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Catalysis of Organic Reactions [Kõva köide]

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  • Formaat: Hardback, 600 pages, kõrgus x laius: 229x152 mm, kaal: 948 g
  • Ilmumisaeg: 30-Mar-2005
  • Kirjastus: CRC Press Inc
  • ISBN-10: 0824727290
  • ISBN-13: 9780824727291
Teised raamatud teemal:
  • Formaat: Hardback, 600 pages, kõrgus x laius: 229x152 mm, kaal: 948 g
  • Ilmumisaeg: 30-Mar-2005
  • Kirjastus: CRC Press Inc
  • ISBN-10: 0824727290
  • ISBN-13: 9780824727291
Teised raamatud teemal:
In these proceedings of the March 2004 conference, participants offer reviews of their research in catalysis as related to organic synthesis with special emphasis on processes with actual or potential applications in industry. Papers on catalytic hydrogenation includes topics such as the hydrogenation of Raney-type catalysts, anchored and supported hydrogenation catalysts, and the hydrogenation of substrates and renewable resources. The section on the conference's symposium on novel concepts and approaches to catalysis of organic reactions includes papers on combinatorial and parallel methods in catalyst design, and optimization and utilization, while the symposium on catalysts in organic synthesis yields papers on deprotection reactions and asymmetric catalysis. Annotation ©2005 Book News, Inc., Portland, OR (booknews.com)

This volume compiles 63 peer-reviewed scientific papers documenting the latest developments in the application of homogeneous, heterogeneous, and immobilized homogenous catalysts used in organic synthesis. Catalysis of Organic Reactions consists of primary research articles accompanied by experimental sections that emphasize chemical processes with actual and potential applications in industry. Each chapter represents current and outstanding research by recognized leaders in the field.

Organized into five major symposia, topics include selective homogeneous and heterogeneous catalysis for the synthesis of fine chemical and pharmaceuticals, solid acid catalysis, selective oxidation, amination, chiral catalysis, combinatorial technologies, nanoparticles, environmentally friendly catalysis, and more. The collection also presents the award-winning research of Jean Lessard, concerning the scope and limitations of electrocatalytic hydrogenation of organic compounds at Raney Metal Electrodes, and Richard Larock, relating to palladium-catalyzed annulation and migration reactions.

These proceedings are of interest to the chemical scientists and engineers whose special interest is to apply homogenous and heterogeneous catalysts in organic synthesis of pharmaceutical, fine, and commodity chemicals.
Board of Editors xiii
Chronology of Organic Reactions Catalysis Society (ORCS) Conferences xiv
Preface xv
I. Symposium on Catalytic Hydrogenation
1(174)
Hydrogenation on Raney-Type Catalysts
2004 Murray Raney Award: Electrocatalytic Hydrogenation of Organic Compounds at Raney Metal Electrodes: Scope and Limitations
3(16)
Jean Lessard
Low Pressure Slurry Hydrogenation Process for the Production of Dimethylaminopropylamine Using Sponge Nickel Catalyst
19(8)
Gregory J. Ward
Bryan C. Blanchard
The Conversion of Ethanolamine to Glycine Salt Over Skeletal Copper Catalysts
27(10)
Dongsheng Liu
Noel W. Cant
Liyan Ma
Mark S. Wainwright
Hydrogenation Catalysis in a Nylon Recycle Process
37(8)
Alan M. Allgeier
Theodore A. Koch
Sourav K. Sengupta
Hydrogenation of Dodecanenitrile Over Raney Type and Supported Group VIII Metal Catalysts and Effect of Metal on Selectivity
45(8)
Sandor Gobolos
Jozsef L. Margitfalvi
Anchored and Supported Hydrogenation Catalysts
51(2)
Highly Efficient Metal Catalysts Supported on Activated Carbon Cloths
53(6)
Alain Perrard
Pierre Gallezot
Anchored Wilkinson's Catalyst
59(6)
Clementina Reyes
Setrak Tanielyan
Robert Augustine
Carbon Supported Anchored Homogeneous Catalysts
65(6)
Pradeep Goel
Clementina Reyes
Setrak Tanielyan
Robert Augustine
Catalytic Hydrogenation of Cinnamaldehyde on Pt/Carbon Catalysts: The Effects of Metal Location, and Dispersion on Activity and Selectivity
71(6)
Nabin K. Nag
Para-substituted Aniline Hydrogenation Over Rhodium Catalysts: Metal Crystallite Size and Catalyst Pore Size Effects
77(8)
Kenneth J. Hindle
S. David Jackson
Geoff Webb
Reductive Alkylation During Nitrobenzene Hydrogenation Over Copper/Silica
85(6)
David S. Anderson
S. David Jackson
David Lennon
Geoff Webb
Hydrogenolysis of Butyl Acetate to Butanol Over Naphtha Reforming Type Catalysts in Conventional and High Throughput Slurry Phase Reactors
91(10)
Sandor Gobolos
M. Hegedus
I. Borbath
J. L. Margitfalvi
New Ways for the Full Hydrogenation of Quinoline in Mild Conditions
101(10)
M. Campanati
S. Franceschini
O. Piccolo
A. Vaccari
Some Recent Developments in Heterogeneous Hydrogenation Catalysts for Organic Synthesis
111(14)
Jianping J.P. Chen
Charles R. Penquite
Hydrogenation of Interesting Substrates and Renewable Sources
123(2)
Hydrogenation of Nitrile Butadiene Rubber Catalyzed by [ Ir(COD)py(PCy3)]PF6
125(10)
Jianzhong Hu
Neil T. McManus
Garry L. Rempel
Catalytic Hydrogenation and Hydrogenolysis of Lignin Model Compounds Using In-Situ, Water-Soluble Ru/P(CH2OH)3 Systems
135(10)
Maria B. Ezhova
Andy Z. Lu
Brian R. James
Thomas Q. Hu
Catalytic Preparation of Pyrrolidones from Renewable Resources
145(10)
John G. Frye, Jr.
Alan H. Zacher
Todd A. Werpy
Yong Wang
Hydrogenation of Glutamic Acid to Value Added Products
155(10)
Johnathan E. Holladay
Todd A. Werpy
Catalytic Hydrogenolysis of 5-Carbon Sugar Alcohols
165(10)
Alan H. Zacher
John G. Frye, Jr.
Todd A. Werpy
Dennis J. Miller
II. Symposium on Novel Concepts and Approaches to Catalysis of Organic Reactions
175(151)
Featured Technology Area: Combinatorial and Parallel Methods in Catalyst Design, Optimization and Utilization
Combinatorial Approaches for New Catalyst Discovery: The First Homogeneous Catalysts Derived from Combinatorial Technologies for a Variety of Cross-Coupling Reactions
177(8)
George Y. Li
High Throughput Experiments in Design and Optimization of Catalytic Package for Direct Synthesis of Diphenylcarbonate
185(10)
Grigorii L. Soloveichik
Kirill V. Shalyaev
Ben P. Patel
Yan Gao
Eric J. Pressman
Rapid Optimization of Hydrogenation Process Variables by Combining Experimental Design and Parallel Reactors
195(6)
Venu Arunajatesan
ShaRee L. McIntosh
Marisa Cruz
Roman F. Renneke
Baoshu Chen
Design and Parallel Synthesis of New Oxidative Dehydrogenation Catalysts
201(10)
Gadi Rothenberg
E. A. (Bart) de Graaf
Jurriaan Beckers
Alfred Bliek
Nanocluster-based Cross-coupling Catalysts: A High-Throughput Approach
211(6)
Mehul B. Thathagar
Jurriaan Beckers
Gadi Rothenberg
General Papers
216(1)
Do You Need A Transition Metal for Biaryl Synthesis?
217(10)
A. S. Kotnis
K. Zhu
B. L. Lotz
K. J. Natalie
J. H. Simpson
D. Kacusr
D. Thurston
J. S. Prasad
S. Mathew
A. K. Singh
Enzyme-like Acceleration in Catalytic Anti-Markovnikov Hydration of Alkynes to Aldehydes
227(10)
Douglas B. Grotjahn
Daniel A. Lev
An Enzyme-like Mechanism Involving Bifunctional Ru Catalysts
237(6)
Daniel A. Lev
Douglas B. Grotjahn
Activation of Dendrimer Encapsulated Pt Nanoparticles for Heterogeneous Catalysts
243(8)
HuiFang Lang
R. Alan May
Brianna L. Iversen
Bert D. Chandler
Avada---a New Green Process for the Production of Ethyl Acetate
251(10)
Flora T. T. Ng
Te Mure
Ming Jiang
Manzoor Sultan
Jin-hai Xie
Pierre Gayraud
Warren J. Smith
Matthew Hague
Robert Watt
Steve Hodge
A Catalytic Distillation Process for the One Step Synthesis of Methyl Isobutyl Ketone from Acetone: Liquid Phase Kinetics of the Hydrogenation of Mesityl Oxide
261(6)
W. K. O'Keefe
M. Jiang
F. T. T. Ng
G. L. Rempel
A Strategy for the Preparation of Isolated Organometallic Catalysts on Silica Supports -- Towards Single-Site Solid Catalysts
267(12)
Michael W. McKittrick
Shara D. McClendon
Christopher W. Jones
Ring Opening of Naphthenes for Clean Diesel Fuel Production
279(14)
David Kubicka
Narendra Kumar
Paivi Maki-Arvela
Marja Tiitta
Tapio Salmi
Dmitry Yu. Murzin
The Use of Copper Catalysts in the Hydrogen Transfer Reduction of 4-Tert-butylcyclohexanone
293(10)
Federica Zaccheria
Achille Fusi
Rinaldo Psaro
Nicoletta Ravasio
The Effect of Ultrasound on the Isomerization versus Reduction Reaction Pathways in the Hydrogenation of 3-Buten-2-ol and 1,4-Pentadien-3-ol on Pd-Black
303(10)
R.S. Disselkamp
C.H.F. Peden
Lessons Learned: Batch Processing, Scaleup from Laboratory to Plant
313(13)
John D. Super
III. Symposium on Acid-Base Catalysis
326(66)
Improved Solid-Acid Catalysis for Sustainable, High 2-Phenyl, LAB Production
327(10)
John F. Knifton
Prakasa Rao Anantaneni
Melvin E. Stockton
Recent Advances in Thermally Stable Resins for Olefin Hydration
337(10)
Ajit Pujari
Setrak Tanielyan
Robert L. Augustine
Dorai Ramprasad
Pat Crawford
Enhancement of Regioselectivity in the Gas-phase Methylation of m-Cresol with Multifunctional Heterogeneous Catalysts
347(10)
F. Cavani
L. Dal Pozzo
C. Felloni
L. Maselli
D. Scagliarini
C. Flego
C. Perego
Hydroxymethylation of 2-Methoxyphenol with Formaldehyde to Yield Vanillic Alcohols: A Comparison Between Homogeneous and Heterogeneous Acid Catalysis
357(6)
M. Ardizzi
F. Cavani
L. Dal Pozzo
L. Maselli
The Aldol Condensation of Acetone Over a CsOH/SiO2 Solid Base Catalyst
363(10)
Arran S. Canning
S. David Jackson
Eilidh McLeod
Elaine M. Vass
Solid Acid Catalysed Esterification of Amino Acids and Other Bio-based Acids
373(6)
N. S. Asthana
Z. Zhang
Dennis J. Miller
One Pot Transformation of Geraniol into Citronellol and Menthol Over Cu/Al2O3
379(6)
Nicoletta Ravasio
Achille Fusi
Rinaldo Psaro
Federica Zaccheria
Investigation of Chlorine Substitution Effects in the Claisen-Schmidt Condensation of 2'-hydroxyacetophenone with Chlorobenzaldehydes Over MgO
385(7)
Sirena C. Hargrove-Leak
Janine Lichtenberger
Michael D. Amiridis
IV. Symposium on Catalytic Oxidation
392(42)
The Effect of Single Metal Variation in Mo-V-Nb-W/Al2O3 System on Propane Selective Oxidation
393(10)
Giacomo Grasso
Julian R.H. Ross
Partial Oxidation of Propylene Over Supported Rhodium Catalysts
403(10)
Rajesh A. Khatri
Rahul Singh
Steven S. C. Chuang
Robert W. Stevens, Jr.
The Effect of Bismuth Promotion on the Selective Oxidation of Alcohols Using Platinum Catalysts
413(10)
J. R. Anderson
G. A. Attard
K. G. Griffin
P. Johnston
Preparation and Activity of a V-Ti/Silica Catalyst for Olefin Epoxidation
423(6)
Susannah L. Scott
Azfar Hassan
Aerobic Formaldehyde Oxidation Under Mild Conditions Mediated by Ce-Containing Polyoxometalates
429(5)
Oxana A. Kholdeeva
Maria N. Timofeeva
Gennadii M. Maksimov
Raisa I. Maksimovskaya
Anastasia A. Rodionova
Craig L. Hill
V. Symposium on Catalysis in Organic Synthesis
434(127)
General Papers
2004 Paul N. Rylander Award: Palladium-Catalyzed Annulation and Migration Reactions
435(14)
Richard C. Larock
New Palladium-Catalysed Processes for the Synthesis of Selectively Substituted Aromatics
449(10)
Marta Catellani
Elena Motti
Sara Deledda
Fiorenza Faccini
O-Acylphosphites: New and Promising Ligands for Isomerizing Hydroformylation
459(12)
Detlef Selent
Klaus-Diether Wiese
Armin Borner
The Synthesis of Carbamate from the Reductive Carbonylation of Nitrobenzene Over Pd-based Catalysts
471(14)
Bei Chen
Steven S. C. Chuang
Microwave Synthesis in the Suzuki-Miyaura Cross Coupling Reaction with Pd/C Catalysts
John R. Sowa, Jr.
Thomas Carrell
Megha Kandhari
Joanna Manansala
Nicole Heuschkel
Katharine Hodock
Amanda Thiel
Lubabalo T. Bululu
Deprotection
484(1)
Improved Catalyst for the Removal of Carbobenzyloxy Protective Groups
485(8)
Kimberly B. Humphries
Konrad Mobus
Tracy D. Dunn
Baoshu Chen
The Effect of N-containing Modifiers on the Deprotection of a Carbobenzyloxy Protected Amino Acid
493(6)
Kimberly B. Humphries
Tracy D. Dunn
Konrad Mobus
Baoshu Chen
Selective Debenzylation in the Presence of Aromatic Chlorine on Pd/C Catalysts: Effects of Catalyst Types and Reaction Kinetics
499(14)
Steve S. Y. Wang
Jun Li
Karen TenHuisen
Jale Muslehiddinoglu
Srinivas Tummala
San Kiang
Jianping J. P. Chen
Asymmetric Catalysis
511(2)
A Comparison Between the Homogeneous and the Anchored Rhodium Skewphos Catalyst
513(6)
Nagendranath Mahata
Setrak Tanielyan
Robert Augustine
Asymmetric Heck Reactions Using Dipeptido Phosphinite Metal Complexes
519(6)
Dushmanthi Jayasinghe
Heinz-Bernhard Kraatz
Enantioselective Hydrogenations of Exo- and Endocyclic C=C Double Bond with Highly Mesoporous Carbon Supported Pd
525(10)
E. Sipos
G. Fogassy
P.V. Samant
J. L. Figueiredo
A. Tungler
Influence of Achiral Tertiary Amines on the Enantioselective Hydrogenation of α,β-diketones Over Cinchonidine-Pt/Al2O3 Catalyst
535(6)
J. L. Margitfalvi
E. Talas
N. Marin-Astorga
T. Marzialetti
Enantioselective Hydrogenation of Diketones on Pt Supported Catalysts
541(6)
N. Marin-Astorga
G. Pecchi
P. Reyes
J. L. Margitfalvi
E. Talas
O. Egyed
Enantioselective Hydrogenation of α,β-Unsaturated Acids or Esters
547(6)
S. Franceschini
A. Vaccari
The Effects of Pt/Al2O3 Structure and Stability on the O-Methyl-10,11-dihydrocinchonidine Modified Enantioselective Hydrogenation of Activated Ketones
553(8)
Daniel J. Ostgard
Rolf Hartung
Jurgen G. E. Krauter
Steffen Seebald
Pavel Kukula
Ukrike Nettekoven
Martin Struderb
Hans-Ulrich Blaser
Author Index 561(6)
Keyword Index 567


John R. Sowa