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Novel Electrochemical Energy Storage Devices: Materials, Architectures, and Future Trends [Kõva köide]

(Napier University, UK), ,
  • Formaat: Hardback, 336 pages, kõrgus x laius x paksus: 244x170x21 mm, kaal: 794 g
  • Ilmumisaeg: 19-May-2021
  • Kirjastus: Blackwell Verlag GmbH
  • ISBN-10: 3527345795
  • ISBN-13: 9783527345793
  • Formaat: Hardback, 336 pages, kõrgus x laius x paksus: 244x170x21 mm, kaal: 794 g
  • Ilmumisaeg: 19-May-2021
  • Kirjastus: Blackwell Verlag GmbH
  • ISBN-10: 3527345795
  • ISBN-13: 9783527345793

Explore the latest developments in electrochemical energy storage device technology 

In Novel Electrochemical Energy Storage Devices, an accomplished team of authors delivers a thorough examination of the latest developments in the electrode and cell configurations of lithium-ion batteries and electrochemical capacitors. Several kinds of newly developed devices are introduced, with information about their theoretical bases, materials, fabrication technologies, design considerations, and implementation presented. 

You’ll learn about the current challenges facing the industry, future research trends likely to capture the imaginations of researchers and professionals working in industry and academia, and still-available opportunities in this fast-moving area. You’ll discover a wide range of new concepts, materials, and technologies that have been developed over the past few decades to advance the technologies of lithium-ion batteries, electrochemical capacitors, and intelligent devices. Finally, you’ll find solutions to basic research challenges and the technologies applicable to energy storage industries. 

Readers will also benefit from the inclusion of: 

  • A thorough introduction to energy conversion and storage, and the history and classification of electrochemical energy storage 
  • An exploration of materials and fabrication of electrochemical energy storage devices, including categories, EDLCSs, pseudocapacitors, and hybrid capacitors 
  • A practical discussion of the theory and characterizations of flexible cells, including their mechanical properties and the limits of conventional architectures 
  • A concise treatment of the materials and fabrication technologies involved in the manufacture of flexible cells 

Perfect for materials scientists, electrochemists, and solid-state chemists, Novel Electrochemical Energy Storage Devices will also earn a place in the libraries of applied physicists, and engineers in power technology and the electrotechnical industry seeking a one-stop reference for portable and smart electrochemical energy storage devices. 

 

Preface xiii
Abbreviations xv
1 Introduction
1(14)
1.1 Energy Conversion and Storage: A Global Challenge
1(2)
1.2 Development History of Electrochemical Energy Storage
3(1)
1.3 Classification of Electrochemical Energy Storage
4(2)
1.4 LIBs and ECs: An Appropriate Electrochemical Energy Storage
6(4)
1.5 Summary and Outlook
10(5)
References
10(5)
2 Materials and Fabrication
15(52)
2.1 Mechanisms and Advantages of LIBs
15(3)
2.1.1 Principles
15(1)
2.1.2 Advantages and Disadvantages
16(2)
2.2 Mechanisms and Advantages of ECs
18(4)
2.2.1 Categories
18(1)
2.2.2 EDLCs
18(2)
2.2.3 Pseudocapacitor
20(1)
2.2.4 Hybrid Capacitors
21(1)
2.3 Roadmap of Conventional Materials for LIBs
22(1)
2.4 Typical Positive Materials for LIBs
23(6)
2.4.1 LiCoC-2 Materials
23(2)
2.4.2 LiNiO2 and Its Derivatives
25(1)
2.4.3 LiMn2O4 Material
26(1)
2.4.4 LiFePO4 Material
27(1)
2.4.5 Lithium-Manganese-rich Materials
28(1)
2.4.6 Commercial Status of Main Positive Materials
28(1)
2.5 Typical Negative Materials for LIBs
29(4)
2.5.1 Graphite
29(2)
2.5.2 Soft and Hard Carbon
31(2)
2.6 New Materials for LIBs
33(6)
2.6.1 Nanocarbon Materials
33(2)
2.6.2 Alloy-Based Materials
35(4)
2.6.3 Metal Lithium Negative
39(1)
2.7 Materials for Conventional ECs
39(3)
2.7.1 Porous Carbon Materials
40(1)
2.7.2 Transition Metal Oxides
41(1)
2.7.3 Conducting Polymers
42(1)
2.8 Electrolytes and Separators
42(4)
2.8.1 Electrolytes
42(3)
2.8.2 Separators
45(1)
2.9 Evaluation Methods
46(4)
2.9.1 Evaluation Criteria for LIBs
46(1)
2.9.2 Theoretical Gravimetric and Volumetric Energy Density
46(1)
2.9.3 Practical Energy and Power Density of LIBs
47(1)
2.9.4 Cycle Life
48(1)
2.9.5 Safety
48(1)
2.9.6 Evaluation Methods for ECs
49(1)
2.10 Production Processes for the Fabrication
50(1)
2.10.1 Design
50(1)
2.10.2 Mixing, Coating, Calendering, and Winding
51(1)
2.10.3 Electrolyte Injecting and Formation
51(1)
2.11 Perspectives
51(16)
References
53(14)
3 Flexible Cells: Theory and Characterizations
67(28)
3.1 Limitations of the Conventional Cells
67(2)
3.1.1 Mechanical Properties of Conventional Materials
67(1)
3.1.2 Limitations of Conventional Architectures
68(1)
3.1.3 Limitations of Electrolytes
69(1)
3.2 Mechanical Process for Bendable Cells
69(3)
3.2.1 Effect of Thickness
70(1)
3.2.2 Effect of Flexible Substrates and Neutral Plane
71(1)
3.3 Mechanics of Stretchable Cells
72(4)
3.3.1 Wavy Architectures by Small Deformation Buckling Process
72(2)
3.3.2 Wavy Architectures by Large Deformation Buckling Process
74(1)
3.3.3 Island Bridge Architectures
75(1)
3.4 Static Electrochemical Performance of Flexible Cells
76(1)
3.5 Dynamic Performance of Flexible Cells
77(13)
3.5.1 Bending Characterization
78(1)
3.5.2 Stretching Characterization
78(1)
3.5.3 Conformability Test
79(1)
3.5.4 Stress Simulation by Finite Element Analysis
79(4)
3.5.5 Dynamic Electrochemical Performance During Bending
83(2)
3.5.6 Dynamic Electrochemical Performance During Stretching
85(5)
3.6 Summary and Perspectives
90(5)
References
90(5)
4 Flexible Cells: Materials and Fabrication Technologies
95(52)
4.1 Construction Principles of Flexible Cells
95(1)
4.2 Substrate Materials for Flexible Cells
95(3)
4.2.1 Polymer Substrates
96(1)
4.2.2 Paper Substrate
97(1)
4.2.3 Textile Substrate
98(1)
4.3 Active Materials for Flexible Cells
98(3)
4.3.1 CNTs
98(1)
4.3.2 Graphene
99(1)
4.3.3 Low-Dimensional Materials
99(2)
4.4 Electrolytes for Flexible LIBs
101(3)
4.4.1 Inorganic Solid-state Electrolytes for Flexible LIBs
102(2)
4.4.2 Solid-state Polymer Electrolytes for Flexible LIBs
104(1)
4.5 Electrolytes for Flexible ECs
104(3)
4.6 Nonconductive Substrates-Based Flexible Cells
107(14)
4.6.1 Paper-Based Flexible Cells
108(4)
4.6.2 Textiles-Based Flexible Cells
112(5)
4.6.3 Polymer Substrates-Based Flexible Cells
117(4)
4.7 CNT and Graphene-Based Flexible Cells
121(6)
4.7.1 Free-standing Graphene and CNTs Films for SCs
121(1)
4.7.2 Free-standing Graphene and CNT Films for LIBs
122(3)
4.7.3 Flexible CNTs/Graphene Composite Films for the Cells
125(2)
4.8 Construction of Stretchable Cells by Novel Architectures
127(3)
4.8.1 Stretchable Cells Based on Wavy Architecture
127(2)
4.8.2 Stretchable Cells Based on Island-Bridge Architecture
129(1)
4.9 Conclusion and Perspectives
130(17)
4.9.1 Mechanical Performance Improvement
131(1)
4.9.2 Innovative Architecture for Stretchable Cells
132(1)
4.9.3 Electrolytes Development
132(1)
4.9.4 Packaging and Tabs
132(1)
4.9.5 Integrated Flexible Devices
133(1)
References
133(14)
5 Architectures Design for Cells with High Energy Density
147(58)
5.1 Strategies for High Energy Density Cells
147(2)
5.2 Gravimetric and Volumetric Energy Density of Electrodes
149(2)
5.3 Classification of Thick Electrodes: Bulk and Foam Electrodes
151(2)
5.4 Design and Fabrication of Bulk Electrodes
153(4)
5.4.1 Advantages of Bulk Electrodes
153(2)
5.4.2 Low Tortuosity: The Key for Bulk Electrodes
155(2)
5.5 Characterization and Numerical Simulation of Tortuosity
157(2)
5.5.1 Characterization of Tortuosity by X-ray Tomography
157(1)
5.5.2 Numerical Simulation of Tortuosity on Rates by Commercial Software
158(1)
5.6 Fabrication Methods for Bulk Electrodes
159(1)
5.7 Thick Electrodes with Random Pore Structure
160(5)
5.7.1 Pressure-less High-temperature Sintering Process
160(1)
5.7.2 Cold Sintering Process
161(1)
5.7.3 Spark Plasma Sintering Technology
162(3)
5.7.4 Brief Summary for Sintering Technologies
165(1)
5.8 Thick Electrodes with Directional Pore Distribution
165(13)
5.8.1 Iterative Extrusion Method
165(3)
5.8.2 Magnetic-Induced Alignment Method
168(1)
5.8.3 Carbonized Wood Template Method
168(4)
5.8.4 Ice Templates Method
172(1)
5.8.5 3D-Printing for Thick Electrodes
173(2)
5.8.6 Brief Summary for Bulk Electrodes
175(3)
5.9 Carbon-Based Foam Electrodes with High Gravimetric Energy Density
178(4)
5.9.1 Graphene Foam
179(2)
5.9.2 CNTs Foam
181(1)
5.9.3 CNT/Graphene Foam
181(1)
5.10 Carbon-Based Thick Electrodes
182(9)
5.10.1 Low Electronic Conductive Material/Carbon Foam
182(4)
5.10.2 Large Volume Variation Materials/Carbon Foam
186(2)
5.10.3 Compact Graphene Electrodes
188(1)
5.10.4 Summary for Carbon Foam Electrodes
189(2)
5.11 Thick Electrodes Based on the Conductive Polymer Gels
191(2)
5.12 Summary and Perspectives
193(12)
References
195(10)
6 Miniaturized Cells
205(58)
6.1 Introduction
205(4)
6.1.1 Definition of the Miniaturized Cells and Their Applications
205(1)
6.1.2 Classification of Miniaturized Cells
206(1)
6.1.3 Development Trends of the Miniaturized Cells
207(2)
6.2 Evaluation Methods for the Miniaturized Cells
209(3)
6.2.1 Evaluation Methods for Electric Double-layer m-ECs
210(1)
6.2.2 Evaluation methods for m-LIBs and m-ECs
211(1)
6.3 Architectures of Various Miniaturized Cells
212(1)
6.4 Materials for the Miniaturized Cells
213(2)
6.4.1 Electrode Materials
213(1)
6.4.2 Electrolytes for the Miniaturized Cells
214(1)
6.5 Fabrication Technologies for Miniaturized Cells
215(5)
6.5.1 Fabrication of Miniaturized Cells with 2D Parallel Plate Configuration
216(4)
6.6 Fabrication Technologies for 2D Interdigitated Cells
220(2)
6.7 Printing Technologies for 2D Interdigitated Cells
222(6)
6.7.1 Advantages of Printing Technologies
222(1)
6.7.2 Classification of Printing Techniques
222(2)
6.7.3 Screen Printing for Miniaturized Cells
224(4)
6.7.4 Inkjet Printing
228(1)
6.8 Electrochemical Deposition Method for 2D Interdigitated Cells
228(3)
6.9 Laser Scribing for 2D Interdigitated Cells
231(3)
6.10 In Situ Electrode Conversion for 2D Interdigitated Cells
234(2)
6.11 Fabrication Technologies for 3D In-plane Miniaturized Cells
236(4)
6.11.1 3D Printing for 3D Interdigitated Configuration Cells
236(3)
6.11.2 3D Interdigitated Configuration by Electrodeposition
239(1)
6.12 Fabrication of Miniaturized Cells with 3D Stacked Configuration
240(7)
6.12.1 3D Stacked Configuration by Template Deposition
241(4)
6.12.2 3D Stacked Configuration by Microchannel-Plated Deposition Methods
245(2)
6.13 Integrated Systems
247(2)
6.14 Summary and Perspectives
249(14)
References
250(13)
7 Smart Cells
263(38)
7.1 Definition of Smart Materials and Cells
263(1)
7.1.1 Definition of Smart Cells
263(1)
7.1.2 Definition of Smart Materials
263(1)
7.2 Type of Smart Materials
264(4)
7.2.1 Self-healing Materials
264(1)
7.2.2 Shape-memory Alloys
265(1)
7.2.3 Thermal-responding PTC Thermistors
266(1)
7.2.4 Electrochromic Materials
267(1)
7.3 Construction of Smart Cells
268(12)
7.3.1 Self-healing Silicon Anodes
268(3)
7.3.2 Aqueous Self-healing Electrodes
271(2)
7.3.3 Liquid-alloy Self-healing Electrode Materials
273(1)
7.3.4 Thermal-responding Layer
274(2)
7.3.5 Thermal-responding Electrodes Based on the PTC Effect
276(2)
7.3.6 Ionic Blocking Effect-Based Thermal-responding Electrodes
278(2)
7.4 Application of Shape-memory Materials in LIBs and ECs
280(2)
7.4.1 Self-adapting Cells
280(1)
7.4.2 Shape-memory Alloy-Based Thermal Regulator
281(1)
7.5 Self-heating and Self-monitoring Designs
282(4)
7.5.1 Self-heating
283(2)
7.5.2 Self-monitoring
285(1)
7.6 Integrated Electrochromic Architectures for Energy Storage
286(5)
7.6.1 Integration Possibilities
286(1)
7.6.2 Integrated Electrochromic ECs
287(2)
7.6.3 Integrated Electrochromic LIBs
289(2)
1.1 Summary and Perspectives
291(10)
References
292(9)
Index 301
Feng Li, PhD, is Professor in the Institute of Metal Research at the Chinese Academy of Sciences, China. He has published over 200 peer-reviewed articles. His research focuses on novel carbon-based materials for energy applications.

Lei Wen, PhD, is Associate Professor in the Institute of Metal Research at the Chinese Academy of Sciences, China. He earned his doctorate from Northeastern University in China. His research focuses on electrochemical energy storage devices.

Hui-ming Cheng, PhD, is Professor in the Institute of Metal Research at Chinese Academy of Sciences, China. His research focuses on low-dimensional materials for energy applications.