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Organic Thermoelectric Materials [Kõva köide]

Edited by (Georgia Institute of Technology, USA), Edited by (Peking University, China)
  • Formaat: Hardback, 328 pages, kõrgus x laius: 234x156 mm, kaal: 667 g, No
  • Sari: Energy and Environment Series Volume 24
  • Ilmumisaeg: 31-Oct-2019
  • Kirjastus: Royal Society of Chemistry
  • ISBN-10: 1788014707
  • ISBN-13: 9781788014700
Teised raamatud teemal:
Organic Thermoelectric MaterialsSuurem pilt
  • Formaat: Hardback, 328 pages, kõrgus x laius: 234x156 mm, kaal: 667 g, No
  • Sari: Energy and Environment Series Volume 24
  • Ilmumisaeg: 31-Oct-2019
  • Kirjastus: Royal Society of Chemistry
  • ISBN-10: 1788014707
  • ISBN-13: 9781788014700
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9781788014700.html
Märksõnad:
Organic thermoelectric materials have gained attention in energy-harvesting and cooling applications due to their intrinsic low cost, energy efficient, and eco-friendly nature. This book summarises the significant progress in the molecular designs, physical characterizations, and performance optimizations of organic thermoelectric materials, focusing especially on the effective routes to minimize the thermal conductivity and maximize the power factor. This informative guide will appeal to graduate students as well as academic and industrial researchers across chemistry, materials science, physics and engineering interested in the materials and their applications.

Organic thermoelectric materials have gained attention in energy-harvesting and cooling applications due to their intrinsic low cost, energy efficient, and eco-friendly nature. This book summarises the significant progress in the molecular designs, physical characterizations, and performance optimizations of organic thermoelectric materials, focusing especially on the effective routes to minimize the thermal conductivity and maximize the power factor. This informative guide will appeal to graduate students as well as academic and industrial researchers across chemistry, materials science, physics and engineering interested in the materials and their applications. Thermoelectric materials have received a great deal of attention in energy-harvesting and cooling applications, primarily due to their intrinsic low cost, energy efficient and eco-friendly nature. The past decade has witnessed heretofore-unseen advances in organic-based thermoelectric materials and devices. This title summarises the significant progress that has been made in the molecular design, physical characterization, and performance optimization of organic thermoelectric materials, focusing on effective routes to minimize thermal conductivity and maximize power factor. Featuring a series of state-of-the-art strategies for enhancing the thermoelectric figure of merit (ZT) of organic thermoelectricity, and highlighting cutting-edge concepts to promote the performance of organic thermoelectricity, chapters will strengthen the exploration of new high-ZT thermoelectric materials and their potential applications. With contributions from leading worldwide authors, Organic Thermoelectric Materials will appeal to graduate students as well as academic and industrial researchers across chemistry, materials science, physics and engineering interested in the materials and their applications.

This book summarises the significant progress made in organic thermoelectric materials, focusing on effective routes to minimize thermal conductivity and maximize power factor.
Chapter 1 Introduction 1(20)
Jaeyoo Choi
Madeleine R.
Gordon
Pengyu Yuan
Hyungmook Kang
Edmond W. Zaia
Jeffrey J. Urban
1.1 Motivation
2(2)
1.2 History of TE Materials: Past to Present and Future
4(3)
1.3 Thermoelectrics: Basic Principles
7(1)
1.4 Charge-carrier Transport
8(2)
1.5 Electrical Conductivity and Seebeck Optimization
10(1)
1.6 Thermal Transport
11(1)
1.7 Module Performance and Design
12(2)
1.8 Measurement Techniques for Organic TE Materials
14(2)
1.9 Perspective
16(1)
References
17(4)
Chapter 2 Thermoelectric Transport Theory in Organic Semiconductors 21(44)
Ling Li
Nianduan Lu
Ming Liu
2.1 Introduction
21(3)
2.1.1 Organic Semiconductors
21(1)
2.1.2 Transport Mechanism of Organic Semiconductors
22(1)
2.1.3 Thermoelectric Effect
23(1)
2.2 Basic Thermoelectric Transport Equations
24(3)
2.2.1 Boltzmann Transport Equation
24(1)
2.2.2 Mott's Type Expression
25(1)
2.2.3 General Expression of the Seebeck Effect
26(1)
2.3 Thermoelectric Transport Theory
27(28)
2.3.1 First-principles Theory
27(8)
2.3.2 Hopping Transport Theory
35(13)
2.3.3 Percolation Theory
48(4)
2.3.4 Hybrid Theory
52(3)
2.4 Monte Carlo Simulation
55(5)
2.5 Conclusion and Outlook
60(1)
Acknowledgements
60(1)
References
61(4)
Chapter 3 Synthesis of Organic Thermoelectric Materials 65(52)
Hui Xu
Chunyan Zhao
Mingming Zhai
3.1 Introduction
65(2)
3.2 Synthesis of Organic Conducting Polymers
67(19)
3.2.1 Synthesis of Polyacetylene (PA)
69(2)
3.2.2 Synthesis of Poly(p-phenylene) (PPP)
71(1)
3.2.3 Synthesis of Polypyrrole (PPy)
72(1)
3.2.4 Synthesis of Polycarbazole (PCz)
73(2)
3.2.5 Synthesis of Polyaniline (PANT)
75(2)
3.2.6 Synthesis of Polythiophene (PTh)
77(2)
3.2.7 Synthesis of Poly(3-alkylthiophenes) (P3AT)
79(2)
3.2.8 Synthesis of PEDOT
81(1)
3.2.9 Synthesis of Polyphenylenevinylene (PPV)
82(4)
3.3 Organic Thermoelectric Materials Based on Complex Polymers
86(3)
3.4 Organic Semiconductors Based on Small Molecules
89(5)
3.5 Summary
94(2)
References
96(21)
Chapter 4 PEDOT-based Thermoelectrics 117(16)
Zeng Fan
Jianyong Ouyang
4.1 Introduction
117(2)
4.2 TE Properties of PEDOT-based Materials
119(7)
4.2.1 Charge Delocalization
119(4)
4.2.2 Doping Level
123(1)
4.2.3 Molecular Weight and Nanostructure
124(1)
4.2.4 Surface Energy Filtering
124(2)
4.3 PEDOT-based Composites
126(1)
4.4 PEDOT-based TE Devices
127(2)
4.5 Summary
129(1)
Acknowledgements
129(1)
References
129(4)
Chapter 5 Carbon Based Thermoelectric Materials 133(37)
Tram Malik
Kamal K. Kar
5.1 Introduction
133(2)
5.2 Carbon Nanomaterial
135(3)
5.2.1 Fullerenes
136(1)
5.2.2 Graphene
136(1)
5.2.3 Carbon Nanotubes
137(1)
5.3 Improvement of TE Properties via Carbon Nanomaterials
138(17)
5.3.1 Improved TE Properties by Defect Structure Modification
139(5)
5.3.2 Improved TE Properties by Graphene Composites
144(5)
5.3.3 Improved TE Properties by CNT Composites
149(6)
5.4 Other Carbon Nanomaterials as TE Materials
155(1)
5.5 Carbon Nanomaterial Based Polymer Thermoelectric Materials
156(9)
5.6 Conclusion and Outlook
165(1)
Acknowledgements
165(1)
References
165(5)
Chapter 6 Organic Hierarchical Thermoelectric Materials 170(43)
Zimeng Zhang
Yuchen Liu
Shiren Wang
6.1 Introduction
170(3)
6.2 OD C60/2D Graphene Hierarchical Nanostructure-based Thermoelectrics
173(21)
6.2.1 OD C60/2D Graphene/Epoxy Polymer Hybrids
173(6)
6.2.2 OD C60/2D rGO/PEDOT:PSS-based Thermoelectrics
179(6)
6.2.3 OD F-C60/2D Graphene Based Hierarchical Nanostructures
185(9)
6.3 OD C60/2D TiS2 Hybrid-based Thermoelectrics
194(11)
6.3.1 Assembly of OD C60/2D TiS2 Hierarchical Nanostructure
195(2)
6.3.2 Electrical Conductivity and Seebeck Coefficient Characterizations
197(3)
6.3.3 Thermal Conductivity Characterization
200(2)
6.3.4 Temperature-dependent Thermoelectric Properties
202(1)
6.3.5 Thermoelectric Device Fabrication and Performance Characterization
202(3)
6.4 Conclusion
205(1)
References
206(7)
Chapter 7 Conducting Polymer-based Organic-Inorganic Thermoelectric Nanocomposites 213(33)
Q. Yao
W. Shi
S.Y. Qu
L.D. Chen
7.1 Introduction
213(1)
7.2 The Regulation of TE Properties of Conducting Polymers and Their Nanocomposites
214(18)
7.2.1 Overview of Thermoelectric Properties of Conducting Polymers
214(4)
7.2.2 Doping Level Adjustment
218(2)
7.2.3 Ordering of Polymer Molecular Chains
220(4)
7.2.4 Organic/Inorganic Interfacial Effect
224(4)
7.2.5 Charge Transfer by the Junctions
228(1)
7.2.6 Nano-intercalated Superlattice Structure
228(4)
7.3 Preparation of Conducting Polymer-based Nanocomposites for Thermoelectric Applications
232(7)
7.3.1 Powder Mixing Method
232(1)
7.3.2 Solution Medium Mixing Method
233(2)
7.3.3 In Situ Polymerization
235(2)
7.3.4 Layer-by-layer Self-assembly
237(1)
7.3.5 Polymerization Using Multifunctional Oxidants
238(1)
7.4 Conclusion
239(1)
References
240(6)
Chapter 8 Thermoelectric Materials by Organic Intercalation 246(28)
Ruoming Tian
Chunlei Wan
Kunihito Koumoto
8.1 Introduction
246(2)
8.2 Two-dimensional Transition Metal Dichalcogenides
248(2)
8.3 Organic Intercalation in Transition Metal Dichalcogenides
250(2)
8.4 TiS2-Organics Hybrid Superlattice Materials
252(12)
8.4.1 Material Synthesis
252(2)
8.4.2 Functional Roles of Inorganic and Organic Layers
254(1)
8.4.3 Suppression of Thermal Conductivity
254(2)
8.4.4 Tuning of Carrier Mobility
256(5)
8.4.5 Optimisation of Carrier Concentration
261(3)
8.5 Scale-up Fabrication for Flexible Thermoelectric Devices
264(6)
8.5.1 Solution-processable Fabrication Method
265(2)
8.5.2 Thermoelectric and Mechanical Properties of Superlattice Films
267(2)
8.5.3 Thermoelectric Performance of Prototype Flexible Thermoelectric Device
269(1)
8.6 Perspective Remarks
270(2)
References
272(2)
Chapter 9 Flexible Organic-based Thermoelectric Devices 274(35)
Kun Zhang
Yuanyuan Zheng
Xinyi Chen
Xue Han
Minzhi Du
Xinzhi Hu
Liming Wang
Jilong Wang
Chunhong Lu
9.1 Introduction
274(1)
9.2 Thin Film-based TEGs
275(7)
9.2.1 Materials Used as Thermoelectric Legs
275(1)
9.2.2 Methods of Manufacturing Thermoelectric Legs
276(3)
9.2.3 Typical Examples of Thin Film-based TEGs
279(3)
9.3 Textile Based TEGs
282(6)
9.3.1 Methods of Manufacturing Textile Based Thermoelectric Units
282(4)
9.3.2 Methods of Manufacturing Textile-based TEGs
286(2)
9.3.3 Potential Applications of Textile-based TEGs
288(1)
9.4 Hybrid Generators
288(2)
9.5 Applications of Organic Flexible Thermoelectric Devices
290(9)
9.5.1 Organic Thermoelectric Based Thermal Sensors
290(3)
9.5.2 Organic Thermoelectric Based Pressure Sensors
293(2)
9.5.3 Organic Thermoelectric Based Strain Sensors
295(2)
9.5.4 Organic Thermoelectric Based Peltier Coolers
297(2)
9.6 Summary and Outlook
299(1)
Acknowledgements
300(1)
References
300(9)
Subject Index 309
Dr. Zhiqun Lin is currently Professor of Materials Science and Engineering at the Georgia Institute of Technology. He received his PhD degree in Polymer Science and Engineering from University of Massachusetts, Amherst in 2002. He did his postdoctoral research at University of Illinois at Urbana-Champaign. His research interests include polymer-based nanocomposites, block copolymers, conjugated polymers, quantum dots (rods, tetrapods and wires), functional nanocrystals (metallic, magnetic, semiconducting, upconversion and thermoelectric) of different architectures, solar cells (perovskite solar cells and dye sensitized solar cells), batteries, hydrogen generation, thermoelectric materials and devices, hierarchically structured and assembled materials, and surface and interfacial properties. He has published more than 220 peer reviewed journal articles (with an h-index of 61), 10 book chapters, and 4 books. Currently, he serves as an Associate Editor for Journal of Materials Chemistry A, and an editorial advisory board member for Nanoscale. He is a recipient of Frank J. Padden Jr. Award in Polymer Physics from American Physical Society, an NSF Career Award, a 3 M Non-Tenured Faculty Award, and an invited participant at the National Academy of Engineerings 2010 US Frontiers of Engineering Symposium. He became a Fellow of Royal Society of Chemistry in 2014 and a Japan Society for Promotion of Science (JSPS) Fellow in 2015.



Dr. Ming He received his B.S. in Materials Science and Engineering from East China University of Science and Technology in 2005, and received his Ph.D. in Polymer Chemistry and Physics from Fudan University in 2011. He was a visiting student at Iowa State university (2009-2011). He worked as a Postdoctoral Fellow at Fudan University (2011-2013) and Georgia Institute of Technology (2013-2017). In July 2017, he became a Research Scientist at Georgia Institute of Technology. His research interests include conjugated polymers, organic-inorganic hybrid semiconductors, solar cells, and thermoelectricity.