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Principles of Inorganic Materials Design 2nd Edition [Kõva köide]

Foreword by , , (Gonzaga University in Spokane, WA)
  • Formaat: Hardback, 612 pages, kõrgus x laius x paksus: 246x167x37 mm, kaal: 1044 g
  • Ilmumisaeg: 19-Feb-2010
  • Kirjastus: Wiley-Blackwell
  • ISBN-10: 0470404035
  • ISBN-13: 9780470404034
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  • Formaat: Hardback, 612 pages, kõrgus x laius x paksus: 246x167x37 mm, kaal: 1044 g
  • Ilmumisaeg: 19-Feb-2010
  • Kirjastus: Wiley-Blackwell
  • ISBN-10: 0470404035
  • ISBN-13: 9780470404034
Teised raamatud teemal:
Typically, students of materials science were required to take an elementary chemistry course, say Chemists Lalena (Evergreen State College, Washington and U. of Maryland-Europe) and Cleary (Gonzaga U., Washington), but any further chemistry was taught in the context of one or another course in materials. Over the past couple decades, however, new materials development has relied ever more heavily on synthetic chemistry, and they decided that materials students could use a course specifically on the fundamentals of designing materials through synthetic chemistry. This text is designed for such a course at the undergraduate level, and the second edition not only been updated and expanded, but corrected. The number of worked examples has been increased, and answers appended for selected chapter-end problems. No date is noted for the first. Annotation ©2010 Book News, Inc., Portland, OR (booknews.com)

With new developments, understanding materials chemistry is key to successfully solving materials-related problems. Principles of Inorganic Materials Design is vital to students in need of the most advanced and updated information on materials chemistry to better equip for such challenges. Compiling recent publications, the text covers topics like microstructural aspects, density functional theory, dielectric properties, mechanical properties, and nanomaterials, as well as topics hardly discussed like the CALPHAD (CALculations of PHAse Diagrams) method. Through a "how-to" approach and end-of-chapter practice problems, students will learn the nature of design materials.
Foreword to Second Edition xiii
Foreword to First Edition xv
Preface to Second Edition xix
Preface to First Edition xxi
Acronyms xxiii
Crystallographic Considerations
Degrees of Crystallinity
2(7)
Monocrystalline Solids
2(1)
Quasicrystalline Solids
3(2)
Polycrystalline Solids
5(1)
Semicrystalline Solids
5(3)
Amorphous Solids
8(1)
Basic Crystallogrphy
9(22)
Space Lattice Geometry
9(22)
Single Crystal Morphology and its Relationship to Lattice Symmetry
31(5)
Twinned Crystals
36(2)
Crystallographic Orientation Relationships in Bicrystals
38(7)
The Coincidence Site Lattice
38(5)
Equivalent Axis-Angle Pairs
43(2)
Amorphous Solids and Glasses
45(10)
Practice Problems
50(2)
References
52(3)
Microstructural Considerations
55(42)
Materials Length Scales
56(5)
Experimental Resolution of Material Features
59(2)
Grain Boundaries in Polycrystalline Materials
61(9)
Grain-Boundary Orientations
61(2)
Dislocation Model of Low Angle Grain Boundaries
63(2)
Grain-Boundary Energy
65(1)
Special Types of Low-Energy Grain Boundaries
66(1)
Grain-Boundary Dynamics
67(1)
Representing Orientation Distributions in Polycrystalline Aggregates
67(3)
Materials Processing and Microstructure
70(12)
Conventional Solidification
70(8)
Deformation Processing
78(1)
Consolidation Processing
78(1)
Thin-Film Formation
79(3)
Microstructure and Materials Properties
82(8)
Mechanical Properties
83(1)
Transport Properties
84(4)
Magnetic and Dielectric Properties
88(2)
Chemical Properties
90(1)
Microstructure Control and Design
90(7)
Practice Problems
93(1)
References
94(3)
Crystal Structures and Binding Forces
97(78)
Structure Description Methods
97(6)
Close Packing
98(3)
Polyhedra
101(2)
The Unit Cell
103(1)
Pearson Symbols
103(1)
Cohesive Forces in Solids
103(8)
Ionic Bonding
103(3)
Covalent Bonding
106(3)
Metallic Bonding
109(1)
Atoms and Bonds as Electron Charge Density
110(1)
Structural Energetics
111(16)
Lattice Energy
112(5)
The Born-Haber Cycle
117(1)
Goldschmidt's Rules and Pauling's Rules
118(2)
Total Energy
120(2)
Electronic Origin of Coordination Polyhedra in Covalent Crystals
122(5)
Common Structure Types
127(26)
Iono-Covalent Solids
127(17)
Intermetallic Compounds
144(9)
Structural Disturbances
153(10)
Intrinsic Point Defects
154(2)
Extrinsic Point Defects
156(1)
Structural Distortions
157(3)
Bond Valence Sum Calculations
160(3)
Structure Control and Synthetic Strategies
163(12)
Practice Problems
167(2)
References
169(6)
The Electronic Level I: An Overview of Band Theory
175(28)
The Many-Body Schrodinger Equation
176(3)
Bloch's Theorem
179(5)
Reciprocal Space
184(3)
A Choice of Basis Sets
187(6)
Plane-Wave Expansion - The Free-Electron Models
188(1)
The Fermi Surface and Phase Stability
189(3)
Bloch Sum Basis Set - The LCAO Method
192(1)
Understanding Band-Structure Diagrams
193(4)
Breakdown of the Independent Electron Approximation
197(1)
Density Functional Theory-The Successor to the Hartree-Fock Approach
198(5)
Practice Problems
199(2)
References
201(2)
The Electronic Level II: The Tight-Binding Electronic Structure Approximation
203(38)
The General LCAO Method
204(6)
Extension of the LCAO Treatment to Crystalline Solids
210(3)
Orbital Interactions in Monatomic Solids
213(8)
σ-Bonding Interactions
213(4)
π-Bonding Interactions
217(4)
Thight-Binding Assumptions
221(2)
Qualitative LCAO Band Structures
223(15)
Transition Metal Oxides with Vertex-Sharing Octahedra
228(3)
Reduced Dimensional Systems
231(2)
Transition Metal Monosxides with Edge-Sharing Octachedra
233(4)
Corollary
237(2)
Total Energy Tight-Binding Calculations
238(3)
Practice Problems
239(1)
References
240(1)
Transport Properties
241(44)
An Introduction to Tensors
241(7)
Thermal Conductivity
248(6)
The Free Electron Contribution
249(2)
The Phonon Contribution
251(3)
Electrical Conductivity
254(18)
Band Structure Considerations
258(5)
Thermoelectric, Photovoltaic, and Magnetotransport Properties
263(9)
Mass Transport
272(13)
Atomic diffusion
273(7)
Ionic Conduction
280(1)
Practice Problems
281(1)
Refernces
282(3)
Metal-Nonmetal Transitions
285(26)
Correlated Systems
287(8)
The Mott-Hubbard Insulating State
289(4)
Charge-Transfer Insulators
293(1)
Marginal Metals
293(2)
Anderson Localization
295(4)
Experimentally Distinguishing Disorder from Electron Correlation
299(3)
Tuning the M-NM Transition
302(3)
Other Types of Electronic Transitions
305(6)
Practice Problems
307(1)
References
308(3)
Magnetic and Dielectric Properties
311(66)
Phenomenological Description of Magnetic Behavior
313(6)
Magnetization Curves
316(1)
Susceptibility Curves
317(2)
Atomic States and Term Symbiols of Free Ions
319(6)
Atomic Origin O Paramagnetism
325(14)
Orbital Angular Momentum Contribution - The Free Ion Case
326(1)
Spin Angular Momentum Contribution - The Free Ion Case
327(1)
Total Magnetic Moment - The Free Ion Case
328(1)
Spin-Orbit Coupling - The Free Ion Case
329(1)
Single Ions in Crystals
330(6)
Solids
336(3)
Diamagnetism
339(1)
Spontaneous Magnetic Ordering
339(20)
Exchange Interactions
341(9)
Itinerant Ferromagnetism
350(3)
Noncolinear Spin Configurations and Magnetocrystalline Anisotropy
353(6)
Magnetotransport Properties
359(4)
The Double Exchange Mechanism
361(1)
The Half-Metallic Ferromagnet Model
361(2)
Magnetostriction
363(1)
Dielectric Properties
364(13)
The Microscopic Equations
365(2)
Piezoelectricity
367(3)
Pyroelectricity
370(1)
Ferroelectricity
371(1)
Practice Problems
372(1)
References
373(4)
Optical Properties of Materials
377(26)
Maxwell's Equations
377(4)
Refractive Index
381(9)
Absorption
390(5)
Nonlinear Effects
395(5)
Summary
400(3)
Practice Problems
400(1)
References
401(2)
Mechanical Properties
403(58)
Stress and Strain
404(3)
Elasticity
407(26)
The Elasticity Tensor
408(5)
Elastically Isotropic Solids
413(8)
The Relation Between Elasticity and the Cohesive Forces in a Solid
421(9)
Superelasticity, Pseudoelasticity, and the Shape Memory Effect
430(3)
Plasticity
433(18)
The Dislocation-Based Mechanism to Plastic Deformation
439(8)
Polycrystalline Metals
447(1)
Brittle and Semibrittle Solids
448(2)
The Correlation Between the Electronic Structure and the Plasticity of Materials
450(1)
Fracture
451(10)
Practice Problems
454(2)
References
456(5)
Phase Equilibria, Phase Diagrams, and Phase Modeling
461(40)
Thermodynamic Systems and Equilibrium
462(7)
Equilibrium Thermodynamics
465(4)
Thermodynamic Potentials and the Laws
469(3)
Understanding Phase Diagrams
472(12)
Unary Systems
472(1)
Binary Metallurgical Systems
472(5)
Binary Nonmetallic Systems
477(1)
Tenary Condensed Systems
478(5)
Metastable Equilibria
483(1)
Experimental Phase-Diagram Determinations
484(1)
Phase-Diagram Modeling
485(16)
Gibbs Energy Expressions for Mixtures and Solid Solutions
485(3)
Gibbs Energy Experssions for Phase with Long-Range Order
488(5)
Other Contributions to the Gibbs Energy
493(1)
Phase Diagram Extrpolations - the CALPHAD Method
494(4)
Practice Problems
498(1)
References
499(2)
Synthetic Strategies
501(30)
Synthetic Strategies
502(24)
Direct Combination
503(1)
Low Temperature
504(8)
Defects
512(2)
Combinatorial Synthesis
514(1)
Spinodal Decomposition
514(3)
Thin Films
517(2)
Photonic Materials
519(2)
Nanosynthesis
521(5)
Summary
526(5)
Practice Problems
526(2)
References
528(3)
An Introduction to Nanomaterials
531(28)
History of Nanotechnology
532(2)
Nanomaterials Properties
534(7)
Electrical Properties
535(1)
Magnetic Properties
536(1)
Optical Properties
537(1)
Thermal Properties
538(1)
Mechancial Properties
538(1)
Chemical Reactivity
539(2)
More on Nanomaterials Preparative Techniques
541(18)
Top-Down Methods for the Fabrication of Nanocrystalline Materials
542(2)
Bottom-Up Methods for the Synthesis of Nanostructured Solids
544(12)
References
556(3)
Appendix 1 559(6)
Appendix 2 565(4)
Appendix 3 569(6)
Index 575
JOHN N. LALENA, PhD, is a Visiting Professor of Chemistry at The Evergreen State College, an Adjunct Assistant Professor of Chemistry at the University of Maryland University College-Europe, and an Affiliate Research Assistant Professor at Virginia Commonwealth University. Previously, Dr. Lalena was a senior research scientist for Honeywell Electronic Materials and a product/process semiconductor fabrication engineer for Texas Instruments. DAVID A. CLEARY, PhD, is Professor and Chair of the Department of Chemistry at Gonzaga University.