Preface |
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ix | |
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Chapter 1 Design and optimization of solid-state batteries |
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1 | (96) |
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1 Description of relations in battery operation |
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3 | (46) |
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3 | (6) |
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1.2 Classification of cells and batteries |
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9 | (3) |
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1.3 Electrochemical insertion process |
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12 | (14) |
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1.4 Transport properties of intercalated compounds |
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26 | (5) |
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1.5 Electrochemical intercalation techniques |
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31 | (18) |
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2 Quality criteria for thin-film materials |
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49 | (48) |
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2.1 Performance of thin-film cells |
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49 | (3) |
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2.2 Relevance of thin-film characteristics to batteries |
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52 | (4) |
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56 | (18) |
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2.4 Thin-fim deposition technology |
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74 | (5) |
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2.5 Influence of the deposition parameters |
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79 | (11) |
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90 | (7) |
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Chapter 2 Materials for electrolyte: Crystalline compounds |
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97 | (86) |
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1 Mechanisms of transport in solid electrolytes |
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98 | (26) |
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1.1 Phenomenological approach of ionic conduction |
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99 | (3) |
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1.2 Theoretical models for ionic conduction |
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102 | (21) |
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1.3 Classification of superionic materials |
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123 | (1) |
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124 | (12) |
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2.1 Fluorine ion conductors |
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124 | (10) |
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2.2 Oxygen ion conductors |
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134 | (2) |
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136 | (34) |
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3.1 Three-dimensional compounds |
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136 | (24) |
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3.2 Low-dimensional compounds |
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160 | (10) |
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170 | (13) |
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175 | (8) |
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Chapter 3 Materials for electrolyte: Fast-ion-conducting glasses |
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183 | (102) |
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1 Fast-ion-conducting glasses |
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186 | (17) |
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1.1 Structural description of glasses |
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187 | (6) |
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1.2 Ionic conductivity in glasses |
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193 | (10) |
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2 Conduction mechanisms in glasses |
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203 | (9) |
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2.1 The strong-electrolyte model |
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203 | (3) |
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2.2 The weak-electrolyte model |
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206 | (2) |
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208 | (2) |
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210 | (2) |
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3 Silver-ion-conducting glasses |
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212 | (7) |
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4 Sodium-ion-conducting glasses |
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219 | (8) |
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5 Lithium-ion-conducting glasses |
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227 | (14) |
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227 | (10) |
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5.2 Sulphide-based glasses |
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237 | (4) |
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6 Glasses with mobile anions |
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241 | (1) |
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7 Structure and optical properties of lithium-borate glasses |
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242 | (12) |
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7.1 Structure of the binary glasses B2O3-xLi2O |
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244 | (6) |
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7.2 Structure of the doped lithium-borate glasses |
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250 | (4) |
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8 Ac conductivity of lithium-borate glasses |
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254 | (31) |
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8.1 Basic considerations for ac conductivity |
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255 | (6) |
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8.2 Ionic conductivity of B2O3-Li2O-Li2SO4 glasses |
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261 | (4) |
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8.3 Annealing effect on conductivity |
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265 | (5) |
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8.4 Frequency dependence of conductivity |
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270 | (1) |
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8.5 Dielectric function of glasses |
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271 | (6) |
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277 | (8) |
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Chapter 4 Materials for electrolyte: Thin films |
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285 | (62) |
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1 Synthesis of thin-films of ionic conductors |
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289 | (26) |
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1.1 Evaporation techniques |
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289 | (9) |
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1.2 Anionic-conducting thin-films |
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298 | (3) |
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1.3 Cationic-conducting thin-films |
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301 | (14) |
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2 Growth and properties of lithium-borate thin-films |
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315 | (32) |
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2.1 Structural properties of borate glass films |
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315 | (7) |
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2.2 Electrical properties of borate glass thin-films |
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322 | (8) |
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2.3 Electric modulus analysis of thin-films |
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330 | (10) |
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340 | (7) |
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Chapter 5 Polymer electrolytes |
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347 | (22) |
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1 Structure and chemistry of polymers |
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347 | (9) |
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348 | (1) |
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1.2 Structural properties |
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349 | (7) |
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2 Electrochemistry of polymers |
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356 | (13) |
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356 | (4) |
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2.2 Redox stability domain |
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360 | (2) |
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2.3 Highly conductive polymers |
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362 | (1) |
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363 | (1) |
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364 | (5) |
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Chapter 6 Materials for electrodes: Crystalline compounds |
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369 | (144) |
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370 | (8) |
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370 | (5) |
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1.2 Intercalation compounds |
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375 | (2) |
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1.3 Classification of 2D-compounds |
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377 | (1) |
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2 Carbon-based electrodes |
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378 | (20) |
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2.1 Structural and elecronic properties of graphite |
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379 | (2) |
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2.2 Transport properties of graphite |
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381 | (1) |
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2.3 Properties of graphite intercalation compounds |
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382 | (6) |
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2.4 Electrodes based on carbon materials |
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388 | (10) |
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3 Inorganic chalcogenides |
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398 | (75) |
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3.1 Transition-metal dichalcogenides |
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398 | (37) |
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3.2 Transition-metal phosphorus trichalcogenides |
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435 | (12) |
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3.3 Non-transition-metal chalcogenides |
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447 | (18) |
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3.4 Fiber-like chalcogenides |
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465 | (4) |
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3.5 Chevrel-phase compounds |
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469 | (4) |
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473 | (18) |
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4.1 Oxides with layered structure |
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474 | (9) |
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4.2 Oxides with framework structure |
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483 | (8) |
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491 | (22) |
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491 | (1) |
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5.2 Performance of composite electrodes |
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492 | (8) |
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500 | (13) |
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Chapter 7 Materials for electrodes: Amorphous and thin-films |
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513 | (66) |
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1 Amorphous cathodic materials |
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514 | (19) |
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1.1 Amorphous chalcogenides |
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515 | (6) |
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521 | (3) |
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1.3 Semiconducting glasses |
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524 | (9) |
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533 | (46) |
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2.1 Titanium dichalcogenide films |
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533 | (5) |
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2.2 Molybdenum dichalcogenide films |
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538 | (6) |
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2.3 Indium selenide films |
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544 | (19) |
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2.4 Transition-metal oxide films |
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563 | (8) |
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2.5 Titanium oxysulphide films |
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571 | (2) |
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573 | (6) |
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Chapter 8 Applications of solid-state ionic materials |
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579 | (44) |
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1 Applications of solid-state ionics to batteries |
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579 | (29) |
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1.1 Advantages of solid-state battery technology |
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580 | (3) |
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1.2 Potential effects on energy conservation |
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583 | (1) |
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1.3 Requirements of solid-state battery technology |
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583 | (1) |
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1.4 High-temperature cells |
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584 | (5) |
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1.5 Polymeric and glass batteries |
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589 | (5) |
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1.6 Solid-state primary lithium batteries |
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594 | (2) |
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1.7 Solid-state secondary lithium batteries |
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596 | (1) |
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1.8 Secondary insertion cathode lithium batteries |
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596 | (6) |
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1.9 Liquid electrolyte primary lithium batteries |
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602 | (2) |
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1.10 Silver and copper batteries |
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604 | (4) |
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2 Lithium metal-free rechargeable batteries |
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608 | (4) |
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612 | (11) |
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3.1 Silver and copper microbatteries |
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612 | (1) |
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3.2 Lithium microbatteries |
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613 | (5) |
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618 | (5) |
Subject index |
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623 | |