Preface |
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xiii | |
Conversion Factors |
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xvii | |
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xix | |
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1 Introduction to Energy Usage, Cost, and Efficiency |
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1 | (18) |
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1.1 Energy Utilization in the United States |
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1 | (1) |
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1 | (3) |
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4 | (6) |
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1.4 The Cost of Self-Generated versus Purchased Electricity |
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10 | (1) |
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1.5 The Cost of Fuel and Fuel Heating Value |
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11 | (1) |
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12 | (3) |
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15 | (1) |
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16 | (3) |
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16 | (1) |
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17 | (2) |
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2 Engineering Economics with VBA Procedures |
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19 | (23) |
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2.1 Introduction to Engineering Economics |
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19 | (1) |
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2.2 The Time Value of Money: Present Value (PV) and Future Value (FV) |
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19 | (3) |
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22 | (7) |
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2.4 Comparing Process Alternatives |
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29 | (4) |
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31 | (1) |
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2.4.2 Rate of Return (ROR) |
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31 | (1) |
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2.4.3 Equivalent Annual Cost/Annual Capital Recovery Factor (CRF) |
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32 | (1) |
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2.5 Plant Design Economics |
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33 | (1) |
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2.6 Formulating Economics-Based Energy Optimization Problems |
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34 | (2) |
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2.7 Economic Analysis with Uncertainty: Monte Carlo Simulation |
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36 | (2) |
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38 | (4) |
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39 | (1) |
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39 | (3) |
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3 Computer-Aided Solutions of Process Material Balances: The Sequential Modular Solution Approach |
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42 | (34) |
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3.1 Elementary Material Balance Modules |
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42 | (4) |
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43 | (1) |
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43 | (1) |
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44 | (1) |
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45 | (1) |
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3.2 Sequential Modular Approach: Material Balances with Recycle |
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46 | (3) |
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3.3 Understanding Tear Stream Iteration Methods |
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49 | (9) |
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3.3.1 Single-Variable Successive Substitution Method |
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49 | (1) |
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3.3.2 Multidimensional Successive Substitution Method |
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50 | (2) |
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3.3.3 Single-Variable Wegstein Method |
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52 | (1) |
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3.3.4 Multidimensional Wegstein Method |
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53 | (5) |
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3.4 Material Balance Problems with Alternative Specifications |
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58 | (3) |
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3.5 Single-Variable Optimization Problems |
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61 | (5) |
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3.5.1 Forming the Objective Function for Single-Variable Constrained Material Balance Problems |
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61 | (1) |
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3.5.2 Bounding Step or Bounding Phase: Swann's Equation |
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61 | (4) |
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3.5.3 Interval Refinement Phase: Interval Halving |
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65 | (1) |
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3.6 Material Balance Problems with Local Nonlinear Specifications |
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66 | (2) |
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68 | (8) |
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69 | (1) |
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70 | (6) |
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4 Computer-Aided Solutions of Process Material Balances: The Simultaneous Solution Approach |
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76 | (22) |
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4.1 Solution of Linear Equation Sets: The Simultaneous Approach |
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76 | (6) |
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4.1.1 The Gauss-Jordan Matrix Elimination Method |
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76 | (2) |
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4.1.2 Gauss-Jordan Coding Strategy for Linear Equation Sets |
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78 | (1) |
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4.1.3 Linear Material Balance Problems: Natural Specifications |
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78 | (4) |
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4.1.4 Linear Material Balance Problems: Alternative Specifications |
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82 | (1) |
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4.2 Solution of Nonlinear Equation Sets: The Newton-Raphson Method |
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82 | (16) |
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4.2.1 Equation Linearization via Taylor's Series Expansion |
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82 | (1) |
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4.2.2 Nonlinear Equation Set Solution via the Newton-Raphson Method |
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83 | (3) |
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4.2.3 Newton-Raphson Coding Strategy for Nonlinear Equation Sets |
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86 | (4) |
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4.2.4 Nonlinear Material Balance Problems: The Simultaneous Approach |
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90 | (2) |
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92 | (1) |
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93 | (5) |
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5 Process Energy Balances |
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98 | (34) |
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98 | (3) |
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5.2 Separator: Equilibrium Flash |
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101 | (8) |
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5.2.1 Equilibrium Flash with Recycle: Sequential Modular Approach |
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103 | (6) |
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5.3 Equilibrium Flash with Recycle: Simultaneous Approach |
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109 | (3) |
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5.4 Adiabatic Plug Flow Reactor (PFR) Material and Energy Balances Including Rate Expressions: Euler's First-Order Method |
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112 | (5) |
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112 | (5) |
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5.5 Styrene Process: Material and Energy Balances with Reaction Rate |
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117 | (4) |
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5.6 Euler's Method versus Fourth-Order Runge-Kutta Method for Numerical Integration |
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121 | (3) |
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5.6.1 The Euler Method: First-Order ODEs |
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121 | (1) |
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5.6.2 RK4 Method: First-Order ODEs |
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122 | (2) |
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124 | (8) |
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125 | (1) |
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125 | (7) |
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6 Introduction to Data Reconciliation and Gross Error Detection |
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132 | (32) |
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6.1 Standard Deviation and Probability Density Functions |
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133 | (3) |
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6.2 Data Reconciliation: Excel Solver |
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136 | (2) |
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6.2.1 Single-Unit Material Balance: Excel Solver |
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136 | (2) |
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6.2.2 Multiple-Unit Material Balance: Excel Solver |
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138 | (1) |
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6.3 Data Reconciliation: Redundancy and Variable Types |
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138 | (5) |
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6.4 Data Reconciliation: Linear and Nonlinear Material and Energy Balances |
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143 | (6) |
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6.5 Data Reconciliation: Lagrange Multipliers |
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149 | (5) |
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6.5.1 Data Reconciliation: Lagrange Multiplier Compact Matrix Notation |
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152 | (2) |
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6.6 Gross Error Detection and Identification |
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154 | (4) |
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6.6.1 Gross Error Detection: The Global Test (GT) Method |
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154 | (1) |
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6.6.2 Gross Error (Suspect Measurement) Identification: The Measurement Test (MT) Method: Linear Constraints |
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155 | (1) |
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6.6.3 Gross Error (Suspect Measurement) Identification: The Measurement Test Method: Nonlinear Constraints |
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156 | (2) |
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158 | (6) |
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158 | (1) |
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158 | (6) |
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7 Gas Turbine Cogeneration System Performance, Design, and Off-Design Calculations: Ideal Gas Fluid Properties |
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164 | (34) |
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7.1 Equilibrium State of a Simple Compressible Fluid: Development of the T ds Equations |
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165 | (2) |
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7.1.1 Application of the T ds Equations to an Ideal Gas |
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166 | (1) |
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7.1.2 Application of the T ds Equations to an Ideal Gas: Isentropic Process |
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166 | (1) |
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7.2 General Energy Balance Equation for an Open System |
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167 | (1) |
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7.3 Cogeneration Turbine System Performance Calculations: Ideal Gas Working Fluid |
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167 | (2) |
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7.3.1 Compressor Performance Calculations |
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167 | (1) |
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7.3.2 Turbine Performance Calculations |
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168 | (1) |
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7.4 Air Basic Gas Turbine Performance Calculations |
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169 | (3) |
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7.5 Energy Balance for the Combustion Chamber |
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172 | (1) |
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7.5.1 Energy Balance for the Combustion Chamber: Ideal Gas Working Fluid |
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172 | (1) |
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7.6 The HRSG: Design Performance Calculations |
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173 | (4) |
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7.6.1 HRSG Design Calculations: Exhaust Gas Ideal and Water-Side Real Properties |
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176 | (1) |
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7.7 Gas Turbine Cogeneration System Performance with Design HRSG |
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177 | (3) |
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7.7.1 HRSG Material and Energy Balance Calculations Using Excel Callable Sheet Functions |
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179 | (1) |
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7.8 HRSG Off-Design Calculations: Supplemental Firing |
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180 | (5) |
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7.8.1 HRSG Off-Design Performance: Overall Energy Balance Approach |
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180 | (1) |
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7.8.2 HRSG Off-Design Performance: Overall Heat Transfer Coefficient Approach |
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181 | (4) |
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7.9 Gas Turbine Design and Off-Design Performance |
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185 | (8) |
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7.9.1 Gas Turbines Types and Gas Turbine Design Conditions |
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185 | (1) |
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7.9.2 Gas Turbine Design and Off-Design Using Performance Curves |
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186 | (1) |
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7.9.3 Gas Turbine Internal Mass Flow Patterns |
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186 | (2) |
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7.9.4 Industrial Gas Turbine Off-Design (Part Load) Control Algorithm |
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188 | (1) |
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7.9.5 Aeroderivative Gas Turbine Off-Design (Part Load) Control Algorithm |
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189 | (1) |
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7.9.6 Off-Design Performance Algorithm for Gas Turbines |
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189 | (4) |
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193 | (5) |
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194 | (1) |
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194 | (4) |
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8 Development of a Physical Properties Program for Cogeneration Calculations |
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198 | (24) |
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8.1 Available Function Calls for Cogeneration Calculations |
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198 | (4) |
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8.2 Pure Species Thermodynamic Properties |
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202 | (5) |
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8.3 Derivation of Working Equations for Pure Species Thermodynamic Properties |
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207 | (2) |
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8.4 Ideal Mixture Thermodynamic Properties: General Development and Combustion Reaction Considerations |
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209 | (2) |
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209 | (1) |
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8.4.2 Changes in Enthalpy and Entropy |
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209 | (2) |
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8.5 Ideal Mixture Thermodynamic Properties: Apparent Difficulties |
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211 | (2) |
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213 | (2) |
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215 | (7) |
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216 | (1) |
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216 | (6) |
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9 Gas Turbine Cogeneration System Performance, Design, and Off-Design Calculations: Real Fluid Properties |
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222 | (21) |
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9.1 Cogeneration Gas Turbine System Performance Calculations: Real Physical Properties |
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223 | (7) |
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9.1.1 Air Compressor (AC) Performance Calculation |
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224 | (1) |
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9.1.2 Energy Balance for the Combustion Chamber (CC) |
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224 | (1) |
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9.1.3 C Functions for Combustion Temperature and Exhaust Gas Physical Properties |
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224 | (5) |
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9.1.4 Gas and Power Turbine (G&PT) Performance Calculations |
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229 | (1) |
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9.1.5 Air Preheater (APH) |
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230 | (1) |
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9.2 HRSG: Design Performance Calculations |
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230 | (2) |
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9.3 HRSG Off-Design Calculations: Supplemental Firing |
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232 | (3) |
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9.3.1 HRSG Off-Design Performance: Overall Energy Balance Approach |
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233 | (1) |
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9.3.2 HRSG Off-Design Performance: Overall Heat Transfer Coefficient Approach |
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234 | (1) |
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9.4 Gas Turbine Design and Off-Design Performance |
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235 | (2) |
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237 | (6) |
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238 | (1) |
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238 | (5) |
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10 Gas Turbine Cogeneration System Economic Design Optimization and Heat Recovery Steam Generator Numerical Analysis |
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243 | (29) |
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10.1 Cogeneration System: Economy of Scale |
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244 | (1) |
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10.2 Cogeneration System Configuration: Site Power-to-Heat Ratio |
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244 | (1) |
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10.3 Economic Optimization of a Cogeneration System: The CGAM Problem |
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245 | (4) |
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10.3.1 The Objective Function: Cogeneration System Capital and Operating Costs |
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246 | (2) |
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10.3.2 Optimization: Variable Selection and Solution Strategy |
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248 | (1) |
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10.3.3 Process Constraints |
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249 | (1) |
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10.4 Economic Design Optimization of the CGAM Problem: Ideal Gas |
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249 | (1) |
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10.4.1 Air Preheater (APH) Equations |
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249 | (1) |
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10.4.2 CGAM Problem Physical Properties |
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249 | (1) |
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10.5 The CGAM Cogeneration Design Problem: Real Physical Properties |
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250 | (3) |
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10.6 Comparing CogenD and General Electric's GateCycle™ |
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253 | (1) |
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10.7 Numerical Solution of HRSG Heat Transfer Problems |
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254 | (12) |
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10.7.1 Steady-State Heat Conduction in a One-Dimensional Wall |
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254 | (1) |
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10.7.2 Unsteady-State Heat Conduction in a One-Dimensional Wall |
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255 | (4) |
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10.7.3 Steady-State Heat Conduction in the HRSG |
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259 | (7) |
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266 | (6) |
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267 | (1) |
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267 | (5) |
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11 Data Reconciliation and Gross Error Detection in a Cogeneration System |
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272 | (12) |
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11.1 Cogeneration System Data Reconciliation |
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272 | (6) |
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11.2 Cogeneration System Gross Error Detection and Identification |
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278 | (3) |
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11.3 Visual Display of Results |
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281 | (1) |
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281 | (3) |
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282 | (1) |
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283 | (1) |
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12 Optimal Power Dispatch in a Cogeneration Facility |
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284 | (30) |
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12.1 Developing the Optimal Dispatch Model |
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284 | (2) |
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12.2 Overview of the Cogeneration System |
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286 | (1) |
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12.3 General Operating Strategy Considerations |
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287 | (1) |
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12.4 Equipment Energy Efficiency |
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287 | (11) |
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12.4.1 Stand-Alone Boiler (Boiler 4) Performance (Based on Fuel Higher Heating Value (HHV)) |
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288 | (1) |
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12.4.2 Electric Chiller Performance |
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289 | (1) |
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12.4.3 Steam-Driven Chiller Performance |
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290 | (1) |
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12.4.4 GE Air Cooler Chiller Performance |
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291 | (3) |
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12.4.5 GE Gas Turbine Performance (Based on Fuel HHV) |
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294 | (1) |
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12.4.6 GE Gas Turbine HRSG Boiler 8 Performance (Based on Fuel HHV) |
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295 | (1) |
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12.4.7 GE Gas Turbine HRSG Boiler 8 Performance Supplemental Firing (Based on Fuel HHV) |
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296 | (1) |
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12.4.8 Allison Gas Turbine Performance (Based on Fuel HHV) |
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296 | (1) |
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12.4.9 Allison Gas Turbine HRSG Boiler 7 Performance (Based on Fuel HHV) |
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297 | (1) |
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12.4.10 Allison Gas Turbine HRSG Boiler 7 Performance Supplemental Firing (Based on Fuel HHV) |
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297 | (1) |
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12.5 Predicting the Cost of Natural Gas and Purchased Electricity |
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298 | (4) |
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299 | (1) |
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12.5.2 Purchased Electricity Cost |
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299 | (3) |
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12.6 Development of a Multiperiod Dispatch Model for the Cogeneration Facility |
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302 | (7) |
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309 | (5) |
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310 | (1) |
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310 | (4) |
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13 Process Energy Integration |
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314 | (29) |
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13.1 Introduction to Process Energy Integration/Minimum Utilities |
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314 | (2) |
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13.2 Temperature Interval/Problem Table Analysis with 0° Approach Temperature |
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316 | (1) |
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13.3 The Grand Composite Curve (GCC) |
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317 | (1) |
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13.4 Temperature Interval/Problem Table Analysis with "Real" Approach Temperature |
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318 | (1) |
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13.5 Determining Hot and Cold Stream from the Process Flow Sheet |
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319 | (5) |
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13.6 Heat Exchanger Network Design with Maximum Energy Recovery (MER) |
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324 | (4) |
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13.6.1 Design above the Pinch |
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325 | (2) |
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13.6.2 Design below the Pinch |
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327 | (1) |
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13.7 Heat Exchanger Network Design with Stream Splitting |
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328 | (1) |
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13.8 Heat Exchanger Network Design with Minimum Number of Units (MNU) |
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329 | (2) |
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13.9 Software for Teaching the Basics of Heat Exchanger Network Design (Teaching Heat Exchanger Networks (THEN)) |
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331 | (1) |
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13.10 Heat Exchanger Network Design: Distillation Columns |
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331 | (5) |
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336 | (7) |
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336 | (1) |
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337 | (6) |
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14 Process and Site Utility Integration |
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343 | (25) |
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14.1 Gas Turbine-Based Cogeneration Utility System for a Processing Plant |
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343 | (10) |
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14.2 Steam Turbine-Based Utility System for a Processing Plant |
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353 | (3) |
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14.3 Site-Wide Utility System Considerations |
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356 | (6) |
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362 | (6) |
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363 | (1) |
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363 | (5) |
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15 Site Utility Emissions |
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368 | (29) |
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15.1 Emissions from Stoichiometric Considerations |
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369 | (1) |
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15.2 Emissions from Combustion Equilibrium Calculations |
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370 | (10) |
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15.2.1 Equilibrium Reactions |
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371 | (1) |
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15.2.2 Combustion Chamber Material Balances |
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371 | (1) |
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15.2.3 Equilibrium Relations for Gas-Phase Reactions/Gas-Phase Combustors |
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372 | (4) |
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15.2.4 Equilibrium Compositions from Equilibrium Constants |
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376 | (4) |
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15.3 Emission Prediction Using Elementary Kinetics Rate Expressions |
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380 | (2) |
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15.3.1 Combustion Chemical Kinetics |
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380 | (1) |
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15.3.2 Compact Matrix Notation for the Species Net Generation (or Production) Rate |
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381 | (1) |
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15.4 Models for Predicting Emissions from Gas Turbine Combustors |
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382 | (11) |
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15.4.1 Perfectly Stirred Reactor for Combustion Processes: The Material Balance Problem |
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382 | (3) |
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15.4.2 The Energy Balance for an Open System with Reaction (Combustion) |
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385 | (1) |
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15.4.3 Perfectly Stirred Reactor Energy Balance |
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385 | (1) |
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15.4.4 Solution of the Perfectly Stirred Reactor Material and Energy Balance Problem Using the Provided CVODE Code |
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386 | (2) |
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15.4.5 Plug Flow Reactor for Combustion Processes: The Material Balance Problem |
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388 | (1) |
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15.4.6 Plug Flow Reactor for Combustion Processes: The Energy Balance Problem |
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389 | (4) |
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393 | (4) |
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393 | (1) |
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393 | (1) |
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394 | (3) |
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16 Coal-Fired Conventional Utility Plants with CO2 Capture (Design and Off-Design Steam Turbine Performance) |
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397 | (22) |
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16.1 Power Plant Design Performance (Using Operational Data for Full-Load Operation) |
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398 | (8) |
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16.1.1 Turbine System: Design Case (See Example 16.1.xls) |
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401 | (1) |
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16.1.2 Extraction Flow Rates and Feedwater Heaters |
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402 | (1) |
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16.1.3 Auxiliary Turbine/High-Pressure Feedwater Pump |
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402 | (1) |
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16.1.4 Low-Pressure Feedwater Pump |
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403 | (1) |
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16.1.5 Turbine Exhaust End Loss |
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403 | (2) |
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16.1.6 Steam Turbine System Heat Rate and Performance Parameters |
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405 | (1) |
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16.2 Power Plant Off-Design Performance (Part Load with Throttling Control Operation) |
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406 | (3) |
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16.2.1 Initial Estimates for All Pressures and Efficiencies: Sub Off_Design_Initial_Estimates () |
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406 | (1) |
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16.2.2 Modify Pressures: Sub Pressure_Iteration () |
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406 | (2) |
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16.2.3 Modify Efficiencies: Sub Update Efficiencies () |
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408 | (1) |
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16.3 Levelized Economics for Utility Pricing |
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409 | (4) |
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16.4 CO2 Capture and Its Impact on a Conventional Utility Power Plant |
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413 | (1) |
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414 | (5) |
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417 | (1) |
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417 | (2) |
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17 Alternative Energy Systems |
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419 | (10) |
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17.1 Levelized Costs for Alternative Energy Systems |
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419 | (1) |
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17.2 Organic Rankine Cycle (ORC): Determination of Levelized Cost |
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420 | (5) |
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425 | (4) |
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17.3.1 A High-Temperature Gas-Cooled Nuclear Reactor (HTGR) |
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425 | (2) |
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427 | (1) |
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427 | (2) |
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Appendix. Bridging Excel and C Codes |
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429 | (29) |
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429 | (2) |
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A.2 Working with Functions |
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431 | (3) |
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434 | (8) |
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A.4 Working with Matrices |
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442 | (4) |
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A.4.1 Gauss-Jordan Matrix Elimination Method |
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442 | (1) |
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A.4.2 Coding the Gauss-Jordan Matrix Elimination Method |
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443 | (3) |
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446 | (12) |
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448 | (1) |
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448 | (1) |
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Microsoft C++ 2008 Express: Creating C Programs and DLLs |
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448 | (10) |
Index |
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458 | |