Muutke küpsiste eelistusi

Geometrical Frustration [Kõva köide]

(Université de Paris XI), (Université de Paris VII (Denis Diderot))
  • Formaat: Hardback, 320 pages, kõrgus x laius x paksus: 244x170x19 mm, kaal: 710 g, 13 Tables, unspecified; 9 Halftones, unspecified; 145 Line drawings, unspecified
  • Sari: Collection Alea-Saclay: Monographs and Texts in Statistical Physics
  • Ilmumisaeg: 12-Aug-1999
  • Kirjastus: Cambridge University Press
  • ISBN-10: 0521441986
  • ISBN-13: 9780521441988
  • Formaat: Hardback, 320 pages, kõrgus x laius x paksus: 244x170x19 mm, kaal: 710 g, 13 Tables, unspecified; 9 Halftones, unspecified; 145 Line drawings, unspecified
  • Sari: Collection Alea-Saclay: Monographs and Texts in Statistical Physics
  • Ilmumisaeg: 12-Aug-1999
  • Kirjastus: Cambridge University Press
  • ISBN-10: 0521441986
  • ISBN-13: 9780521441988
Clear account of how the application of geometrical frustration elucidates the structure and properties of non-periodic materials.

This book shows how the concept of geometrical frustration can be used to elucidate the structure and properties of nonperiodic materials such as metallic glasses, quasicrystals, amorphous semiconductors and complex liquid crystals. Examples and idealized models introduce geometric frustration, illustrating how it can be used to identify ordered and defective regions in real materials. The book goes on to show how these principles can also be used to model physical properties of materials, in particular specific volume, melting, the structure factor and the glass transition. Final chapters consider geometric frustration in periodic structures with large cells and quasiperiodic order. Appendices give all necessary background on geometry, symmetry and tilings. The text considers geometrical frustration at different scales in many types of materials and structures, including metals, amorphous solids, liquid crystals, amphiphiles, cholisteric systems, polymers, phospholipid membranes, atomic clusters, and quasicrystals. This book will be of great interest to researchers in condensed matter physics, materials science and structural chemistry, as well as mathematics and structural biology.

Muu info

A clear account of how the application of geometrical frustration elucidates the structure and properties of non-periodic materials.
Preface xi
1 Introduction to geometrical frustration
1(13)
1.1 From cubism to icosahedrism
1(4)
1.2 Geometry
5(4)
1.3 Geometrical frustration
9(5)
2 Ideal models
14(31)
2.1 A unified approach to very different materials
14(1)
2.2 Simple two-dimensional examples
15(2)
2.3 Metals
17(4)
2.4 The {3,3,5} polytope: an ideal template for amorphous metals
21(4)
2.5 Covalent tetracoordinated structures
25(8)
2.6 Frustration in lamellar liquid crystals and amphiphiles
33(3)
2.7 Lamellar structures in curved spaces
36(3)
2.8 Frustration and curved space structure for blue phases
39(4)
2.9 Frustration in polymers
43(2)
3 Finite structures
45(12)
3.1 Finite clusters
45(6)
3.2 Toroidal vesicles with phospholipid membranes
51(6)
4 Decurving and disclinations
57(43)
4.1 Disclinations
57(7)
4.2 Wedge and screw disclinations
64(8)
4.3 Coordination number, disclination density and Regge calculus
72(14)
4.4 Conservation laws
86(3)
4.5 Defects and topology
89(11)
5 Hierarchical polytopes
100(28)
5.1 Hierarchical polytopes and symmetry groups
100(6)
5.2 Hierarchy and scaling
106(5)
5.3 Matrix formulation of the hierarchical structures
111(2)
5.4 Disorder and non-commutative defects
113(6)
5.5 Deflation of the orthoscheme
119(9)
6 Some physical properties
128(30)
6.1 Structure factor of polytopes and orientational order
128(6)
6.2 Specific volume variation in disordered solids: a simple model
134(1)
6.3 Landau theory of frustrated systems
134(5)
6.4 Two-level systems
139(7)
6.5 Frustration-limited domain theory
146(2)
6.6 Excitation spectrum
148(10)
7 Periodic structures with large cells
158(38)
7.1 Frustration and large cell crystals
158(1)
7.2 Complex structures in metals
158(23)
7.3 Melting of model structures
181(7)
7.4 Tetracoordinated structures
188(1)
7.5 Liquid crystal structures
189(7)
8 Quasiperiodic order and frustration
196(18)
8.1 Quasicrystals: the spectacular appearance of quasiperiodic order in solid state physics
196(2)
8.2 Hierarchical clusters in quasicrystals
198(1)
8.3 Random tilings
199(2)
8.4 Random tilings in one dimension
201(1)
8.5 Two-dimensional tilings
202(7)
8.6 Three-dimensional rhombohedral tilings
209(2)
8.7 Glass-like properties in quasicrystals
211(3)
A1 Spaces with constant curvature
214(10)
A1.1 The three geometries
214(2)
A1.2 Spherical spaces
216(4)
A1.3 Two-and three-dimensional cylindrical spaces
220(2)
A1.4 Intrinsic curvature
222(2)
A2 Quaternions and related groups
224(6)
A2.1 Quaternions
224(1)
A2.2 Some continuous groups acting on spheres
225(2)
A2.3 Discrete groups
227(3)
A3 Hopf fibration
230(7)
A3.1 Fibrations
230(1)
A3.2 Hopf fibration
231(6)
A4 Polytopes and honeycombs
237(11)
A4.1 Symmetries and orthoscheme tetrahedra
237(8)
A4.2 Polytopes and honeycombs
245(3)
A5 Polytope {3,3,5}
248(7)
A5.1 The geometry of polytope {3,3,5}
248(4)
A5.2 Description in terms of toroidal shells
252(3)
A6 Frank and Kasper coordination polyhedra
255(8)
A6.1 Frank and Kasper polyhedra
255(2)
A6.2 Positive and negative disclinations
257(6)
A7 Quasiperiodic tilings: cut and projection
263(10)
A7.1 Cut and projection algorithm
263(2)
A7.2 Codimension 1 approximants
265(2)
A7.3 Approximants of the octagonal tiling
267(4)
A7.4 An almost octagonal quasiperiodic tiling: the labyrinth
271(2)
A8 Differential geometry and parallel transport
273(13)
A8.1 Manifold and tangent space
273(1)
A8.2 Geodesic equation
274(1)
A8.3 Parallel transport and curvature
275(11)
A9 Icosahedral quasicrystals and the E8 lattice
286(12)
A9.1 Introduction
286(1)
A9.2 The E8 lattice
286(1)
A9.3 A discrete Hopf fibration on the Gosset polytope
287(2)
A9.4 Shelling the quasicrystal
289(3)
A9.5 The 2d-1d aspect of the shell-by-shell construction of the quasicrystal
292(4)
A9.6 Quasicrystals of lower dimension
296(2)
Bibliography 298(7)
Index 305