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1 Integrated Process Design. |
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1.1 Motivation and Objectives. |
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1.2 Sustainable Process Design. |
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1.3 Integrated Process Design. |
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2 Process Synthesis by Hierarchical Approach. |
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2.1 Hierarchical Approach of Process Design. |
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2.3 Chemistry and Thermodynamics. |
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2.4 Input/Output Analysis. |
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2.5 Reactor/Separation/Recycle Structure. |
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2.6 Separation System Design. |
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2.7 Optimization of Material Balance. |
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2.9 Integration of Design and Control. |
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3 Synthesis of Separation System. |
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3.2 Vapor Recovery and Gas-Separation System. |
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3.3 Liquid-Separation System. |
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3.4 Separation of Zeotropic Mixtures by Distillation. |
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3.5 Enhanced Distillation. |
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3.7 Azeotropic Distillation. |
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3.8 Reactive Separations. |
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4 Reactor/Separation/Recycle Systems. |
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4.2 Plantwide Control Structures. |
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4.3 Processes Involving One Reactant. |
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4.4 Processes Involving Two Reactants. |
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4.5 The Effect of the Heat of Reaction. |
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4.6 Example – Toluene Hydrodealkylation Process. |
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5 Phenol Hydrogenation to Cyclohexanone. |
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5.2 Chemical Reaction Analysis. |
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5.3 Thermodynamic Analysis. |
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5.4 Input/Output Structure. |
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5.5 Reactor/Separation/Recycle Structure. |
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5.7 Material-Balance Flowsheet. |
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5.10 Process Dynamics and Control. |
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5.11 Environmental Impact. |
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6 Alkylation of Benzene by Propylene to Cumene. |
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6.2 Reaction-Engineering Analysis. |
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6.3 Reactor/Separator/Recycle Structure. |
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6.4 Mass Balance and Simulation. |
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6.6 Complete Process Flowsheet. |
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6.7 Reactive Distillation Process. |
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7 Vinyl Chloride Monomer Process. |
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7.2 Reactions and Thermodynamics. |
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7.3 Chemical-Reaction Analysis. |
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7.6 Material-Balance Simulation. |
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7.8 Dynamic Simulation and Plantwide Control. |
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7.9 Plantwide Control of Impurities. |
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8 Fatty-Ester Synthesis by Catalytic Distillation. |
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8.3 Esterifi cation of Lauric Acid with 2-Ethylhexanol. |
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8.4 Esterifi cation of Lauric Acid with Methanol. |
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8.5 Esterifi cation of Lauric Acid with Propanols. |
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9.3 Input–Output Structure. |
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9.4 Reactor/Separation/Recycle. |
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9.6 Plantwide Control and Dynamic Simulation. |
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10 Vinyl Acetate Monomer Process. |
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10.2 Reactions and Thermodynamics. |
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10.3 Input–Output Analysis. |
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10.4 Reactor/Separation/Recycles. |
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10.6 Material-Balance Simulation. |
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11 Acrylonitrile by Propene Ammoxidation. |
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11.1 Problem Description. |
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11.2 Reactions and Thermodynamics. |
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11.3 Chemical-Reactor Analysis. |
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11.4 The First Separation Step. |
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11.5 Liquid-Separation System. |
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11.8 Emissions and Waste. |
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11.10 Further Developments. |
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12 Biochemcial Process for NOx Removal. |
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12.4 The Mathematical Model. |
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12.5 Sizing of the Absorber and Bioreactor. |
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12.6 Flowsheet and Process Control. |
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13 PVC Manufacturing by Suspension Polymerization. |
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13.2 Large-Scale Reactor Technology. |
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13.3 Kinetics of Polymerization. |
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13.4 Molecular-Weight Distribution. |
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13.7 Design of the Reactor. |
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14 Biodiesel Manufacturing. |
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14.1 Introduction to Biofuels. |
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14.2 Fundamentals of Biodiesel Manufacturing. |
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14.3 Manufacturing Processes. |
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14.4 Kinetics and Catalysis. |
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14.5 Reaction-Engineering Issues. |
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14.6 Phase-Separation Issues. |
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15 Bioethanol Manufacturing. |
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15.6 Biorefi nery Concept. |
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15.8 Manufacturing Technologies. |
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15.9 Process Design: Ethanol from Lignocellulosic Biomass. |
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Appendix A Residue Curve Maps for Reactive Mixtures. |
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Appendix B Heat-Exchanger Design. |
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Appendix C Materials of Construction. |
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Appendix D Saturated Steam Properties. |
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Appendix E Vapor Pressure of Some Hydrocarbons. |
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Appendix F Vapor Pressure of Some Organic Components. |
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Appendix G Conversion Factors to SI Units. |
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