| Preface |
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v | |
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1 Review of Thermal- and Membrane-based Water Desalination Technologies and Integration with Alternative Energy Sources |
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1 | (40) |
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1 | (2) |
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3 | (2) |
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1.3 Thermal Treatment for Water Desalination |
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5 | (4) |
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5 | (1) |
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1.3.1.1 Multi-stage flash distillation |
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5 | (1) |
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1.3.1.2 Multiple-effect distillation |
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6 | (1) |
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1.3.1.3 Vapor compression distillation |
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7 | (1) |
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8 | (1) |
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1.4 Pressure-Driven Membranes Process in Water Desalination |
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9 | (8) |
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10 | (5) |
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15 | (2) |
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1.5 Concentration-Driven Membranes Process in Water Desalination |
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17 | (2) |
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1.6 Electro-Driven Membranes Process in Water Desalination |
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19 | (7) |
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20 | (3) |
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1.6.2 Membrane capacitive deionization |
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23 | (3) |
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1.7 Temperature-Driven Membranes Process in Water Desalination |
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26 | (1) |
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1.8 New Energy-Drive Process in Water Desalination |
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27 | (4) |
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1.8.1 Solar energy process in water desalination |
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27 | (2) |
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1.8.2 Nuclear energy in water desalination |
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29 | (2) |
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1.8.3 Wind energy in water desalination |
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31 | (1) |
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1.9 Conclusions and Outlook |
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31 | (4) |
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35 | (6) |
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2 Desalination, Energy and Environment Nexus |
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41 | (40) |
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41 | (2) |
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2.2 Global Brine Production |
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43 | (1) |
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2.3 The True Cost of Water |
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44 | (1) |
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2.4 Energy Consumption of Desalination |
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45 | (3) |
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2.5 Potential Environmental Impacts of Desalination |
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48 | (3) |
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51 | (22) |
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2.6.1 Middle East-Ashkelon and Sorek/Palmachim (Israel) |
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51 | (1) |
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52 | (6) |
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2.6.1.2 Sorek and Palmachim |
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58 | (4) |
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62 | (1) |
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2.6.3 Europe-Mediterranean coast of Spain |
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63 | (2) |
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2.6.4 North America-Carlsbad and Tampa Bay (US) |
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65 | (1) |
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65 | (2) |
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67 | (1) |
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2.6.5 Australia-Sydney and Adelaide |
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68 | (1) |
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68 | (3) |
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71 | (2) |
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73 | (1) |
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74 | (7) |
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3 Application of Reverse Osmosis (RO) and Nanofiltration (NF) Processes for Desalination and Reuse of Membrane Bioreactor (MBR) Effluent as Irrigation and Process Water |
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81 | (48) |
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81 | (7) |
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3.2 Desalination of MBR Effluent by NF and RO Processes for Agricultural Irrigation |
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88 | (13) |
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3.3 Utilization of MBR Effluent for Industrial Reuse after NF and RO Treatments |
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101 | (13) |
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3.4 Membrane Fouling and Concentrate Management for RO and NF Processes Used for Treatment of MBR Effluent |
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114 | (8) |
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122 | (1) |
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123 | (1) |
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123 | (6) |
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4 Polyelectrolyte Coagulants and Flocculants in Wastewater Treatment: A Fundamental Perspective |
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129 | (40) |
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129 | (2) |
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4.2 Coagulation & Flocculation in Water Treatment |
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131 | (11) |
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4.2.1 Colloidal interparticle interactions |
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132 | (4) |
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4.2.2 Mechanisms for coagulation and flocculation |
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136 | (2) |
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4.2.3 Factors influencing coagulation and flocculation |
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138 | (1) |
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138 | (2) |
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140 | (2) |
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142 | (1) |
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4.3 Polyelectrolyte Coagulants and Flocculants |
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142 | (15) |
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4.3.1 Polyelectrolyte-colloid interactions: A fundamental perspective |
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144 | (1) |
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4.3.1.1 Structure of polyelectrolyte-colloid mixtures |
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144 | (4) |
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4.3.1.2 Phase behavior of polyelectrolyte-colloidal particle mixtures |
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148 | (4) |
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4.3.2 Biopolymer flocculants |
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152 | (1) |
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4.3.2.1 Chitosan-based flocculants |
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152 | (1) |
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4.3.2.2 Starch-based flocculants |
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153 | (1) |
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4.3.3 Incorporation and performance of polyelectrolytes in wastewater treatment |
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154 | (3) |
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4.4 Summary and Future Perspectives |
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157 | (1) |
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157 | (12) |
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5 Pressure Retarded Osmosis: Modelling, Mirages and Prospects |
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169 | (24) |
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169 | (4) |
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173 | (13) |
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5.2.1 Concentration polarisation in PRO |
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173 | (7) |
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180 | (1) |
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5.2.3 Modelling of the barrier layer and overall equation |
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181 | (1) |
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5.2.4 Modelling PRO using the SKK model |
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182 | (2) |
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5.2.5 State of the art model for PRO |
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184 | (2) |
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186 | (3) |
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189 | (1) |
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189 | (4) |
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6 Modeling Ion Transport in Electrodialysis of Concentrated Solutions |
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193 | (34) |
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193 | (3) |
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196 | (15) |
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6.2.1 Modeling transport in channels |
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198 | (3) |
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6.2.2 Modeling transport in membranes |
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201 | (4) |
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6.2.3 The ideal solution model |
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205 | (1) |
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205 | (1) |
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6.2.4.1 Spacer-free channels |
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205 | (1) |
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6.2.4.2 Spacer-filled channels |
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205 | (1) |
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6.2.5 Boundary conditions |
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206 | (1) |
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6.2.6 Numerical method and mesh structure |
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207 | (1) |
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6.2.7 Comparison of the model results with the experimental data |
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208 | (3) |
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6.3 Results and Discussion |
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211 | (10) |
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6.3.1 Ideal solution-spacer-free cell |
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211 | (2) |
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6.3.2 Non-ideal solution impacts |
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213 | (4) |
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217 | (4) |
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221 | (1) |
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222 | (1) |
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222 | (5) |
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7 Membrane Distillation Pilot Units for Seawater Desalination |
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227 | (36) |
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227 | (2) |
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7.2 Membrane Distillation Projects |
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229 | (9) |
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7.3 Commercial MD Modules for Pilot Scale Applications |
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238 | (4) |
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7.3.1 Scarab development AB (Sweden) |
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239 | (1) |
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7.3.2 Solar spring GmbH (Germany) |
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240 | (1) |
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7.3.3 Aquastill BV (The Netherlands) |
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241 | (1) |
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7.3.4 Memsys GmbH (Germany) |
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241 | (1) |
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7.3.5 Econity, INC (Korea)) |
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242 | (1) |
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7.4 Membrane Distillation Pilot Plants |
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242 | (13) |
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7.4.1 Membrane Distillation pilots for seawater treatment |
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248 | (4) |
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7.4.2 Membrane Distillation pilots for RO brine treatment |
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252 | (1) |
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7.4.2.1 AGMD and PGMD/LGMD modules |
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252 | (2) |
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254 | (1) |
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7.5 Membrane Crystallization in Desalination |
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255 | (1) |
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7.6 Future Research and Main Conclusions |
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256 | (1) |
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257 | (6) |
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8 Energy Efficiency Metrics in Membrane Distillation |
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263 | (26) |
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263 | (2) |
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8.2 MD Energy Efficiency Metrics |
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265 | (16) |
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265 | (1) |
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8.2.2 First-law efficiency: GOR, evaporation efficiency, SEC |
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266 | (4) |
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270 | (2) |
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8.2.4 Heat recovery parameter (e-NTU) |
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272 | (3) |
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8.2.5 Second law efficiency |
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275 | (2) |
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8.2.6 Relating performance parameters to one another |
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277 | (2) |
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279 | (2) |
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8.2.8 Performance metric summary |
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281 | (1) |
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8.3 Designing MD Configuration with MD Metrics |
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281 | (2) |
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283 | (1) |
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283 | (2) |
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285 | (4) |
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9 Capacitive Deionization |
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289 | (48) |
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9.1 Introduction to Capacitive Deionization |
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289 | (1) |
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290 | (10) |
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9.2.1 Basic CDI architectures |
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292 | (2) |
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294 | (1) |
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295 | (2) |
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9.2.4 CDI operating methods |
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297 | (1) |
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9.2.4.1 Electrical control methods |
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297 | (2) |
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9.2.4.2 Flowrate control methods |
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299 | (1) |
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9.3 CDI Performance and Water Cost |
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300 | (15) |
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9.3.1 Energy consumption and thermodynamic efficiency |
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301 | (1) |
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9.3.2 Salinity reduction and water recovery |
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301 | (3) |
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304 | (4) |
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9.3.4 Performance indicators: Charge efficiency |
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308 | (2) |
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9.3.5 Performance indicators: Capacitance and salt adsorption capacity |
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310 | (2) |
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9.3.6 Performance indicators: Resistance |
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312 | (3) |
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9.4 Selective Removal of Contaminant Ions |
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315 | (9) |
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315 | (1) |
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9.4.2 Overview of selectivity in CDI and i-CDI |
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316 | (1) |
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9.4.3 Theory: Intrinsic and cycle ion selectivity |
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316 | (2) |
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9.4.4 Quantification of intrinsic selectivity |
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318 | (2) |
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9.4.5 Quantification of cycle selectivity in i-CDI |
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320 | (3) |
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9.4.6 Effect of regeneration voltage and the ratio of concentrations in cycle selectivity in i-CDI |
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323 | (1) |
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324 | (1) |
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325 | (1) |
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325 | (12) |
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10 Surface Modified Reverse Osmosis Membranes |
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337 | (76) |
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10.1 Overview of Reverse Osmosis (RO) |
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337 | (7) |
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10.1.1 Water and salt transport in RO membranes |
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337 | (2) |
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10.1.2 Polyamide (PA) thin film composite (TFC) membrane |
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339 | (1) |
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10.1.3 Water permeability and water/salt selectivity tradeoff |
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340 | (2) |
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10.1.4 Polyamide interfacial polymerization |
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342 | (1) |
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10.1.5 Seawater reverse osmosis (SWRO) membrane fouling |
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343 | (1) |
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10.2 The Impact of PA Surface Modification on RO Desalination Performance |
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344 | (57) |
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344 | (1) |
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10.2.2 Coating (physical adsorption) |
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345 | (8) |
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10.2.3 Layer-by-layer (LbL) assembly |
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353 | (13) |
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10.2.4 Initiated chemical vapor deposition (iCVD) |
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366 | (8) |
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10.2.5 Polymer grafting ("Grafting to") |
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374 | (6) |
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10.2.6 Graft polymerization ("Grafting from") |
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380 | (21) |
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10.3 Salt Rejection-Permeability Tradeoff |
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401 | (4) |
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405 | (8) |
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11 Scale-up of Nanocomposite Membranes Embedded with Silver Nanoparticles: From Laboratory Scale to Production Scale |
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413 | (28) |
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11.1 Background and Discussion |
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413 | (11) |
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11.1.1 Incorporation of AgNPs into polymeric membranes |
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415 | (1) |
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11.1.1.1 Blending AgNPs into the membrane matrix |
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416 | (1) |
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11.1.1.2 Surface modification |
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417 | (1) |
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11.1.1.3 Layer-by-layer (LBL) assembly |
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418 | (1) |
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11.1.2 Scalable fabrication of AgNPs membranes in a production scale |
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419 | (1) |
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11.1.2.1 Comparison of doctor blade casting and slot die casting of nanocomposite membranes |
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420 | (1) |
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11.1.2.2 Advantage of slot die casting for scale up |
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421 | (3) |
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11.2 Fabricate AgNPs Membranes from Laboratory to Production Scale |
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424 | (10) |
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11.2.1 Performance of AgNPs membranes fabricated at laboratory and production scales |
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424 | (3) |
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11.2.2 Thiol-based covalent addition of AgNPs to membranes |
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427 | (3) |
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11.2.3 Scale-up work of thiol-based covalent addition of AgNPs to membranes |
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430 | (4) |
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434 | (1) |
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434 | (1) |
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434 | (7) |
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12 Application of MOFs Nanomaterials and MOFs-Membranes in Water Treatment |
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441 | (18) |
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Dipeshkumar D. Kachhadiya |
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441 | (2) |
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12.2 Nanotechnology for Wastewater Treatment |
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443 | (8) |
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443 | (1) |
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12.2.1.1 Carbon based nano-adsorbents |
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443 | (2) |
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12.2.1.2 Metal-based nano-adsorbents |
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445 | (1) |
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12.2.1.3 Polymer-based nano-adsorbents |
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446 | (1) |
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12.2.2 Membrane and membrane-based processes |
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446 | (1) |
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446 | (2) |
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12.2.2.2 MOF and MOF based membrane application for wastewater treatment |
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448 | (3) |
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12.3 Conclusions and Futuristic Aspects |
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451 | (1) |
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452 | (7) |
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13 Light Transmitting Substrates for Convenient Solar Illumination of Nanophotocatalyst Coatings on Membranes for Low Pressure Water Filtration |
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459 | (32) |
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459 | (2) |
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461 | (4) |
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13.2.1 Titania as a photocatalyst in water treatment |
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461 | (2) |
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13.2.2 Photocatalytic membranes |
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463 | (2) |
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13.3 Light Transmitting Photocatalytic Membrane |
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465 | (16) |
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13.3.1 Titania immobilisation methods |
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465 | (1) |
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13.3.2 Choosing an appropriate substrate |
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466 | (1) |
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13.3.3 Light transparent substrates for photocatalytic membrane water treatment |
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466 | (1) |
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467 | (1) |
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13.3.3.2 Phase separated porous glass |
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468 | (2) |
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13.3.3.3 Shirasu porous glass |
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470 | (2) |
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13.3.3.4 Other innovative light transmitting substrates |
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472 | (9) |
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13.4 Conclusion and Future Perspectives |
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481 | (1) |
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482 | (9) |
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14 Transport in Carbon Nanotube Pores: Implications for Next Generation Water Purification Technologies |
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491 | (38) |
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14.1 Introduction: Biomimetic Nanopore Membranes |
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491 | (2) |
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493 | (5) |
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494 | (1) |
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495 | (1) |
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14.2.3 Mechanical properties |
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496 | (1) |
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14.2.4 Vibrational spectra of CNTs |
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497 | (1) |
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14.3 Molecular Dynamic Simulations and Early Experimental Observation of Water in CNTs |
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498 | (3) |
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14.4 Experimental Platforms for Observing Transport in CNTs |
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501 | (7) |
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14.4.1 Aligned and semi-aligned carbon nanotube membranes |
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502 | (2) |
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14.4.2 Single CNT channel platforms |
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504 | (2) |
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14.4.3 Carbon nanotube porins: biomimetic CNT membrane pores |
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506 | (2) |
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14.5 Water Transport in Carbon Nanotube Channels |
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508 | (4) |
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14.6 Ion Transport, Ion Rejection, and Water/Ion Permselectivity in Carbon Nanotube Pores |
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512 | (8) |
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14.7 Outlook: Carbon Nanotube Pores in the Next Generation Advanced Water Purification Solutions |
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520 | (1) |
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521 | (1) |
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521 | (8) |
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15 Carbon Nanomaterials in Desalination Process |
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529 | (54) |
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529 | (1) |
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15.2 Desalination Technologies |
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530 | (9) |
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531 | (1) |
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15.2.1.1 Multi effect distillation |
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531 | (1) |
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15.2.1.2 Multi-stage flash |
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532 | (2) |
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15.2.1.3 Membrane distillation |
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534 | (1) |
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535 | (4) |
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539 | (12) |
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539 | (1) |
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15.3.2 CNT-based membranes |
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540 | (1) |
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15.3.2.1 CNT-based membrane properties |
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540 | (6) |
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15.3.2.2 Advantages of CNT-based membranes |
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546 | (2) |
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15.3.2.3 Challenges and strategic research prospects of CNT membranes |
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548 | (2) |
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15.3.3 Graphene oxide based membranes |
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550 | (1) |
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15.4 Electrical Potential |
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551 | (9) |
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551 | (2) |
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15.4.1.1 Carbon nanotubes (CNT) |
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553 | (1) |
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15.4.1.2 Graphene and its derivatives |
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554 | (1) |
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15.4.1.3 Carbon nanofibers (CNFs) |
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555 | (1) |
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15.4.1.4 Activated carbon |
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556 | (1) |
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15.4.2 Capacitive deionization |
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557 | (3) |
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560 | (1) |
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561 | (22) |
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16 Nanomaterials for Pressure Retarded Osmosis |
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583 | (36) |
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583 | (1) |
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16.2 Energy Generation through Salinity Gradient |
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584 | (3) |
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16.3 Pressure Retarded Osmosis |
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587 | (24) |
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16.3.1 Benefits, drawbacks and challenges in PRO |
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587 | (3) |
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16.3.2 Internal Concentration Polarization (ICP) impacts on PRO process |
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590 | (3) |
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16.3.3 PRO process design at estuaries |
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593 | (1) |
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16.3.4 PRO for power generation and desalination |
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594 | (1) |
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595 | (2) |
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16.3.5.1 Thin Film Composite (TFC) membranes |
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597 | (3) |
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16.3.5.2 Thin Film Nanocomposite (TFN) membranes |
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600 | (11) |
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16.4 Conclusion and Perspective |
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611 | (1) |
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612 | (7) |
| Index |
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619 | |