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Organometallics in Environment and Toxicology [Kõva köide]

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  • Formaat: Hardback, 608 pages, kõrgus x laius: 234x156 mm, kaal: 1028 g, 1 Illustrations, color
  • Sari: Metal Ions in Life Sciences Volume 7
  • Ilmumisaeg: 29-Jan-2010
  • Kirjastus: Royal Society of Chemistry
  • ISBN-10: 1847551777
  • ISBN-13: 9781847551771
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  • Formaat: Hardback, 608 pages, kõrgus x laius: 234x156 mm, kaal: 1028 g, 1 Illustrations, color
  • Sari: Metal Ions in Life Sciences Volume 7
  • Ilmumisaeg: 29-Jan-2010
  • Kirjastus: Royal Society of Chemistry
  • ISBN-10: 1847551777
  • ISBN-13: 9781847551771
This volume deals mainly with metal(loid)-alkyl derivatives but also with the rarer aryl compounds. Most of these compounds are formed in the environment by microorganisms, but some anthropogenic input occurs as well.


This volume, closely related to MILS-6, deals mainly with metal(loid)-alkyl derivatives but also with the rarer aryl compounds. Most of these (commonly toxic) compounds are formed in the environment by microorganisms, but some anthropogenic input occurs as well. MILS-7, providing a most up-to-date view, is of special relevance for researchers in analytical and bioinorganic chemistry, enzymology, environmental chemistry, physiology, toxicology, and related medical fields.
Historical Development and Perspectives of the Series v
Preface to Volume 7 vii
Contributors to Volume 7 xv
Titles of Volumes 1-44 in the Metal Ions in Biological Systems Series xix
Contents of Volumes in the Metal Ions in Life Sciences Series xxi
Roles of Organometal(LOID) Compounds in Environmental Cycles
1(32)
John S. Thayer
Abstract
2(1)
Introduction
3(2)
Form and Distribution of Organometal(loid)s
5(5)
Environmental Transport
10(3)
Specific Elements and Cycles
13(9)
Conclusions
22(11)
Acknowledgments
23(1)
References
23(10)
Analysis of Organometal(LOID) Compounds in Environmental and Biological Samples
33(38)
Christopher F. Harrington
Daniel S. Vidler
Richard O. Jenkins
Abstract
34(1)
Introduction
34(1)
Sample Preparation
35(8)
Sample Analysis
43(17)
Quality Management
60(1)
Future developments
60(11)
Acknowledgements
61(1)
Abbreviations and Definitions
61(3)
References
64(7)
Evidence for Organometallic Intermediates in Bacterial Methane Formation Involving the Nickel Coenzyme F430
71(40)
Mishtu Dey
Xianghui Li
Yuzhen Zhou
Stephen W. Ragsdale
Abstract
72(1)
Introduction
73(11)
A Brief Introduction to Methanogenesis
84(3)
General Properties of Methyl-Coenzyme M Reductase and Coenzyme F430
87(5)
Organonickel Intermediates on Methyl-Coenzyme M Reductase
92(11)
Perspective and Prospective
103(8)
Acknowledgments
104(1)
Abbreviations and Definitions
104(1)
References
105(6)
Organotins, Formation, use, Speciation, and Toxicology
111(42)
Tamas Gajda
Attila Janeso
Abstract
112(1)
Introduction
112(1)
Synthetic Aspects
113(5)
Applications and Sources of Organotin Pollution
118(5)
(Bio)Inorganic Speciation in the Aquatic Environment
123(11)
Concentration and Destination in the Environment
134(6)
Toxicity
140(3)
Concluding Remarks
143(10)
Acknowledgment
143(1)
Abbreviations
144(1)
References
144(9)
Alkyllead Compounds and their Environmental Toxicology
153(12)
Henry G. Abadin
Hana R. Pohl
Abstract
153(1)
Introduction
154(1)
Formation of Alkyllead Compounds
154(1)
Releases to the Environment
155(1)
Environmental Fate
155(2)
Health Effects
157(3)
Toxicokinetics
160(1)
Concluding Remarks
161(4)
Abbreviations
162(1)
References
162(3)
Organoarsenicals. Distribution and Transformation in the Environment
165(66)
Kenneth J. Reimer
Iris Koch
William R. Cullen
Abstract
167(1)
Introduction
167(6)
Organoarsenicals in Natural Waters and Sediments
173(2)
Organoarsenicals in the Atmosphere
175(2)
Prokaryotae
177(6)
Protoctista
183(4)
Plankton
187(2)
Fungi
189(4)
Plantae
193(2)
Animalia
195(14)
Arsenolipids
209(1)
Organoarsenicals with Arsenic-Sulfur Bonds
210(3)
Arsenic Transformations
213(18)
Acknowledgment
216(1)
Abbreviations
216(1)
References
217(14)
Organoarsenicals. Uptake, Metabolism, and Toxicity
231(36)
Elke Dopp
Andrew D. Kligerman
Roland A. Diaz-Bone
Abstract
232(1)
Introduction
232(1)
Systemic Toxicity and Carcinogenicity of Arsenic
233(3)
Uptake and Metabolism of Arsenic Species
236(8)
Modes of Action of Organoarsenicals
244(10)
Arsenic Carcinogenesis and Oxidative Stress
254(13)
Abbreviations
256(2)
References
258(9)
Alkyl Derivatives of Antimony in the Environment
267(36)
Montserrat Filella
Abstract
268(1)
Introduction
268(1)
Physical and Chemical Characteristics of Methylantimony Compounds
269(3)
Occurrence in the Environment
272(12)
Microbial Transformations of Antimony Compounds
284(11)
Ecotoxicity
295(1)
Concluding Remarks
295(8)
Abbreviations
296(1)
References
297(6)
Alkyl Derivatives of Bismuth in Environmental and Biological Media
303(16)
Montserrat Filella
Abstract
303(1)
Introduction
304(1)
Physical and Chemical Characteristics of Methylbismuth Compounds
305(2)
Detection and Quantification
307(1)
Occurrence in Environmental and Biological Media
307(3)
Microbial Transformations of Bismuth Compounds
310(1)
Toxicity
311(3)
Concluding Remarks
314(5)
Abbreviations
315(1)
References
315(4)
Formation, Occurrence, Significance, and Analysis of Organoselenium and Organotellurium Compounds in the Environment
319(46)
Dirk Wallschlager
Jorg Feldmann
Abstract
320(1)
Introduction
320(1)
Organoselenium Species
321(33)
Organotellurium Compounds
354(11)
Abbreviations
359(1)
References
360(5)
Organomercurials. their Formation and Pathways in the Environment
365(38)
Holger Hintelmann
Abstract
366(1)
Introduction
366(1)
Speciation of Organomercury Compounds
367(4)
Formation of Organomercury Compounds
371(10)
Degradation of Organomercurials
381(1)
Distribution and Pathways of Organomercurials in the Environment
382(9)
Concluding Remarks and Future Directions
391(12)
Abbreviations
392(1)
References
392(11)
Toxicology of Alkylmercury Compounds
403(32)
Michael Aschner
Natalia Onishchenko
Sandra Ceccatelli
Abstract
404(1)
Introduction
404(3)
Mercury Species of Relevance to Human Health
407(3)
Neurotoxicity of Mercury Species
410(5)
Mechanisms of Neurotoxicity
415(4)
Mercury and Neurodegenerative Disorders: A Literature Survey
419(6)
General Conclusions
425(10)
Acknowledgments
426(1)
Abbreviations
427(1)
References
427(8)
Environmental Bioindication, Biomonitoring, and Bioremediation of Organometal(LOID)S
435(30)
John S. Thayer
Abstract
436(1)
Introduction
436(2)
Biomarkers and Bioindicators
438(4)
Biomonitors
442(4)
Bioremediation
446(6)
Conclusions
452(13)
Acknowledgments
453(1)
References
453(12)
Methylated Metal(LOID) Species in Humans
465(58)
Alfred V. Hirner
Albert W. Rettenmeier
Abstract
466(1)
Introduction
466(2)
Exposure of Humans to Alkylated Metal(loid)s
468(2)
Disposition and Transport of Methylated Metal(loid)s in the Human Body
470(19)
Toxicology of Methylated Metal(loid)s
489(16)
General Conclusions
505(18)
Abbreviations
506(1)
References
507(16)
Subject Index 523
Astrid Sigel has studied languages and was an editor of the Metal Ions in Biological Systems series (until Volume 44) and also of the Handbooks on Toxicity of Inorganic Compounds (1988), on Metals in Clinical and Analytical Chemistry (1994; both with H. G. Seiler) and on Metalloproteins (2001; with Ivano Bertini). Helmut Sigel is Emeritus Professor (2003) of Inorganic Chemistry at the University of Basel, Switzerland, and a previous editor of the MIBS series until Volume 44. He serves on various editorial and advisory boards, published over 300 articles on metal ion complexes of nucleotides, coenzymes, and other ligands of biological relevance, and lectured worldwide. He was named Protagonist in Chemistry (2002) by ICA (issue 339); among further honors are the P. Ray Award (Indian Chemical Society, of which he is also an Honorary Fellow), the Werner Award (Swiss Chemical Society), a Doctor of Science honoris causa degree (Kalyani University, India), appointments as Visiting Professor (e.g., Austria, China, Japan, UK) and Endowed Lectureships. Roland K. O. Sigel is Associate Professor (2009) of Inorganic Chemistry at the University of Z³rich, Switzerland,; from 2003 to 2008 he was endowed with a F÷rderungsprofessur of the Swiss National Science Foundation. He received his doctoral degree summa cum laude (1999) from the University of Dortmund, Germany, working with Bernhard Lippert. Thereafter he spent nearly three years at Columbia University, New York, USA, with Anna Marie Pyle (now Yale University). During the six years abroad he received several prestigeous fellowships from various sources, and he was awarded the EuroBIC Medal in 2008. His research focuses on the structural and catalytic role of metal ions in ribozymes, especially group II introns, and on related topics. He was also an editor of Volumes 43 and 44 of the MIBS series.