Preface |
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xiii | |
Author |
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xvii | |
Introduction |
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xix | |
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1 | (18) |
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1 | (3) |
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4 | (3) |
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7 | (1) |
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1.4 Scales of temperature |
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8 | (11) |
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16 | (2) |
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18 | (1) |
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Chapter 2 Reversible Processes and Work |
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19 | (24) |
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19 | (8) |
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27 | (7) |
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34 | (4) |
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2.4 Example of the calculation of work in a reversible process |
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38 | (5) |
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39 | (2) |
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41 | (2) |
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Chapter 3 The First Law of Thermodynamics |
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43 | (30) |
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3.1 The work of Thompson and Joule |
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43 | (2) |
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3.2 The first law of thermodynamics |
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45 | (3) |
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48 | (6) |
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3.4 Kinetic theory of gases |
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54 | (4) |
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3.5 Ideal gases and the first law |
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58 | (5) |
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3.6 The Joule--Kelvin effect |
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63 | (2) |
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3.7 Steady flow process---the turbine |
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65 | (8) |
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68 | (4) |
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72 | (1) |
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Chapter 4 The Second Law of Thermodynamics |
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73 | (28) |
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73 | (1) |
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4.2 Efficiency of an engine |
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74 | (2) |
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4.3 Statements of the second law of thermodynamics |
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76 | (6) |
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82 | (3) |
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4.5 The thermodynamic temperature scale |
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85 | (5) |
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4.6 Engines and refrigerators |
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90 | (6) |
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96 | (5) |
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97 | (3) |
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100 | (1) |
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101 | (28) |
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5.1 The Clausius inequality |
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101 | (4) |
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105 | (5) |
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5.3 The principle of increasing entropy |
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110 | (9) |
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5.4 Entropy--temperature diagrams |
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119 | (1) |
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5.5 The thermodynamic identity |
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120 | (1) |
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5.6 Other examples of entropy calculations |
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121 | (8) |
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123 | (4) |
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127 | (2) |
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Chapter 6 Statistical Mechanics |
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129 | (34) |
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6.1 Introduction to probability and statistics |
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129 | (4) |
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6.2 Microscopic view of entropy |
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133 | (11) |
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6.3 Maxwell-Boltzmann statistics |
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144 | (5) |
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149 | (14) |
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157 | (4) |
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161 | (2) |
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Chapter 7 The Thermodynamic Potentials and the Maxwell Relations |
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163 | (36) |
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7.1 Thermodynamic potentials |
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163 | (1) |
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164 | (1) |
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165 | (3) |
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168 | (9) |
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177 | (9) |
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7.6 Availability function A |
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186 | (4) |
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7.7 The thermodynamic square |
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190 | (2) |
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7.8 Example using a Maxwell relation |
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192 | (7) |
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194 | (4) |
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198 | (1) |
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Chapter 8 General Thermodynamic Relations |
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199 | (24) |
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8.1 Difference in heat capacities, CP -- CV |
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199 | (2) |
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8.2 Evaluation of (∂CV/∂V)T and (∂CP/∂P)T |
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201 | (2) |
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203 | (1) |
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8.4 Ratio of heat capacities, CP/CV |
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204 | (3) |
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8.5 Revisiting the entropy of an ideal gas |
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207 | (2) |
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8.6 Joule and Joule--Kelvin coefficients |
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209 | (14) |
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218 | (4) |
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222 | (1) |
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Chapter 9 Magnetic Systems |
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223 | (16) |
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9.1 Thermodynamics of magnetic materials |
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223 | (5) |
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228 | (11) |
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236 | (1) |
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237 | (2) |
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239 | (28) |
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239 | (5) |
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10.2 Clausius--Clapeyron equation for first-order phase changes |
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244 | (6) |
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10.3 Variation of Gibbs function G in first-order transitions |
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250 | (3) |
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10.4 Second-order phase changes |
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253 | (1) |
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10.5 Examples of phase changes of different orders |
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254 | (6) |
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10.6 Superconductivity and superfluidity |
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260 | (7) |
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262 | (4) |
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266 | (1) |
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Chapter 11 Open Systems and Chemical Potential |
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267 | (16) |
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267 | (9) |
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11.2 Three applications of the chemical potential |
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276 | (7) |
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280 | (2) |
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282 | (1) |
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Chapter 12 The Third Law of Thermodynamics |
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283 | (14) |
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12.1 Statements of the third law |
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283 | (7) |
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12.2 Consequences of the third law |
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290 | (3) |
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12.3 The unattainability of absolute zero |
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293 | (4) |
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295 | (1) |
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296 | (1) |
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Chapter 13 Quantum Statistics |
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297 | (38) |
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13.1 Classical and quantum statistics |
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297 | (8) |
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13.2 Photons and thermal radiation |
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305 | (13) |
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13.3 Application of FD statistics to electrons in metals |
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318 | (6) |
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324 | (11) |
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328 | (4) |
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332 | (3) |
Appendix A Values of Physical Constants and Conversion Factors |
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335 | (2) |
Appendix B Some Mathematical Relations Used in Thermodynamics |
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337 | (6) |
Appendix C The Work Required to Magnetize a Magnetic Material and to Polarize a Dielectric |
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343 | (6) |
Appendix D Answers to Selected Problems |
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349 | (6) |
Index |
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355 | |