Preface |
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xi | |
Acknowledgements |
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xiii | |
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1 Introduction (The view of solids) |
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1 | (14) |
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1 | (3) |
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4 | (2) |
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1.3 Chapters and appendices |
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6 | (1) |
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1.4 Supporting considerations |
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7 | (3) |
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10 | (3) |
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13 | (2) |
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2 Flow phenomena (The tools for study) |
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15 | (30) |
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2.1 Bulk and wall temperature |
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16 | (5) |
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2.2 Pressure drop in pipelines |
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21 | (5) |
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26 | (1) |
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2.4 Two-phase flow in pipelines |
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27 | (5) |
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2.5 Convective mass transfer |
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32 | (3) |
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2.6 Boundary layer theory |
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35 | (1) |
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2.7 Particle mass transfer |
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36 | (4) |
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40 | (4) |
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44 | (1) |
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3 Asphaltene (The tar-like solids) |
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45 | (40) |
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46 | (2) |
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3.2 Crude oil SARA values |
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48 | (4) |
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52 | (2) |
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3.4 Molecules and particles |
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54 | (3) |
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3.5 Polarity and dipole moment |
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57 | (3) |
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3.6 Reservoir to surface conditions |
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60 | (2) |
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62 | (3) |
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65 | (3) |
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3.9 Precipitation envelope |
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68 | (2) |
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70 | (3) |
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73 | (4) |
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77 | (5) |
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82 | (3) |
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4 Paraffin wax (The candle-like solids) |
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85 | (44) |
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4.1 Wax in oil and condensate |
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85 | (4) |
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89 | (3) |
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4.3 Viscosity of oil-wax slurry |
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92 | (3) |
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4.4 Thermodynamics of precipitation |
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95 | (5) |
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4.5 Spatial and temporal buildup |
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100 | (5) |
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105 | (2) |
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4.7 Flow loop observations |
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107 | (2) |
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109 | (5) |
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4.9 Selected deposition models |
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114 | (3) |
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4.10 Monitoring of pipelines |
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117 | (4) |
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121 | (6) |
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127 | (2) |
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5 Natural gas hydrate (The ice-like solids) |
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129 | (30) |
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130 | (5) |
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5.2 Water in oil and gas production |
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135 | (2) |
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5.3 Water vapour in natural gas |
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137 | (2) |
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139 | (3) |
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5.5 Non-hydrocarbon gases and water salinity |
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142 | (3) |
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5.6 Prevention by antifreeze |
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145 | (4) |
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5.7 Prevention by low-dosage chemicals |
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149 | (2) |
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5.8 Prevention by cold flow |
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151 | (4) |
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5.9 Further considerations |
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155 | (1) |
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156 | (3) |
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6 Inorganic scale (The salt-like solids) |
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159 | (40) |
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6.1 Main factors and issues |
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159 | (2) |
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161 | (3) |
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164 | (1) |
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165 | (4) |
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6.5 Equilibrium and activity |
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169 | (3) |
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172 | (2) |
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6.7 Solubility of scaling minerals |
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174 | (5) |
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179 | (2) |
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181 | (7) |
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188 | (2) |
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190 | (6) |
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196 | (3) |
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7 Naphthenate (The soap-like solids) |
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199 | (30) |
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199 | (5) |
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204 | (2) |
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7.3 Tetracarboxylic acids |
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206 | (2) |
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7.4 Composition of deposits |
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208 | (3) |
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7.5 Deposition parameters |
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211 | (4) |
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215 | (4) |
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219 | (1) |
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7.8 Size of bubbles and droplets |
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220 | (3) |
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223 | (4) |
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227 | (2) |
References |
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229 | (18) |
Appendix A Temperature in pipelines |
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247 | (4) |
Appendix B Pipeline wall heat transfer |
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251 | (6) |
Appendix C Boundary layer temperature profile |
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257 | (4) |
Appendix D Darcy-Weisbach equation |
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261 | (2) |
Appendix E Transfer equations |
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263 | (4) |
Appendix F Friction factor of structured deposits |
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267 | (6) |
Appendix G Pressure drop in gas pipelines and wells |
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273 | (8) |
Appendix H Universal velocity profile |
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281 | (6) |
Appendix I Particle velocity and stopping distance |
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287 | (4) |
Appendix J Diffusion coefficient |
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291 | (2) |
Appendix K Deposition-release models |
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293 | (4) |
Appendix L1 Dipole moment of hydrocarbons |
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297 | (2) |
Appendix L2 Regular solution model |
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299 | (4) |
Appendix M1 Viscosity and activation energy |
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303 | (6) |
Appendix M2 Wax-in-kerosene deposition model |
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309 | (2) |
Appendix M3 Pigging model for wax |
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311 | (6) |
Appendix N Water vapour in natural gas |
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317 | (6) |
Appendix O Hydrate dissociation pressure |
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323 | (2) |
Appendix P Boiling point elevation of seawater |
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325 | (2) |
Appendix Q1 Solubility of gases in water |
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327 | (8) |
Appendix Q2 Chemical equilibrium |
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335 | (4) |
Appendix R Ionic strength and activity coefficient |
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339 | (4) |
Appendix S Gibbs free energy |
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343 | (6) |
Appendix T Chemical potential |
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349 | (4) |
Appendix U Solubility product constants |
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353 | (4) |
Appendix V Solubility and nucleation |
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357 | (2) |
Appendix W Calcite and silica chemistry |
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359 | (4) |
Appendix X1 Crude oil composition |
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363 | (6) |
Appendix X2 Emulsions of crude oil and brine |
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369 | (6) |
Appendix X3 Energy dissipation and bubble diameter |
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375 | (6) |
Appendix Y1 Two-phase flow variables and equations |
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381 | (6) |
Appendix Y2 Two-phase flow regimes |
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387 | (6) |
Appendix Z Multiplier pressure drop method |
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393 | (4) |
Index |
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397 | |