| Preface |
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vii | |
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Chapter 1 Application of NMR Spectra of Paramagnetic Systems for Structural Studies of Organic Ligands |
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1 | (40) |
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1.1 Nature of Hyperfine Contact Coupling in Paramagnetic Complexes |
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2 | (12) |
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1.1.1 Complexes of First Transition Group Elements |
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2 | (8) |
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1.1.2 Complexes of Rare-Earth Elements |
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10 | (4) |
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1.2 Study of Spatial Structure of Organic Compounds |
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14 | (12) |
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1.2.1 Complexes of First Transition Group Elements |
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15 | (4) |
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1.2.2 Complexes of Rare-Earth Elements |
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19 | (7) |
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1.3 Problems of Hyperfine Coupling Theory and Relaxation Processes in Paramagnetic Complexes with Heterorganic Ligands |
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26 | (15) |
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Chapter 2 Method of Paramagnetic Additives |
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41 | (80) |
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43 | (8) |
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2.2 Paramagnetic Additives of Iron Group Elements |
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51 | (12) |
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2.2.1 1 - Methyl-2-Aminobenzimidazole |
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59 | (3) |
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2.2.2 1,1-Divinyl-2,2-Biimidazolyl |
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62 | (1) |
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2.3 Lanthanide Paramagnetic Additives |
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63 | (32) |
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2.3.1.1 Ethyl-2-Methylimidazole |
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63 | (2) |
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2.3.3 Vinyl Derivatives of Imidazole, Pyrazole, Triazole |
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65 | (11) |
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2.3.4 Vinyloxyphenylazomethines |
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76 | (2) |
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2.3.5 3- and 5-Substituted Flavones |
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78 | (7) |
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2.3.6 2-, 3-, 4-Pyridylcarbinol Vinyl Ethers |
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85 | (3) |
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2.3.7 2,5-Dimethyl-4-Methylene-1,3-Oxathiolane |
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88 | (1) |
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2.3.8 Configuration and Conformation of 8-(3,4-dihydropyranyl-2) Oxyquinoline Derivatives |
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89 | (4) |
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2.3.9 2H,6H-2,6-Dimethyl-4-Amino-1,3,5-Dithiazine and Its Derivatives |
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93 | (2) |
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2.4 Application of Paramagnetic Complexes for the NMR Spectra Analysis |
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95 | (26) |
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2.4.1 Experimental Procedures |
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107 | (5) |
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2.4.2 Experimental Data Analysis |
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112 | (9) |
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Chapter 3 Application of Complex Formation Process in Structural Studies |
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121 | (36) |
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3.1 Spatial Structure of 1-Vinylimidazole |
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121 | (5) |
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3.2 Complexing Ability and Structure of |
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126 | (6) |
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Si-Substituted Silatranes |
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126 | (6) |
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3.3 Structure of Methyl Thienyl Ketone Oxime Studied |
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132 | (3) |
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By Paramagnetic Additives Method |
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132 | (3) |
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3.4 Peculiarities of Molecular Structure of Nickel Paramagnetic Complexes with Nitroxyl Radicals |
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135 | (10) |
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3.5 Peculiarities of Intramolecular Exchange and Valence Tautomerism in Metal Semi-Quinolates |
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145 | (12) |
| Conclusion |
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157 | (2) |
| References |
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159 | (18) |
| Index |
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177 | |
