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Modern Mössbauer Spectroscopy: New Challenges Based on Cutting-Edge Techniques 2021 ed. [Kõva köide]

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  • Formaat: Hardback, 523 pages, kõrgus x laius: 235x155 mm, kaal: 1067 g, 253 Illustrations, color; 66 Illustrations, black and white; XV, 523 p. 319 illus., 253 illus. in color., 1 Hardback
  • Sari: Topics in Applied Physics 137
  • Ilmumisaeg: 20-Jan-2021
  • Kirjastus: Springer Verlag, Singapore
  • ISBN-10: 981159421X
  • ISBN-13: 9789811594212
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Modern Mössbauer Spectroscopy: New Challenges Based on Cutting-Edge Techniques 2021 ed.Suurem pilt
  • Formaat: Hardback, 523 pages, kõrgus x laius: 235x155 mm, kaal: 1067 g, 253 Illustrations, color; 66 Illustrations, black and white; XV, 523 p. 319 illus., 253 illus. in color., 1 Hardback
  • Sari: Topics in Applied Physics 137
  • Ilmumisaeg: 20-Jan-2021
  • Kirjastus: Springer Verlag, Singapore
  • ISBN-10: 981159421X
  • ISBN-13: 9789811594212
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9789811594212.html
Märksõnad:

This book presents an overview of the latest Mössbauer spectroscopy research. It sheds light on various cutting-edge research subjects: (i) nuclear resonance scattering experiments implemented at synchrotron radiation facilities, e.g., ESRF, DESY and Spring-8; (ii) multidisciplinary materials research related to chemistry, biology, geoscience, molecular magnetism of metal complexes, batteries, and magnetism; (iii) novel imaging techniques based on probing diffusion in solids using Mössbauer spectroscopy.

 

The first three chapters introduce recent research on modern Mössbauer spectroscopy, including nuclear resonant scattering experiments and development of related techniques at synchrotron accelerator facilities. Chapters 4 and 5 then demonstrate the applications of such pioneering techniques to chemistry, biology and geoscience. Chapters 6 and 7 describe the applications to new functional materials, i.e., metal complexes and Li- and Na-ion batteries, while the final two chapters are devoted to two important measuring techniques: Mössbauer spectroscopy under external magnetic fields, and microscopic Mössbauer techniques on diffusion in solids, which are expected to play an essential role in the investigation and characterization of magnetic structures and microstructures in materials.

 

The cutting-edge content provides readers with quick updates on the latest research topics in the field, while the tutorial-style descriptions allow readers unfamiliar with Mössbauer spectroscopy to learn and implement the techniques. As such, the book is especially useful for advanced undergraduate and early graduate students who have recently been assigned to a laboratory.

1 Historical Developments and Future Perspectives in Nuclear Resonance Scattering
1(56)
Rudolf Ruffer
Aleksandr I. Chumakov
1.1 Introduction
3(9)
1.1.1 Nuclear Resonance
3(3)
1.1.2 Synchrotron Radiation
6(6)
1.2 Historical Development
12(7)
1.2.1 Scientific Dreams
12(1)
1.2.2 Technical Challenges
13(2)
1.2.3 Political Facts
15(1)
1.2.4 First Results--The Needle in the Haystack
16(3)
1.3 Techniques in NRS
19(5)
1.3.1 Synchrotron Mossbauer Source
19(2)
1.3.2 Synchrotron Radiation Based Mossbauer Spectroscopy
21(1)
1.3.3 Nuclear Forward Scattering
21(1)
1.3.4 Synchrotron Radiation Based Perturbed Angular Correlation
22(1)
1.3.5 Time Interferometry and Rayleigh Scattering
22(1)
1.3.6 Inelastic Scattering
23(1)
1.3.7 Other Techniques
24(1)
1.4 Hyperfine Spectroscopy
24(4)
1.4.1 Absorption
25(1)
1.4.2 Dynamical Beats
25(1)
1.4.3 Quantum Beats
25(3)
1.5 Structural Dynamics
28(3)
1.5.1 Quasi-elastic Dynamics
28(1)
1.5.2 Phonon Density of States
29(2)
1.6 Experimental Details
31(6)
1.6.1 X-Ray Optics
32(3)
1.6.2 Detectors
35(1)
1.6.3 Sample Environment
36(1)
1.7 Applications
37(11)
1.7.1 Nano-Scale Science
37(8)
1.7.2 Micro-eV Atomic Dynamics
45(3)
1.8 NRS with X-Ray Free Electron Lasers
48(2)
1.9 Summary
50(7)
References
50(7)
2 Synchrotron-Radiation-Based Energy-Domain Mossbauer Spectroscopy, Nuclear Resonant Inelastic Scattering, and Quasielastic Scattering Using Mossbauer Gamma Rays
57(48)
Makoto Seto
Ryo Masuda
Makina Saito
2.1 Introduction
58(2)
2.2 Synchrotron Radiation-Based Mossbauer Spectroscopy
60(11)
2.2.1 Special Features
61(1)
2.2.2 Instrumentation
62(3)
2.2.3 Analysis of the Spectra
65(5)
2.2.4 Comparison with Other Methods Using SR
70(1)
2.3 Nuclear Resonant Inelastic Scattering
71(12)
2.3.1 Instrumentation and Analysis of the Basic Method of NRIS
71(7)
2.3.2 Examples of Frontier Science, Especially Biological Application
78(2)
2.3.3 Advanced NRIS Method
80(1)
2.3.4 Summary
81(2)
2.4 Quasielastic Scattering Using Mossbauer y-Rays
83(22)
2.4.1 Introduction
83(1)
2.4.2 Basic Concept of Quasielastic Scattering by Nonresonant Samples
84(2)
2.4.3 Time-Domain Measurement of Quasielastic Scattering of Mossbauer Gamma Rays Using Synchrotron Radiation
86(6)
2.4.4 Effect of Energy Width of Incident Synchrotron Radiation
92(4)
2.4.5 Time-Domain Interferometry Using Multiline Mossbauer Gamma Rays
96(2)
2.4.6 Results Obtained by Quasielastic Scattering Experiment Using Time-Domain Interferometry of Mossbauer Gamma Rays
98(1)
2.4.7 Summary and Perspective of Quasielastic Scattering of Mossbauer Gamma Rays
99(1)
References
99(6)
3 Quantum Optical Phenomena in Nuclear Resonant Scattering
105(68)
Ralf Rohlsberger
Jorg Evers
3.1 Introduction
106(5)
3.1.1 Light Sources for X-Ray Quantum Optics
106(1)
3.1.2 X-Ray Quantum Optics with Atomic Resonances
106(2)
3.1.3 Collective and Virtual Effects in Quantum Optics
108(1)
3.1.4 X-Ray Cavities as Enabling Tool for Nuclear Quantum Optics
109(1)
3.1.5 Outline of this Review
110(1)
3.2 Nuclear Resonances of Mossbauer Isotopes as Two-Level Systems
111(2)
3.3 The Nuclear Level Width in a Cooperative Atomic Environment
113(2)
3.4 The Nuclear Exciton, Radiative Eigenstates and Single-Photon Superradiance
115(7)
3.4.1 Radiative Normal Modes
115(3)
3.4.2 Forward Scattering
118(2)
3.4.3 Bragg Scattering
120(2)
3.5 Cooperative Emission and the Collective Lamb Shift in a Cavity
122(4)
3.6 Quantum Optics of Mossbauer Nuclei in X-Ray Cavities
126(5)
3.6.1 Quantum Optics of the Empty Cavity
128(1)
3.6.2 Quantum Optics of a Cavity Containing Resonant Nuclei
129(1)
3.6.3 Nuclear Dynamics in the Cavity
130(1)
3.7 Quantum Optical Effects in Cavities
131(13)
3.7.1 Interferometric Phase Detection via Fano Resonance Control
131(2)
3.7.2 Electromagnetically Induced Transparency
133(4)
3.7.3 Spontaneously Generated Coherences
137(3)
3.7.4 Tunable Subluminal Propagation of Resonant X-Rays
140(4)
3.8 Collective Strong Coupling of Nuclei in Coupled Cavities and Superlattices
144(14)
3.8.1 Strong Coupling of X-Rays and Nuclei in Photonic Lattices: Normal-Mode Splitting
145(6)
3.8.2 Rabi Oscillations via Strong Coupling of Two Nuclear Cavities
151(7)
3.9 Nuclear Quantum Optics with Advanced Sources of X-Rays
158(5)
3.9.1 Diffraction-Limited Storage Rings
159(1)
3.9.2 X-Ray Free-Electron Lasers: SASE-XFEL and XFELO
159(4)
3.10 Concluding Remarks
163(10)
References
164(9)
4 From Small Molecules to Complex Systems: A Survey of Chemical and Biological Applications of the Mossbauer Effect
173(48)
Volker Schunemann
4.1 Iron Centers in Chemical Complexes and Biomolecules: Structural Overview, Biological Relevance and Physical Properties
174(3)
4.2 Spectroscopic Techniques to Investigate Iron Centers in Chemistry and Biology Based on the Mossbauer Effect: Strategy and Requirements
177(11)
4.2.1 Sample Requirements for Conventional Mossbauer Spectroscopy and Synchrotron Based Techniques
178(2)
4.2.2 Spectral Analysis: Thin Absorber Approximation and Transmission Integral
180(1)
4.2.3 Mossbauer Spectroscopy of Iron in Molecules: The Spin Hamiltonian Concept
181(5)
4.2.4 Calculation of Mossbauer Parameters with Quantum Chemical Methods
186(2)
4.2.5 Calculation of Iron Ligand Modes in Chemical Complexes and Proteins
188(1)
4.3 Exploring Spin States in Iron (II) Containing Compounds
188(8)
4.3.1 Thermal Spin Crossover (SCO) and Mossbauer Spectroscopy
188(2)
4.3.2 Light Induced Excited Spin State Trapping (LIESST)
190(4)
4.3.3 Exploration of Iron Ligand Modes by Synchrotron Based Nuclear Inelastic Scattering (NIS)
194(2)
4.4 Electronic and Vibrational Properties of a Heme Protein: The NO Transporter Protein Nitrophorin
196(8)
4.4.1 Probing Small Ligand Binding to Nitrophorin with Mossbauer Spectroscopy
197(3)
4.4.2 Investigation of Vibrational Properties of Nitrophorins
200(2)
4.4.3 Calculation of Mossbauer Parameters of Nitrophorins Using DFT Based Methods to Proof Structural Models of Heme Centers
202(2)
4.5 Investigation of Iron-Sulfur Proteins
204(8)
4.5.1 Identification of Fe-S-Centers by Mossbauer Spectroscopy
205(4)
4.5.2 Exploration of the Unusual 4Fe-4S Center of the LytB Protein
209(2)
4.5.3 In Vivo Mossbauer Spectroscopy of Iron-Sulfur Proteins Inside E. Coli Cells
211(1)
4.6 Future Applications of the Mossbauer Effect in Chemistry and Biology
212(3)
4.7 Summary
215(6)
References
216(5)
5 Mossbauer Spectroscopy with High Spatial Resolution: Spotlight on Geoscience
221(46)
Catherine McCammon
5.1 Introduction
222(1)
5.2 Mossbauer Sources for High Spatial Resolution
223(7)
5.2.1 Conventional Radioactive Source
224(1)
5.2.2 High Specific Activity (Point) Radioactive Source
225(1)
5.2.3 Synchrotron Source
226(1)
5.2.4 Mossbauer Source Comparison
227(3)
5.3 Measurement Approach
230(5)
5.3.1 Energy and Time Domain Comparison: Spectral Deconvolution
231(2)
5.3.2 Energy and Time Domain Comparison: Counting Time
233(2)
5.4 Practical Considerations for Small Beam Size
235(8)
5.4.1 Spectrometer Geometry
235(2)
5.4.2 Sample Preparation
237(3)
5.4.3 Texture Effects
240(1)
5.4.4 Sample Thickness
240(3)
5.5 Analysis Software
243(2)
5.5.1 Spectral Deconvolution
243(1)
5.5.2 Mapping on a Microscopic Scale
244(1)
5.6 Applications of High Spatial Resolution Measurements
245(9)
5.6.1 In Situ High-Pressure Studies with a Radioactive Source
245(2)
5.6.2 In Situ High-Pressure Studies with a Synchrotron Source
247(2)
5.6.3 Ex Situ High-Pressure and/or High-Temperature Studies
249(2)
5.6.4 Inclusions in Diamond
251(1)
5.6.5 Rare and/or Unusual Natural Samples
252(1)
5.6.6 Heterogeneous Samples
253(1)
5.7 Conclusions and Outlook
254(13)
References
256(11)
6 Molecular Magnetism of Metal Complexes and Light-Induced Phase Transitions
267(52)
Norimichi Kojima
Atsushi Okazawa
6.1 Introduction
268(1)
6.2 Spin Crossover Phenomena
269(10)
6.2.1 Static and Dynamic Spin Crossover Phenomena
269(4)
6.2.2 Dynamic Spin Crossover Phenomena of A[ MnFeni(mto)3] (A = Counter Cation; M = Zn, Cd; mto = C203S)
273(3)
6.2.3 Spin Frustration Induced by Dynamic Spin Crossover Phenomena for A[ MnnFeIU(mto)3]
276(3)
6.3 Mixed-Valence System and Charger Transfer Phase Transition
279(20)
6.3.1 Classification of Mixed-Valence System
279(1)
6.3.2 Prussian Blue and Its Analogues Salts Showing Photo-Induced Magnetism
280(3)
6.3.3 Mixed-Valence System, A[ FenFeIU (dto)3] (A = Counter Cation; dto = C2O2S2), and the Charge Transfer Phase Transition
283(4)
6.3.4 Dynamics of Charge Transfer Phase Transition in A[ FenFem (dto)3] by Means of Muon Spectroscopy
287(5)
6.3.5 Size Effect of Intercalated Cation on the Charge Transfer Phase Transition and Ferromagnetism for A[ FenFeIU (dto)3]
292(4)
6.3.6 New Type of Photo-Induced Magnetism Induced by the Photo-Isomerization of Intercalated Cation
296(3)
6.4 Single-Molecule Magnets and Single-Chain Magnets
299(14)
6.4.1 Single-Molecule Magnets of Transition-Metal Clusters
299(6)
6.4.2 Linear Two-Coordinate Fe11 and Fe1 Complexes
305(3)
6.4.3 Single-Chain Magnets: Unique Chain Magnet with Easy-Plane Anisotropy
308(5)
6.5 Conclusion
313(6)
References
314(5)
7 Application of Mossbauer Spectroscopy to Li-Ion and Na-Ion Batteries
319(62)
Pierre-Emmanuel Lippens
7.1 Introduction
319(3)
7.2 Electrochemical Energy Storage
322(4)
7.2.1 Li-Ion Batteries
322(2)
7.2.2 Electrochemical Mechanisms
324(1)
7.2.3 Characterization of Electrochemical Reactions
325(1)
7.3 Basic Aspects of Mossbauer Spectroscopy
326(17)
7.3.1 The Mossbauer Effect
326(2)
7.3.2 Isomer Shift
328(3)
7.3.3 Quadrupole Splitting
331(3)
7.3.4 Magnetic Splitting
334(1)
7.3.5 Recoil-Free Fraction
335(2)
7.3.6 The Mossbauer Spectrum
337(3)
7.3.7 In Situ Experiments
340(3)
7.4 Insertion Reactions
343(5)
7.4.1 Solid-Solution Reactions
343(2)
7.4.2 Two-Phase Reactions
345(3)
7.5 Alloying Reactions
348(11)
7.5.1 Negative Electrode Materials for Li-Ion Batteries
348(1)
7.5.2 βSn as Negative Electrode Material for Li-Ion Batteries
349(2)
7.5.3 LixSn Reference Materials
351(4)
7.5.4 Si as Negative Electrode Material for Li-Ion Batteries
355(1)
7.5.5 βSn as Negative Electrode Material for Na-Ion Batteries
356(3)
7.6 Conversion Reactions
359(15)
7.6.1 FeSn2 as Negative Electrode Material for Li-Ion Batteries
359(4)
7.6.2 Other Tin Based Intermetallic Compounds
363(4)
7.6.3 Aging Phenomena
367(3)
7.6.4 Tin Oxides
370(4)
7.7 Conclusions
374(7)
References
375(6)
8 Mossbauer Spectroscopy in External Magnetic Fields
381(64)
Michael Reissner
8.1 Introduction
381(1)
8.2 Hyperfine Field
382(4)
8.3 Simple Magnetic Structures
386(6)
8.4 Experimental
392(3)
8.5 Applications
395(43)
8.5.1 Ga Substituted Co Ferrite
395(5)
8.5.2 RE6Fei3X compounds
400(13)
8.5.3 Spin Glasses
413(6)
8.5.4 Y(Fe,A1)2
419(19)
8.6 Conclusion
438(7)
References
440(5)
9 Mossbauer Spectroscopic Studies on Atomic Diffusion in Materials
445(66)
Yutaka Yoshida
9.1 Introduction
446(2)
9.2 Historical Development of Diffusion Studies
448(10)
9.2.1 Fick' Principles and Brownian Motion Theory
448(2)
9.2.2 Hyperfine Interactions of 57Fe Nuclei and Mossbauer Experimental Set-Up
450(4)
9.2.3 Principle of Mossbauer Study on Atomic Diffusion
454(4)
9.3 Search for Point Defects in Pure Iron by Thermal Scanning Method
458(9)
9.3.1 Thermal Scanning Study on C-doped Fe
458(4)
9.3.2 Thermal Scanning Studies of 57Co-doped-Fe Irradiated by Neutrons and Electrons at Low Temperature
462(5)
9.4 In-Situ Observations of Elementary Jump Processes in Iron and Silicon
467(18)
9.4.1 High-Temperature UHV-Furnace and Encapsulation Techniques
469(3)
9.4.2 In-Beam Technique Using Coulomb Excitation and Recoil-Implantation
472(5)
9.4.3 In-Beam Technique Using 56Fe (d, p) 57mFe Nuclear Reaction
477(5)
9.4.4 On-Line Implantation of 57Mn/57Fe into Si Using Projectile Fragment Separator
482(3)
9.5 Mossbauer Spectroscopic Camera
485(15)
9.5.1 Mapping Technique for Mossbauer Spectroscopic Microscope (MSM)
486(6)
9.5.2 MSM Mappings and Complemental Techniques Installed in Our Set-Up
492(5)
9.5.3 MSM Image Data Processing to Deduce the Concentration Distributions
497(2)
9.5.4 Imaging Technique Using sCMOS-Camera
499(1)
9.6 Diffusion and Segregation Studies by Mossbauer Spectroscopic Camera
500(10)
9.6.1 Fe Impurity Diffusion in Single-Crystalline Si Wafer [ 87]
500(4)
9.6.2 Fe Impurity Diffusion in Multi-crystalline Si Wafer [ 90]
504(4)
9.6.3 Carbon Diffusion in Fe Steel
508(2)
9.7 Summary
510(1)
References 511(6)
Index 517
Yutaka Yoshida is a professor of Materials and Bioscience at Shizuoka Institute of Science and Technology, Japan. He received his doctoral degree from Osaka University in 1983. After serving as Guest Scientist in the group led by Professor Gero Vogl at the Hahn-Meitner Institute, Berlin, and as Research Assistant at the Institute of Solid State Physics, Universität Wien, he was appointed to associate professor at Shizuoka Institute of Science and Technology in 1991, and promoted to his current position in 2004. Since 1993 he has held a position as Guest Scientist at the Japanese scientific research institute, RIKEN.



Guido Langouche is Emeritus Professor of Nuclear Solid-State Physics at the University of Leuven. He received his PhD and habilitation in Physics from K. U. Leuven in 1973 and 1986, respectively. After carrying out postdoctoral research at K. U. Leuven, the University of Groningen and Stanford University, he was appointed to assistant professor in 1986, associateprofessor in 1989, and full professor in 1991. He has held positions as Guest Professor at Osaka University, the University of Lyon, and the University of Kinshasa. He has served in various positions throughout his career, such as Vice-Rector of K. U. Leuven, Chairman of the Coimbra Group, Vice-president of the Accreditation Organization of the Netherlands and Flanders (NAVO), Secretary General of the International Network for Quality Assurance Agencies in Higher Education (INQAAHE). Furthermore, he is the Editor-in-Chief of the Hyperfine Interaction Journal.