Preface |
|
xiii | |
Chapter 1 Elementary Materials Science Concepts |
|
3 | (122) |
|
1.1 Atomic Structure and Atomic Number |
|
|
3 | (5) |
|
|
8 | (1) |
|
1.3 Bonding and Types of Solids |
|
|
9 | (16) |
|
1.3.1 Molecules and General Bonding Principles |
|
|
9 | (2) |
|
1.3.2 Covalently Bonded Solids: Diamond |
|
|
11 | (2) |
|
1.3.3 Metallic Bonding: Copper |
|
|
13 | (1) |
|
1.3.4 Ionically Bonded Solids: Salt |
|
|
14 | (4) |
|
|
18 | (4) |
|
|
22 | (3) |
|
1.4 Kinetic Molecular Theory |
|
|
25 | (12) |
|
1.4.1 Mean Kinetic Energy and Temperature |
|
|
25 | (7) |
|
|
32 | (5) |
|
1.5 Molecular Velocity and Energy Distribution |
|
|
37 | (4) |
|
1.6 Molecular Collisions and Vacuum Deposition |
|
|
41 | (4) |
|
1.7 Heat, Thermal Fluctuations, and Noise |
|
|
45 | (5) |
|
1.8 Thermally Activated Processes |
|
|
50 | (5) |
|
1.8.1 Arrhenius Rate Equation |
|
|
50 | (2) |
|
1.8.2 Atomic Diffusion and the Diffusion Coefficient |
|
|
52 | (3) |
|
1.9 The Crystalline State |
|
|
55 | (14) |
|
|
55 | (6) |
|
1.9.2 Crystal Directions and Planes |
|
|
61 | (5) |
|
1.9.3 Allotropy and Carbon |
|
|
66 | (3) |
|
1.10 Crystalline Defects and Their Significance |
|
|
69 | (13) |
|
1.10.1 Point Defects: Vacancies and Impurities |
|
|
69 | (4) |
|
1.10.2 Line Defects: Edge and Screw Dislocations |
|
|
73 | (4) |
|
1.10.3 Planar Defects: Grain Boundaries |
|
|
77 | (2) |
|
1.10.4 Crystal Surfaces and Surface Properties |
|
|
79 | (3) |
|
1.10.5 Stoichiometry, Nonstoichiometry, and Defect Structures |
|
|
82 | (1) |
|
1.11 Single-Crystal Czochralski Growth |
|
|
82 | (3) |
|
1.12 Glasses and Amorphous Semiconductors |
|
|
85 | (5) |
|
1.12.1 Glasses and Amorphous Solids |
|
|
85 | (3) |
|
1.12.2 Crystalline and Amorphous Silicon |
|
|
88 | (2) |
|
1.13 Solid Solutions and Two-Phase Solids |
|
|
90 | (12) |
|
1.13.1 Isomorphous Solid Solutions: Isomorphous Alloys |
|
|
90 | (1) |
|
1.13.2 Phase Diagrams: Cu-Ni and Other Isomorphous Alloys |
|
|
91 | (4) |
|
1.13.3 Zone Refining and Pure Silicon Crystals |
|
|
95 | (2) |
|
1.13.4 Binary Eutectic Phase Diagrams and Pb-Sn Solders |
|
|
97 | (5) |
|
|
102 | (5) |
|
|
102 | (3) |
|
|
105 | (2) |
|
|
107 | (4) |
|
|
111 | (14) |
Chapter 2 Electrical and Thermal Conduction in Solids: Mainly Classical Concepts |
|
125 | (88) |
|
2.1 Classical Theory: The Drude Model |
|
|
126 | (8) |
|
2.2 Temperature Dependence of Resistivity: Ideal Pure Metals |
|
|
134 | (3) |
|
2.3 Matthiessen's and Nordheim's Rules |
|
|
137 | (15) |
|
2.3.1 Matthiessen's Rule and the Temperature Coefficient of Resistivity (alpha) |
|
|
137 | (8) |
|
2.3.2 Solid Solutions and Nordheim's Rule |
|
|
145 | (7) |
|
2.4 Resistivity of Mixtures and Porous Materials |
|
|
152 | (5) |
|
2.4.1 Heterogeneous Mixtures |
|
|
152 | (4) |
|
2.4.2 Two-Phase Alloy (Ag-Ni) Resistivity and Electrical Contacts |
|
|
156 | (1) |
|
2.5 The Hall Effect and Hall Devices |
|
|
157 | (5) |
|
|
162 | (5) |
|
2.6.1 Thermal Conductivity |
|
|
162 | (4) |
|
|
166 | (1) |
|
2.7 Electrical Conductivity of Nonmetals |
|
|
167 | (10) |
|
|
168 | (4) |
|
2.7.2 Ionic Crystals and Glasses |
|
|
172 | (5) |
|
|
177 | (19) |
|
2.8 Skin Effect: HF Resistance of a Conductor |
|
|
177 | (3) |
|
|
180 | (4) |
|
|
184 | (6) |
|
2.10.1 Conduction in Thin Metal Films |
|
|
184 | (1) |
|
2.10.2 Resistivity of Thin Films |
|
|
184 | (6) |
|
2.11 Interconnects in Microelectronics |
|
|
190 | (4) |
|
2.12 Electromigration and Black's Equation |
|
|
194 | (2) |
|
|
196 | (2) |
|
|
198 | (15) |
Chapter 3 Elementary Quantum Physics |
|
213 | (100) |
|
|
213 | (14) |
|
|
213 | (3) |
|
3.1.2 The Photoelectric Effect |
|
|
216 | (5) |
|
|
221 | (3) |
|
3.1.4 Black Body Radiation |
|
|
224 | (3) |
|
3.2 The Electron as a Wave |
|
|
227 | (8) |
|
3.2.1 De Broglie Relationship |
|
|
227 | (4) |
|
3.2.2 Time-Independent Schrbdinger Equation |
|
|
231 | (4) |
|
3.3 Infinite Potential Well: A Confined Electron |
|
|
235 | (6) |
|
3.4 Heisenberg's Uncertainty Principle |
|
|
241 | (3) |
|
3.5 Confined Electron in a Finite Potential Energy Well |
|
|
244 | (4) |
|
3.6 Tunneling Phenomenon: Quantum Leak |
|
|
248 | (6) |
|
3.7 Potential Box: Three Quantum Numbers |
|
|
254 | (3) |
|
|
257 | (21) |
|
3.8.1 Electron Wavefunctions |
|
|
257 | (5) |
|
3.8.2 Quantized Electron Energy |
|
|
262 | (4) |
|
3.8.3 Orbital Angular Momentum and Space Quantization |
|
|
266 | (5) |
|
3.8.4 Electron Spin and Intrinsic Angular Momentum S |
|
|
271 | (2) |
|
3.8.5 Magnetic Dipole Moment of the Electron |
|
|
273 | (4) |
|
3.8.6 Total Angular Momentum J |
|
|
277 | (1) |
|
3.9 The Helium Atom and the Periodic Table |
|
|
278 | (5) |
|
3.9.1 He Atom and Pauli Exclusion Principle |
|
|
278 | (3) |
|
|
281 | (2) |
|
3.10 Stimulated Emission and Lasers |
|
|
283 | (9) |
|
3.10.1 Stimulated Emission and Photon Amplification |
|
|
283 | (4) |
|
|
287 | (3) |
|
3.10.3 Laser Output Spectrum |
|
|
290 | (2) |
|
|
292 | (2) |
|
3.11 Optical Fiber Amplifiers |
|
|
292 | (2) |
|
|
294 | (4) |
|
|
298 | (15) |
Chapter 4 Modern Theory of Solids |
|
313 | (98) |
|
4.1 Hydrogen Molecule: Molecular Orbital Theory of Bonding |
|
|
313 | (6) |
|
4.2 Band Theory of Solids |
|
|
319 | (9) |
|
4.2.1 Energy Band Formation |
|
|
319 | (6) |
|
4.2.2 Properties of Electrons in a Band |
|
|
325 | (3) |
|
|
328 | (6) |
|
4.4 Electron Effective Mass |
|
|
334 | (2) |
|
4.5 Density of States in an Energy Band |
|
|
336 | (7) |
|
4.6 Statistics: Collections of Particles |
|
|
343 | (3) |
|
4.6.1 Boltzmann Classical Statistics |
|
|
343 | (1) |
|
4.6.2 Fermi-Dirac Statistics |
|
|
344 | (2) |
|
4.7 Quantum Theory of Metals |
|
|
346 | (6) |
|
4.7.1 Free Electron Model |
|
|
346 | (3) |
|
4.7.2 Conduction in Metals |
|
|
349 | (3) |
|
4.8 Fermi Energy Significance |
|
|
352 | (12) |
|
4.8.1 Metal-Metal Contacts: Contact Potential |
|
|
352 | (3) |
|
4.8.2 The Seebeck Effect and the Thermocouple |
|
|
355 | (9) |
|
4.9 Thermionic Emission and Vacuum Tube Devices |
|
|
364 | (10) |
|
4.9.1 Thermionic Emission: Richardson-Dushman Equation |
|
|
364 | (4) |
|
4.9.2 Schottky Effect and Field Emission |
|
|
368 | (6) |
|
|
374 | (14) |
|
4.10.1 Harmonic Oscillator and Lattice Waves |
|
|
374 | (5) |
|
4.10.2 Debye Heat Capacity |
|
|
379 | (5) |
|
4.10.3 Thermal Conductivity of Nonmetals |
|
|
384 | (3) |
|
4.10.4 Electrical Conductivity |
|
|
387 | (1) |
|
|
388 | (9) |
|
4.11 Band Theory of Metals: Electron Diffraction in Crystals |
|
|
388 | (9) |
|
|
397 | (2) |
|
|
399 | (12) |
Chapter 5 Semiconductors |
|
411 | (116) |
|
5.1 Intrinsic Semiconductors |
|
|
412 | (14) |
|
5.1.1 Silicon Crystal and Energy Band Diagram |
|
|
412 | (1) |
|
5.1.2 Electrons and Holes |
|
|
413 | (3) |
|
5.1.3 Conduction in Semiconductors |
|
|
416 | (2) |
|
5.1.4 Electron and Hole Concentrations |
|
|
418 | (8) |
|
5.2 Extrinsic Semiconductors |
|
|
426 | (9) |
|
|
427 | (2) |
|
|
429 | (1) |
|
5.2.3 Compensation Doping |
|
|
430 | (5) |
|
5.3 Temperature Dependence of Conductivity |
|
|
435 | (12) |
|
5.3.1 Carrier Concentration Temperature Dependence |
|
|
435 | (5) |
|
5.3.2 Drift Mobility: Temperature and Impurity Dependence |
|
|
440 | (3) |
|
5.3.3 Conductivity Temperature Dependence |
|
|
443 | (2) |
|
5.3.4 Degenerate and Nondegenerate Semiconductors |
|
|
445 | (2) |
|
5.4 Direct and Indirect Recombination |
|
|
447 | (4) |
|
5.5 Minority Carrier Lifetime |
|
|
451 | (6) |
|
5.6 Diffusion and Conduction Equations, and Random Motion |
|
|
457 | (6) |
|
|
463 | (6) |
|
5.7.1 Time-Dependent Continuity Equation |
|
|
463 | (2) |
|
5.7.2 Steady-State Continuity Equation |
|
|
465 | (4) |
|
|
469 | (4) |
|
|
473 | (4) |
|
|
477 | (10) |
|
|
477 | (5) |
|
5.10.2 Schottky Junction Solar Cell and Photodiode |
|
|
482 | (5) |
|
5.11 Ohmic Contacts and Thermoelectric Coolers |
|
|
487 | (5) |
|
|
492 | (16) |
|
5.12 Seebeck Effect in Semiconductors and Voltage Drift |
|
|
492 | (3) |
|
5.13 Direct and Indirect Bandgap Semiconductors |
|
|
495 | (10) |
|
5.14 Indirect Recombination |
|
|
505 | (1) |
|
5.15 Amorphous Semiconductors |
|
|
505 | (3) |
|
|
508 | (3) |
|
|
511 | (16) |
Chapter 6 Semiconductor Devices |
|
527 | (132) |
|
|
528 | (13) |
|
6.1.1 No Applied Bias: Open Circuit |
|
|
528 | (5) |
|
6.1.2 Forward Bias: Diffusion Current |
|
|
533 | (6) |
|
6.1.3 Forward Bias: Recombination and Total Current |
|
|
539 | (2) |
|
|
541 | (12) |
|
6.2 pn Junction Band Diagram |
|
|
548 | (1) |
|
|
548 | (2) |
|
6.2.2 Forward and Reverse Bias |
|
|
550 | (3) |
|
6.3 Depletion Layer Capacitance of the pn Junction |
|
|
553 | (6) |
|
6.4 Diffusion (Storage) Capacitance and Dynamic Resistance |
|
|
559 | (3) |
|
6.5 Reverse Breakdown: Avalanche and Zener Breakdown |
|
|
562 | (4) |
|
6.5.1 Avalanche Breakdown |
|
|
562 | (2) |
|
|
564 | (2) |
|
6.6 Light Emitting Diodes (LED) |
|
|
566 | (6) |
|
|
566 | (2) |
|
6.6.2 Heterojunction High-Intensity LEDs |
|
|
568 | (1) |
|
6.6.3 Quantum Well High Intensity LEDs |
|
|
569 | (3) |
|
6.7 Led Materials and Structures |
|
|
572 | (4) |
|
|
576 | (6) |
|
6.9 Brightness and Efficiency of LEDs |
|
|
582 | (4) |
|
|
586 | (12) |
|
6.10.1 Photovoltaic Device Principles |
|
|
586 | (7) |
|
6.10.2 Series and Shunt Resistance |
|
|
593 | (2) |
|
6.10.3 Solar Cell Materials, Devices, and Efficiencies |
|
|
595 | (3) |
|
6.11 Bipolar Transistor (BJT) |
|
|
598 | (16) |
|
6.11.1 Common Base (CB) DC Characteristics |
|
|
598 | (9) |
|
6.11.2 Common Base Amplifier |
|
|
607 | (2) |
|
6.11.3 Common Emitter (CE) DC Characteristics |
|
|
609 | (2) |
|
6.11.4 Low-Frequency Small-Signal Model |
|
|
611 | (3) |
|
6.12 Junction Field Effect Transistor (JFET) |
|
|
614 | (10) |
|
6.12.1 General Principles |
|
|
614 | (6) |
|
|
620 | (4) |
|
6.13 Metal-Oxide-Semiconductor Field Effect Transistor (MOSFET) |
|
|
624 | (11) |
|
6.13.1 Field Effect and Inversion |
|
|
624 | (2) |
|
6.13.2 Enhancement MOSFET |
|
|
626 | (5) |
|
|
631 | (2) |
|
6.13.4 Ion Implanted MOS Transistors and Poly-Si Gates |
|
|
633 | (2) |
|
|
635 | (6) |
|
6.14 pin Diodes, Photodiodes, and Solar Cells |
|
|
635 | (3) |
|
6.15 Semiconductor Optical Amplifiers and Lasers |
|
|
638 | (3) |
|
|
641 | (4) |
|
|
645 | (14) |
Chapter 7 Dielectric Materials and Insulation |
|
659 | (108) |
|
7.1 Matter Polarization and Relative Permittivity |
|
|
660 | (11) |
|
7.1.1 Relative Permittivity: Definition |
|
|
660 | (1) |
|
7.1.2 Dipole Moment and Electronic Polarization |
|
|
661 | (4) |
|
7.1.3 Polarization Vector P |
|
|
665 | (4) |
|
7.1.4 Local Field Eloc and Clausius-Mossotti Equation |
|
|
669 | (2) |
|
7.2 Electronic Polarization: Covalent Solids |
|
|
671 | (2) |
|
7.3 Polarization Mechanisms |
|
|
673 | (6) |
|
|
673 | (1) |
|
7.3.2 Orientational (Dipolar) Polarization |
|
|
674 | (2) |
|
7.3.3 Interfacial Polarization |
|
|
676 | (2) |
|
|
678 | (1) |
|
7.4 Frequency Dependence: Dielectric Constant and Dielectric Loss |
|
|
679 | (12) |
|
|
679 | (9) |
|
7.4.2 Debye Equations, Cole-Cole Plots, and Equivalent Series Circuit |
|
|
688 | (3) |
|
7.5 Gauss's Law and Boundary Conditions |
|
|
691 | (5) |
|
7.6 Dielectric Strength and Insulation Breakdown |
|
|
696 | (14) |
|
7.6.1 Dielectric Strength: Definition |
|
|
696 | (1) |
|
7.6.2 Dielectric Breakdown and Partial Discharges: Gases |
|
|
697 | (3) |
|
7.6.3 Dielectric Breakdown: Liquids |
|
|
700 | (1) |
|
7.6.4 Dielectric Breakdown: Solids |
|
|
701 | (9) |
|
7.7 Capacitor Dielectric Materials |
|
|
710 | (9) |
|
7.7.1 Typical Capacitor Constructions |
|
|
710 | (5) |
|
7.7.2 Dielectrics: Comparison |
|
|
715 | (4) |
|
7.8 Piezoelectricity, Ferroelectricity, and Pyroelectricity |
|
|
719 | (15) |
|
|
719 | (5) |
|
7.8.2 Piezoelectricity: Quartz Oscillators and Filters |
|
|
724 | (3) |
|
7.8.3 Ferroelectric and Pyroelectric Crystals |
|
|
727 | (7) |
|
|
734 | (16) |
|
7.9 Electric Displacement and Depolarization Field |
|
|
734 | (4) |
|
7.10 Local Field and the Lorentz Equation |
|
|
738 | (2) |
|
7.11 Dipolar Polarization |
|
|
740 | (2) |
|
7.12 Ionic Polarization and Dielectric Resonance |
|
|
742 | (5) |
|
7.13 Dielectric Mixtures and Heterogeneous Media |
|
|
747 | (3) |
|
|
750 | (3) |
|
|
753 | (14) |
Chapter 8 Magnetic Properties and Superconductivity |
|
767 | (92) |
|
8.1 Magnetization of Matter |
|
|
768 | (10) |
|
8.1.1 Magnetic Dipole Moment |
|
|
768 | (1) |
|
8.1.2 Atomic Magnetic Moments |
|
|
769 | (1) |
|
8.1.3 Magnetization Vector M |
|
|
770 | (3) |
|
8.1.4 Magnetizing Field or Magnetic Field Intensity H |
|
|
773 | (1) |
|
8.1.5 Magnetic Permeability and Magnetic Susceptibility |
|
|
774 | (4) |
|
8.2 Magnetic Material Classifications |
|
|
778 | (4) |
|
|
778 | (2) |
|
|
780 | (1) |
|
|
781 | (1) |
|
|
781 | (1) |
|
|
782 | (1) |
|
8.3 Ferromagnetism Origin and the Exchange Interaction |
|
|
782 | (3) |
|
8.4 Saturation Magnetization and Curie Temperature |
|
|
785 | (2) |
|
8.5 Magnetic Domains: Ferromagnetic Materials |
|
|
787 | (14) |
|
|
787 | (2) |
|
8.5.2 Magnetocrystalline Anisotropy |
|
|
789 | (1) |
|
|
790 | (3) |
|
|
793 | (1) |
|
|
794 | (1) |
|
8.5.6 Polycrystalline Materials and the M versus H Behavior |
|
|
795 | (4) |
|
|
799 | (2) |
|
8.6 Soft and Hard Magnetic Materials |
|
|
801 | (2) |
|
|
801 | (1) |
|
8.6.2 Initial and Maximum Permeability |
|
|
802 | (1) |
|
8.7 Soft Magnetic Materials: Examples and Uses |
|
|
803 | (3) |
|
8.8 Hard Magnetic Materials: Examples and Uses |
|
|
806 | (6) |
|
8.9 Energy Band Diagrams and Magnetism |
|
|
812 | (3) |
|
8.9.1 Pauli Spin Paramagnetism |
|
|
812 | (2) |
|
8.9.2 Energy Band Model of Ferromagnetism |
|
|
814 | (1) |
|
8.10 Anisotropic and Giant Magnetoresistance |
|
|
815 | (5) |
|
8.11 Magnetic Recording Materials |
|
|
820 | (9) |
|
8.11.1 General Principles of Magnetic Recording |
|
|
820 | (5) |
|
8.11.2 Materials for Magnetic Storage |
|
|
825 | (4) |
|
|
829 | (9) |
|
8.12.1 Zero Resistance and the Meissner Effect |
|
|
829 | (3) |
|
8.12.2 Type I and Type II Superconductors |
|
|
832 | (2) |
|
8.12.3 Critical Current Density |
|
|
834 | (4) |
|
8.13 Superconductivity Origin |
|
|
838 | (2) |
|
|
840 | (3) |
|
|
840 | (2) |
|
|
842 | (1) |
|
|
843 | (4) |
|
|
847 | (12) |
Chapter 9 Optical Properties of Materials |
|
859 | (82) |
|
9.1 Light Waves in a Homogeneous Medium |
|
|
860 | (3) |
|
|
863 | (2) |
|
9.3 Dispersion: Refractive Index-Wavelength Behavior |
|
|
865 | (5) |
|
9.4 Group Velocity and Group Index |
|
|
870 | (3) |
|
9.5 Magnetic Field: Irradiance and Poynting Vector |
|
|
873 | (2) |
|
9.6 Snell's Law and Total Internal Reflection (TIR) |
|
|
875 | (4) |
|
|
879 | (11) |
|
9.7.1 Amplitude Reflection and Transmission Coefficients |
|
|
879 | (6) |
|
9.7.2 Intensity, Reflectance, and Transmittance |
|
|
885 | (5) |
|
9.8 Complex Refractive Index and Light Absorption |
|
|
890 | (8) |
|
|
898 | (2) |
|
9.10 Band-To-Band Absorption |
|
|
900 | (3) |
|
9.11 Light Scattering in Materials |
|
|
903 | (1) |
|
9.12 Attenuation in Optical Fibers |
|
|
904 | (3) |
|
9.13 Luminescence, Phosphors, and White LEDs |
|
|
907 | (5) |
|
|
912 | (2) |
|
|
914 | (6) |
|
9.15.1 Uniaxial Crystals and Fresnel's Optical Indicatrix |
|
|
915 | (4) |
|
9.15.2 Birefringence of Calcite |
|
|
919 | (1) |
|
|
920 | (1) |
|
9.16 Birefringent Retarding Plates |
|
|
920 | (2) |
|
9.17 Optical Activity and Circular Birefringence |
|
|
922 | (2) |
|
9.18 Liquid Crystal Displays (LCDs) |
|
|
924 | (4) |
|
9.19 Electro-Optic Effects |
|
|
928 | (4) |
|
|
932 | (3) |
|
|
935 | (6) |
Appendix A Bragg's Diffraction Law and X-ray Diffraction |
|
941 | (6) |
Appendix B Major Symbols and Abbreviations |
|
947 | (8) |
Appendix C Elements to Uranium |
|
955 | (4) |
Appendix D Constants and Useful Information |
|
959 | (2) |
Index |
|
961 | (17) |
Periodic Table |
|
978 | |