Muutke küpsiste eelistusi

Green Chemistry for Surface Coatings, Inks and Adhesives: Sustainable Applications [Kõva köide]

Edited by (Editorial Ecosiris, Germany), Edited by (University of York, UK), Edited by (Chinese Academy of Sciences, China)
  • Formaat: Hardback, 444 pages, kõrgus x laius: 234x156 mm, kaal: 833 g, No
  • Sari: Green Chemistry Series Volume 60
  • Ilmumisaeg: 26-Jun-2019
  • Kirjastus: Royal Society of Chemistry
  • ISBN-10: 1782629947
  • ISBN-13: 9781782629948
Teised raamatud teemal:
Green Chemistry for Surface Coatings, Inks and Adhesives: Sustainable ApplicationsSuurem pilt
  • Formaat: Hardback, 444 pages, kõrgus x laius: 234x156 mm, kaal: 833 g, No
  • Sari: Green Chemistry Series Volume 60
  • Ilmumisaeg: 26-Jun-2019
  • Kirjastus: Royal Society of Chemistry
  • ISBN-10: 1782629947
  • ISBN-13: 9781782629948
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9781782629948.html
Märksõnad:
Highlighting sustainable technologies and applications of renewable raw materials within the framework of green and sustainable chemistry, circular economy and resource efficiency, provides a cradle-to-cradle perspective. From potential feedstocks to recycling/reuse opportunities and the de-manufacture of adhesives and solvents, the book applies green chemistry principles to all aspects of adhesive and sealant manufacture. The book is ideal for researchers and industrialists working in green chemistry, industrial coatings, adhesives and inks and printing technologies.

Many modern surface coatings and adhesives are derived from fossil feedstocks. With fossil fuels becoming more polluting and expensive to extract as supplies dwindle, industry is turning increasingly to nature, mimicking natural solutions using renewable raw materials and employing new technologies.

Highlighting sustainable technologies and applications of renewable raw materials within the framework of green and sustainable chemistry, circular economy and resource efficiency, this book provides a cradle-to-cradle perspective. From potential feedstocks to recycling/reuse opportunities and the de-manufacture of adhesives and solvents, green chemistry principles are applied to all aspects of surface coating, printing, adhesive and sealant manufacture.

This book is ideal for students, researchers and industrialists working in green sustainable chemistry, industrial coatings, adhesives, inks and printing technologies.

Chapter 1 Green Chemistry Principles and Global Drivers for Sustainability -- An Introduction
1(17)
Avtar S. Matharu
Kadambari Lokesh
1.1 Introduction: Drivers for Change
1(1)
1.2 Biobased Markets and Trends
2(2)
1.3 Circular Economy, SDGs, Waste, and Legislation
4(2)
1.4 Green Chemistry: Guiding Principles
6(1)
1.5 Green Chemistry: Renewable Feedstocks to Biorefineries to Circular Bioeconomies
6(9)
1.5.1 Green Chemistry: Green Metrics and Life Cycle Analysis (LCA)
10(5)
1.6 Conclusions
15(1)
References
15(3)
Chapter 2 Green Solubility for Coatings and Adhesives
18(33)
Steven Abbott
Seishi Shimizu
2.1 Introduction
18(5)
2.1.1 Are you Really Being Green?
18(5)
2.2 Current Approaches to Solubility and Solubilization
23(7)
2.2.1 Lattice Models -- the Minimum Necessary Theory
23(3)
2.2.2 Conductor-like Screening Models -- the Minimum Necessary Theory
26(1)
2.2.3 Using Solubility Theories for Solvent Replacement
27(3)
2.3 The Importance of Compromise in Finding a Solvent Replacement
30(1)
2.4 Choosing a Suitable Solubility Tool
31(1)
2.5 Solubilization -- When Solubility Fails
32(3)
2.5.1 Accessing KBI Values
34(1)
2.6 Putting it All into Practice
35(9)
2.6.1 Rational Substitution via HSP
35(2)
2.6.2 Rational Substitution via COSMO-RS
37(1)
2.6.3 Your New Polymer, Additive etc. -- HSP Only
37(4)
2.6.4 Strong Bonding Across Polymer Interfaces -- HSP Only
41(1)
2.6.5 Going Aqueous with KB
42(2)
2.7 Conclusions
44(1)
Acknowledgements
44(1)
References
45(6)
Section 1 Natural Adhesive and Surface Coating Concepts
Chapter 3 Diversified Biological Adhesives and Their Differences with Synthetic Polymers
51(18)
Kei Kamino
3.1 Introduction: Conceptual Gap Between Chemical Synthetic Polymers and Bio-molecular Materials
51(2)
3.2 Diversity in Biological Underwater Adhesion and Adhesives
53(3)
3.3 Barnacle Adhesive
56(4)
3.3.1 Molecular Design in Barnacle Cement Proteins
56(1)
3.3.2 Significance of Intermolecular Hydrophobic Interaction in the Bulk of the Barnacle Adhesive
57(1)
3.3.3 Different Conformational Concepts at Barnacle Adhesive Interfaces
58(2)
3.4 Comparison of Biological Adhesives at the Molecular Level
60(4)
3.4.1 Mussel Byssal Thread and Tubeworm Cement
60(1)
3.4.2 Comparison of Molecular Mechanisms Among the Three Representative Model Systems
61(3)
3.5 Impacts of Biological Adhesives
64(1)
3.6 Concluding Remarks
65(1)
Acknowledgements
66(1)
References
66(3)
Chapter 4 Bioinspired Attachment Systems for Adhesive Tapes in Green Tribology Applications
69(23)
Jonathan B. Puthoff
4.1 Green Tribology and Adhesives
69(3)
4.2 Natural Fibrillar Adhesives
72(4)
4.3 Fibrillar Adhesives as Dry, Reduced-additive Adhesives
76(2)
4.4 Wear Resistance
78(1)
4.5 Anti-contaminating and Self-cleaning Properties
79(5)
4.6 Strong Adhesion and Low-energy Detachment
84(3)
4.7 Closing Remarks
87(1)
References
87(5)
Chapter 5 Lotus Effect-based Superhydrophobic Surfaces: Candle Soot as a Promising Class of Nanoparticles for Self-cleaning and Oil-Water Separation Applications
92(28)
Sanjay S. Latthe
Kazuya Nakata
Rainer Hofer
Akira Fujishima
Chiaki Terashima
5.1 Introduction
92(3)
5.2 Commercial Industrial Applications
95(5)
5.2.1 Exterior Wall Paints
96(1)
5.2.2 Door and Window Glass and Skyscrapers of Buildings
96(2)
5.2.3 Textiles
98(1)
5.2.4 Automotive Industry
98(1)
5.2.5 Anticorrosion
98(1)
5.2.6 Others
99(1)
5.3 Candle Soot Nanoparticles for Self-cleaning Superhydrophobic Coatings
100(8)
5.4 Candle Soot Nanoparticles Deposited on Mesh/Sponge for Oil-water Separation
108(6)
5.5 Conclusion
114(1)
Acknowledgement
114(1)
References
115(5)
Chapter 6 Adhesives for Medical Applications
120(27)
Katharina Richter
Marta Pinheiro
Kai Borcherding
Andreas Hartwig
Janek von Byern
Ingo Grunwald
6.1 Introduction
120(4)
6.2 State of the Art -- Application Areas and Examples
124(3)
6.3 Research to Market -- Novel Biomimetic Adhesives
127(6)
6.4 Product to Market -- Regulatory Aspects
133(4)
6.5 Market Size and Innovation Processes
137(2)
6.6 Conclusion
139(1)
Acknowledgements
140(1)
References
140(7)
Section 2 Biobased Binders and Additives
Chapter 7 White Biotechnology for Polymer Building Blocks: Strategies for Enhanced Production of Bio-based 1,3-Propanediol and Its Applications
147(36)
Narisetty Vivek
Rajendran Omana Rajesh
Tharangattumana Krishnan Godan
Ashok Pandey
Parameswaran Binod
7.1 Introduction
147(2)
7.2 Production of 1,3-PDO
149(15)
7.2.1 The Shell Process
149(1)
7.2.2 The Degussa/DuPont Process
150(1)
7.2.3 Hydrogenolysis of Glycerol
150(2)
7.2.4 Biological Production
152(2)
7.2.5 Substrate and Co-Substrate for 1,3-PDO Production
154(1)
7.2.6 Genetics of Glycerol Dissimilation
154(3)
7.2.7 Strain Development to Improve Production Titers
157(7)
7.3 Synthesis of Polyurethane
164(2)
7.4 Synthesis of Bio-based Polyesters
166(3)
7.4.1 Polytrimethylene Terephthalate
167(1)
7.4.2 Polytrimethylene Succinate
168(1)
7.4.3 Polytrimethylene Furandicarboxylates
169(1)
7.5 Conclusions and Future Outlook
169(2)
Acknowledgements
171(1)
References
171(12)
Chapter 8 Biosilicate Binders
183(22)
Marko Petric
Avtar S. Matharu
8.1 Introduction and Market Overview
183(2)
8.2 Background to Silicon and Silica
185(1)
8.3 Silicon, Silica and Silicates in Biomass
186(1)
8.4 Chemistry of Alkali Silicates
187(5)
8.4.1 Setting Processes
190(1)
8.4.2 Composition and Inorganic Distribution of Alkali Silicates in Biomass
191(1)
8.5 Compounds of Silicon in Adhesives
192(7)
8.5.1 Inorganic Compounds of Si (Silica, Silicates, Clay, and Other Inorganic Compounds)
192(1)
8.5.2 Wood- and Lignocellulosic-based Composites Containing Si Compounds
193(6)
8.6 Concluding Remarks: Biosilicates from Biomass Ash Burning as Binders for Agricultural Straw Composites
199(1)
Acknowledgements
200(1)
References
201(4)
Chapter 9 Adhesives Derived From Biomass Waste Streams
205(30)
Zhanrong Zhang
Avtar S. Matharu
9.1 Introduction
205(7)
9.1.1 Biorefinery for Renewable Waste Streams
206(2)
9.1.2 Lignocellulosic Biomass
208(1)
9.1.3 Wood Chips, Waste Paper and Paper Deinking Residue (DIR)
209(1)
9.1.4 Microwave-assisted Fast Pyrolysis
210(2)
9.2 Microwave-assisted Fast Pyrolysis
212(1)
9.3 Adhesion Properties of Organic Phase Bio-oils
212(8)
9.3.1 Adhesion Tests of Organic Phase Bio-oils
214(1)
9.3.2 Adhesion Strengths of Organic Phase Bio-oils
215(5)
9.4 Model Compound Study of Adhesive Properties of Bio-oils
220(11)
9.4.1 Adhesion Properties of Single Model Compounds
221(3)
9.4.2 Adhesion Properties of Mixtures of Two Model Compounds
224(4)
9.4.3 Adhesion Properties of Mixtures of the Three Model Compounds
228(3)
Conclusion
231(1)
References
231(4)
Chapter 10 Soy Protein Based Bio-adhesives
235(25)
Jiarong Zhang
Zhanrong Zhang
10.1 Introduction
235(2)
10.2 Introduction to Soy Proteins
237(1)
10.3 Chemical Modification of Soy Protein
238(7)
10.3.1 Denaturation of Soy Protein
238(2)
10.3.2 Cross-linking Agent Modification
240(5)
10.3.3 Molecular Modification of Soy Proteins
245(1)
10.4 Soy Protein Blends
245(5)
10.4.1 Soy Protein Combined with Synthetic Polymers
246(1)
10.4.2 Soy Protein Blends with Natural Polymers
247(3)
10.4.3 Incorporation of Inorganic Matter into Soy Protein Adhesives
250(1)
10.5 Enzymatic Modification
250(1)
10.6 Conclusions
251(1)
References
251(9)
Chapter 11 Natural Oil Polyols
260(27)
Frederic Hapiot
Eric Monflier
11.1 Introduction
260(2)
11.2 The NOP Market
262(1)
11.3 Synthesis of NOPs
263(4)
11.3.1 Cleavage of Carbon--Carbon Double Bonds
264(1)
11.3.2 Functionalization of Carbon--Carbon Double Bonds
265(2)
11.4 NOP-based Surface Coatings and Adhesives
267(10)
11.4.1 From Castor Oil
268(2)
11.4.2 From Soybean Oil
270(3)
11.4.3 From Palm Oil
273(1)
11.4.4 From Linseed Oil
274(1)
11.4.5 From Sunflower Oil
275(1)
11.4.6 From Jatropha Oil
276(1)
11.4.7 From Karanja and Cottonseed Oil
276(1)
11.4.8 From Camelina Oil
277(1)
11.5 Conclusion
277(1)
References
278(9)
Section 3 Sustainable Adhesive and Surface Coating Technologies
Chapter 12 Bio-based Switchable Adhesives for Carpet Tiles
287(23)
Hangbo Yue
Peter S. Shuttle-worth
12.1 Introduction
287(1)
12.2 Adhesives
288(12)
12.2.1 Background and Theory
288(3)
12.2.2 Mechanics of Adhesion
291(5)
12.2.3 Switchable Adhesives
296(4)
12.3 Carpet Tiles
300(7)
12.3.1 Uses
300(2)
12.3.2 Construction
302(1)
12.3.3 Switchable Adhesives for Carpet Tiles
303(4)
12.4 Conclusion
307(1)
Acknowledgements
307(1)
References
308(2)
Chapter 13 Debondable Adhesive Systems
310(29)
Nicolas Schuwer
Reichard Vendamme
13.1 Introduction
310(2)
13.2 Temporary Adhesive Systems in Nature
312(3)
13.2.1 Biophysical Approaches Toward Temporary Adhesion
313(1)
13.2.2 Biochemical Substances with Sticking and Un-sticking Properties
313(2)
13.3 Light Mediated Debondable Adhesives
315(4)
13.3.1 Overcured Adhesives
315(1)
13.3.2 Photocleavage
316(2)
13.3.3 Photodimerization
318(1)
13.3.4 Photoisomerization
318(1)
13.3.5 Others
319(1)
13.4 Heat Mediated Debondable Adhesives
319(7)
13.4.1 Thermal Degradation and Thermo-cleavage
319(2)
13.4.2 Shape-memory Polymer
321(1)
13.4.3 Melting Additives
321(1)
13.4.4 Expandable and Gas Forming Additives
322(2)
13.4.5 Diels-Alder Chemistry
324(1)
13.4.6 LCST and UCST Based Systems
325(1)
13.4.7 Tg Based Systems
326(1)
13.5 Cooling Mediated Debondable Adhesives
326(1)
13.6 Fluid and Solution Mediated Debondable Adhesives
327(1)
13.7 Electric Current Mediated Debondable Adhesives
328(1)
13.8 Magnetic Field Mediated Debondable Adhesives
329(1)
13.9 Other Triggers
329(2)
13.10 Commercial Examples
331(1)
13.11 Conclusion
332(1)
Abbreviations
332(1)
Acknowledgements
333(1)
References
333(6)
Chapter 14 Printing Inks From Renewable Resources
339(29)
Tobias Robert
14.1 Introduction
339(3)
14.2 Printing Ink Composition
342(2)
14.2.1 Colorants
342(1)
14.2.2 Vehicle or Binder Resin
343(1)
14.2.3 Solvents
343(1)
14.2.4 Additives
344(1)
14.3 Printing Processes
344(12)
14.3.1 Flexographic Inks
345(3)
14.3.2 Gravurelnks
348(2)
14.3.3 Lithographic Offset Inks
350(5)
14.3.4 Screen Printing Inks
355(1)
14.4 Inks for Digital Printing
356(2)
14.5 UV-curing Printing Inks
358(2)
14.6 Conclusion and Outlook
360(2)
References
362(6)
Chapter 15 Green Chemistry for Automotive Coatings: Sustainable Applications
368(27)
Hui Zhang
Marshall Shuai Yang
Mohammad T. I. Bhuiyan
Jesse Zhu
15.1 Basics of Coatings
368(9)
15.1.1 A Brief Introduction to Liquid Coatings
369(1)
15.1.2 A Brief Introduction to Powder Coatings
370(7)
15.2 Introduction to Automotive OEM Coating Systems
377(4)
15.2.1 Current OEM Coating Systems
377(3)
15.2.2 Conventional Painting Procedures
380(1)
15.3 Sustainability Issues in Automotive Coatings and Their Applications
381(1)
15.4 Powder Coatings Currently Used in the Automotive Industry
382(5)
15.4.1 Ultrafine Powder Coatings
383(2)
15.4.2 Low-temperature-cure (LTC) Powder Coatings
385(2)
15.5 Coatings for OEM Automotive Plastic Parts
387(2)
15.5.1 Liquid Coatings for OEM Automotive Plastic Parts
387(1)
15.5.2 Powder Coatings for OEM Plastic Parts
388(1)
15.6 Waterborne Automotive OEM Coatings
389(1)
15.6.1 Current Waterborne OEM Coatings
389(1)
15.6.2 Innovations in Waterborne Coating Applications
390(1)
15.7 Conclusion
390(1)
References
391(4)
Chapter 16 Dry Powder Coating of Pharmaceutical Solid Dosages
395(24)
Jesse Zhu
Zhehao Jing
Qingliang Yang
Yingliang Ma
Kwok Chow
Kaiqi Shi
16.1 Introduction
395(1)
16.2 Developments of Pharmaceutical Coating
396(8)
16.2.1 Sugar Coating
397(1)
16.2.2 Solvent Coating
397(1)
16.2.3 Aqueous Coating
398(1)
16.2.4 Potential Developments for Pharmaceutical Coating
399(1)
16.2.5 Earlier Attempts in Dry Coating
400(4)
16.3 Electrostatic Powder Coating
404(3)
16.3.1 Industrial Powder Coating Process
404(1)
16.3.2 Pharm Powder Coating Process
404(2)
16.3.3 Film Formation Mechanism
406(1)
16.4 "ExsicCoat" Technology
407(8)
16.4.1 Technology and Processing Apparatus
407(2)
16.4.2 Developments of "ExsicCoat" Technology
409(3)
16.4.3 Extended Applications of "ExsicCoat" Technology
412(3)
16.5 Conclusions
415(1)
References
415(4)
Subject Index 419