1 Reinforcement Materials |
|
1 | (20) |
|
1.0 Reinforcement Materials — Rigid |
|
|
1 | (1) |
|
|
1 | (1) |
|
|
2 | (3) |
|
|
2 | (1) |
|
|
3 | (1) |
|
|
4 | (1) |
|
|
4 | (1) |
|
1.3 Glass Fiber Manufacturing |
|
|
5 | (2) |
|
|
7 | (1) |
|
1.5 Glass Types and Construction |
|
|
7 | (2) |
|
|
9 | (2) |
|
|
9 | (1) |
|
|
9 | (1) |
|
|
10 | (1) |
|
|
10 | (1) |
|
|
11 | (1) |
|
1.7 Surfacing Mat, Paper, or Veil |
|
|
11 | (1) |
|
|
12 | (1) |
|
|
12 | (1) |
|
1.10 Properties of Glass Fabrics |
|
|
13 | (1) |
|
1.10.1 Moisture and Chemical Resistance |
|
|
13 | (1) |
|
1.10.2 Electrical Properties |
|
|
13 | (1) |
|
1.10.3 Heat and Fire Resistance |
|
|
14 | (1) |
|
1.10.4 Thermal Conductivity |
|
|
14 | (1) |
|
|
14 | (2) |
|
1.11.1 Nonwoven Aramid (Thermount®) |
|
|
14 | (2) |
|
1.12 Constraining Dielectric Materials (Kevlar) |
|
|
16 | (3) |
|
|
19 | (2) |
2 Resins |
|
21 | (18) |
|
|
21 | (1) |
|
|
22 | (1) |
|
|
23 | (8) |
|
|
24 | (1) |
|
2.2.2 Multifunctional Epoxy |
|
|
25 | (2) |
|
2.2.2.1 General-Purpose Systems Having a Tg between 135 and 145°C |
|
|
26 | (1) |
|
2.2.2.2 Higher-Performance Multifunctional Epoxies with a Tg between 150 and 165°C |
|
|
26 | (1) |
|
2.2.2.3 High-Temperature Multifunctional Epoxy with a Tg between 170 and 185°C |
|
|
27 | (1) |
|
2.2.3 Tetrafunctional Epoxy |
|
|
27 | (1) |
|
|
27 | (3) |
|
|
30 | (1) |
|
|
31 | (2) |
|
2.3.1 Epoxy-Blended Polyimide |
|
|
32 | (1) |
|
2.4 Cyanate Ester and Cyanate Ester Blends (BT Resin) |
|
|
33 | (1) |
|
2.4.1 Cyanate Ester Resins |
|
|
33 | (1) |
|
2.5 Polyphenylene Oxide (PPO) Epoxy Blends |
|
|
34 | (1) |
|
|
35 | (1) |
|
2.6 Polytetrafluoroethylene Resin (PTFE) |
|
|
35 | (2) |
|
|
37 | (2) |
3 Flexible Films |
|
39 | (26) |
|
|
39 | (1) |
|
3.1 Types of Flexible Materials |
|
|
40 | (8) |
|
3.1.1 Polyethylene Terephthalate ([ PET] Polyester) |
|
|
40 | (2) |
|
|
42 | (1) |
|
3.1.2 Polyethylene Naphthalate (PEN) |
|
|
42 | (1) |
|
3.1.3 Fluorocarbons (FEP) |
|
|
42 | (2) |
|
|
44 | (2) |
|
|
45 | (1) |
|
3.1.4.2 Dimensional Stability |
|
|
45 | (1) |
|
|
46 | (2) |
|
|
48 | (7) |
|
3.2.1 Types and Use of Adhesive |
|
|
49 | (1) |
|
3.2.2 Coating Process (Adhesive) |
|
|
50 | (2) |
|
3.2.2.1 Major Adhesive Types |
|
|
50 | (2) |
|
3.2.3 Adhesiveless Systems |
|
|
52 | (2) |
|
|
53 | (1) |
|
3.2.3.2 Vapor Deposition on Film |
|
|
53 | (1) |
|
3.2.3.3 Direct Vapor/Sputter Metallization onto Polyimide Film |
|
|
53 | (1) |
|
|
54 | (1) |
|
3.2.4 Adhesiveless Properties |
|
|
54 | (3) |
|
3.2.4.1 Electrical Advantage |
|
|
54 | (1) |
|
3.2.4.2 Mechanical Advantage |
|
|
55 | (1) |
|
3.2.4.3 Thermal Advantage |
|
|
55 | (1) |
|
3.3 Cover Coat/Cover Layer |
|
|
55 | (2) |
|
|
57 | (1) |
|
|
57 | (2) |
|
3.5.1 Electrodeposited Copper |
|
|
58 | (1) |
|
3.5.2 Rolled Annealed Copper (RA) |
|
|
59 | (1) |
|
3.6 Copper-Clad Laminates |
|
|
59 | (4) |
|
|
63 | (2) |
4 Copper Foils |
|
65 | (12) |
|
|
65 | (1) |
|
4.1 Electrodeposited Copper Foil (also called ED foil) |
|
|
65 | (2) |
|
4.2 Rolled Copper Foils (also called RA foil) |
|
|
67 | (4) |
|
4.2.1 Fabricating Rolled Copper Foils |
|
|
67 | (2) |
|
|
69 | (2) |
|
|
69 | (1) |
|
|
69 | (2) |
|
|
71 | (4) |
|
|
71 | (2) |
|
4.3.1.1 Grade-1 or Standard Electrodeposited (STD-Type E) |
|
|
71 | (1) |
|
4.3.1.2 Grade-2 or High-Ductility Electrodeposited Foils (HDE-Type E) |
|
|
71 | (1) |
|
4.3.1.3 Grade-3 or High-Temperature Elongation Foil (HTE-Type E) |
|
|
72 | (1) |
|
4.3.1.4 Grade-4 Annealed Electrodeposited or "Super High Duct" (ANN-Type E) |
|
|
73 | (1) |
|
|
73 | (2) |
|
4.3.2.1 Grade-5 "As Rolled" Wrought Copper (AR-Type W) |
|
|
73 | (1) |
|
4.3.2.2 Grade-6 or Light Cold Rolled Wrought (LCR-Type W Special Temper) |
|
|
73 | (1) |
|
4.3.2.3 Grade-7 or Rolled Annealed Wrought (ANN-Type W) |
|
|
74 | (1) |
|
4.3.2.4 Grade-8 or "As Rolled" Wrought Low-Temperature Annealable (Type LTA) |
|
|
75 | (1) |
|
|
75 | (1) |
|
|
75 | (1) |
|
|
75 | (1) |
|
|
76 | (1) |
5 Laminates, Rigid |
|
77 | (36) |
|
|
77 | (1) |
|
|
77 | (3) |
|
5.1.1 Paper-Based Laminates |
|
|
77 | (1) |
|
|
78 | (2) |
|
|
78 | (1) |
|
|
79 | (1) |
|
|
79 | (1) |
|
|
79 | (1) |
|
|
80 | (1) |
|
5.1.3 Properties, Construction, and Specifications (Paper-Based Laminates) |
|
|
80 | (1) |
|
5.1.4 Processing Paper-Grade Laminates |
|
|
80 | (1) |
|
|
80 | (12) |
|
|
82 | (5) |
|
5.2.1.1 Surfacing Mats, Paper, or Veil |
|
|
86 | (1) |
|
5.2.1.2 Glass Fiber "Paper" |
|
|
86 | (1) |
|
5.2.1.3 Polyester Glass Mat |
|
|
86 | (1) |
|
5.2.2 Types of Composite Laminate |
|
|
87 | (1) |
|
|
87 | (1) |
|
|
87 | (1) |
|
|
87 | (1) |
|
|
88 | (1) |
|
5.2.2.5 Properties, Construction, and Specifications (Composite Laminates) |
|
|
88 | (1) |
|
|
88 | (4) |
|
5.2.4 Material Recommendation |
|
|
92 | (1) |
|
5.3 Rigid Laminates (Glass-Reinforced) |
|
|
92 | (3) |
|
5.3.1 Electrical Characteristics |
|
|
94 | (1) |
|
|
94 | (1) |
|
5.4 Laminates, Rigid Glass Reinforcement |
|
|
95 | (7) |
|
5.4.1 Epoxy Laminate (FR-4) |
|
|
95 | (3) |
|
5.4.1.1 Difunctional Epoxies |
|
|
96 | (2) |
|
|
98 | (2) |
|
5.4.3 Polyimide Laminates |
|
|
100 | (2) |
|
|
100 | (1) |
|
5.4.3.2 Polyimide Glass and Copper-Invar-Copper |
|
|
101 | (1) |
|
|
101 | (1) |
|
5.4.4 Polyphenylene Oxide (PPO®) |
|
|
102 | (1) |
|
|
102 | (4) |
|
|
102 | (2) |
|
5.5.1.1 Multifunctional Epoxy/Nonwoven Aramid Reinforcement |
|
|
104 | (1) |
|
5.5.2 Epoxy on Woven Kevlar° |
|
|
104 | (2) |
|
|
106 | (1) |
|
5.6.1 Manufacturing Prepreg |
|
|
106 | (1) |
|
|
107 | (3) |
|
|
107 | (1) |
|
5.7.2 Semiadditive Laminates |
|
|
107 | (6) |
|
5.7.2.1 Ultrathin Copper Foil Clad |
|
|
108 | (1) |
|
|
108 | (1) |
|
5.7.2.3 Unclad or Adhesive-Coated |
|
|
109 | (1) |
|
5.7.2.4 Catalytic or Seeded |
|
|
109 | (1) |
|
|
110 | (3) |
6 High-Speed/High-Frequency Laminates |
|
113 | (20) |
|
|
113 | (1) |
|
6.1 High-Speed/High-Frequency Laminates |
|
|
113 | (3) |
|
6.1.1 RF Analog Circuit Characteristics |
|
|
114 | (1) |
|
6.1.2 Digital Circuit Characteristics |
|
|
114 | (1) |
|
6.1.3 Two Major Classes of Reinforcements |
|
|
114 | (1) |
|
6.1.4 Goal of Each Application Area |
|
|
115 | (1) |
|
|
116 | (1) |
|
|
116 | (6) |
|
6.3.1 Polytetrafluoroethylene Laminates |
|
|
116 | (4) |
|
6.3.2 Ceramic-Filled Polytetrafluoroethylene |
|
|
120 | (1) |
|
6.3.3 New Fluoropolymer Composite Materials |
|
|
120 | (2) |
|
|
122 | (1) |
|
6.4 High-Frequency Laminate Designations |
|
|
122 | (7) |
|
6.4.1 GRN Type Laminates with Glass Microfibers |
|
|
122 | (2) |
|
6.4.1.1 GRN Type Laminates with Nonwoven Fiberglass |
|
|
123 | (1) |
|
6.4.2 GTN Type Laminates with E-Glass |
|
|
124 | (1) |
|
6.4.3 Type GXN Laminates with E-Glass |
|
|
124 | (1) |
|
6.4.4 GYN Type Laminates with E-Glass |
|
|
125 | (1) |
|
6.4.5 High-Dk (6.0 to 10.5) Laminates with E-Glass |
|
|
126 | (1) |
|
6.4.6 Temperature-Stable Dielectric Constant and Low-CTE Laminates with E-Glass |
|
|
127 | (1) |
|
6.4.7 Commercial-Grade Laminates |
|
|
128 | (1) |
|
6.5 Laminate Construction |
|
|
129 | (1) |
|
6.5.1 Cross-Plied and Non-Cross-Plied Construction (meet type GT) |
|
|
129 | (1) |
|
|
130 | (1) |
|
6.7 Dimensional Stability |
|
|
130 | (1) |
|
|
131 | (1) |
|
|
131 | (2) |
7 Metal Core and Constraining Core Materials |
|
133 | (10) |
|
|
133 | (1) |
|
7.1 Copper-Invar-Copper (CIC) |
|
|
134 | (1) |
|
7.2 Copper-Molybdenum-Copper (CMC) |
|
|
135 | (3) |
|
7.3 Silicon Carbide—Reinforced Aluminum (SiC/A1) |
|
|
138 | (2) |
|
7.4 Coefficient of Thermal Expansion Trade-Offs (CTE) |
|
|
140 | (1) |
|
|
141 | (2) |
Appendix Abbreviations, Definitions, and Terms |
|
143 | (10) |
Index |
|
153 | |