| Preface |
|
xix | |
|
|
|
xxiii | |
|
On the Origins and Development of ``Surface Organometallic Chemistry'' |
|
|
1 | (22) |
|
|
|
|
|
|
|
1 | (3) |
|
Use of Probe Molecules on Metallic Surfaces as Evidence of Coordination and Organometallic Chemistry at Metal Surfaces |
|
|
4 | (1) |
|
Chemical and Strutural Analogy between Molecular Clusters and Small Metallic Particles |
|
|
5 | (1) |
|
Analogy between Supported Molecular Clusters and Small Supported Catalytic Particles |
|
|
6 | (3) |
|
Foundation of Surface Organometallic Chemistry |
|
|
9 | (4) |
|
From Organometallic Surface Chemistry to the Elementary Steps Occurring on Surfaces and Stabilization by the Surface of Rather Unstable Molecular Species |
|
|
13 | (2) |
|
From Surface Organometallic Chemistry on Oxides to Surface Organometallic Chemistry on Metals |
|
|
15 | (1) |
|
From Surface Organometallic Chemistry to Surface-Mediated Organometallic Synthesis |
|
|
16 | (1) |
|
Single Metal Site Heterogeneous Catalysts and the Design of New Catalysts |
|
|
17 | (6) |
|
|
|
18 | (5) |
|
Preparation of Single Site Catalysts on Oxides and Metals Prepared via Surface Organometallic Chemistry |
|
|
23 | (52) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
23 | (3) |
|
Surface Organometallic Chemistry on Oxides |
|
|
26 | (30) |
|
Boron. (Case of Weakly Coordinating Lewis Acids, Such as (C6F5)3B, in the Presence of a Brønsted Base) |
|
|
26 | (1) |
|
|
|
27 | (1) |
|
|
|
27 | (1) |
|
|
|
28 | (1) |
|
|
|
29 | (1) |
|
|
|
30 | (1) |
|
Synthesis and Characterization of Aerosil Silica and MCM-41 Supported Complexes (≡SiO)nTi(CH2CMe3)4-n (n = 1 and 2) |
|
|
30 | (1) |
|
Synthesis and Characterization of Titanium Hydride [ (≡SiO)pTiH4-p] Supported on MCM-41 |
|
|
31 | (2) |
|
Various Syntheses of (≡SiO)nTi(OX)4-n (n = 1, 2 or 3) Complexes Supported on Silica |
|
|
33 | (2) |
|
|
|
35 | (1) |
|
Cp*ZrMe3 Chemistry on Silica SiO2(800) |
|
|
35 | (1) |
|
|
|
36 | (2) |
|
|
|
38 | (1) |
|
Synthesis and Characterization of (≡SiO)Ta(CH2CMe3)2(=CHCMe3) Supported on MCM-41 |
|
|
39 | (1) |
|
Synthesis, Characterization and Properties of the Tantalum Hydride [ (≡SiO)2TaHx] Supported on MCM-41 |
|
|
40 | (2) |
|
Synthesis and Characterization of Silica Supported Ta Imido Comlplexes |
|
|
42 | (6) |
|
|
|
48 | (1) |
|
|
|
49 | (1) |
|
Grafting of W(CH2CMe3)3(≡CCMe3) Complex on Silica(200) and Silica(700) |
|
|
50 | (1) |
|
Grafting of the Complex W(CH2CMe3)3(≡CCMe3) on Silica-Alumina and Alumina |
|
|
51 | (1) |
|
Preparation of Tungsten Hydrides on Silica, Silica-Alumina and Alumina |
|
|
51 | (1) |
|
|
|
52 | (1) |
|
Surface Cationic Derivatives |
|
|
53 | (3) |
|
Reaction of Organometallic Compounds with Supported or Unsupported Group VIII Metals Particles |
|
|
56 | (11) |
|
Definitions Regarding Metallic Nanoparticles |
|
|
56 | (3) |
|
Characterization of Metallic Surfaces and Metal Particles |
|
|
59 | (1) |
|
Reactivity of Organometallic Compounds with Metallic Surfaces |
|
|
60 | (4) |
|
Mercury: Reaction of Mercuric Compounds with Ni |
|
|
64 | (1) |
|
Silicon; Reaction of Silanes with Ni, Rh, Pd, Pt |
|
|
65 | (1) |
|
Germanium: Reaction of Germanes with Ni, Rh, Pd, Pt |
|
|
66 | (1) |
|
Arsenic: Reaction of AsPh3 with Ni |
|
|
66 | (1) |
|
|
|
67 | (8) |
|
|
|
68 | (7) |
|
Catalytic Properties of Single Site Catalysts Prepared via Surface Organometallic Chemistry on Oxides and on Metals |
|
|
75 | (62) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
75 | (1) |
|
Stoichiometric Activation of Alkane C-H Bonds |
|
|
76 | (6) |
|
Activation of CH4 with [ Zr]-H/silica: a Tool to Demonstrate ``Surface Heterogeneity'' and to Identify Difficulties in Achieving Single Sites on Classical Supports |
|
|
76 | (5) |
|
Stoichiometric Activation of Cyclic Alkanes by Tantalum Complexes |
|
|
81 | (1) |
|
Alkane C-C Bond Activation by Tantalum Hydrides. Low Temperature Catalytic Hydrogenolysis of Alkanes |
|
|
82 | (5) |
|
Hydrogenolysis of Acyclic Alkanes |
|
|
82 | (4) |
|
Study of the Hydrogenolysis of Cyclic Alkanes |
|
|
86 | (1) |
|
Metathesis of Acyclic Alkanes |
|
|
87 | (5) |
|
Generalities about Alkane Metathesis Reaction |
|
|
87 | (1) |
|
Alkane Metathesis in a Continuous Flow Reactor (Mechanistic Assertion) |
|
|
88 | (3) |
|
Propane Metathesis: Comparison between Supported Tantalum and Tungsten Hydrides |
|
|
91 | (1) |
|
Cross-Metathesis Reactions of Alkanes |
|
|
92 | (3) |
|
Cross-Metathesis between Toluene and Ethane |
|
|
92 | (1) |
|
Methane-Propane Cross-Metathesis (``Alkane Methane-Olysis'') |
|
|
93 | (2) |
|
|
|
95 | (4) |
|
Polystyrene Modification and Hydrogenolysis of Linear Alkanes and Polyethylene by a Supported Zirconium Hydride |
|
|
99 | (9) |
|
|
|
101 | (2) |
|
Some Aspects of Linear Alkanes and Polyethylene Hydrogenolysis |
|
|
103 | (5) |
|
|
|
108 | (5) |
|
|
|
113 | (3) |
|
Influence of the Number of Bonds (n) with the Surface on Catalytic Activity of (≡SiO)nTi(OCap)4-n |
|
|
113 | (1) |
|
Influence of -OCap Ligands of Tripodal (≡SiO)3TiOCap Complexes on the Initial Catalytic Activity |
|
|
113 | (1) |
|
OCap Ligand Lability of (≡SiO)3TiOCap During the Reaction |
|
|
114 | (1) |
|
Influence of the -OCap Ligand on Titanium Lixiviation with (≡SiO)3TiOCap |
|
|
115 | (1) |
|
|
|
115 | (1) |
|
Deperoxidation of Cyclohexyl Hydroperoxide |
|
|
116 | (1) |
|
Some Applications of Supported Nanoparticles Modified by Organometallics |
|
|
117 | (14) |
|
|
|
117 | (2) |
|
Group a: Evidence for a Selective Effect in Catalysis of the Grafted ``Organometallic Ligand'' |
|
|
119 | (1) |
|
Competitive Hydrogenation of Hex-2-en-1-ol and Hex-5-en-1-ol Unsaturated Alcohols |
|
|
119 | (2) |
|
Hydrogenation of α,β-Unsaturated Aldehydes |
|
|
121 | (2) |
|
Group b: Role of ``Adatoms'' on Selectivity |
|
|
123 | (1) |
|
Isomerization of 3-Carene into 2-Carene |
|
|
124 | (1) |
|
Dehydrogenation of Butan-2-ol into Methyl Ethyl Ketone |
|
|
124 | (1) |
|
Selective Hydrogenation of Acetophenone into Phenylethanol |
|
|
124 | (1) |
|
Group c: Phenomenon of ``Site Isolation'' |
|
|
125 | (1) |
|
Decane Dehydrogenation into Decene |
|
|
126 | (2) |
|
Dehydrogenation of Isobutane into Isobutene |
|
|
128 | (1) |
|
Selective Hydrogenolysis of Esters and Acids to Aldehydes and Alcohols |
|
|
129 | (2) |
|
|
|
131 | (6) |
|
|
|
132 | (5) |
|
Building Block Approaches to Nanostructured, Single Site, Heterogeneous Catalysts |
|
|
137 | (30) |
|
|
|
|
|
137 | (1) |
|
Current Challenges in Catalysis |
|
|
138 | (1) |
|
What is a Nanostructured Catalyst? |
|
|
139 | (2) |
|
Benefits of Nanostructuring Catalysts |
|
|
141 | (1) |
|
Current Approaches to Nanostructured Catalysts |
|
|
141 | (5) |
|
Building Block Approaches to Nanostructured Materials and Catalysis |
|
|
146 | (2) |
|
Nanostructured Catalysts via a Non-Aqueous Building Block Methodology |
|
|
148 | (3) |
|
A Model for the Growth of Building Block Matrices and a Nanostructuring Strategy |
|
|
151 | (2) |
|
A General Procedure for Preparing Nanostructured Catalysts in Silicate Matrices |
|
|
153 | (3) |
|
Atomically Dispersed Titanium and Vanadium, Single Site Catalysts |
|
|
156 | (3) |
|
Bridge between Nanostructuring and Catalysis |
|
|
159 | (3) |
|
|
|
162 | (5) |
|
|
|
162 | (1) |
|
|
|
163 | (4) |
|
Transition Metal Single Site Catalysts---From Homogeneous to Immobilized Systems |
|
|
167 | (72) |
|
|
|
|
|
|
|
|
|
167 | (1) |
|
Covalently Anchored Organometallic Complexes on Unmodified Silica |
|
|
168 | (9) |
|
Monosiloxy Organometallic Complexes |
|
|
169 | (5) |
|
Disiloxy Organometallic Complexes |
|
|
174 | (1) |
|
Trisiloxy Organometallic Complexes |
|
|
175 | (2) |
|
Anchoring of Organometallic Complexes via the Metal Center |
|
|
177 | (2) |
|
|
|
178 | (1) |
|
|
|
178 | (1) |
|
Organometallic Complexes Anchored via a Covalent Linkage to a Ligand |
|
|
179 | (16) |
|
|
|
180 | (12) |
|
|
|
192 | (3) |
|
Noncovalently Anchored Organometallic Complexes |
|
|
195 | (14) |
|
Noncovalently Anchoring of Organometallic Complexes via Ionic Interactions |
|
|
196 | (8) |
|
Noncovalent Anchoring of Organometallic Complexes via Adsorption |
|
|
204 | (5) |
|
Encapsulated Organometallic Complexes |
|
|
209 | (19) |
|
Encapsulation Using the Intrazeolite Complexation Method |
|
|
211 | (6) |
|
Encapsulation Using the Intrazeolite Template Synthesis Method |
|
|
217 | (7) |
|
Encapsulation Using the Sol-Gel Method |
|
|
224 | (4) |
|
|
|
228 | (11) |
|
|
|
230 | (1) |
|
|
|
231 | (8) |
|
Controlled Preparation of Heterogeneous Catalysts for Chemo- and Enantioselective Hydrogenation Reactions |
|
|
239 | (54) |
|
|
|
|
|
|
|
239 | (3) |
|
|
|
239 | (1) |
|
Conventional Impregnation Techniques |
|
|
239 | (1) |
|
Synthesis of Supported Bimetallic Catalysts from Molecular Cluster Precursors |
|
|
240 | (1) |
|
Ship-in-a-Bottle Synthesis of Bimetallic Clusters in Zeolites |
|
|
240 | (1) |
|
Controlled Assembly of Bimetallic Species on Oxide Surfaces |
|
|
240 | (1) |
|
Surface Organometallic Chemistry on Metals (SOMC/M) Approach |
|
|
241 | (1) |
|
Catalyst Preparation and Characterization |
|
|
242 | (17) |
|
|
|
242 | (1) |
|
Preparation of Organobimetallic and Bimetallic Catalysts |
|
|
243 | (3) |
|
Characterization of Bimetallic Catalysts |
|
|
246 | (7) |
|
Characterization of Pt-Based Catalysts by XPS and EXAFS/XANES |
|
|
253 | (6) |
|
Hydrogenation of α,β-Unsaturated Aldehydes |
|
|
259 | (7) |
|
|
|
259 | (2) |
|
Selective Hydrogenation of Crotonaldehyde |
|
|
261 | (5) |
|
Hydrogenation of Aromatic Ketones |
|
|
266 | (12) |
|
|
|
266 | (3) |
|
Selective Hydrogenation of Aromatic Ketones with Catalysts Prepared via SOMC/M Techniques |
|
|
269 | (1) |
|
Acetophenone Hydrogenation |
|
|
269 | (4) |
|
Stability of the Catalysts |
|
|
273 | (2) |
|
Selective Hydrogenation of Benzophenone to Diphenylmethanol |
|
|
275 | (3) |
|
Enantioselective Hydrogenation Reactions |
|
|
278 | (9) |
|
|
|
278 | (1) |
|
Synthesis of Asymmetric Heterogeneous Catalysts |
|
|
278 | (1) |
|
Synthesis of the Organotin Precursors |
|
|
278 | (1) |
|
|
|
279 | (1) |
|
Hydrogenation of Ethyl Pyruvate |
|
|
279 | (2) |
|
Hydrogenation of Acetophenone |
|
|
281 | (2) |
|
Hydrogenation of 3, 4-Dimethoxyacetophenone |
|
|
283 | (4) |
|
|
|
287 | (6) |
|
|
|
287 | (1) |
|
|
|
287 | (6) |
|
Well-Defined Surface Rhodium Siloxide Complexes and Their Application to Catalysis |
|
|
293 | (20) |
|
|
|
|
|
|
|
|
|
Molecular versus Immobilized Transition Metal Siloxide Complexes in Catalysis |
|
|
293 | (4) |
|
Synthesis, Characterization and Catalytic Activity of Well-Defined Surface Rhodium Siloxide Complexes |
|
|
297 | (5) |
|
Solid-State NMR Method in Catalysis by Surface Organometallics |
|
|
302 | (6) |
|
Mechanism of Hydrosilylation Catalyzed by Surface versus Soluble Rhodium Siloxide Complexes |
|
|
308 | (5) |
|
|
|
310 | (3) |
|
Carbonyl Compounds as Metallic Precursors of Tailored Supported Catalysts |
|
|
313 | (34) |
|
|
|
Pilar Ramirez de la Piscina |
|
|
|
|
313 | (4) |
|
|
|
313 | (2) |
|
Reasons for the Use of Metal Binary Carbonyl Compounds as Precursors in the Preparation of Tailored Supported Catalysts |
|
|
315 | (2) |
|
Catalysts Prepared from Metal Carbonyls of Groups 6, 7, 10 and Gold |
|
|
317 | (6) |
|
Chromium, Molybdenum and Tungsten Catalysts |
|
|
317 | (2) |
|
Manganese and Rhenium Catalysts |
|
|
319 | (1) |
|
Catalysts Containing Nickel, Palladium, Platinum and Gold |
|
|
320 | (1) |
|
Bimetallic Pt-M (M = Re, Ru) Catalysts |
|
|
321 | (2) |
|
Catalysts Prepared from Metal Carbonyls of Group 8: Iron, Ruthenium and Osmium |
|
|
323 | (7) |
|
|
|
323 | (2) |
|
Fe-M (M = Mn, Ru) Catalysts |
|
|
325 | (2) |
|
|
|
327 | (3) |
|
|
|
330 | (1) |
|
Catalysts Prepared from Metal Carbonyls of Group 9: Cobalt, Rhodium and Iridium |
|
|
330 | (8) |
|
|
|
331 | (3) |
|
|
|
334 | (1) |
|
Co-Rh, Co-Ru and Rh-Fe Bimetallic Catalyst |
|
|
335 | (2) |
|
|
|
337 | (1) |
|
|
|
338 | (9) |
|
|
|
339 | (1) |
|
|
|
339 | (8) |
|
Exploiting Surface Chemistry to Prepare Metal-Supported Catalysts by Organometallic Chemical Vapor Deposition |
|
|
347 | (28) |
|
|
|
|
|
|
|
|
|
347 | (2) |
|
Surface Organometallic Chemistry |
|
|
349 | (10) |
|
Active Functionalities on Alumina Supports |
|
|
349 | (1) |
|
Reactivity of [ Mo(CO)6)] Towards Hydroxyl Groups |
|
|
350 | (1) |
|
Reactivity of [ Mo(CO)6] with OH Surface Groups |
|
|
351 | (1) |
|
Hnteraction of [ Mo(CO)6] with Highly Hydroxylated Alumina |
|
|
351 | (4) |
|
Interaction of [ Mo(CO)6] with Partially and Fully Dehydroxylated Alumina |
|
|
355 | (2) |
|
Reactivity of [ Mo(CO)6] with OH Surface Groups of Different Supports |
|
|
357 | (1) |
|
The Peculiar Case of Zeolites |
|
|
358 | (1) |
|
General Trends in Metal Complex/Surface Reactivity, and Further Requirements for Metal-Supported Catalyst Preparation |
|
|
359 | (1) |
|
Strategies to Avoid the Contamination of Metal Deposits |
|
|
359 | (8) |
|
Assistance by Reactive Gases |
|
|
360 | (1) |
|
|
|
360 | (2) |
|
|
|
362 | (2) |
|
|
|
364 | (1) |
|
Decomposition Assisted by a Pre-deposited Metal |
|
|
365 | (2) |
|
How to Manage the Nucleation and Growth Steps |
|
|
367 | (2) |
|
|
|
369 | (6) |
|
|
|
370 | (5) |
|
Advanced Design of Catalyst Surfaces with Metal Complexes for Selective Catalysis |
|
|
375 | (42) |
|
|
|
|
|
|
|
375 | (1) |
|
Isolation and Epoxidation Activity of a Coordinatively Unsaturated Ru Complex at a SiO2 Surface |
|
|
376 | (7) |
|
Isolation of Unsaturated Ru Complexes at SiO2 Surface |
|
|
377 | (3) |
|
DFT Calculations for the Structural Transformations |
|
|
380 | (1) |
|
p-Cymene Ligand Elimination by IBA and O2 |
|
|
380 | (1) |
|
Unsaturated Ru Complex Stabilized with O2 |
|
|
380 | (1) |
|
Catalytic Epoxidation of Stilbene |
|
|
381 | (2) |
|
Chiral Self-Dimerization of V Complexes on a SiO2 Surface for Asymmetric Catalysis |
|
|
383 | (9) |
|
Chiral Self-Dimerization of V-Schiff-Base Monomer Complexes on SiO2 |
|
|
384 | (5) |
|
Asymmetric Oxidative Coupling of 2-Naphthol to BINOL |
|
|
389 | (3) |
|
Molecular Imprinting Rh-Dimer and Rh-Monomer Catalysts |
|
|
392 | (9) |
|
Principle of Molecular Imprinting for Metal Complexes on Surfaces |
|
|
392 | (1) |
|
Molecular Imprinting of Rh Dimers and Rh Monomers at SiO2 Surfaces |
|
|
393 | (5) |
|
Shape- and Size-Selective Hydrogenation of Alkenes on the Imprinted Rh Dimer Catalyst |
|
|
398 | (3) |
|
Re Clusters in HZSM-5 Pores for Direct Phenol Synthesis |
|
|
401 | (10) |
|
Preparation of the Novel HZSM-5-Supported Re Catalyst by CVD |
|
|
402 | (1) |
|
Phenol Synthesis from Benzene and O2 on the Re Catalysts |
|
|
403 | (2) |
|
Active Re-Cluster on HZSM-5 for the Phenol Synthesis |
|
|
405 | (4) |
|
Catalytically Active Structure and its Structural Transformation during the Phenol Synthesis |
|
|
409 | (2) |
|
|
|
411 | (6) |
|
|
|
412 | (5) |
|
Surface Organometallic Chemistry of d(0) Metal Complexes |
|
|
417 | (38) |
|
|
|
|
|
|
|
417 | (1) |
|
Ligands Susceptible to React with Hydroxyl Groups of an Inorganic Oxide |
|
|
418 | (2) |
|
Nucleophilic Substitution: Alkyl, Alkoxide/Phenoxide, Halides and Amido |
|
|
418 | (1) |
|
Addition to a Double Bond: Alkylidene, Imido |
|
|
418 | (1) |
|
Addition to a Triple Bond: Alkylidine, Nitrido |
|
|
419 | (1) |
|
|
|
419 | (1) |
|
Ligands Susceptible to Reaction with Lewis Acid Sites of Inorganic Oxides |
|
|
420 | (1) |
|
Reactivity of Hydrocarbyl-Metal Complexes and the Metal Atom |
|
|
420 | (5) |
|
Stability and Reactivity of (≡SiO)xMNp4-x (M = Ti, Zr, Hf) |
|
|
422 | (1) |
|
|
|
422 | (2) |
|
Reactivity towards Oxygen, Alcohols and Water |
|
|
424 | (1) |
|
Inorganic Oxides as Supports for Organometallic Species |
|
|
425 | (3) |
|
|
|
425 | (1) |
|
|
|
426 | (1) |
|
|
|
427 | (1) |
|
Models for Surface Organometallic Species |
|
|
428 | (1) |
|
|
|
428 | (1) |
|
|
|
428 | (1) |
|
Tuning the Catalytic Activity of Surface Organometallic Species |
|
|
429 | (8) |
|
|
|
429 | (2) |
|
Alkane Activation (Metathesis, Depolymerization) |
|
|
431 | (2) |
|
|
|
433 | (2) |
|
|
|
435 | (2) |
|
Relevant Aspects of the Full Characterization of Some Selected Species |
|
|
437 | (11) |
|
|
|
437 | (1) |
|
Basic Overview of Solid-State NMR |
|
|
437 | (3) |
|
High-Resolution SS NMR: Common Techniques and Examples of Applications to Organometallics Grafted on Surfaces |
|
|
440 | (6) |
|
X-Ray Absorption Spectroscopy |
|
|
446 | (2) |
|
|
|
448 | (7) |
|
|
|
450 | (5) |
|
Surface Organolanthanide and -Actinide Chemistry |
|
|
455 | (58) |
|
|
|
|
|
|
|
455 | (6) |
|
|
|
455 | (2) |
|
Structure and Surface Properties of Oxidic Supports |
|
|
457 | (1) |
|
|
|
457 | (3) |
|
|
|
460 | (1) |
|
|
|
461 | (1) |
|
Surface Organolanthanide Chemistry SOLnC |
|
|
461 | (19) |
|
Immobilization of Rare-Earth Metal Alkoxide and β-Diketonate Complexes |
|
|
464 | (2) |
|
Immobilization of Rare-Earth Metal (Silyl)amide Complexes |
|
|
466 | (9) |
|
Immobilization of Rare-Earth Metal Hydride, Alkyl, and Cyclopentadienyl Complexes |
|
|
475 | (3) |
|
Immobilization of Organorare-Earth Metal Chloro Complexes |
|
|
478 | (2) |
|
Surface Organoactinide Chemistry, SOAnC |
|
|
480 | (6) |
|
Catalytic Applications of SOLnC and SOAnC |
|
|
486 | (18) |
|
|
|
486 | (1) |
|
Polymerization of Ethylene and α-Olefins |
|
|
486 | (4) |
|
Polymerization of 1, 3-Butadiene and Isoprene |
|
|
490 | (3) |
|
Polymerization of Methyl Methacrylate |
|
|
493 | (1) |
|
Ring-Opening Polymerization of Oxygenated Heterocycles |
|
|
494 | (2) |
|
|
|
496 | (1) |
|
|
|
496 | (1) |
|
|
|
496 | (2) |
|
|
|
498 | (1) |
|
|
|
498 | (1) |
|
Nitroaldol (Henry) Reaction |
|
|
499 | (1) |
|
Hetero Diels---Alder Reaction |
|
|
500 | (2) |
|
|
|
502 | (1) |
|
Meerwein---Ponndorf---Verley (MPV) Reduction |
|
|
503 | (1) |
|
Conclusions and Perspectives |
|
|
504 | (9) |
|
|
|
506 | (7) |
|
Isocyanide Binding Modes on Metal Surfaces and in Metal Complexes |
|
|
513 | (44) |
|
|
|
|
|
|
|
513 | (1) |
|
Modes of Isocyanide Coordination in Transition Metal Complexes |
|
|
513 | (6) |
|
Isocyanide Coordination to One Metal Atom |
|
|
513 | (2) |
|
Isocyanide Coordination to Two Metal Atoms |
|
|
515 | (3) |
|
Isocyanide Coordination to Three Metal Atoms |
|
|
518 | (1) |
|
Adsorption of Isocyanides (C≡N-R) on Metal Surfaces |
|
|
519 | (31) |
|
|
|
519 | (17) |
|
|
|
536 | (2) |
|
|
|
538 | (1) |
|
|
|
539 | (3) |
|
|
|
542 | (5) |
|
|
|
547 | (1) |
|
|
|
548 | (2) |
|
|
|
550 | (1) |
|
|
|
550 | (7) |
|
|
|
552 | (5) |
|
Molecular Insight for Silica-Supported Organometallic Chemistry through Transition Metal Silsesquioxanes |
|
|
557 | (42) |
|
Elsje Alessandra Quadrelli |
|
|
|
|
557 | (4) |
|
Analogy between Silica Surface Silanols and Silsesquioxane Molecules |
|
|
557 | (3) |
|
Analogy between Metal Compounds Grafted on Silica and Metal-Derivative Silsesquioxanes |
|
|
560 | (1) |
|
Goal and Scope of the
Chapter |
|
|
560 | (1) |
|
Organometallic POSS Derivatives |
|
|
561 | (15) |
|
|
|
561 | (1) |
|
Titanium, Zirconium and Hafnium |
|
|
561 | (1) |
|
|
|
561 | (9) |
|
|
|
570 | (6) |
|
|
|
576 | (1) |
|
|
|
576 | (16) |
|
|
|
576 | (2) |
|
|
|
578 | (1) |
|
Chromium, Molybdenum, and Tungsten |
|
|
579 | (1) |
|
|
|
579 | (1) |
|
|
|
580 | (3) |
|
|
|
583 | (1) |
|
|
|
584 | (1) |
|
|
|
584 | (3) |
|
|
|
587 | (2) |
|
|
|
589 | (1) |
|
|
|
589 | (1) |
|
|
|
589 | (1) |
|
|
|
590 | (1) |
|
|
|
590 | (2) |
|
|
|
592 | (1) |
|
|
|
592 | (7) |
|
|
|
593 | (6) |
|
Surface-Mediated Nanoscale Fabrication of Metal Particles and Wires Using Mesoporous Silica Templates and Their Shape/Size Dependency in Catalysis |
|
|
599 | (40) |
|
|
|
|
|
|
|
599 | (1) |
|
Surface-Mediated Synthesis of Metal/Alloy Nanowires Using Mesoporous Templates |
|
|
600 | (6) |
|
Characterization of Nanowires and Nanoparticles in FSM-16 and HMM-1 |
|
|
606 | (5) |
|
Mechanism for Formation of Pt Nanowires in Mesoporous Silica Templates |
|
|
611 | (4) |
|
Isolation and Characterization of Metal/Alloy Nanowires Free from the Silica Supports |
|
|
615 | (3) |
|
Novel Surface-Mediated Fabrication of Rh and RhPt Nanoparticles Using Mesoporous Templates in Supercritical Carbon Dioxide |
|
|
618 | (5) |
|
Other Surface-Mediated Synthesis of Metal Nanowires on Porous Membrane and Graphite Steps |
|
|
623 | (1) |
|
Shape/Size Dependency in Catalysis of Metal/Alloy Nanowires and Particles in Mesoporous Silica Templates |
|
|
624 | (7) |
|
Active and Selective Catalysis of Pt Nanowires/FSM-16 in the PROX Reaction |
|
|
624 | (4) |
|
Catalytic CO Oxidation on Pd and Au Nanowires and Particles in FSM-16 and HMM-1 |
|
|
628 | (1) |
|
Butane Hydrogenolysis by Pt Nanowires and Particles in FSM-16 and HMM-1 |
|
|
628 | (2) |
|
|
|
630 | (1) |
|
Synthesis of Pt and Au Nanoparticle Arrays in Mesoporous Silica Films and their Electric/Magnetic Properties in Terms of the Quantum-Size Effect |
|
|
631 | (3) |
|
|
|
634 | (5) |
|
|
|
635 | (1) |
|
|
|
635 | (4) |
|
Surface-Mediated Organometallic Syntheses |
|
|
639 | (40) |
|
|
|
|
|
|
|
|
|
|
|
|
|
639 | (11) |
|
|
|
650 | (2) |
|
Neutral Complexes: [ Re2(CO)10] and [ Re(CO)3OH]4 |
|
|
650 | (1) |
|
[ Re2(CO)10] on the Surface of SiO2 |
|
|
650 | (1) |
|
[ Re(CO)3OH]4 on the Surface of SiO2 |
|
|
650 | (1) |
|
Anionic Clusters: [ Re2(CO)6(μ-OH)3]-, [ H2Re3(CO)12]- and [ Re2(CO)9]2- |
|
|
651 | (1) |
|
[ Re2(CO)6(μ-OH)3]- on the Surface of SiO2 |
|
|
651 | (1) |
|
[ H2Re3(CO)12]- and [ Re2(CO)9]2- on the Surface of MgO |
|
|
651 | (1) |
|
|
|
652 | (13) |
|
|
|
652 | (1) |
|
Anionic Cluster: [ HFe3(CO)11]- on the Surface of MgO, Al2O3 and ZnO |
|
|
652 | (1) |
|
|
|
652 | (1) |
|
Neutral Complexes and Clusters: [ Ru(CO)3Cl2]2, [ H4Ru4(CO)12], [ Ru3(CO)12], and [ Ru3(CO)10Cl2] |
|
|
652 | (3) |
|
Anionic Clusters: [ Ru6C(CO)16]2-, [ H3Ru4(CO)12]-, [ HRu3(CO)11]-, [ HRu6(CO)18]-, [ Ru6(CO)18]2- |
|
|
655 | (2) |
|
Nucleation of Ru(II) Carbonyl Species to Various Ruthenium Carbonyl Clusters on a Silica Surface |
|
|
657 | (1) |
|
|
|
658 | (1) |
|
Neutral Complexes and Clusters: α-[ Os(CO)3Cl2]2, [ Os3(CO)12], [ H4Os4(CO)12] and [ HOs3(CO)10Y] (Y = OH, OR, Cl, Br, O2CR) |
|
|
658 | (3) |
|
Anionic Clusters: [ H3Os4(CO)12]-, [ H2Os4(CO)12]2-, [ Os10C(CO)24]2-, [ Os5C(CO)14]2- and [ H5Os10(CO)24]- |
|
|
661 | (2) |
|
Nucleation of Os(II) Carbonyl Species to Various Osmium Carbonyl Clusters |
|
|
663 | (2) |
|
|
|
665 | (9) |
|
|
|
665 | (1) |
|
Neutral Cluster: [ Co4(CO)12] on a SiO2 Surface |
|
|
665 | (1) |
|
|
|
665 | (2) |
|
Neutral Complexes and Clusters: [ Rh(CO)2Cl]2, [ Rh4(CO)12] and [ Rh6(CO)16] |
|
|
667 | (1) |
|
Anionic Clusters: [ Rh12(CO)30]2-, [ Rh5(CO)15]- and [ Rh6(CO)15]2- |
|
|
668 | (1) |
|
|
|
669 | (1) |
|
Neutral Complexes and Clusters: [ Ir(CO)3Cl]n and [ Ir4(CO)12] |
|
|
669 | (2) |
|
Anionic Clusters: [ Ir4(CO)11Cl]- [ HIr4(CO)11]-, [ Ir6(CO)15]2- and [ Ir8(CO)22]2- |
|
|
671 | (1) |
|
Nucleation of Ir(I) Carbonyl Species to Various Iridium Carbonyl Clusters on a SiO2 Surface |
|
|
672 | (2) |
|
|
|
674 | (3) |
|
|
|
674 | (1) |
|
Anionic Clusters: [ Pt6(CO)12]2-, [ Pt9(CO)18]2-, [ Pt12(CO)24]2-, [ Pt15(CO)30]2- and [ Pt18(CO)36]2- |
|
|
674 | (3) |
|
Bimetallic Clusters: [ RuCo3(CO)12]-and [ PtRh5(CO)15]- |
|
|
677 | (1) |
|
[ PtRh5(CO)15]- on the Surface of MgO |
|
|
677 | (1) |
|
[ RuCo3(CO)12]- on the Surface of SiO2 |
|
|
677 | (1) |
|
|
|
677 | (2) |
| Acknowledgments |
|
679 | (1) |
| References |
|
679 | (6) |
| Index |
|
685 | |
Lisainfo e-raamatute kohta