This compendium of articles from the March 2000 symposium deals primarily with fullerenes, fullerides and carbon nanotubes, but there are also contributions on conducting polymers, on molecular clusters and on nucleic acids. Various aspects of the compounds are examined, from synthesis and sample characterization over chemical, mechanical and electronic properties to industrial applications. One article is on hydrogen storage. Well illustrated with photographs and diagrams. Annotation c. Book News, Inc., Portland, OR (booknews.com)
The proceedings of the XIV International Winterschool on Electronic Properties of Novel Materials provides a platform for new developments in the field of molecular nanostructures and their applications. Topics included are: fullerenes and fullerides, fullerene polymers, endohedrals, nanotube preparation, nanotube characterization, as well as transport, doping and electronic properties of nanotubes and other molecular materials and applications.
Preface xiii Organizer, Patronage, Supporters, Sponsors xv Table of Previous Kirchberg Winterschools xvi I. INTRODUCTION Fullerenes and Nanotubes---An Introduction 3(6) W. Kratschmer II. FULLERENES AND FULLERIDES Resistivity of Metallic A3C60(A=K, Rb): No Lower Limit to the Mean Free Path? 9(5) O. Gunnarsson J. E. Han Electronic Structure of Body-Centered Lattice Fullerides 14(5) S. Saito K. Umemoto Broken-Symmetry Band Structure Description of the Spectroscopy of K3C60 19(5) L. F. Chibotaru A. Ceulemans Molecular Motions and T Site Symmetry in the sc Phase of Na2C60 24(5) V. Brouet H. Alloul T. Saito L. Forro Crystal Structure and Magnetic Properties of EuxSr6-xC60 29(4) K. Ishii H. Ootoshi Y. Nishi A. Fujiwara H. Suematsu Y. Kubozono Mott-Hubbard Transition and Antiferromagnetism in Ammoniated Alkali Fullerides 33(4) T. Takenobu V. Iwasa T. Mitani Structural Studies of (NH3)K3C60 at Ambient and High Pressure 37(5) S. Margadonna K. Prassides H. Shimoda Y. Iwasa First NMR Study on a C60 Ternary ``Superconductor Compound: K6C60(C6H6)1.5 42(4) A.-S. Grell B. Burteaux A. Hamwi F. Masin Jahn-Teller Distortion and Rotational Ordering Transition of C-60 in (A+(C6H5)4)2 C-60B- - Salts (A+=P+, As+; B-=I-, Cl-) 46(4) W. Bietsch J. Bao P. Medick S. Trabl Globular Amphiphiles: Membrane Forming Hexakisadducts of Fullerene C60 50(4) O. Vostrowsky M. Brettreich S. Burghardt A. Hirsch C. Bottcher A. P. Maierhofer M. Hetzer S. Bayerl T. M. Bayerl Ion Chromatographic Determination of Th-hexakis-dicarboxymethanofullerene-C60 54(4) J. Cerar M. Pompe J. Skerjanc Small Reorganization Energies in Fullerenes 58(5) D. M. Guldi K.-D. Asmus A. Hirsch M. Prato Singlet Oxygen Generation by C60 and C70-An Esr Study 63(4) A. Sienkiewicz S. Garaj E. Bialkowski-Jaworska L. Forro Electrochemical Quartz Crystal Microbalance Study of Redox Active C60/Pd Polymer Films 67(6) K. Winkler K. Noworyta W. Kutner A. L. Balch III. FULLERENE POLYMERS Physical Properties of Highly-Oriented Rhombohedral C60 Polymer 73(4) M. Tokumoto B. Narymbetov H. Kobayashi T. L. Makarova V. A. Davydov A> V. Rakhmania L. S. Kashevarova Dimerization of C70 under High Pressure: Thermal Dissociation and Photophysical Properties of the Dimer C140 77(4) S. Lebedkin W. E. Hull A. Soldatov B. Renker M. M. Kappes Chain Orientation and Layer Stacking in the High-Pressure Polymers of C60: Single Crystal Studies 81(4) R. Moret P. Launois T. Wagberg B. Sundqvist Structures of C60 Superhard Phases as a Mirror of 3D Polymerization 85(5) N. R. Serebryanaya L. A. Chernozatonskii B. N. Mavrin Density Functional Study of the Phase Diagram of 3D C60-Polymers 90(4) P. Rajczy J. Kurti S. Pekker G. Oszlanyi The Phases of RbxC59N from Raman Spectroscopy 94(5) T. Pichler W. Plank H. Kuzmany N. Tagmatarchis K. Prassides Single Bonded Charged Fullerene Dimers: (C59N)2 versus (C-60)2 99(4) W. Plank T. Pichler M. Krause H. Kuzmany HREELS Investigations of Adsorbed (C59N)2 103(4) J. M. Auerhammer T. Kim M. Knupfer M. S. Golden J. Fink N. Tagmatarchis K. Prassides Electron Spin Density Distribution in the Polymer Phase of CsC60: Assignment of the NMR Spectrum 107(5) T. M. de Swiet Preparation of RbC60 by Coevaporation 112(4) M. Haluska M. Krause P. Knoll H. Kuzmany Optical Properties of the Polymeric Phase in Na2CsC60 116(4) B. Ruzicka L. Degiorgi L. Forro 13C and 23Na NMR Study of Na2KC60 in Polymer Phase 120(4) T. Saito V. Brouet H. Alloul L. Forro X-ray Diffraction of Na4C60 at Low Temperature under High Pressure 124(7) Y. Takabayashi Y. Kubozono S. Fujiki Y. Iwasa S. Kashino IV. ENDOHEDRALS Structure and Dynamics of Endohedral Fullerenes 131(4) K. Vietze G. Seifert P. W. Fowler The Encapsulation of Trimetallic Nitride Clusters in Fullerene Cages 135(7) H. C. Dorn S. Stevenson J. Craft F. Cromer J. Duchamp G. Rice T. Glass K. Harich P. W. Fowler T. Heine E. Hajdu R. Bible M. M. Olmstead K. Maitra A. J. Fisher A. L. Balch Photoemission Spectroscopy of Gd@C82 142(4) T. Schwieger H. Peisert M. Knupfer M. S. Golden J. Fink T. Pichler H. Kato H. Shinohara Sc2@C84/Au(110): A Synchrotron Radiation Study 146(4) I. Marenne P. Rudolf M. R. C. Hunt J. Schiessling L. Kjeldgaard P. Bruhwiler M. S. Golden T. Pichler M. Inakuma H. Shinohara Bonding and Dynamics of Diatomic Metal Encapsulates in Carbon Cages 150(5) M. Krause M. Hulman H. Kuzmany P. Georgi L. Dunsch M. Inakuma T. J. S. Dennis H. Shinohara Temperature and Field Dependent ESR Measurements on Sc3@C82 155(4) J. Rahmer A. Grupp M. Mehring A. Bartl U. Kirbach L. Dunsch The Samarium Fullerene Family 159(5) P. Georgi S. Lieb J. Navarro de San Pio P. Kuran L. Dunsch Thin Films of Li@C60 164(4) R. Ehlich C. Stanciu K. Buttke Metal Doped Fullerenes: Endohedral and Networked Dopants 168(6) W. Eberhardt R. Klingeler P. S. Bechthold M. Neeb Synthesis and EPR Studies of N@C60 and N@C70 Radical Anions 174(4) P. Jakes B. Goedde M. Waiblinger N. Weiden K.-P. Dinse A. Weidinger Squeezing and Shielding of Atoms in Fullerene Traps 178(5) K.-P. Dinse N. Weiden B. Goedde P. Jakes M. Waiblinger A. Weidinger Thermodynamic Properties of N@C60 183(4) F. Uhlik Z. Slanina E. Osawa The Exchange Coupling between the N Atom and the Fullerene Cage in N@Cn- 60 187(4) L. Udvardi Electron Spin Relaxation Rates T-1 1 and T-1 2 in Diluted Solid N@C60 191(4) S. Knorr A. Grupp M. Mehring M. Waiblinger A. Weidinger Magnetic Interaction in Diluted N@C60 195(4) M. Waiblinger B. Goedde K. Lips W. Harneit P. Jakes A. Weidinger K.-P. Dinse Electron Spin Resonance of N@C60 6- in the Fulleride Salt Rb6C60 199(4) A. Janossy S. Pekker F. Fulop F. Simon G. Oszlanyi N@C120-The First Step to Endohedral Polymers 203(4) B. Goedde M. Waiblinger P. Jakes N. Weiden K.-P. Dinse A. Weidinger N@C60 for Quantum Computing 207(6) W. Harneit M. Waiblinger K. Lips S. Makarov A. Weidinger Single-Wall Carbon Nanotubes: Study of Production Parameters Using cw CO2-Laser Ablation Technique 213(4) W. K. Maser E. Munoz A. M. Benito M. T. Martinez G. F. De la Fuente E. Anglaret A. Righi J.-L. Sauvajol Mechanism of Metal Catalysts Controlling Formation of Single-Wall Carbon Nanotubes 217(5) M. Yudasaka Y. Kasuya M. Takizawa S. Bandow K. Takahashi F. Kokai S. Iijima Investigation of the Role of Yttrium in the Production of SWNT by Arc Discharge 222(4) J. Gavillet A. Loiseau O. Stephan S. Tahir P. Bernier Simple Energetics of Single-Walled, Open-Ended, Finite Carbon Nanotubes 226(4) M. W. Radny P. V. Smith Template-Based Plasma Synthesis of Carbnonaceous Nanostructures 230(4) A. Huczko H. Lange J. Tyczkowski P. kazimierski P. Tomassi Iron Catalyzed Growth of Carbon Nanotubes 234(4) F. Rohmund L. K. L. Falk E. E. B. Campbell Calculation of Single-Wall Carbon Nanotube Diameters from Experimental Parameters 238(4) H. Kanzow C. Lenski A. Ding Control of the Outer Diameter of Thin Carbon Nanotubes Synthesized by Catalytic Decomposition of Hydrocarbons 242(4) I. Willems Z. Konya J.-F. Colomer G. Van Tendeloo N. Nagaraju A. Fonseca J. B. Nagy Novel Purification Procedure and Derivatization Method of Single-Walled Carbon Nanotubes (SWNTs) 246(4) M. Holzinger A. Hirsch P. Bernier G. S. Duesberg M. Burghard Growth of Elongated Structures in a Longitudinal Electrical Field 250(4) A. V. Eletskii Characterization of Carbon Atoms Chemical States in Nanotubes Containing Soot Materials and Fullerene by XPS, XAES 254(4) A. Dementjev A. Eletskii V. Bezmelnitsyn K. Maslakov In-situ Raman and Vis-NIR Spectroelectrochemistry at Carbon Nanotubes 258(4) L. Kavan P. Rapta L. Dunsch Bundle Effects of Single-Wall Carbon Nanotubes 262(4) H. Kataura Y. Maniwa S. Masubuchi S. Kazama X. Zhao Y. Ando Y. Ohtsuka S. Suzuki Y. Achiba R. Saito Contribution to the Characterization of Nanotubes Atomic Structure: Breathing Mode of Finite and Infinite Bundles 266(5) L. Henrard P. Lambin A. Rubio Resonance Excitation, Intertube Coupling and Distribution of Helicities in Single-Wall Carbon Nanotubes 271 M. Hulman W. Plank J. Kurti H. Kuzmany Raman Spectra of Single-Wall Carbon Nanotubes from 77K to 1000K 276(280) E. D. Obrazstova S. V. Terekhov A. V. Osadchy Characterization of Single-Walled Carbon Nanotubes through Raman Spectroscopy 280(4) A. Marucci S. D. M. Brown P. Corio M. A. Pimenta M. S. Dresselhaus Scanning Tunneling Microscopy and Spectroscopy of Multiwall Carbon Nanotubes 284(4) A. Hassanien M. Tokumoto X. Zhao Y. Ando The Spectroscopic Investigation of the Optical and Electronic Properties SWCNT 288(6) X. Liu H. Peisert R. Friedlein M. Knupfer M. S. Golden J. Fink O. Jost A. A. Gorbunov W. Pompe T. Pichler Rolling Nanotubes: Atomic Lattices as Gears and Contacts 294(5) M. R. Falvo J. Steele S. Paulson R. M. Taylor II S. Washburn R. Superfine Modeling of Nanotube as a Molecular Tool 299(4) I. Laszlo Computer Simulation of Scanning Tunneling Spectroscopy of Supported Carbon Nanotube Aggregates 303(6) G. I. Mark L. P. Biro J. Gyulai P. A. Thiry P. Lambin VI. NANOTUBES: TRANSPORT, DOPING, ELECTRONIC PROPERTIES A Brief Introduction to Luttinger Liquids 309(10) J. Voit Theory of Quantum Transport in Carbon Nanotubes 319(6) T. Ando Conductance of Carbon Based Macro-Molecular Structures 325(5) S. Stafstrom A. Hansson M. Paulsson Band Structure, Conductivity and Thermoelectric Power of Carbon Nanotube Bundle 330(4) V. E. Kaminskii Impurity Scattering in Carbon Nanotubes with Superconducting Pair Correlations 334(4) K. Harigaya Electrical and Thermal Transport in Cabron Nanotubes 338(6) D. Tomanek Transport Properties of Single-Walled Nanotube Mats under Hydrostatic Pressure 344(5) B. B. Liu B. Sundqvist O. Andersson T. Wagberg G. Zou Single Carbon Nanotube Electronic Devices 349(6) A. T. Johnson J. Lefebvre M. Radosavljevic M. Llaguno J. F. Lynch Locally Measured Electronic Properties of Single Wall Carbon Nanotubes 355(4) M. Freitag A. T. Johnson The Measurement of Work Function of Carbon Nanotubes 359(4) M. Shiraishi K. Hinokuma M. Ata Electrical Properties of Single-Walled Carbon Nanotubes-PMMA Composites 363(4) C. Stephan T. P. Nguyen S. Lefrant L. Vaccarini Bernier Role of the Metal in Contacting Single-Walled Carbon Nanotubes 367(4) V. Krstic G. T. Kim J. G. Park D. S. Suh Y. W. Park S. Roth M. Burghard Effect of Pressure on the Electronic Properties of Carbon Nanotubes 371(5) Y. I. Prylutskyy O. V. Ogloblya E. V.Buzaneva S. O. Putselyk P. C. Eklund P. Scharff Interaction of Lithium Atoms with Graphitic Walls 376(4) J. S. Arellano L. M. Molina M. J. Lopez A. Rubio J. A. Alonso Electronic Structure of Doped Fullerenes and Single Wall Carbon Nanotubes 380(5) S. Eisebitt A. Karl A. Zimina R. Scherer M. Freiwald W. Eberhardt F. Hauke A. Hirsch Y. Achiba Multiple-Shell Diffusive Conduction in Multimwalled Carbon Nanotubes 385(5) P. G. Collins R. Martel K. Liu P. Avouris Superconductivity and Normal State Resistance of Carbon Nanotubes 390(5) A. Y. Kasumov R. Deblock M. Kociak B. Reulet H. Bouchiat S. Gueron I. I. Khodos Y. B. Gorbatov V. T. Volkov C. Journet P. Bernier M. Burghard Tuning the Electronic Properties of Single Wall Carbon Nanotubes by Chemical Doping 395(5) P. Petit E. Jouguelet C. Mathis P. Bernier Chemical and Electrochemical Doping of Single Wall Carbon Nanotube Films Probed by Optical Absorption Spectroscopy 400(4) S. Kazaoui N. Minami H. Kataura Y. Achiba Pressure and Doping Dependence of Electronic Properties of Carbon Nanotube Ropes 404(4) R. Gaal J.-P.Salvetat J.-M. Bonard L. Thien-Nga S. Garaj L. Forro B. Ruzicka L. Degiorgi Intercalation of Heavy Alkali Metals (K, Rb and Cs) in the Bundles of Single Wall Nanotubes 408(7) L. Duclaux K. Metenier P. Lauginie J. P. Salvetat S. Bonnamy F. Beguin VII. OTHER MOLECULAR MATERIALS On the Electronic Structure of Non Carbon Nanotubes 415(4) G. Seifert Self-Organized Growth of Indium-Tin-Oxide Nanowires 419(4) N. Roos T. P. Sidiki J. Seekamp C. M. Sotomayo Torres Synthesis of Carbon Nanofibers by Catalytic Pyrolysis of Hydrocarbons 423(4) M. Ritschel C. Taschner D. Selbmann A. Leonhardt A. Graff J. Fink Nanotextured Carbon Films from Fluorinated Hydrocarbons: Kinetics and Mechanism of Their Growth 427(4) L. Kavan Synthesis of Silicon Nanowires and Novel Nano-Dendrite Structures 431(6) S. Sinha B. Gao O. Zhou CdSe Nanoparticle Arrays Contacted on Electron Transparent Substrates 437(4) G. Philipp M. Burghard S. Roth Nanoparticles of CdCl2 with Closed Cage Structures 441(7) R. Popovitz-Biro A. Twersky Y. Rosenfeld Hacohen R. Tenne Structures and Dynamics in the Methylated Exopyridine Anthracene Rotaxane: 13C, 1H and 19F Solid-State NMR Studies 448(4) X. Bourdon J. Leupold M. Mehring J. Thies T. Kidd T. Loontjens Direct Measurements of Electrical Transport Through DNA Molecules 452(5) D. Porath A. Bezryadin S. de Vries C. Dekker Electrical Conduction Through DNA Molecules 457(5) H.-W. Fink Conductivity and Dielectric Constant of the DNA Double Helix 462(6) G. Gruner The Electronic Properties for DNA/CNT Chip on Si 468(5) E. V. Buzaneva A. Y. Karlash S. O. Putselyk Y. V. Shtogun K. O. Gorehinskyy Y. I. Prylutskyy S. V. Prylutska O. P. Matyshevska P. Scharff Resonance Raman Scattering from Carbyne Materials 473(4) T. Danno K. Murakami M. Krause H. Kuzmany A Near Field EEL Spectroscopy Study of Surface Modes in Nanotubes and Onions from Various Layered Materials 477(5) O. Stephan M. Kociak. L. Henrard K. Suenaga E. Sandre C. Colliex Mechanical Properties of Individual Microtubules Measured Using Atomic Force Microscopy 482(7) N. H. Thomson A. Kis. S. Kasas A. J. Kulik L. Forro VIII. APPLICATIONS Devices and Machines at the Molecular Level 489(6) M. Vennun A. Credi V. Balzani Field Emission from Nanostructured Carbon 495(4) J. Robertson Environmental Stability of Carbon Nanotube Field Emitters 499(5) L. Nilssen O. Groning P. Groning O. Kuttel L. Schlapbach Single-Wall Carbon Nanotube Devices Prepared by Chemical Vapor Deposition 504(4) P. R. Poulsen J. Borggreen J. Nygard D. H. Cobden M. M. Andreasen P. E. Lindelof Giant Magnetoresistance from a Co Wire Incorporating Carbon-Encapsulated Magnetic Nanoparticles 508(4) J.-M. Bonard A. Sallin J.-E. Wegrowe Sensibilization of Polymer/Fullerene Photovoltaic Cells Using Zinc Phtalocyanine Studied by Combinatorial Technique 512(4) E. Godovsky L. Chen L. Petterson O. Inganas Field-Effect Mobility Measurements of Conjugated Polymer/Fullerene Photovoltaic Blends 516(5) W. Geens S. E. Shaheen C. J. Brabec J. Poortmans N. Serdar Sariciftci Reinforcement of an Epoxy Resin by Single Walled Nanotubes 521(5) L. Vaccarini G. Desarmot R. Almairac S. Tahir C. Goze P. Bernier Sharpened Nanotubes, Nanobearings, and Nanosprings 526(7) A. Zettl J. Cumings Storage of Energy in Supercapacitors from Nanotubes 533(4) F. Frackowiak K. Jurewicz. S. Delpeux V. Bertagna S. Bonnamy F. Beguin Report on the Evening Discussion: ``Hydrogen Storage in Carbon Materials 537(10) A. Quintel Author Index 547
