Systems |
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167 | (72) |
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167 | (1) |
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Covalently Anchored Organometallic Complexes on Unmodified Silica |
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168 | (9) |
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Monosiloxy Organometallic Complexes |
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169 | (5) |
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Disiloxy Organometallic Complexes |
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174 | (1) |
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Trisiloxy Organometallic Complexes |
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175 | (2) |
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Anchoring of Organometallic Complexes via the Metal Center |
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177 | (2) |
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178 | (1) |
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178 | (1) |
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Organometallic Complexes Anchored via a Covalent Linkage to a Ligand |
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179 | (16) |
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180 | (12) |
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192 | (3) |
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Noncovalently Anchored Organometallic Complexes |
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195 | (14) |
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Noncovalently Anchoring of Organometallic Complexes via Ionic Interactions |
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196 | (8) |
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Noncovalent Anchoring of Organometallic Complexes via Adsorption |
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204 | (5) |
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Encapsulated Organometallic Complexes |
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209 | (19) |
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Encapsulation Using the Intrazeolite Complexation Method |
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211 | (6) |
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Encapsulation Using the Intrazeolite Template Synthesis Method |
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217 | (7) |
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Encapsulation Using the Sol-Gel Method |
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224 | (4) |
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228 | (11) |
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230 | (1) |
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231 | (8) |
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Controlled Preparation of Heterogeneous Catalysts for Chemo- and Enantioselective Hydrogenation Reactions |
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239 | (54) |
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239 | (3) |
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239 | (1) |
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Conventional Impregnation Techniques |
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239 | (1) |
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Synthesis of Supported Bimetallic Catalysts from Molecular Cluster Precursors |
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240 | (1) |
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Ship-in-a-Bottle Synthesis of Bimetallic Clusters in Zeolites |
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240 | (1) |
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Controlled Assembly of Bimetallic Species on Oxide Surfaces |
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240 | (1) |
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Surface Organometallic Chemistry on Metals (SOMC/M) Approach |
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241 | (1) |
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Catalyst Preparation and Characterization |
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242 | (17) |
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242 | (1) |
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Preparation of Organobimetallic and Bimetallic Catalysts |
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243 | (3) |
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Characterization of Bimetallic Catalysts |
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246 | (7) |
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Characterization of Pt-Based Catalysts by XPS and EXAFS/XANES |
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253 | (6) |
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Hydrogenation of α,β-Unsaturated Aldehydes |
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259 | (7) |
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259 | (2) |
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Selective Hydrogenation of Crotonaldehyde |
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261 | (5) |
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Hydrogenation of Aromatic Ketones |
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266 | (12) |
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266 | (3) |
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Selective Hydrogenation of Aromatic Ketones with Catalysts Prepared via SOMC/M Techniques |
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269 | (1) |
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Acetophenone Hydrogenation |
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269 | (4) |
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Stability of the Catalysts |
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273 | (2) |
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Selective Hydrogenation of Benzophenone to Diphenylmethanol |
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275 | (3) |
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Enantioselective Hydrogenation Reactions |
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278 | (9) |
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278 | (1) |
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Synthesis of Asymmetric Heterogeneous Catalysts |
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278 | (1) |
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Synthesis of the Organotin Precursors |
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278 | (1) |
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279 | (1) |
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Hydrogenation of Ethyl Pyruvate |
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279 | (2) |
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Hydrogenation of Acetophenone |
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281 | (2) |
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Hydrogenation of 3, 4-Dimethoxyacetophenone |
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283 | (4) |
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287 | (6) |
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287 | (1) |
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287 | (6) |
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Well-Defined Surface Rhodium Siloxide Complexes and Their Application to Catalysis |
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293 | (20) |
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Molecular versus Immobilized Transition Metal Siloxide Complexes in Catalysis |
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293 | (4) |
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Synthesis, Characterization and Catalytic Activity of Well-Defined Surface Rhodium Siloxide Complexes |
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297 | (5) |
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Solid-State NMR Method in Catalysis by Surface Organometallics |
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302 | (6) |
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Mechanism of Hydrosilylation Catalyzed by Surface versus Soluble Rhodium Siloxide Complexes |
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308 | (5) |
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310 | (3) |
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Carbonyl Compounds as Metallic Precursors of Tailored Supported Catalysts |
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313 | (34) |
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Pilar Ramirez de la Piscina |
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313 | (4) |
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313 | (2) |
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Reasons for the Use of Metal Binary Carbonyl Compounds as Precursors in the Preparation of Tailored Supported Catalysts |
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315 | (2) |
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Catalysts Prepared from Metal Carbonyls of Groups 6, 7, 10 and Gold |
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317 | (6) |
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Chromium, Molybdenum and Tungsten Catalysts |
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317 | (2) |
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Manganese and Rhenium Catalysts |
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319 | (1) |
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Catalysts Containing Nickel, Palladium, Platinum and Gold |
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320 | (1) |
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Bimetallic Pt-M (M = Re, Ru) Catalysts |
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321 | (2) |
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Catalysts Prepared from Metal Carbonyls of Group 8: Iron, Ruthenium and Osmium |
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323 | (7) |
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323 | (2) |
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Fe-M (M = Mn, Ru) Catalysts |
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325 | (2) |
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327 | (3) |
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330 | (1) |
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Catalysts Prepared from Metal Carbonyls of Group 9: Cobalt, Rhodium and Iridium |
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330 | (8) |
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331 | (3) |
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334 | (1) |
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Co-Rh, Co-Ru and Rh-Fe Bimetallic Catalyst |
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335 | (2) |
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337 | (1) |
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338 | (9) |
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339 | (1) |
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339 | (8) |
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Exploiting Surface Chemistry to Prepare Metal-Supported Catalysts by Organometallic Chemical Vapor Deposition |
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347 | (28) |
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347 | (2) |
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Surface Organometallic Chemistry |
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349 | (10) |
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Active Functionalities on Alumina Supports |
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349 | (1) |
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Reactivity of [ Mo(CO)6)] Towards Hydroxyl Groups |
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350 | (1) |
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Reactivity of [ Mo(CO)6] with OH Surface Groups |
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351 | (1) |
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Hnteraction of [ Mo(CO)6] with Highly Hydroxylated Alumina |
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351 | (4) |
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Interaction of [ Mo(CO)6] with Partially and Fully Dehydroxylated Alumina |
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355 | (2) |
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Reactivity of [ Mo(CO)6] with OH Surface Groups of Different Supports |
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357 | (1) |
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The Peculiar Case of Zeolites |
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358 | (1) |
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General Trends in Metal Complex/Surface Reactivity, and Further Requirements for Metal-Supported Catalyst Preparation |
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359 | (1) |
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Strategies to Avoid the Contamination of Metal Deposits |
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359 | (8) |
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Assistance by Reactive Gases |
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360 | (1) |
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360 | (2) |
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362 | (2) |
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364 | (1) |
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Decomposition Assisted by a Pre-deposited Metal |
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365 | (2) |
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How to Manage the Nucleation and Growth Steps |
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367 | (2) |
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369 | (6) |
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370 | (5) |
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Advanced Design of Catalyst Surfaces with Metal Complexes for Selective Catalysis |
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375 | (42) |
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375 | (1) |
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Isolation and Epoxidation Activity of a Coordinatively Unsaturated Ru Complex at a SiO2 Surface |
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376 | (7) |
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Isolation of Unsaturated Ru Complexes at SiO2 Surface |
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377 | (3) |
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DFT Calculations for the Structural Transformations |
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380 | (1) |
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p-Cymene Ligand Elimination by IBA and O2 |
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380 | (1) |
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Unsaturated Ru Complex Stabilized with O2 |
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380 | (1) |
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Catalytic Epoxidation of Stilbene |
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381 | (2) |
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Chiral Self-Dimerization of V Complexes on a SiO2 Surface for Asymmetric Catalysis |
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383 | (9) |
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Chiral Self-Dimerization of V-Schiff-Base Monomer Complexes on SiO2 |
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384 | (5) |
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Asymmetric Oxidative Coupling of 2-Naphthol to BINOL |
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389 | (3) |
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Molecular Imprinting Rh-Dimer and Rh-Monomer Catalysts |
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392 | (9) |
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Principle of Molecular Imprinting for Metal Complexes on Surfaces |
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392 | (1) |
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Molecular Imprinting of Rh Dimers and Rh Monomers at SiO2 Surfaces |
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393 | (5) |
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Shape- and Size-Selective Hydrogenation of Alkenes on the Imprinted Rh Dimer Catalyst |
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398 | (3) |
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Re Clusters in HZSM-5 Pores for Direct Phenol Synthesis |
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401 | (10) |
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Preparation of the Novel HZSM-5-Supported Re Catalyst by CVD |
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402 | (1) |
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Phenol Synthesis from Benzene and O2 on the Re Catalysts |
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403 | (2) |
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Active Re-Cluster on HZSM-5 for the Phenol Synthesis |
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405 | (4) |
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Catalytically Active Structure and its Structural Transformation during the Phenol Synthesis |
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409 | (2) |
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411 | (6) |
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412 | (5) |
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Surface Organometallic Chemistry of d(0) Metal Complexes |
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417 | (38) |
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417 | (1) |
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Ligands Susceptible to React with Hydroxyl Groups of an Inorganic Oxide |
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418 | (2) |
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Nucleophilic Substitution: Alkyl, Alkoxide/Phenoxide, Halides and Amido |
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418 | (1) |
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Addition to a Double Bond: Alkylidene, Imido |
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418 | (1) |
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Addition to a Triple Bond: Alkylidine, Nitrido |
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419 | (1) |
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419 | (1) |
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Ligands Susceptible to Reaction with Lewis Acid Sites of Inorganic Oxides |
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420 | (1) |
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Reactivity of Hydrocarbyl-Metal Complexes and the Metal Atom |
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420 | (5) |
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Stability and Reactivity of (≡SiO)xMNp4-x (M = Ti, Zr, Hf) |
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422 | (1) |
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422 | (2) |
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Reactivity towards Oxygen, Alcohols and Water |
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424 | (1) |
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Inorganic Oxides as Supports for Organometallic Species |
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425 | (3) |
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425 | (1) |
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426 | (1) |
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427 | (1) |
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Models for Surface Organometallic Species |
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428 | (1) |
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428 | (1) |
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428 | (1) |
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Tuning the Catalytic Activity of Surface Organometallic Species |
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429 | (8) |
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429 | (2) |
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Alkane Activation (Metathesis, Depolymerization) |
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431 | (2) |
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433 | (2) |
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435 | (2) |
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Relevant Aspects of the Full Characterization of Some Selected Species |
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437 | (11) |
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437 | (1) |
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Basic Overview of Solid-State NMR |
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437 | (3) |
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High-Resolution SS NMR: Common Techniques and Examples of Applications to Organometallics Grafted on Surfaces |
|
|
440 | (6) |
|
X-Ray Absorption Spectroscopy |
|
|
446 | (2) |
|
|
|
448 | (7) |
|
|
|
450 | (5) |
|
Surface Organolanthanide and -Actinide Chemistry |
|
|
455 | (58) |
|
|
|
|
|
|
|
455 | (6) |
|
|
|
455 | (2) |
|
Structure and Surface Properties of Oxidic Supports |
|
|
457 | (1) |
|
|
|
457 | (3) |
|
|
|
460 | (1) |
|
|
|
461 | (1) |
|
Surface Organolanthanide Chemistry SOLnC |
|
|
461 | (19) |
|
Immobilization of Rare-Earth Metal Alkoxide and β-Diketonate Complexes |
|
|
464 | (2) |
|
Immobilization of Rare-Earth Metal (Silyl)amide Complexes |
|
|
466 | (9) |
|
Immobilization of Rare-Earth Metal Hydride, Alkyl, and Cyclopentadienyl Complexes |
|
|
475 | (3) |
|
Immobilization of Organorare-Earth Metal Chloro Complexes |
|
|
478 | (2) |
|
Surface Organoactinide Chemistry, SOAnC |
|
|
480 | (6) |
|
Catalytic Applications of SOLnC and SOAnC |
|
|
486 | (18) |
|
|
|
486 | (1) |
|
Polymerization of Ethylene and α-Olefins |
|
|
486 | (4) |
|
Polymerization of 1, 3-Butadiene and Isoprene |
|
|
490 | (3) |
|
Polymerization of Methyl Methacrylate |
|
|
493 | (1) |
|
Ring-Opening Polymerization of Oxygenated Heterocycles |
|
|
494 | (2) |
|
|
|
496 | (1) |
|
|
|
496 | (1) |
|
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|
496 | (2) |
|
|
|
498 | (1) |
|
|
|
498 | (1) |
|
Nitroaldol (Henry) Reaction |
|
|
499 | (1) |
|
Hetero Diels---Alder Reaction |
|
|
500 | (2) |
|
|
|
502 | (1) |
|
Meerwein---Ponndorf---Verley (MPV) Reduction |
|
|
503 | (1) |
|
Conclusions and Perspectives |
|
|
504 | (9) |
|
|
|
506 | (7) |
|
Isocyanide Binding Modes on Metal Surfaces and in Metal Complexes |
|
|
513 | (44) |
|
|
|
|
|
|
|
513 | (1) |
|
Modes of Isocyanide Coordination in Transition Metal Complexes |
|
|
513 | (6) |
|
Isocyanide Coordination to One Metal Atom |
|
|
513 | (2) |
|
Isocyanide Coordination to Two Metal Atoms |
|
|
515 | (3) |
|
Isocyanide Coordination to Three Metal Atoms |
|
|
518 | (1) |
|
Adsorption of Isocyanides (C≡N-R) on Metal Surfaces |
|
|
519 | (31) |
|
|
|
519 | (17) |
|
|
|
536 | (2) |
|
|
|
538 | (1) |
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|
|
539 | (3) |
|
|
|
542 | (5) |
|
|
|
547 | (1) |
|
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|
548 | (2) |
|
|
|
550 | (1) |
|
|
|
550 | (7) |
|
|
|
552 | (5) |
|
Molecular Insight for Silica-Supported Organometallic Chemistry through Transition Metal Silsesquioxanes |
|
|
557 | (42) |
|
Elsje Alessandra Quadrelli |
|
|
|
|
557 | (4) |
|
Analogy between Silica Surface Silanols and Silsesquioxane Molecules |
|
|
557 | (3) |
|
Analogy between Metal Compounds Grafted on Silica and Metal-Derivative Silsesquioxanes |
|
|
560 | (1) |
|
Goal and Scope of the
Chapter |
|
|
560 | (1) |
|
Organometallic POSS Derivatives |
|
|
561 | (15) |
|
|
|
561 | (1) |
|
Titanium, Zirconium and Hafnium |
|
|
561 | (1) |
|
|
|
561 | (9) |
|
|
|
570 | (6) |
|
|
|
576 | (1) |
|
|
|
576 | (16) |
|
|
|
576 | (2) |
|
|
|
578 | (1) |
|
Chromium, Molybdenum, and Tungsten |
|
|
579 | (1) |
|
|
|
579 | (1) |
|
|
|
580 | (3) |
|
|
|
583 | (1) |
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|
|
584 | (1) |
|
|
|
584 | (3) |
|
|
|
587 | (2) |
|
|
|
589 | (1) |
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|
|
589 | (1) |
|
|
|
589 | (1) |
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|
|
590 | (1) |
|
|
|
590 | (2) |
|
|
|
592 | (1) |
|
|
|
592 | (7) |
|
|
|
593 | (6) |
|
Surface-Mediated Nanoscale Fabrication of Metal Particles and Wires Using Mesoporous Silica Templates and Their Shape/Size Dependency in Catalysis |
|
|
599 | (40) |
|
|
|
|
|
|
|
599 | (1) |
|
Surface-Mediated Synthesis of Metal/Alloy Nanowires Using Mesoporous Templates |
|
|
600 | (6) |
|
Characterization of Nanowires and Nanoparticles in FSM-16 and HMM-1 |
|
|
606 | (5) |
|
Mechanism for Formation of Pt Nanowires in Mesoporous Silica Templates |
|
|
611 | (4) |
|
Isolation and Characterization of Metal/Alloy Nanowires Free from the Silica Supports |
|
|
615 | (3) |
|
Novel Surface-Mediated Fabrication of Rh and RhPt Nanoparticles Using Mesoporous Templates in Supercritical Carbon Dioxide |
|
|
618 | (5) |
|
Other Surface-Mediated Synthesis of Metal Nanowires on Porous Membrane and Graphite Steps |
|
|
623 | (1) |
|
Shape/Size Dependency in Catalysis of Metal/Alloy Nanowires and Particles in Mesoporous Silica Templates |
|
|
624 | (7) |
|
Active and Selective Catalysis of Pt Nanowires/FSM-16 in the PROX Reaction |
|
|
624 | (4) |
|
Catalytic CO Oxidation on Pd and Au Nanowires and Particles in FSM-16 and HMM-1 |
|
|
628 | (1) |
|
Butane Hydrogenolysis by Pt Nanowires and Particles in FSM-16 and HMM-1 |
|
|
628 | (2) |
|
|
|
630 | (1) |
|
Synthesis of Pt and Au Nanoparticle Arrays in Mesoporous Silica Films and their Electric/Magnetic Properties in Terms of the Quantum-Size Effect |
|
|
631 | (3) |
|
|
|
634 | (5) |
|
|
|
635 | (1) |
|
|
|
635 | (4) |
|
Surface-Mediated Organometallic Syntheses |
|
|
639 | (40) |
|
|
|
|
|
|
|
|
|
|
|
|
|
639 | (11) |
|
|
|
650 | (2) |
|
Neutral Complexes: [ Re2(CO)10] and [ Re(CO)3OH]4 |
|
|
650 | (1) |
|
[ Re2(CO)10] on the Surface of SiO2 |
|
|
650 | (1) |
|
[ Re(CO)3OH]4 on the Surface of SiO2 |
|
|
650 | (1) |
|
Anionic Clusters: [ Re2(CO)6(μ-OH)3]-, [ H2Re3(CO)12]- and [ Re2(CO)9]2- |
|
|
651 | (1) |
|
[ Re2(CO)6(μ-OH)3]- on the Surface of SiO2 |
|
|
651 | (1) |
|
[ H2Re3(CO)12]- and [ Re2(CO)9]2- on the Surface of MgO |
|
|
651 | (1) |
|
|
|
652 | (13) |
|
|
|
652 | (1) |
|
Anionic Cluster: [ HFe3(CO)11]- on the Surface of MgO, Al2O3 and ZnO |
|
|
652 | (1) |
|
|
|
652 | (1) |
|
Neutral Complexes and Clusters: [ Ru(CO)3Cl2]2, [ H4Ru4(CO)12], [ Ru3(CO)12], and [ Ru3(CO)10Cl2] |
|
|
652 | (3) |
|
Anionic Clusters: [ Ru6C(CO)16]2-, [ H3Ru4(CO)12]-, [ HRu3(CO)11]-, [ HRu6(CO)18]-, [ Ru6(CO)18]2- |
|
|
655 | (2) |
|
Nucleation of Ru(II) Carbonyl Species to Various Ruthenium Carbonyl Clusters on a Silica Surface |
|
|
657 | (1) |
|
|
|
658 | (1) |
|
Neutral Complexes and Clusters: α-[ Os(CO)3Cl2]2, [ Os3(CO)12], [ H4Os4(CO)12] and [ HOs3(CO)10Y] (Y = OH, OR, Cl, Br, O2CR) |
|
|
658 | (3) |
|
Anionic Clusters: [ H3Os4(CO)12]-, [ H2Os4(CO)12]2-, [ Os10C(CO)24]2-, [ Os5C(CO)14]2- and [ H5Os10(CO)24]- |
|
|
661 | (2) |
|
Nucleation of Os(II) Carbonyl Species to Various Osmium Carbonyl Clusters |
|
|
663 | (2) |
|
|
|
665 | (9) |
|
|
|
665 | (1) |
|
Neutral Cluster: [ Co4(CO)12] on a SiO2 Surface |
|
|
665 | (1) |
|
|
|
665 | (2) |
|
Neutral Complexes and Clusters: [ Rh(CO)2Cl]2, [ Rh4(CO)12] and [ Rh6(CO)16] |
|
|
667 | (1) |
|
Anionic Clusters: [ Rh12(CO)30]2-, [ Rh5(CO)15]- and [ Rh6(CO)15]2- |
|
|
668 | (1) |
|
|
|
669 | (1) |
|
Neutral Complexes and Clusters: [ Ir(CO)3Cl]n and [ Ir4(CO)12] |
|
|
669 | (2) |
|
Anionic Clusters: [ Ir4(CO)11Cl]- [ HIr4(CO)11]-, [ Ir6(CO)15]2- and [ Ir8(CO)22]2- |
|
|
671 | (1) |
|
Nucleation of Ir(I) Carbonyl Species to Various Iridium Carbonyl Clusters on a SiO2 Surface |
|
|
672 | (2) |
|
|
|
674 | (3) |
|
|
|
674 | (1) |
|
Anionic Clusters: [ Pt6(CO)12]2-, [ Pt9(CO)18]2-, [ Pt12(CO)24]2-, [ Pt15(CO)30]2- and [ Pt18(CO)36]2- |
|
|
674 | (3) |
|
Bimetallic Clusters: [ RuCo3(CO)12]-and [ PtRh5(CO)15]- |
|
|
677 | (1) |
|
[ PtRh5(CO)15]- on the Surface of MgO |
|
|
677 | (1) |
|
[ RuCo3(CO)12]- on the Surface of SiO2 |
|
|
677 | (1) |
|
|
|
677 | (2) |
| Acknowledgments |
|
679 | (1) |
| References |
|
679 | (6) |
| Index |
|
685 | |
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