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Introduction to the Thermodynamics of Materials 6th edition [Kõva köide]

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(Purdue University, West Lafayette, Indiana, USA), (Carnegie Mellon University, Pittsburgh, Pennsylvania, USA)
  • Formaat: Hardback, 694 pages, kõrgus x laius: 234x156 mm, kaal: 1220 g, 11 Tables, black and white; 259 Illustrations, black and white
  • Ilmumisaeg: 18-Aug-2017
  • Kirjastus: CRC Press Inc
  • ISBN-10: 1498757006
  • ISBN-13: 9781498757003
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Introduction to the Thermodynamics of Materials 6th editionSuurem pilt
  • Formaat: Hardback, 694 pages, kõrgus x laius: 234x156 mm, kaal: 1220 g, 11 Tables, black and white; 259 Illustrations, black and white
  • Ilmumisaeg: 18-Aug-2017
  • Kirjastus: CRC Press Inc
  • ISBN-10: 1498757006
  • ISBN-13: 9781498757003
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9781498757003.html
Märksõnad:

Maintaining the substance that made Introduction to the Thermodynamic of Materials a perennial best seller for decades, this Sixth Edition is updated to reflect the broadening field of materials science and engineering. The new edition is reorganized into three major sections to align the book for practical coursework, with the first (Thermodynamic Principles) and second (Phase Equilibria) sections aimed at use in a one semester undergraduate course. The third section (Reactions and Transformations) can be used in other courses of the curriculum that deal with oxidation, energy, and phase transformations. The book is updated to include the role of work terms other than PV work (e.g., magnetic work) along with their attendant aspects of entropy, Maxwell equations, and the role of such applied fields on phase diagrams. There is also an increased emphasis on the thermodynamics of phase transformations and the Sixth Edition features an entirely new chapter 15 that links specific thermodynamic applications to the study of phase transformations. The book also features more than 50 new end of chapter problems and more than 50 new figures.

Arvustused

"I love this book and will strongly recommend it to my students. It is an excellent textbook for undergraduate students who are studying in materials science." Jongee Park, Atlm University, Ankara, Turkey

"A comprehensive book on thermodynamics in metallic systems with the underlying theory crystal clear explained." Sybrand van der Zwaag, Delft University of Technology, Netherlands

"The book is logically organized in three sections: thermodynamic principles, phase equilibria, and reactions and transformations. Each chapter contains a summary and nearly every chapter provides detailed examples. The new edition includes additional thermodynamic work terms beyond pdV or Tds or udN such as magnetic work and how the fields within these work terms are experimentally relevant." Bill Knowlton, Boise State University, Idaho, USA

"The text is easy to follow for undergraduate students doing a course in thermodynamics of materials. The thermodynamic consideration of magnetic materials is particularly useful for graduate students working on magnetic materials. I find the effect of magnetism and magnetic work in the analysis very useful. The introduction of Magnetic flavor in this textbook set it apart from other books on thermodynamics of materials" Oh Joo Tien, Nanyang Technological University, Singapore

"This book gives a step-by-step introduction to the thermodynamics of materials. After an exposition of the fundamental concepts, examples of increasing difficulty are treated, which contain many real-world applications. Many examples are laid out in details, and numerous diagrams are given to make sure that a solid understanding is reached. Therefore, this book gives solid foundations in thermodynamics for engineering students. Equipped with this knowledge, the students can go on toward more specialized studies or to the reading of research papers."Mathis Plapp, CNRS/Ecole Polytechnique, Palaiseau, France

"This book provides a solid foundation in the thermodynamic theory necessary for any study of Materials Science. It would be ideal for undergraduate students who are learning this topic for the first time, but is also useful as a refresher of the fundamentals for graduate students and researchers working in this field. The inclusion of worked examples and problems is particularly valuable in helping to practice the application of thermodynamic theory to real examples in Materials Science." Joseph Robson, University of Manchester, United Kingdom

"This book, Introduction to the Thermodynamics of Materials, Sixth Edition, is very suitable to be a text book for undergraduate students. This book can easily bring them to enter the world of Thermodynamics of Materials and make them well know concept about Thermodynamics. I always tell my friends and colleagues that this book is the Bible of the Thermodynamics of Materials. In Taiwan, this book is also a text book for graduated school entrance examinations." Yee-Wen Yen, National Taiwan University of Science and Technology

"This text is by far the best text I have yet found for teaching thermodynamics to undergrads. I believe the emphasis on graphical representations of thermodynamic data is a very real strength for interpreting this material to the beginner. I also see significant improvements in the organization that provides greater clarity. The addition of qualitative example problems at the end of each chapter is welcome. The new Chapter 15 is a valuable contribution. This chapter is probably unlikely to be used in undergraduate teaching, but it will be extremely useful for a new generation of graduate students." Garry Warren, University of Alabama, USA

"this new edition of classic book on thermodynamics of materials written by two stalwarts in the subject, Professors David R. Gaskell and David E. Laughlin, is the need of the hour. Although Professor Gaskell is not among us physically to inspire us, his legacy will be seen whenever we open this book on thermodynamics of materials. A great effort from Professor Laughlin in bringing out this revised edition." Koteswararao V. Rajulapati, University of Hyderabad, India

"This textbook has a very rigorous and deep approach to chemical thermodynamics. It is very clear in explaining the complex meaning of the thermodynamics rules and equations, starting from the potentials and their use to solve thermodynamics problems. Without being too advanced, it reaches all the necessary points for a thorough discussion of the matter, even entering in some detail which is not often taught in the undergraduate courses, I really appreciate the clarity and the accuracy of the language."

"This Sixth Edition is updated to reflect the broadening field of materials science and engineering. The new edition is reorganized into three major sections to align the book for practical coursework, with the first (Thermodynamic Principles) and second (Phase Equilibria) sections aimed at use in a one semester undergraduate course. The third section (Reactions and Transformations) can be used in other courses of the curriculum that deal with oxidation, energy, and phase transformations. The book is updated to include the role of work terms other than PV work (e. g., magnetic work) along with their attendant aspects of entropy, Maxwell equations, and the role of such applied fields on phase diagrams. There is also an increased emphasis on the thermodynamics of phase transformations and the Sixth Edition features an entirely new chapter 15 that links specific thermodynamic applications to the study of phase transformations. The book also features more than 50 new end of chapter problems and more than 50 new figures." HTM J. Heat Treatm. Mat. 72 (2017)

Marco Marengo, University of Brighton, United Kingdom

"In my opinion, this book represents an excellent resource material on the topic of thermodynamics for students (both in the undergraduate and graduate levels) and instructors. I strongly recommend the utilization of this book as a reference and companion in undergraduate courses involving thermodynamics for materials science. This book is comprehensive, articulate, well-organized, and the reading is enjoy-able."

J. of Mater Sci (2018) "I love this book and will strongly recommend it to my students. It is an excellent textbook for undergraduate students who are studying in materials science." Jongee Park, Atlm University, Ankara, Turkey

"A comprehensive book on thermodynamics in metallic systems with the underlying theory crystal clear explained." Sybrand van der Zwaag, Delft University of Technology, Netherlands

"The book is logically organized in three sections: thermodynamic principles, phase equilibria, and reactions and transformations. Each chapter contains a summary and nearly every chapter provides detailed examples. The new edition includes additional thermodynamic work terms beyond pdV or Tds or udN such as magnetic work and how the fields within these work terms are experimentally relevant." Bill Knowlton, Boise State University, Idaho, USA

"The text is easy to follow for undergraduate students doing a course in thermodynamics of materials. The thermodynamic consideration of magnetic materials is particularly useful for graduate students working on magnetic materials. I find the effect of magnetism and magnetic work in the analysis very useful. The introduction of Magnetic flavor in this textbook set it apart from other books on thermodynamics of materials" Oh Joo Tien, Nanyang Technological University, Singapore

"This book gives a step-by-step introduction to the thermodynamics of materials. After an exposition of the fundamental concepts, examples of increasing difficulty are treated, which contain many real-world applications. Many examples are laid out in details, and numerous diagrams are given to make sure that a solid understanding is reached. Therefore, this book gives solid foundations in thermodynamics for engineering students. Equipped with this knowledge, the students can go on toward more specialized studies or to the reading of research papers."Mathis Plapp, CNRS/Ecole Polytechnique, Palaiseau, France

"This book provides a solid foundation in the thermodynamic theory necessary for any study of Materials Science. It would be ideal for undergraduate students who are learning this topic for the first time, but is also useful as a refresher of the fundamentals for graduate students and researchers working in this field. The inclusion of worked examples and problems is particularly valuable in helping to practice the application of thermodynamic theory to real examples in Materials Science." Joseph Robson, University of Manchester, United Kingdom

"This book, Introduction to the Thermodynamics of Materials, Sixth Edition, is very suitable to be a text book for undergraduate students. This book can easily bring them to enter the world of Thermodynamics of Materials and make them well know concept about Thermodynamics. I always tell my friends and colleagues that this book is the Bible of the Thermodynamics of Materials. In Taiwan, this book is also a text book for graduated school entrance examinations." Yee-Wen Yen, National Taiwan University of Science and Technology

"This text is by far the best text I have yet found for teaching thermodynamics to undergrads. I believe the emphasis on graphical representations of thermodynamic data is a very real strength for interpreting this material to the beginner. I also see significant improvements in the organization that provides greater clarity. The addition of qualitative example problems at the end of each chapter is welcome. The new Chapter 15 is a valuable contribution. This chapter is probably unlikely to be used in undergraduate teaching, but it will be extremely useful for a new generation of graduate students." Garry Warren, University of Alabama, USA

"this new edition of classic book on thermodynamics of materials written by two stalwarts in the subject, Professors David R. Gaskell and David E. Laughlin, is the need of the hour. Although Professor Gaskell is not among us physically to inspire us, his legacy will be seen whenever we open this book on thermodynamics of materials. A great effort from Professor Laughlin in bringing out this revised edition." Koteswararao V. Rajulapati, University of Hyderabad, India

"This textbook has a very rigorous and deep approach to chemical thermodynamics. It is very clear in explaining the complex meaning of the thermodynamics rules and equations, starting from the potentials and their use to solve thermodynamics problems. Without being too advanced, it reaches all the necessary points for a thorough discussion of the matter, even entering in some detail which is not often taught in the undergraduate courses, I really appreciate the clarity and the accuracy of the language." Marco Marengo, University of Brighton, United Kingdom

"This Sixth Edition is updated to reflect the broadening field of materials science and engineering. The new edition is reorganized into three major sections to align the book for practical coursework, with the first (Thermodynamic Principles) and second (Phase Equilibria) sections aimed at use in a one semester undergraduate course. The third section (Reactions and Transformations) can be used in other courses of the curriculum that deal with oxidation, energy, and phase transformations. The book is updated to include the role of work terms other than PV work (e. g., magnetic work) along with their attendant aspects of entropy, Maxwell equations, and the role of such applied fields on phase diagrams. There is also an increased emphasis on the thermodynamics of phase transformations and the Sixth Edition features an entirely new chapter 15 that links specific thermodynamic applications to the study of phase transformations. The book also features more than 50 new end of chapter problems and more than 50 new figures." HTM J. Heat Treatm. Mat. 72 (2017)

"In my opinion, this book represents an excellent resource material on the topic of thermodynamics for students (both in the undergraduate and graduate levels) and instructors. I strongly recommend the utilization of this book as a reference and companion in undergraduate courses involving thermodynamics for materials science. This book is comprehensive, articulate, well-organized, and the reading is enjoy-able."

J. of Mater Sci (2018)

Preface xvii
Authors xix
Part I: Thermodynamic Principles
Chapter 1 Introduction and Definition of Terms
3(20)
1.1 Introduction
3(1)
1.2 The Concept of State
4(4)
1.3 Example of Equilibrium
8(1)
1.4 The Equation of State of an Ideal Gas
9(3)
1.5 The Units of Energy and Work
12(1)
1.6 Extensive and Intensive Thermodynamic Variables
13(1)
1.7 Equilibrium Phase Diagrams and Thermodynamic Components
13(3)
1.8 Laws of Thermodynamics
16(1)
1.8.1 The First Law of Thermodynamics
17(1)
1.8.2 The Second Law of Thermodynamics
17(1)
1.8.3 The Third Law of Thermodynamics
17(1)
1.9 Summary
17(1)
1.10 Concepts and Terms Introduced in
Chapter 1
18(1)
1.11 Qualitative Example Problems
19(1)
1.12 Quantitative Example Problems
20(1)
Problems
21(2)
Chapter 2 The First Law of Thermodynamics
23(34)
2.1 Introduction
23(1)
2.2 The Relationship between Heat and Work
24(1)
2.3 Internal Energy and the First Law of Thermodynamics
25(4)
2.4 Constant-Volume Processes
29(1)
2.5 Constant-Pressure Processes and the Enthalpy, H
30(1)
2.6 Heat Capacity
31(6)
2.7 Reversible Adiabatic Processes
37(3)
2.8 Reversible Isothermal Pressure or Volume Changes of an Ideal Gas
40(1)
2.9 Other Forms of Work
41(2)
2.9.1 Magnetic Work on a Paramagnetic Material
41(1)
2.9.2 Electrical Work on a Dielectric Material
42(1)
2.9.3 Work to Create or Extend a Surface
42(1)
2.10 Summary
43(2)
2.11 Concepts and Terms Introduced in
Chapter 2
45(1)
2.12 Qualitative Example Problems
45(2)
2.13 Quantitative Example Problems
47(4)
Problems
51(3)
Appendix 2A: Note on the Sign Convention of deltaw
54(3)
Chapter 3 The Second Law of Thermodynamics
57(36)
3.1 Introduction
57(1)
3.2 Spontaneous or Natural Processes
58(1)
3.3 Entropy and the Quantification of Irreversibility
59(2)
3.4 Reversible Processes
61(1)
3.5 Illustration of Reversible and Irreversible Processes
61(3)
3.5.1 The Reversible Isothermal Expansion of an Ideal Gas
62(1)
3.5.2 The Free Expansion of an Ideal Gas
63(1)
3.6 Further Differences between Reversible and Irreversible Expansion
64(1)
3.7 Compression of an Ideal Gas
65(1)
3.7.1 Reversible Isothermal Compression
65(1)
3.8 The Adiabatic Expansion of an Ideal Gas
66(1)
3.9 Summary Statements
67(1)
3.10 The Properties of Heat Engines
67(4)
3.11 The Thermodynamic Temperature Scale
71(3)
3.12 The Second Law of Thermodynamics
74(2)
3.13 Maximum Work
76(2)
3.14 Entropy and the Criterion for Equilibrium
78(1)
3.15 The Combined Statement of the First and Second Laws of Thermodynamics
79(2)
3.16 Summary
81(2)
3.17 Concepts and Terms Introduced in
Chapter 3
83(1)
3.18 Qualitative Example Problems
83(2)
3.19 Quantitative Example Problems
85(5)
Problems
90(3)
Chapter 4 The Statistical Interpretation of Entropy
93(28)
4.1 Introduction
93(1)
4.2 Entropy and Disorder on an Atomic Scale
94(1)
4.3 The Concept of Microstate
95(1)
4.4 The Microcanonical Approach
96(8)
4.4.1 Identical Particles on Distinguishable Sites with Different Assigned Energies
96(2)
4.4.2 Configurational Entropy of Differing Atoms in a Crystal
98(4)
4.4.3 Configurational Entropy of Magnetic Spins on an Array of Atoms
102(2)
4.5 The Boltzmann Distribution
104(4)
4.6 The Influence of Temperature
108(2)
4.7 Thermal Equilibrium and the Boltzmann Equation
110(1)
4.8 Heat Flow and the Production of Entropy
111(2)
4.9 Summary
113(1)
4.10 Concepts and Terms Introduced in
Chapter 4
114(1)
4.11 Qualitative Example Problems
115(1)
4.12 Quantitative Example Problems
116(3)
Problems
119(2)
Chapter 5 Fundamental Equations and Their Relationships
121(34)
5.1 Introduction
121(2)
5.2 The Enthalpy, H
123(1)
5.3 The Helmholtz Free Energy, A
123(5)
5.4 The Gibbs Free Energy, G
128(1)
5.5 The Fundamental Equations for a Closed System
129(2)
5.6 The Variation of the Composition within a Closed System
131(1)
5.7 The Chemical Potential
131(3)
5.8 Thermodynamic Relations
134(1)
5.9 Maxwell's Relations
135(2)
5.10 Examples of the Application of Maxwell Relations
137(8)
5.10.1 The First TdS Equation
137(2)
5.10.2 The Second TdS Equation
139(2)
5.10.3 S and V as Dependent Variables and T and P as Independent Variables
141(1)
5.10.4 An Energy Equation (Infernal Energy)
142(1)
5.10.5 Another Energy Equation (Enthalpy)
143(1)
5.10.6 A Magnetic Maxwell Relation
143(1)
5.10.7 S, V, and M with Independent Variables T, P, and H
144(1)
5.11 Another Important Formula
145(1)
5.12 The Gibbs-Helmholtz Equation
145(2)
5.13 Summary
147(1)
5.14 Concepts and Terms Introduced in
Chapter 5
148(1)
5.15 Qualitative Example Problems
148(2)
5.16 Quantitative Example Problems
150(2)
Problems
152(3)
Chapter 6 Capacity, Enthalpy, Entropy, and the Third Law of Thermodynamics
155(44)
6.1 Introduction
155(1)
6.2 Theoretical Calculation of the Heat Capacity
156(6)
6.3 The Empirical Representation of Heat Capacities
162(1)
6.4 Enthalpy as a Function of Temperature and Composition
162(10)
6.5 The Dependence of Entropy on Temperature and the Third Law of Thermodynamics
172(5)
6.5.1 Development of the Third Law of Thermodynamics
172(3)
6.5.2 Apparent Contradictions to the Third Law of Thermodynamics
175(2)
6.6 Experimental Verification of the Third Law
177(5)
6.7 The Influence of Pressure on Enthalpy and Entropy
182(2)
6.8 Summary
184(1)
6.9 Concepts and Terms Introduced in
Chapter 6
185(1)
6.10 Qualitative Example Problems
186(1)
6.11 Quantitative Example Problems
187(6)
Problems
193(1)
Appendix 6A
194(5)
Part II: Phase Equilibria
Chapter 7 Phase Equilibrium in a One-Component System
199(30)
7.1 Introduction
199(1)
7.2 The Variation of Gibbs Free Energy with Temperature at Constant Pressure
200(4)
7.3 The Variation of Gibbs Free Energy with Pressure at Constant Temperature
204(1)
7.4 The Gibbs Free Energy as a Function of Temperature and Pressure
205(5)
7.5 Equilibrium between the Vapor Phase and a Condensed Phase
210(2)
7.6 Graphical Representation of Vapor Phase and Condensed Phase Equilibria
212(1)
7.7 Solid-Solid Equilibria
212(5)
7.8 The Effect of an Applied Magnetic Field on the P-T Diagram
217(1)
7.9 Summary
218(1)
7.10 Concepts and Terms Introduced in
Chapter 7
219(1)
7.11 Qualitative Example Problems
220(2)
7.12 Quantitative Example Problems
222(4)
Problems
226(3)
Chapter 8 The Behavior of Gases
229(38)
8.1 Introduction
229(1)
8.2 The P-V-T Relationships of Gases
229(1)
8.3 The Thermodynamic Properties of Ideal Gases and Mixtures of Ideal Gases
230(6)
8.3.1 Mixtures of Ideal Gases
230(4)
8.3.1.1 Mole Fraction
231(1)
8.3.1.2 Dalton's Law of Partial Pressures
231(1)
8.3.1.3 Partial Molar Quantities
232(2)
8.3.2 The Enthalpy of Mixing of Ideal Gases
234(1)
8.3.3 The Gibbs Free Energy of Mixing of Ideal Gases
235(1)
8.3.4 The Entropy of Mixing of Ideal Gases
236(1)
8.4 Deviation From Ideality and Equations of State for Real Gases
236(4)
8.5 The Van Der Waals Fluid
240(10)
8.6 Other Equations of State for Nonideal Gases
250(1)
8.7 Further Thermodynamic Treatment of Nonideal Gases
251(8)
8.8 Summary
259(1)
8.9 Concepts and Terms Introduced in
Chapter 8
260(1)
8.10 Qualitative Example Problems
260(1)
8.11 Quantitative Example Problems
261(4)
Problems
265(2)
Chapter 9 The Behavior of Solutions
267(54)
9.1 Introduction
267(1)
9.2 Raoult's Law and Henry's Law
267(4)
9.3 The Thermodynamic Activity of a Component in Solution
271(2)
9.4 The Gibbs-Duhem Equation
273(2)
9.5 The Gibbs Free Energy of Formation of a Solution
275(4)
9.5.1 The Molar Gibbs Free Energy of a Solution and the Partial Molar Gibbs Free Energies of the Components of the Solution
275(2)
9.5.2 The Change in Gibbs Free Energy due to the Formation of a Solution
277(1)
9.5.3 The Method of Tangential Intercepts
278(1)
9.6 The Properties of Ideal Solutions
279(6)
9.6.1 The Change in Volume Accompanying the Formation of an Ideal Solution
279(2)
9.6.2 The Enthalpy of Formation of an Ideal Solution
281(1)
9.6.3 The Entropy of Formation of an Ideal Solution
282(3)
9.7 Nonideal Solutions
285(3)
9.8 Application of the Gibbs-Duhem Relation to the Determination of Activity
288(4)
9.8.1 The Relationship between Henry's and Raoult's Laws
289(1)
9.8.3 Direct Calculation of the Total Molar Gibbs Free Energy of Mixing
290(2)
9.9 Regular Solutions
292(6)
9.10 A Statistical Model of Solutions
298(9)
9.10.1 Extensions of the Regular Solution Model: The Atomic Order Parameter
303(3)
9.10.2 Including Second-Neighbor Interactions
306(1)
9.11 Subregular Solutions
307(2)
9.12 Modified Regular Solution Model for Application to Polymers
309(1)
9.12.1 The Flory-Huggins Model
309(1)
9.13 Summary
310(3)
9.14 Concepts and Terms Introduced in
Chapter 9
313(1)
9.15 Qualitative Example Problems
313(2)
9.16 Quantitative Example Problems
315(2)
Problems
317(4)
Chapter 10 Gibbs Free Energy Composition and Phase Diagrams of Binary Systems
321(60)
10.1 Introduction
321(1)
10.2 Gibbs Free Energy and Thermodynamic Activity
322(2)
10.3 Qualitative Overview of Common Binary Equilibrium Phase Diagrams
324(7)
10.3.1 The Lens Diagram: Regular Solution Model
324(1)
10.3.2 Unequal Enthalpies of Mixing
325(1)
10.3.3 The Low-Temperature Regions in Phase Diagrams
326(1)
10.3.4 The Eutectic and Eutectoid Phase Diagrams
327(2)
10.3.5 The Peritectic and Peritectoid Phase Diagrams
329(2)
10.4 Liquid and Solid Standard States
331(7)
10.5 The Gibbs Free Energy of Formation of Regular Solutions
338(3)
10.6 Criteria for Phase Stability in Regular Solutions
341(5)
10.7 Phase Diagrams, Gibbs Free Energy, and Thermodynamic Activity
346(10)
10.8 The Phase Diagrams of Binary Systems That Exhibit Regular Solution Behavior in the Liquid and Solid States
356(6)
10.9 Summary
362(2)
10.10 Concepts and Terms Introduced in
Chapter 10
364(1)
10.11 Qualitative Example Problems
364(2)
10.12 Quantitative Example Problems
366(5)
Problems
371(2)
Appendix 10A
373(3)
Appendix 10B
376(5)
Part III: Reactions and Transformations of Phases
Chapter 11 Reactions Involving Gases
381(32)
11.1 Introduction
381(1)
11.2 Reaction Equilibrium in a Gas Mixture and the Equilibrium Constant
382(6)
11.3 The Effect of Temperature on the Equilibrium Constant
388(2)
11.4 The Effect of Pressure on the Equilibrium Constant
390(1)
11.5 Reaction Equilibrium as a Compromise between Enthalpy and Entropy
391(3)
11.6 Reaction Equilibrium in the System SO2(g)-SO3(g)-O2(g)
394(5)
11.6.1 The Effect of Temperature
395(1)
11.6.2 The Effect of Pressure
396(1)
11.6.3 The Effect of Changes in Temperature and Pressure
397(2)
11.7 Equilibrium in H2O-H2 and CO2-CO Mixtures
399(2)
11.8 Summary
401(1)
11.9 Concepts and Terms Introduced in
Chapter 11
402(1)
11.10 Qualitative Example Problems
403(1)
11.11 Quantitative Example Problems
404(6)
Problems
410(3)
Chapter 12 Reactions Involving Pure Condensed Phases and a Gaseous Phase
413(54)
12.1 Introduction
413(1)
12.2 Reaction Equilibrium in a System Containing Pure Condensed Phases and a Gas Phase
414(5)
12.3 The Variation of the Standard Gibbs Free Energy Change with Temperature
419(3)
12.4 Ellingham Diagrams
422(8)
12.5 The Effect of Phase Transformations
430(5)
12.5.1 Example of the Oxidation of Copper
431(2)
12.5.2 Example of the Chlorination of Iron
433(2)
12.6 The Oxides of Carbon
435(8)
12.6.1 The Equilibrium 2CO + O2 = 2CO2
440(3)
12.7 Graphical Representation of Equilibria in the System Metal-Carbon- Oxygen
443(4)
12.8 Summary
447(1)
12.9 Concepts and Terms Introduced in
Chapter 12
448(1)
12.10 Qualitative Example Problems
448(2)
12.11 Quantitative Example Problems
450(6)
Problems
456(2)
Appendix 12A
458(1)
Appendix 12B
459(8)
Chapter 13 Reaction Equilibria in Systems Containing Components in Condensed Solution
467(100)
13.1 Introduction
467(2)
13.2 The Criteria for Reaction Equilibrium in Systems Containing Components in Condensed Solution
469(8)
13.3 Alternative Standard States
477(7)
13.4 The Gibbs Equilibrium Phase Rule
484(5)
13.5 Phase Stability Diagrams
489(14)
13.6 Binary Systems Containing Compounds
503(13)
13.7 Graphical Representation of Phase Equilibria
516(7)
13.7.1 Phase Equilibria in the System Mg-Al-O
516(4)
13.7.2 Phase Equilibria in the System Al-C-O-N Saturated with Carbon
520(3)
13.8 The Formation of Oxide Phases of Variable Composition
523(9)
13.9 The Solubility of Gases in Metals
532(5)
13.10 Solutions Containing Several Dilute Solutes
537(10)
13.11 Summary
547(3)
13.12 Concepts and Terms Introduced in
Chapter 13
550(1)
13.13 Qualitative Example Problems
550(1)
13.14 Quantitative Example Problems
551(10)
Problems
561(6)
Chapter 14 Electrochemistry
567(54)
14.1 Introduction
567(2)
14.2 The Relationship between Chemical and Electrical Driving Forces
569(5)
14.3 The Effect of Concentration on EMF
574(2)
14.4 Formation Cells
576(1)
14.5 Concentration Cells
577(7)
14.6 The Temperature Coefficient of the EMF
584(2)
14.7 Thermal Energy (Heat) Effects
586(1)
14.8 The Thermodynamics of Aqueous Solutions
587(4)
14.9 The Gibbs Free Energy of Formation of Ions and Standard Reduction Potentials
591(10)
14.9.1 Solubility Products
596(3)
14.9.2 The Influence of Acidity
599(2)
14.10 Pourbaix Diagrams
601(10)
14.10.1 The Pourbaix Diagram for Aluminum
603(1)
14.10.2 The Equilibrium between the Two Dissolved Substances
604(1)
14.10.3 The Equilibrium between the Two Solids
605(2)
14.10.4 One Solid in Equilibrium with a Dissolved Substance
607(2)
14.10.5 The Solubility of Alumina in Aqueous Solutions
609(2)
14.11 Summary
611(2)
14.12 Concepts and Terms introduced in
Chapter 14
613(1)
14.13 Qualitative Example Problem
613(1)
14.14 Quantitative Example Problems
614(4)
Problems
618(3)
Chapter 15 Thermodynamics of Phase Transformations
621(28)
15.1 Thermodynamics and Driving Force
622(4)
15.1.1 Phase Transformations with No Change in Composition
622(2)
15.1.2 Phase Transformations with Change in Composition
624(2)
15.2 Use of the T0 Curves
626(4)
15.2.1 Martensitic Transformation
628(1)
15.2.2 Massive Transformations
628(1)
15.2.3 The Formation of Amorphous Phases from the Liquid
629(1)
15.3 Surface Energy
630(2)
15.3.1 Equilibrium Shape
630(2)
15.4 Nucleation and Surface Energy
632(2)
15.4.1 Homogeneous Nucleation
632(1)
15.4.2 Heterogeneous Nucleation
632(2)
15.5 Capillarity and Local Equilibrium
634(2)
15.6 Thermodynamics of the Landau Theory of Phase Transformations
636(7)
15.7 Summary
643(1)
15.8 Concepts and Terms Introduced in
Chapter 15
643(1)
15.9 Qualitative Example Problems
644(1)
Problems
645(4)
Appendix A: Selected Thermodynamic and Thermochemical Data 649(8)
Appendix B: Exact Differential Equations 657(2)
Appendix C: The Generation of Additional Thermodynamic Potentials as Legendre Transformations 659(10)
Nomenclature 669(2)
Answers to Selected Problems 671(16)
Index 687
David R. Gaskell received a B.Sc. in Metallurgy and Technical Chemistry from the University of Glasgow and a Ph.D. from McMaster University. Dr. Gaskells first faculty position was at the University of Pennsylvania, Philadelphia, where he taught from 1967 to1982 in Metallurgy and Materials Science. He was recruited in 1982 to Purdue University at the rank of Professor where he taught until 2013. During Dr. Gaskells career he served as a Visiting Professor, National Research Council of Canada, Atlantic Regional Laboratory, in Halifax, Nova Scotia (1975-1976) and as a Visiting Professor, G.C. Williams Co-operative Research Centre for Extraction Metallurgy, in the Department of Chemical Engineering, University of Melbourne (1995). He also held a position during his sabbatical in Australia as a Visiting Scientist, Commonwealth Scientific and Industrial Research Organisation (CSIRO), in Clayton, Victoria. Dr. Gaskell authored the textbooks Introduction to Metallurgical Thermodynamics, Introduction to the Thermodynamics of Materials, and Introduction to Transport Phenomena in Materials Engineering.

David E. Laughlin is the ALCOA Professor of Physical Metallurgy in the Department of Materials Science and Engineering of CMU and also has a courtesy appointment on the Electrical and Computer Engineering Department. He was the Principal Editor of Metallurgical and Materials Transactions from 1987 to 2016. David is a graduate of Drexel University (1969) and the Massachusetts Institute of Technology (1973). He is a Fellow of TMS, an Honorary member of AIME, and a Fellow of ASM International. He is also the recipient of several CMU awards for teaching and research excellence and a Distinguished Scientist of the TMS Electronic, Magnetic & Photonic Materials Division. He has authored more than 400 technical publications in the field of phase transformations, physical metallurgy, and magnetic materials, and has edited or coedited seven books including the fifth edition of Physical Metallurgy, and has been awarded 12 patents.