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Solid State Batteries: Materials Design and Optimization Softcover reprint of the original 1st ed. 1994 [Pehme köide]

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The field of solid state ionics is multidisciplinary in nature. Chemists, physicists, electrochimists, and engineers all are involved in the research and development of materials, techniques, and theoretical approaches. This science is one of the great triumphs of the second part of the 20th century. For nearly a century, development of materials for solid-state ionic technology has been restricted. During the last two decades there have been remarkable advances: more materials were discovered, modem technologies were used for characterization and optimization of ionic conduction in solids, trial and error approaches were deserted for defined predictions. During the same period fundamental theories for ion conduction in solids appeared. The large explosion of solid-state ionic material science may be considered to be due to two other influences. The first aspect is related to economy and connected with energy production, storage, and utilization. There are basic problems in industrialized countries from the economical, environmental, political, and technological points of view. The possibility of storing a large amount of utilizable energy in a comparatively small volume would make a number of non-conventional intermittent energy sources of practical convenience and cost. The second aspect is related to huge increase in international relationships between researchers and exchanges of results make considerable progress between scientists; one find many institutes joined in common search programs such as the material science networks organized by EEC in the European countries.

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Springer Book Archives
Preface ix
Chapter 1 Design and optimization of solid-state batteries
1(96)
1 Description of relations in battery operation
3(46)
1.1 Basic concepts
3(6)
1.2 Classification of cells and batteries
9(3)
1.3 Electrochemical insertion process
12(14)
1.4 Transport properties of intercalated compounds
26(5)
1.5 Electrochemical intercalation techniques
31(18)
2 Quality criteria for thin-film materials
49(48)
2.1 Performance of thin-film cells
49(3)
2.2 Relevance of thin-film characteristics to batteries
52(4)
2.3 Limiting parameters
56(18)
2.4 Thin-fim deposition technology
74(5)
2.5 Influence of the deposition parameters
79(11)
References for chapter 1
90(7)
Chapter 2 Materials for electrolyte: Crystalline compounds
97(86)
1 Mechanisms of transport in solid electrolytes
98(26)
1.1 Phenomenological approach of ionic conduction
99(3)
1.2 Theoretical models for ionic conduction
102(21)
1.3 Classification of superionic materials
123(1)
2 Anionic conductors
124(12)
2.1 Fluorine ion conductors
124(10)
2.2 Oxygen ion conductors
134(2)
3 Cationic conductors
136(34)
3.1 Three-dimensional compounds
136(24)
3.2 Low-dimensional compounds
160(10)
4 Composite electrolytes
170(13)
References for chapter 2
175(8)
Chapter 3 Materials for electrolyte: Fast-ion-conducting glasses
183(102)
1 Fast-ion-conducting glasses
186(17)
1.1 Structural description of glasses
187(6)
1.2 Ionic conductivity in glasses
193(10)
2 Conduction mechanisms in glasses
203(9)
2.1 The strong-electrolyte model
203(3)
2.2 The weak-electrolyte model
206(2)
2.3 Defect-based theory
208(2)
2.4 The coupling model
210(2)
3 Silver-ion-conducting glasses
212(7)
4 Sodium-ion-conducting glasses
219(8)
5 Lithium-ion-conducting glasses
227(14)
5.1 Oxide-based glasses
227(10)
5.2 Sulphide-based glasses
237(4)
6 Glasses with mobile anions
241(1)
7 Structure and optical properties of lithium-borate glasses
242(12)
7.1 Structure of the binary glasses B2O3-xLi2O
244(6)
7.2 Structure of the doped lithium-borate glasses
250(4)
8 Ac conductivity of lithium-borate glasses
254(31)
8.1 Basic considerations for ac conductivity
255(6)
8.2 Ionic conductivity of B2O3-Li2O-Li2SO4 glasses
261(4)
8.3 Annealing effect on conductivity
265(5)
8.4 Frequency dependence of conductivity
270(1)
8.5 Dielectric function of glasses
271(6)
References for chapter 3
277(8)
Chapter 4 Materials for electrolyte: Thin films
285(62)
1 Synthesis of thin-films of ionic conductors
289(26)
1.1 Evaporation techniques
289(9)
1.2 Anionic-conducting thin-films
298(3)
1.3 Cationic-conducting thin-films
301(14)
2 Growth and properties of lithium-borate thin-films
315(32)
2.1 Structural properties of borate glass films
315(7)
2.2 Electrical properties of borate glass thin-films
322(8)
2.3 Electric modulus analysis of thin-films
330(10)
References for chapter 4
340(7)
Chapter 5 Polymer electrolytes
347(22)
1 Structure and chemistry of polymers
347(9)
1.1 Synthesis
348(1)
1.2 Structural properties
349(7)
2 Electrochemistry of polymers
356(13)
2.1 Ionic conductivity
356(4)
2.2 Redox stability domain
360(2)
2.3 Highly conductive polymers
362(1)
2.4 Applications
363(1)
References for chapter 5
364(5)
Chapter 6 Materials for electrodes: Crystalline compounds
369(144)
1 Introduction
370(8)
1.1 Electrode process
370(5)
1.2 Intercalation compounds
375(2)
1.3 Classification of 2D-compounds
377(1)
2 Carbon-based electrodes
378(20)
2.1 Structural and elecronic properties of graphite
379(2)
2.2 Transport properties of graphite
381(1)
2.3 Properties of graphite intercalation compounds
382(6)
2.4 Electrodes based on carbon materials
388(10)
3 Inorganic chalcogenides
398(75)
3.1 Transition-metal dichalcogenides
398(37)
3.2 Transition-metal phosphorus trichalcogenides
435(12)
3.3 Non-transition-metal chalcogenides
447(18)
3.4 Fiber-like chalcogenides
465(4)
3.5 Chevrel-phase compounds
469(4)
4 Inorganic oxides
473(18)
4.1 Oxides with layered structure
474(9)
4.2 Oxides with framework structure
483(8)
5 Composite electrodes
491(22)
5.1 Introduction
491(1)
5.2 Performance of composite electrodes
492(8)
References for chapter 6
500(13)
Chapter 7 Materials for electrodes: Amorphous and thin-films
513(66)
1 Amorphous cathodic materials
514(19)
1.1 Amorphous chalcogenides
515(6)
1.2 Amorphous oxides
521(3)
1.3 Semiconducting glasses
524(9)
2 Thin-film cathodes
533(46)
2.1 Titanium dichalcogenide films
533(5)
2.2 Molybdenum dichalcogenide films
538(6)
2.3 Indium selenide films
544(19)
2.4 Transition-metal oxide films
563(8)
2.5 Titanium oxysulphide films
571(2)
References for chapter 7
573(6)
Chapter 8 Applications of solid-state ionic materials
579(44)
1 Applications of solid-state ionics to batteries
579(29)
1.1 Advantages of solid-state battery technology
580(3)
1.2 Potential effects on energy conservation
583(1)
1.3 Requirements of solid-state battery technology
583(1)
1.4 High-temperature cells
584(5)
1.5 Polymeric and glass batteries
589(5)
1.6 Solid-state primary lithium batteries
594(2)
1.7 Solid-state secondary lithium batteries
596(1)
1.8 Secondary insertion cathode lithium batteries
596(6)
1.9 Liquid electrolyte primary lithium batteries
602(2)
1.10 Silver and copper batteries
604(4)
2 Lithium metal-free rechargeable batteries
608(4)
3 Microbatteries
612(11)
3.1 Silver and copper microbatteries
612(1)
3.2 Lithium microbatteries
613(5)
References for chapter 8
618(5)
Subject index 623