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Chapter 1 Introduction -- Carbon Capture and Storage |
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1 | (7) |
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1 | (4) |
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5 | (3) |
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6 | (2) |
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Chapter 2 Understanding the Role of CCS Deployment in Meeting Ambitious Climate Goals |
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8 | (28) |
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8 | (3) |
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2.2 Climate Science Fundamentals |
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11 | (6) |
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2.2.1 Cumulative Emissions and Peak Warming |
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12 | (4) |
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2.2.2 Carbon Budgets and Historical Emissions |
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16 | (1) |
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2.3 Taxonomy of Climate-economic Scenarios Meeting-Temperature Goals |
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17 | (11) |
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2.3.1 Integrated Assessment of Climate Change |
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17 | (2) |
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2.3.2 Dimensions of Mitigation Pathways |
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19 | (6) |
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2.3.3 Climate Constraints on the Fate of Extracted Carbon |
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25 | (3) |
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2.4 Characteristics of CCS Deployment in IAM Scenarios |
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28 | (1) |
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29 | (7) |
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30 | (1) |
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31 | (5) |
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Chapter 3 Solvent-based Absorption |
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36 | (33) |
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3.1 History of Solvent-based Absorption |
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36 | (8) |
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3.1.1 History of Solvents |
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36 | (4) |
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3.1.2 The Development of Solvent-based CO2 Capture Processes |
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40 | (4) |
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44 | (1) |
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3.3 Amines in Organic Co-solvents |
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45 | (3) |
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3.4 Concentrated Solvents |
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48 | (4) |
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52 | (8) |
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3.5.1 Evaporative Losses, Toxicity and Foaming |
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53 | (1) |
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54 | (1) |
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3.5.3 Oxidative Degradation |
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55 | (1) |
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3.5.4 Heat Stable Salts (HSS) |
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56 | (2) |
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3.5.5 Thermal Degradation |
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58 | (2) |
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60 | (1) |
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3.7 What is Next for Solvent Absorption? |
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61 | (8) |
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62 | (1) |
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62 | (7) |
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69 | (37) |
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69 | (2) |
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4.2 Task-specific ILs/Functionalised ILs for Chemisorption of CO2 |
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71 | (6) |
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4.2.1 Amine-functionalised Cations |
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71 | (3) |
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4.2.2 Amine-functionalised Anions |
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74 | (1) |
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4.2.3 Aprotic Heterocyclic Anions (AHAs) |
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75 | (2) |
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4.2.4 Alternative Functional Groups |
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77 | (1) |
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4.3 CO2 Capture through IL-based Proton Transfer |
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77 | (3) |
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4.4 ILs with Multiple Functional Groups for Capture |
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80 | (1) |
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4.5 Methods for Overcoming Mass Transport Limits |
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81 | (1) |
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4.6 IL Blends with Amines |
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81 | (1) |
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82 | (5) |
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4.8 Ionic Liquid Membranes |
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87 | (3) |
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4.9 Molecular Simulations of CO2 with ILs |
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90 | (4) |
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4.10 Challenges and Opportunities with IL-based CCS |
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94 | (1) |
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95 | (11) |
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95 | (11) |
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Chapter 5 CO2 Capture by Adsorption Processes |
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106 | (62) |
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106 | (1) |
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5.2 Adsorbents for CO2 Capture |
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107 | (26) |
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5.2.1 Applications and Opportunities |
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107 | (2) |
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5.2.2 Mechanisms of Adsorption |
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109 | (2) |
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5.2.3 Mechanisms of Selectivity and Separation |
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111 | (3) |
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5.2.4 Carbonaceous Adsorbents |
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114 | (2) |
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5.2.5 Silicas and Aluminas |
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116 | (1) |
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116 | (2) |
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5.2.7 Metal-organic frameworks |
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118 | (6) |
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5.2.8 Microporous Organic Polymers |
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124 | (2) |
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5.2.9 Amine Hybridised Adsorbents |
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126 | (3) |
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5.2.10 Adsorbents for High Temperature Separations |
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129 | (3) |
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5.2.11 Stimuli Responsive Adsorbents |
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132 | (1) |
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133 | (2) |
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5.4 Requirements of an Adsorbent to be Useful in Practice |
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135 | (2) |
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5.5 Gas/Solid Contacting Devices |
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137 | (2) |
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5.6 Regeneration of the Adsorbent |
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139 | (12) |
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5.6.1 Pressure Swing Adsorption |
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140 | (7) |
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5.6.2 Temperature Swing Adsorption |
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147 | (3) |
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5.6.3 Alternative Regeneration Technologies and Hybrid Systems |
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150 | (1) |
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151 | (17) |
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152 | (16) |
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Chapter 6 Oxy-fuel Combustion Capture Technology |
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168 | (21) |
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168 | (2) |
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170 | (8) |
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6.2.1 Cryogenic Air Separation Units |
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171 | (6) |
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6.2.2 Membrane Technology |
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177 | (1) |
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178 | (4) |
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179 | (2) |
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181 | (1) |
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6.3.3 Opportunities for Improvement |
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181 | (1) |
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182 | (2) |
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184 | (5) |
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185 | (1) |
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185 | (4) |
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Chapter 7 Chemical Looping Technologies for CCS |
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189 | (49) |
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189 | (2) |
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191 | (1) |
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7.3 Chemical Looping Air Separation |
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192 | (6) |
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193 | (2) |
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7.3.2 Oxygen Carrier Materials |
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195 | (2) |
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7.3.3 Practical Experience |
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197 | (1) |
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7.3.4 Economics and Scale-up |
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197 | (1) |
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7.3.5 Research Priorities |
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197 | (1) |
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7.4 Chemical Looping Combustion |
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198 | (7) |
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199 | (2) |
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201 | (2) |
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7.4.3 Practical Experience |
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203 | (1) |
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7.4.4 Economics and Scale-up |
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203 | (1) |
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7.4.5 Research Priorities |
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204 | (1) |
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7.5 Chemical Looping Hydrogen Production |
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205 | (10) |
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205 | (3) |
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208 | (5) |
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7.5.3 Practical Experience |
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213 | (1) |
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7.5.4 Economics and Scale-up |
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214 | (1) |
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7.5.5 Research Priorities |
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214 | (1) |
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215 | (9) |
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215 | (2) |
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7.6.2 Practical Experience |
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217 | (3) |
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220 | (2) |
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7.6.4 Economics and Scale-up |
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222 | (1) |
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7.6.5 Research Priorities |
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223 | (1) |
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224 | (14) |
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224 | (14) |
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Chapter 8 An Introduction to Subsurface CO2 Storage |
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238 | (58) |
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238 | (1) |
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8.2 The Geological Setting |
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239 | (5) |
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8.3 Geological Fluid Dynamics |
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244 | (34) |
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8.3.1 The Reactive Flow Processes of CO2 Storage |
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244 | (2) |
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8.3.2 Fluid Chemical, Thermophysical, and Interfacial Properties |
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246 | (5) |
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8.3.3 Geochemical Reaction Processes |
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251 | (6) |
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8.3.4 Fluid Flow through the Pores of Rocks |
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257 | (3) |
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8.3.5 The Continuum Flow Properties of Subsurface Rocks |
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260 | (6) |
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8.3.6 Large Scale Characteristics of Flow |
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266 | (6) |
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8.3.7 Geomechanics -- Fractures, Faults, and Seismicity |
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272 | (6) |
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8.4 Engineering Aspects of Subsurface CO2 Storage |
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278 | (3) |
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8.4.1 Site Characterisation and Reservoir Management |
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278 | (1) |
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8.4.2 Monitoring the Subsurface |
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279 | (2) |
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281 | (15) |
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8.5.1 Mass Flows and Analogues for Large Scale Storage |
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281 | (3) |
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8.5.2 Resource Assessment for CO2 Storage Potential |
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284 | (2) |
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8.5.3 Models for Estimating Storable Quantities |
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286 | (1) |
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8.5.4 Estimates of Regional and Global Storage Resources |
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287 | (1) |
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288 | (8) |
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Chapter 9 Carbon Capture and Storage from Industrial Sources |
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296 | (19) |
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296 | (2) |
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9.2 Differences Between CCS in the Industrial and Power Sectors |
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298 | (4) |
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9.3 Carbon Capture Technologies and Opportunities by Sector |
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302 | (5) |
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9.3.1 Iron and Steel Industry |
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302 | (2) |
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304 | (1) |
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9.3.3 Petroleum Refining Industry |
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305 | (1) |
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306 | (1) |
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9.3.5 High Purity Sources |
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307 | (1) |
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9.4 Cost of Industrial CCS |
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307 | (2) |
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309 | (1) |
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9.6 Prospects for Industrial CCS Compared to Power CCS |
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310 | (1) |
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311 | (4) |
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312 | (3) |
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Chapter 10 Applications of CCS in the Cement Industry |
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315 | (38) |
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10.1 Introduction to Cement |
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315 | (2) |
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10.2 Non-CCS Mitigation Opportunities |
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317 | (2) |
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10.3 Carbon Capture in the Cement Industry |
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319 | (16) |
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10.3.1 Post-combustion Capture |
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320 | (8) |
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328 | (5) |
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333 | (2) |
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10.4 Notable Pilot Projects |
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335 | (1) |
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10.4.1 Dania, Denmark, 2009-2012 |
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335 | (1) |
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10.4.2 HECLOT, Taiwan, 2013 |
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335 | (1) |
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10.4.3 Norcem CO2 Capture Project, Norway, 2014-2017 |
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335 | (1) |
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10.4.4 LEILAC, Belgium, 2016-2020 |
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336 | (1) |
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10.5 Cost of CO2 Capture at Cement Plants |
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336 | (5) |
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10.5.1 Capital Cost Estimations |
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336 | (2) |
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10.5.2 Estimated Operating Costs and Overall Costs of Capture |
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338 | (2) |
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10.5.3 Cost of Carbon Capture on Cement Plants -- Conclusion |
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340 | (1) |
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10.6 Installing Carbon Capture at Cement Plants |
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341 | (4) |
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10.6.1 Available Space and Permissions |
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341 | (1) |
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10.6.2 Carbon Capture Technology Availability |
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342 | (1) |
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10.6.3 Opportunity Cost of Retrofit |
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342 | (2) |
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10.6.4 Access to CO2 Transport and Storage Infrastructure |
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344 | (1) |
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10.7 Capturing CO2 in Portland Cement Products |
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345 | (1) |
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10.8 Conclusion: The Way Forward for CCS in Cement |
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346 | (7) |
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348 | (5) |
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Chapter 11 CCS in the Iron and Steel Industry |
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353 | (39) |
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11.1 Introduction to Iron and Steel |
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353 | (10) |
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11.1.1 Process CO2 Emissions |
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357 | (3) |
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11.1.2 Iron and Steel Plant Lifetimes |
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360 | (2) |
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362 | (1) |
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11.2 Post-combustion Capture -- Retrofit Technologies |
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363 | (9) |
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363 | (2) |
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365 | (1) |
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366 | (1) |
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11.2.4 Mineral Carbonation |
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367 | (2) |
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11.2.5 Oxyfuel Top Gas Recycled Blast Furnace (TGRBF) with CCS |
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369 | (3) |
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11.3 New Builds and Technology Changes |
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372 | (5) |
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11.3.1 Hydrogen Direct Reduction Technology |
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373 | (1) |
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11.3.2 Smelting Reduction Technologies |
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374 | (1) |
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11.3.3 Direct Reduced Iron with Natural Gas |
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375 | (1) |
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11.3.4 Direct Electrolysis of Iron |
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376 | (1) |
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11.4 Technology Development Initiatives and Pilot Scale Projects |
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377 | (4) |
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379 | (1) |
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379 | (1) |
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11.4.3 Pohang Iron and Steel Company (POSCO) |
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380 | (1) |
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11.4.4 CO2 Ultimate Reduction in Steelmaking Process by Innovative Technology for Cool Earth 50 (COURSE50) |
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380 | (1) |
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380 | (1) |
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11.5 Cost of CO2 Capture from Iron and Steel Production |
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381 | (3) |
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11.5.1 Costs per Tonne of CO2 |
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381 | (2) |
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11.5.2 Capital, Operating and Maintenance Costs |
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383 | (1) |
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11.5.3 Policy Considerations |
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384 | (1) |
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384 | (8) |
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385 | (7) |
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Chapter 12 CCS in Electricity Systems |
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392 | (34) |
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392 | (2) |
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12.2 The Electricity System Transition |
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394 | (7) |
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395 | (1) |
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12.2.2 Electricity Markets |
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396 | (4) |
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400 | (1) |
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12.3 Systemic Technology Valuation |
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401 | (4) |
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12.3.1 The Systems Perspective |
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401 | (1) |
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12.3.2 Essential Technology Features and Integration Effects |
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402 | (1) |
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12.3.3 Systemic Technology Valuation |
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403 | (2) |
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12.4 The Role and Value of CCS-equipped Power Generation |
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405 | (12) |
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12.4.1 Illustrative System Integration Effects of CCS Deployment |
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405 | (4) |
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12.4.2 Quantitative Evaluation of CCS Deployment via Whole-systems Modelling |
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409 | (8) |
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12.5 Flexibility in CCS-equipped Power Generation |
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417 | (3) |
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12.5.1 The Value of Flexible CCS-equipped Power Plants in the Electricity System |
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417 | (1) |
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12.5.2 Comparison of Flexible CCS Technologies |
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418 | (2) |
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420 | (6) |
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421 | (1) |
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422 | (1) |
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422 | (4) |
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Chapter 13 Carbon Capture and Utilisation |
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426 | (21) |
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426 | (3) |
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13.2 CO2 into Fuels and Chemicals |
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429 | (7) |
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436 | (3) |
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13.4 CO2 as a Working Fluid to Extract Additional Energy Sources |
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439 | (2) |
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13.5 CO2 Utilisation and Climate Change |
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441 | (2) |
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443 | (4) |
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444 | (3) |
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Chapter 14 Negative Emissions Technologies |
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447 | (65) |
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14.1 The Need for Negative Emissions |
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447 | (1) |
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14.2 Proposed Negative Emissions Technologies |
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448 | (4) |
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14.2.1 Afforestation and Reforestation (AR) |
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448 | (1) |
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14.2.2 Biochar and Soil Carbon Sequestration (SCS) |
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449 | (1) |
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14.2.3 Enhanced Weathering of Minerals |
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450 | (1) |
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14.2.4 Ocean Fertilisation |
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451 | (1) |
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14.3 Bio-energy with Carbon Capture and Storage (BECCS) |
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452 | (31) |
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452 | (3) |
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14.3.2 Which Feedstock for BECCS? |
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455 | (5) |
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14.3.3 Comparing BECCS Pathways to Negative Emissions |
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460 | (6) |
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14.3.4 Sustainability Challenges of BECCS |
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466 | (14) |
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14.3.5 Converting Bioenergy into Negative Emissions: BECCS Carbon Efficiency |
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480 | (1) |
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481 | (2) |
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14.4 Direct Air Capture (DAC) |
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483 | (16) |
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14.4.1 Motivations for DAC |
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483 | (2) |
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14.4.2 CO2 Separation Technologies |
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485 | (1) |
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14.4.3 Thermodynamics of Capturing CO2 from Air |
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486 | (3) |
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14.4.4 Current Technology |
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489 | (7) |
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14.4.5 Cost of Direct Air Capture |
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496 | (1) |
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14.4.6 Scalability and Roll-out Potential |
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497 | (2) |
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14.5 Economic and Energetic Analysis of NETs |
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499 | (2) |
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501 | (1) |
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502 | (10) |
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503 | (1) |
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503 | (9) |
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Chapter 15 New Technology Development for Carbon Capture |
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512 | (24) |
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512 | (1) |
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15.2 Benchmarking CO2 Technology |
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513 | (19) |
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15.2.1 Metric of Comparison |
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513 | (1) |
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15.2.2 Framework for Technology Evaluation |
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514 | (1) |
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15.2.3 Theory Supporting Evaluation: 1st and 2nd Law Analysis |
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515 | (11) |
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15.2.4 Cost Considerations in CCS Technology Evaluation |
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526 | (4) |
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15.2.5 Size Considerations in Evaluation |
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530 | (2) |
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15.3 Impactful R&D Trajectories Beyond the CCS System |
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532 | (1) |
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533 | (1) |
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534 | (2) |
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535 | (1) |
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Chapter 16 The Political Economy of Carbon Capture and Storage |
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536 | (23) |
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536 | (3) |
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539 | (2) |
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16.3 Comparative Political Economy |
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541 | (10) |
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543 | (1) |
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544 | (1) |
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544 | (1) |
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545 | (1) |
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546 | (1) |
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547 | (1) |
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548 | (1) |
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548 | (2) |
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550 | (1) |
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16.3.10 Peripheral Countries |
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550 | (1) |
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551 | (3) |
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16.4.1 Perfect Storm of 2009 |
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552 | (1) |
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16.4.2 Getting the Policies Right |
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552 | (1) |
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16.4.3 CCS as a Trendsetter for Climate Policy |
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553 | (1) |
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16.4.4 Damaged Reputation |
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553 | (1) |
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16.4.5 The Lumpy Nature of CCS Projects |
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553 | (1) |
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16.4.6 A Role for Industrial Policy? |
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554 | (1) |
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554 | (5) |
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555 | (4) |
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Chapter 17 CCS -- From an Oil Crisis to a Climate Crisis Response |
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559 | (4) |
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17.1 CCS -- From an Oil Crisis to a Climate Crisis Response |
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559 | (4) |
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561 | (2) |
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Chapter 18 Getting CO2 Storage Right -- Arithmetically and Politically |
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563 | (5) |
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18.1 Getting CO2 Storage Right -- Arithmetically and Politically |
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563 | (5) |
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566 | (1) |
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566 | (2) |
Subject Index |
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568 | |